CN106009928A - Antistatic antibacterial water-based ceramic three-dimensional printing ink and preparation method thereof - Google Patents

Antistatic antibacterial water-based ceramic three-dimensional printing ink and preparation method thereof Download PDF

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Publication number
CN106009928A
CN106009928A CN201610377224.3A CN201610377224A CN106009928A CN 106009928 A CN106009928 A CN 106009928A CN 201610377224 A CN201610377224 A CN 201610377224A CN 106009928 A CN106009928 A CN 106009928A
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preparation
mixed
antistatic
60min
ceramic
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邱杰华
江潺
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FOSHAN CITY GAOMING DISTRICT HAIDI CERAMIC MATERIALS Co Ltd
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FOSHAN CITY GAOMING DISTRICT HAIDI CERAMIC MATERIALS Co Ltd
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Priority to CN201610377224.3A priority Critical patent/CN106009928A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/30—Inkjet printing inks
    • C09D11/32—Inkjet printing inks characterised by colouring agents
    • C09D11/322—Pigment inks

Abstract

The invention discloses an antistatic antibacterial water-based ceramic three-dimensional printing ink and a preparation method thereof. The printing ink is composed of a color slurry A and a diluent B in a weight ratio of 1:1. The color slurry A comprises the following components by weight percentage: 40-45% of a ceramic pigment, 2-8% of resin, 10-18% of propylene glycol, 15-30% of water, 10-20% of a dispersant, 0.3-5% of a silane coupling agent, and 0.05-0.5% of a defoaming agent. The diluent B consists of the following components by weight percentage: 50-60% of ethylene glycol, 30-35% of water, 0.5-10% of sodium citrate, 0.5-5% of a pH regulator, 4-8% of a composite antistatic agent, and 1-2% of a composite antibacterial agent. The ceramic ink not only has antibacterial function but also has antistatic function.

Description

A kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink and preparation method thereof
Technical field
The present invention relates to technology of ceramic tile decoration field, anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink having particularly related to a kind of ceramic ink jet printing and preparation method thereof.
Background technology
In daily life, in the winter being especially dried in the north, indoor have " electric " everywhere, and touching door handle can be electrically shocked, and touching water pipe can be electrically shocked, and going home to hold a baby in one's arms also can be electrically shocked, and even unblanks to touch keyhole, also can be electrically shocked.Research finds, these shock phenomenon bring the biggest harm, the physiological equilibrium of impact person human body can to the body & mind of people, cause all illness subtlely, accelerate human senescence.
Antibacterial, mycete has the biggest harm as pathogen to the mankind and animals and plants, affects the health even threat to life of people, brings great economic loss.Therefore the research of anti-biotic material and goods thereof causes the concern of people day by day, and the demand of antibacterial product will constitute huge market.
Wall brick, no matter household interior decoration, or for commercial production or public place, after meeting outward appearance practicality, how to make it possess more function concerned in terms of health of people guarantee, be also that industry researcher is kept up with the trend of the times and life wind vane and the thinking made.Anti-static ceramic tile is extensively applied by every profession and trade at present, but according to using wire gauze or copper strips construction more complicated in the past, cost is high, and of long duration oxidizable, it is difficult to ensure that the stability of volume resistance；Also having and use anti-electrostatic antibiotic wall brick ceramic ink to obtain the wall brick with anti-static effect, but stability is more weak, abrasion resistance is inadequate, easily weares and teares and lose anti-static effect during use.At present, there is the ceramic ink of more anti-electrostatic antibiotic function, but in prior art, its antibacterial stability of wall brick being coated with antibacterial ink is more weak, and both effect is more difficult takes into account, and abrasion resistance is inadequate, is easy to abrasion and loses antibacterial and anti-static effect during use.
Summary of the invention
The technical problem to be solved there is provided a kind of had not only possessed antibacterial functions but also the aqueous ceramic three-dimensional printing ink of anti-electrostatic antibiotic possessing electrostatic-proof function and preparation method thereof.
The technical problem to be solved is achieved by the following technical programs:
A kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, is made up of by weight 1:1 mill base liquid A and diluent B；Described mill base liquid A component count by weight percentage: ceramic pigment 40 ~ 45%, resin 2 ~ 8%, propylene glycol 10 ~ 18%, water 15 ~ 30%, dispersant 10 ~ 20%, silane coupler 0.3 ~ 5%, defoamer 0.05 ~ 0.5%；
Diluent B component count by weight percentage: ethylene glycol 50 ~ 60%, water 30 ~ 35%, sodium citrate 0.5 ~ 10%, pH adjusting agent 0.5 ~ 5%, compounded antistatic agent 4 ~ 8% and complex antimicrobials 1 ~ 2%；Described compounded antistatic agent by the first antistatic composite powder and second antistatic part by weight (1 ~ 2): (1 ~ 2) mixing forms, wherein said first antistatic composite powder is mixed by weight 13:1 with Graphene by the first conductor oxidate, and described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 15 ~ 25%, tin ash 40 ~ 60% and copper oxide 25 ~ 40%；Described second antistatic composite powder is mixed by weight 8:1 by the second conductor oxidate and multi-walled carbon nano-tubes, and described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 15 ~ 30%, oxidation receive 60 ~ 80 and diboron trioxide 5 ~ 10%；Described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, and weight ratio is: inorganic-organic composite antibiotic agent: Graphene=(1 ~ 3): 1, described inorganic antiseptic: organic antibacterial agent=2:1.
In the present invention, described first oxide is made up of following raw material by weight percentage: zinc oxide 20%, tin ash 50% and copper oxide 30%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 20%, oxidation receive 70 and diboron trioxide 10%.Described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 40%, opal 34%, montmorillonite 8%, silica 1 5%, germanium oxide 1%, Thorium tetrachloride. 2%.
In the present invention, the soluble inorganic salt of one or more compositions during described inorganic antiseptic is silver, zinc, copper ion.Described organic antibacterial agent is parabens.
In the present invention, described ceramic pigment be praseodymium yellow, cobalt blue, reddish brown, orange, chrome tin pink, cobalt black at least one.
In the present invention, described resin is polyacrylate resin；Described dispersant is one or more mixing in polyacrylate dispersant, urethane acrylate class dispersant, and adducible trade name includes but not limited to: the Dispers-715w of BYK-180, BYK-183, BYK-191, Tego company of Bi Ke company, Dispers-755w, the HLD-5/HLD-6/HLD-18AJ etc. of permanent HX-40Y, Silcona company joining chemical industry.
In the present invention, the one or more kinds of mixture during described pH adjusting agent is triethanolamine, diethanolamine, monoethanolamine.Described defoamer is defoamer commonly used in the art, as a kind of preferred version, this defoamer preferred water-soluble organic silicon class defoamer, mineral oil defoaming agent or its mixture.Described silane coupler is the KH-550(γ-aminopropyl triethoxysilane of product Ninghua, Nanjing work) or KH-560(γ-(2,3-epoxy the third oxygen) propyl trimethoxy silicane), this silane coupler can improve ceramic pigment wettability in fluoropolymer resin, improves its dispersibility.
The preparation method of a kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of complex antimicrobials: inorganic-organic composite antibiotic agent, Graphene are mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) being placed in UV light region by colorant, ultraviolet source irradiance controls at 200 ~ 300W/m2Scope, irradiation 30 ~ 60min；First powder for antistatic, the second powder for antistatic and complex antimicrobials are respectively put in microwave oven, under 700 ~ 1000W microwave power, microwave treatment 1 ~ 10min；
(5) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 30 ~ 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 8 ~ 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(6) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(mill base liquid A and diluent B is mixed by 7 by weight 1:1, is sufficiently mixed uniformly in homogenizer, and ultrasonic disperse 2h obtains anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink after filtration.
The aqueous ceramic ink that the present invention is prepared substantially meets following requirement: viscosity is 10 ~ 15cP/25 DEG C；Surface tension is 25 ~ 40mN/m；Mean diameter D50 is 200 ~ 350nm；Maximum particle diameter is≤800nm；Zeta potential is-35 ~-45mv, can print 10000m on the printer of Xaar shower nozzle continuously2；Can stablize color development when 1200 DEG C, suspension stability is more than 2 months.
There is advantages that
Ceramic ink surface obtained by the present invention does not has big corner angle, there is excellent stability and rheological characteristic, will not wear and tear, block and corrode shower nozzle, extend the service life of shower nozzle, cost-effective, owing to the solvent used is based on aqueous, clean environment firendly, environment will not be caused the biggest pollution, meet the theory of environmental protection；The product that the product that the present invention provides is antistatic, antibacterial two functions are compatible, after tested, product reaches country's anti-static ceramic tile standard GB26539-2011 requirement, the requirement of " antibacterial ceramic products anti-microbial property " JC/T897-2002.Achieve on identical product, have antistatic, antibacterial two performances concurrently, improve its stability simultaneously, extend anti-electrostatic antibiotic effect, both economized on resources, reduce product cost, expand again range of application, and construction and installation are convenient.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention, is not limitation of the invention.
Embodiment 1
A kind of antistatic aqueous ceramic three-dimensional printing ink, it is made up of by weight 1:1 mill base liquid A and diluent B；Described mill base liquid A component count by weight percentage: praseodymium yellow 42%, polyacrylate resin 6%, propylene glycol 15%, water 25%, Dispers-715w 10%, KH-550 1.5%, defoamer 0.5%；
Diluent B component count by weight percentage: ethylene glycol 52%, water 35%, sodium citrate 5%, triethanolamine 3%, compounded antistatic agent 5%.
Described compounded antistatic agent is made up of by weight 1:2 mixing the first antistatic composite powder and second antistatic part, wherein said first antistatic composite powder is mixed by weight 13:1 with Graphene by the first conductor oxidate, and described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 15%, tin ash 60% and copper oxide 25%；Described second antistatic composite powder is mixed by weight 8:1 by the second conductor oxidate and multi-walled carbon nano-tubes, and described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 30%, oxidation receive 65% and diboron trioxide 5%.
The preparation method of a kind of antistatic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) being placed in UV light region by colorant, ultraviolet source irradiance controls at 300W/m2Scope, irradiation 40min；First powder for antistatic and the second powder for antistatic are respectively put in microwave oven, under 700W microwave power, microwave treatment 5min；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
Obtained ceramic ink surface does not has big corner angle, has excellent stability and rheological characteristic, will not wear and tear, blocks and corrode shower nozzle, extends the service life of shower nozzle, cost-effective.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance level Four, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.6 × 107Ω；Surface gloss is higher, decorative effect is preferable, meets GB/T4100-2006 national standard, is a kind of excellent static-electricity proof tile.
Embodiment 2
Based on embodiment 1, difference is: described colorant is reddish brown；Described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 20%, tin ash 50% and copper oxide 30%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 20%, oxidation receive 70% and diboron trioxide 10%.
Obtained ceramic ink surface does not has big corner angle, has excellent stability and rheological characteristic, will not wear and tear, blocks and corrode shower nozzle, extends the service life of shower nozzle, cost-effective.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance level Four, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 3.1 × 106Ω；Surface gloss is higher, decorative effect is preferable, meets GB/T4100-2006 national standard, is a kind of excellent static-electricity proof tile.
Embodiment 3
Based on embodiment 1, difference is: described colorant is cobalt blue and reddish brown mixture；Described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 25%, tin ash 40% and copper oxide 35%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 15%, oxidation receive 80% and diboron trioxide 5%.
Obtained ceramic ink surface does not has big corner angle, has excellent stability and rheological characteristic, will not wear and tear, blocks and corrode shower nozzle, extends the service life of shower nozzle, cost-effective.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance level Four, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 4.3 × 107Ω；Surface gloss is higher, decorative effect is preferable, meets GB/T4100-2006 national standard, is a kind of excellent static-electricity proof tile.
Comparative example 1
Based on embodiment 1, difference is: described first antistatic composite powder and the second antistatic composite powder are not added with Graphene and multi-walled carbon nano-tubes respectively.
The preparation method of a kind of antistatic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
Obtained ceramic ink surface does not has big corner angle, has good stability and rheological characteristic, will not wear and tear, blocks and corrode shower nozzle, extends the service life of shower nozzle, cost-effective.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance three grades, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 6.8 × 108Ω。
Comparative example 2
Based on embodiment 1, difference is: described first antistatic composite powder adds Graphene.
The preparation method of a kind of antistatic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
Obtained ceramic ink surface does not has big corner angle, has stability and rheological characteristic, will not wear and tear, blocks and corrode shower nozzle, extends the service life of shower nozzle, cost-effective.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance three grades, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 7.8 × 109Ω。
Comparative example 3
Based on embodiment 1, difference is: described second antistatic composite powder adds multi-walled carbon nano-tubes.
The preparation method of a kind of antistatic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
Obtained ceramic ink surface does not has big corner angle, has stability and rheological characteristic, will not wear and tear, blocks and corrode shower nozzle, extends the service life of shower nozzle, cost-effective.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance three grades, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 2.6 × 109Ω。
Comparative example 4
Based on embodiment 1, difference is: do not dose described compounded antistatic agent, i.e. diluent B component count by weight percentage: ethylene glycol 55%, water 37%, sodium citrate 5%, triethanolamine 3%.
The preparation method of a kind of antistatic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
Obtained ceramic ink surface does not has big corner angle, has stability and rheological characteristic, weares and teares, blocks and corrode shower nozzle sometimes, limits the service life of shower nozzle.In the present embodiment, select the technique disclosed in application publication number CN103113133A, preparation adobe, the ceramic ink then selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then klining is entered, preparation Ceramic Tiles, test shows, abrasion resistance two grades, product after sintering according to GB26539 2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 8.2 × 1014Ω；Surface gloss is general, decorative effect is general.
Embodiment 4
A kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, it is made up of by weight 1:1 mill base liquid A and diluent B；Described mill base liquid A component count by weight percentage: praseodymium yellow 42%, polyacrylate resin 6%, propylene glycol 15%, water 25%, Dispers-715w 10%, KH-550 1.5%, defoamer 0.5%；
Diluent B component count by weight percentage: ethylene glycol 50%, water 35%, sodium citrate 5%, triethanolamine 3%, compounded antistatic agent 5% and complex antimicrobials 2%.
Described compounded antistatic agent is made up of by weight 1:2 mixing the first antistatic composite powder and second antistatic part, wherein said first antistatic composite powder is mixed by weight 13:1 with Graphene by the first conductor oxidate, and described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 15%, tin ash 60% and copper oxide 25%；Described second antistatic composite powder is mixed by weight 8:1 by the second conductor oxidate and multi-walled carbon nano-tubes, and described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 30%, oxidation receive 65% and diboron trioxide 5%；Described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, and weight ratio is: inorganic-organic composite antibiotic agent: Graphene=1:1, described inorganic antiseptic: organic antibacterial agent=2:1；Described inorganic antiseptic is the soluble inorganic salt of silver ion, based on inorganic antiseptic gross weight, is added with the calcium phosphate of 5%；Described organic antibacterial agent is parabens.
The preparation method of a kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of complex antimicrobials: inorganic-organic composite antibiotic agent, Graphene are mixed in proportion stirring 50min, use grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) being placed in UV light region by colorant, ultraviolet source irradiance controls at 300W/m2Scope, irradiation 40min；First powder for antistatic, the second powder for antistatic and complex antimicrobials are respectively put in microwave oven, under 700W microwave power, microwave treatment 5min；
(5) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(6) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(7) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, abrasion resistance level Four, and the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 6.5 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 98.6% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 98.3%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect, sheet resistance 8.2 × 10 according to the method described above7Ω, colibacillary bacteriostasis rate is 98.2%, and the bacteriostasis rate to staphylococcus aureus is 97.9%.
Embodiment 5
Based on embodiment 4, difference is: described colorant is reddish brown；Described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, and weight ratio is: inorganic-organic composite antibiotic agent: Graphene=2:1, described inorganic antiseptic: organic antibacterial agent=2:1；Described inorganic antiseptic is silver ion and the soluble inorganic salt of copper ion combination, based on inorganic antiseptic gross weight, is added with the calcium phosphate of 5%；Described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 20%, tin ash 50% and copper oxide 30%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 20%, oxidation receive 70% and diboron trioxide 10%.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, abrasion resistance level Four, and the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 106Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 99.5% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 99.6%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect according to the method described above, sheet resistance is 8.8 × 106Ω, colibacillary bacteriostasis rate is 99.1%, and the bacteriostasis rate to staphylococcus aureus is 99.2%.
Embodiment 6
Based on embodiment 4, difference is: described colorant is cobalt blue and reddish brown mixture；Described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, and weight ratio is: inorganic-organic composite antibiotic agent: Graphene=3:1, described inorganic antiseptic: organic antibacterial agent=2:1；Described inorganic antiseptic is the soluble inorganic salt of silver ion, based on inorganic antiseptic gross weight, is added with the calcium phosphate of 5%；Described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 25%, tin ash 40% and copper oxide 35%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 15%, oxidation receive 80% and diboron trioxide 5%.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, abrasion resistance level Four, and the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.4 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 97.7% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 98.5%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect according to the method described above, sheet resistance is 8.4 × 107Ω, colibacillary bacteriostasis rate is 96.5%, and the bacteriostasis rate to staphylococcus aureus is 97.8%.
Comparative example 5
Based on embodiment 4, difference is: described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, and weight ratio is: inorganic-organic composite antibiotic agent: Graphene=1:3.
The preparation method of a kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of complex antimicrobials: inorganic-organic composite antibiotic agent, Graphene are mixed in proportion stirring 50min, use grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.7 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 92.6% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 93.5%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect according to the method described above, sheet resistance is 9.5 × 107Ω, colibacillary bacteriostasis rate is 91.1%, and the bacteriostasis rate to staphylococcus aureus is 92.3%.
Comparative example 6
Based on embodiment 4, difference is: described complex antimicrobials is inorganic antiseptic, and described inorganic antiseptic is the soluble inorganic salt of silver ion, based on inorganic antiseptic gross weight, is added with the calcium phosphate of 5%.
The preparation method of a kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 85.3% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 86.8%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect according to the method described above, sheet resistance is 9.2 × 107Ω, colibacillary bacteriostasis rate is 84.0%, and the bacteriostasis rate to staphylococcus aureus is 85.5%.
Comparative example 7
Based on embodiment 4, difference is: described complex antimicrobials is organic antibacterial agent.
The preparation method of a kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 86.5% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 87.6%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect according to the method described above, sheet resistance is 9.1 × 107Ω, colibacillary bacteriostasis rate is 84.6%, and the bacteriostasis rate to staphylococcus aureus is 85.5%.
Comparative example 8
Based on embodiment 4, difference is: described complex antimicrobials is inorganic-organic composite antibiotic agent, described inorganic antiseptic: organic antibacterial agent=2:1；Described inorganic antiseptic is the soluble inorganic salt of silver ion, based on inorganic antiseptic gross weight, is added with the calcium phosphate of 5%.
The preparation method of a kind of anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 60min, then add Graphene mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(4) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(5) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 88.5% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 89.6%.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction, sample clean is dried, and test anti-electrostatic antibiotic effect according to the method described above, sheet resistance is 9.3 × 107Ω, colibacillary bacteriostasis rate is 86.0%, and the bacteriostasis rate to staphylococcus aureus is 87.1%.
Embodiment 7
A kind of purification air aqueous ceramic three-dimensional printing ink, it is made up of by weight 1:1 mill base liquid A and diluent B；Described mill base liquid A component count by weight percentage: praseodymium yellow 42%, polyacrylate resin 6%, propylene glycol 15%, water 25%, Dispers-715w 10%, KH-550 1.5%, defoamer 0.5%；
Diluent B component count by weight percentage: ethylene glycol 52%, water 35%, sodium citrate 4%, triethanolamine 3%, compounded antistatic agent 5% and and composite negative ion powder 1%.
Described compounded antistatic agent is made up of by weight 2:1 mixing the first antistatic composite powder and second antistatic part, wherein said first antistatic composite powder is mixed by weight 13:1 with Graphene by the first conductor oxidate, and described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 15%, tin ash 60% and copper oxide 25%；Described second antistatic composite powder is mixed by weight 8:1 by the second conductor oxidate and multi-walled carbon nano-tubes, and described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 30%, oxidation receive 65% and diboron trioxide 5%；Described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 40%, opal 34%, montmorillonite 8%, silica 1 5%, germanium oxide 1%, Thorium tetrachloride. 2%.
A kind of preparation method purifying air aqueous ceramic three-dimensional printing ink, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of composite negative ion powder: component each in formula is mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) being placed in UV light region by colorant, ultraviolet source irradiance controls at 300W/m2Scope, irradiation 40min；First powder for antistatic, the second powder for antistatic and composite negative ion powder are respectively put in microwave oven, under 700W microwave power, microwave treatment 5min；
(5) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(6) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(7) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 1500～2000/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.3 × 106Ω, its anion burst size can reach 1300～1700/cm3。
Embodiment 8
Based on embodiment 7, difference is: the adding proportion of described composite negative ion powder is 4%, and described praseodymium yellow changes to 27% praseodymium yellow and 10% cobalt blue.Described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 20%, tin ash 50% and copper oxide 30%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 20%, oxidation receive 70% and diboron trioxide 10%.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 3.5 × 106Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 2400～3000/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 8.8 × 106Ω, its anion burst size can reach 1900～2700/cm3。
Embodiment 9
Based on embodiment 7, difference is: the adding proportion of described composite negative ion powder is 6%, and described praseodymium yellow changes to 25% praseodymium yellow and 10% cobalt blue.Described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 25%, tin ash 40% and copper oxide 35%；Described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 15%, oxidation receive 80% and diboron trioxide 5%.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.6 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 1900～2600/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 8.2 × 107Ω, its anion burst size can reach 1600～2300/cm3。
Embodiment 10
Based on embodiment 7, difference is: described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 40%, opal 34%, montmorillonite 8%, silica 1 5%, germanium oxide 1%, Thorium tetrachloride. 1%, Graphene 1%.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.4 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 1500～2000/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 8.6 × 107Ω, its anion burst size can reach 1400～1800/cm3。
Embodiment 11
Based on embodiment 7, difference is: a kind of purification air aqueous ceramic three-dimensional printing ink, it is made up of by weight 1:1 mill base liquid A and diluent B；Described mill base liquid A component count by weight percentage: praseodymium yellow 42%, polyacrylate resin 6%, propylene glycol 15%, water 25%, Dispers-715w 10%, KH-550 1.5%, defoamer 0.5%；Diluent B component count by weight percentage: ethylene glycol 50%, water 35%, sodium citrate 4%, triethanolamine 3%, compounded antistatic agent 5%, composite negative ion powder 1% and complex antimicrobials 2%, wherein, described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, weight ratio is: inorganic-organic composite antibiotic agent: Graphene=2:1, described inorganic antiseptic: organic antibacterial agent=2:1；Described inorganic antiseptic is silver ion and the soluble inorganic salt of copper ion combination, based on inorganic antiseptic gross weight, is added with the calcium phosphate of 5%.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；According to JC/T897-2002 " antibacterial ceramic products anti-microbial property " standard detection, being 98.6% to colibacillary bacteriostasis rate, the bacteriostasis rate to staphylococcus aureus is 98.9%；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 1500～2000/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.2 × 107Ω, its anion burst size can reach 1300～1800/cm3, colibacillary bacteriostasis rate is 96.7%, and the bacteriostasis rate to staphylococcus aureus is 96.5%.
Comparative example 9
Based on embodiment 7, difference is: described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 25%, opal 35%, montmorillonite 20%, silicon dioxide 5%, nano titanium oxide 5%, nano zine oxide 8%, germanium oxide 1%, Thorium tetrachloride. 1%.
A kind of preparation method purifying air aqueous ceramic three-dimensional printing ink, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of composite negative ion powder: component each in formula is mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 900～1500/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.2 × 106Ω, its anion burst size can reach 400～900/cm3。
Comparative example 10
Based on embodiment 7, difference is: described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 20%, opal 40%, montmorillonite 15%, silica 1 0%, nano titanium oxide 7.5%, nano zine oxide 5%, germanium oxide 1%, Thorium tetrachloride. 1.5%.
A kind of preparation method purifying air aqueous ceramic three-dimensional printing ink, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of composite negative ion powder: component each in formula is mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 900～1600/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.2 × 106Ω, its anion burst size can reach 400～1000/cm3。
Comparative example 11
Based on embodiment 7, difference is: described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 35%, opal 30%, montmorillonite 10%, silicon dioxide 7%, nano titanium oxide 10%, nano zine oxide 5%, germanium oxide 1.5%, Thorium tetrachloride. 1.5%.
A kind of preparation method purifying air aqueous ceramic three-dimensional printing ink, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of composite negative ion powder: component each in formula is mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 900～1500/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.2 × 106Ω, its anion burst size can reach 500～900/cm3。
Comparative example 12
Based on embodiment 7, difference is: described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 25%, opal 30%, montmorillonite 11%, silica 1 0%, nano titanium oxide 10%, nano zine oxide 10%, germanium oxide 2%, Thorium tetrachloride. 2%.
A kind of preparation method purifying air aqueous ceramic three-dimensional printing ink, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of composite negative ion powder: component each in formula is mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 1000～1500/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.2 × 106Ω, its anion burst size can reach 600～1000/cm3。
Comparative example 13
Based on embodiment 7, difference is: described composite negative ion powder is made up of following raw material by weight percentage: lithium Anhydrite 30%, opal 30%, montmorillonite 10%, silica 1 0%, nano titanium oxide 8%, nano zine oxide 10%, germanium oxide 1%, Thorium tetrachloride. 1%.
A kind of preparation method purifying air aqueous ceramic three-dimensional printing ink, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of composite negative ion powder: component each in formula is mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(5) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(6) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, it is purified air aqueous ceramic three-dimensional printing ink after filtration.
In the present embodiment, select the technique disclosed in application publication number CN103113133A, prepare adobe, then the ceramic ink selecting the present embodiment to be provided in adobe carries out ink-jet printed, forms printed layer, then enters klining, preparation Ceramic Tiles, surface gloss is high, good decorating effect.Test shows, the product after sintering according to GB26539-2011 " anti-static ceramic tile " standard detection the present embodiment, sheet resistance is 5.5 × 107Ω；Using Japan to produce the test of COM-3010PRO type ion detector, its anion burst size can reach 1000～1500/cm3.Being simulated using wear testing by above product, the abrasive material that wear testing selects Mohs' hardness to be 3～4, in printed layer, the effect after paving uses 2 years is imitated in friction for 1000 times.After friction drying sample clean, and test effect according to the method described above, sheet resistance is 9.2 × 106Ω, its anion burst size can reach 500～1200/cm3。
Embodiment described above only have expressed embodiments of the present invention; it describes more concrete and detailed; but therefore can not be interpreted as the restriction to the scope of the claims of the present invention; in every case the technical scheme using the form of equivalent or equivalent transformation to be obtained, all should fall within the scope and spirit of the invention.

Claims (7)

1. an anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink, is made up of by weight 1:1 mill base liquid A and diluent B；Described mill base liquid A component count by weight percentage: ceramic pigment 40 ~ 45%, resin 2 ~ 8%, propylene glycol 10 ~ 18%, water 15 ~ 30%, dispersant 10 ~ 20%, silane coupler 0.3 ~ 5%, defoamer 0.05 ~ 0.5%；
Diluent B component count by weight percentage: ethylene glycol 50 ~ 60%, water 30 ~ 35%, sodium citrate 0.5 ~ 10%, pH adjusting agent 0.5 ~ 5%, compounded antistatic agent 4 ~ 8% and complex antimicrobials 1 ~ 2%；Described compounded antistatic agent by the first antistatic composite powder and second antistatic part by weight (1 ~ 2): (1 ~ 2) mixing forms, wherein said first antistatic composite powder is mixed by weight 13:1 with Graphene by the first conductor oxidate, and described first conductor oxidate is made up of following raw material by weight percentage: zinc oxide 15 ~ 25%, tin ash 40 ~ 60% and copper oxide 25 ~ 40%；Described second antistatic composite powder is mixed by weight 8:1 by the second conductor oxidate and multi-walled carbon nano-tubes, and described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 15 ~ 30%, oxidation receive 60 ~ 80 and diboron trioxide 5 ~ 10%；Described complex antimicrobials is the mixture of inorganic-organic composite antibiotic agent and Graphene, and weight ratio is: inorganic-organic composite antibiotic agent: Graphene=(1 ~ 3): 1, described inorganic antiseptic: organic antibacterial agent=2:1.
Anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink the most according to claim 1, it is characterised in that described first oxide is made up of following raw material by weight percentage: zinc oxide 20%, tin ash 50% and copper oxide 30%.
Anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink the most according to claim 1, it is characterised in that described second conductor oxidate is made up of following raw material by weight percentage: calcium oxide 20%, oxidation receive 70 and diboron trioxide 10%.
Anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink the most according to claim 1, it is characterised in that described inorganic antiseptic is the soluble inorganic salt of one or more compositions in silver, zinc, copper ion.
Anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink the most according to claim 1, it is characterised in that described organic antibacterial agent is parabens.
Anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink the most according to claim 1, it is characterised in that described colorant be praseodymium yellow, cobalt blue, reddish brown, orange, chrome tin pink, cobalt black at least one.
7. a preparation method for anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink as claimed in claim 1, it comprises the following steps:
The preparation of (1) first antistatic composite powder: zinc oxide, tin ash, copper oxide are mixed in proportion dispersed with stirring 30 ~ 60min, then add Graphene mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
The preparation of (2) second antistatic composite powders: by calcium oxide, oxidation receives and diboron trioxide is mixed in proportion dispersed with stirring 30 ~ 60min, then adds multi-walled carbon nano-tubes mix and blend dispersion 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(3) preparation of complex antimicrobials: inorganic-organic composite antibiotic agent, Graphene are mixed in proportion stirring 40 ~ 60min, uses grinder to grind 10h so that it is particle diameter distribution≤3 μm；
(4) being placed in UV light region by colorant, ultraviolet source irradiance controls at 200 ~ 300W/m2Scope, irradiation 30 ~ 60min；First powder for antistatic, the second powder for antistatic and complex antimicrobials are respectively put in microwave oven, under 700 ~ 1000W microwave power, microwave treatment 1 ~ 10min；
(5) preparation of mill base liquid A: proportionally weighed by each component in formula, then carries out disperseing 30 ~ 60min with homogenizer；Scattered mixed liquor is loaded in grinder, grind 8 ~ 12h, obtain the mill base liquid A of particle diameter distribution≤1 μm；
(6) preparation of diluent B: each component mixed, stirs with homogenizer, obtains diluent B；
(7) mill base liquid A and diluent B is mixed by weight 1:1, be sufficiently mixed uniformly in homogenizer, ultrasonic disperse 2h, obtain anti-electrostatic antibiotic aqueous ceramic three-dimensional printing ink after filtration.
CN201610377224.3A 2016-06-01 2016-06-01 Antistatic antibacterial water-based ceramic three-dimensional printing ink and preparation method thereof Pending CN106009928A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101084756A (en) * 2007-07-09 2007-12-12 中钞油墨有限公司 Antibiotic printing ink and making method thereof
CN102675967A (en) * 2012-05-08 2012-09-19 中山大学 Water-based ceramic three-dimensional pattern printing ink and preparation method thereof
CN102795893A (en) * 2012-09-10 2012-11-28 山东电盾科技有限公司 Antistatic antimicrobial ceramic glaze
CN103073953A (en) * 2013-02-07 2013-05-01 苏州牛剑新材料有限公司 Waterborne conductive ink and preparation method thereof
CN103382328A (en) * 2013-07-19 2013-11-06 广东东鹏陶瓷股份有限公司 Antibacterial ink for ceramic ink-jet printing and ceramic tile with antibacterial function
CN103975951A (en) * 2014-04-25 2014-08-13 常州月夜灯芯绒有限公司 Graphene oxide / silver complex antibacterial material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101084756A (en) * 2007-07-09 2007-12-12 中钞油墨有限公司 Antibiotic printing ink and making method thereof
CN102675967A (en) * 2012-05-08 2012-09-19 中山大学 Water-based ceramic three-dimensional pattern printing ink and preparation method thereof
CN102795893A (en) * 2012-09-10 2012-11-28 山东电盾科技有限公司 Antistatic antimicrobial ceramic glaze
CN103073953A (en) * 2013-02-07 2013-05-01 苏州牛剑新材料有限公司 Waterborne conductive ink and preparation method thereof
CN103382328A (en) * 2013-07-19 2013-11-06 广东东鹏陶瓷股份有限公司 Antibacterial ink for ceramic ink-jet printing and ceramic tile with antibacterial function
CN103975951A (en) * 2014-04-25 2014-08-13 常州月夜灯芯绒有限公司 Graphene oxide / silver complex antibacterial material and preparation method thereof

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Application publication date: 20161012