CN105970721A - Papermaking additive composition and preparation method thereof - Google Patents
Papermaking additive composition and preparation method thereof Download PDFInfo
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- CN105970721A CN105970721A CN201610267740.0A CN201610267740A CN105970721A CN 105970721 A CN105970721 A CN 105970721A CN 201610267740 A CN201610267740 A CN 201610267740A CN 105970721 A CN105970721 A CN 105970721A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/09—Sulfur-containing compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/14—Carboxylic acids; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/53—Polyethers; Polyesters
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
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- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
Abstract
The invention discloses a papermaking additive composition mainly prepared from the following raw materials in parts by mass: 10-14 parts of carboxymethyl chitosan, 20-30 parts of dolomite, 10-18 parts of borax, 2-6 parts of polyethylene glycol, 1-5 parts of glycerin monostearate, 2-4 parts of hydroxypropyl starch, 1-3 parts of sodium dodecyl benzene sulfonate, 2-4 parts of a high alcohol fatty acid ester complex, 1-1.6 parts of hydroquinone, 2-4 parts of white wax, 1-1.8 parts of ammonium persulfate, 1-3 parts of sodium hexametaphosphate, and 3-6 parts of mannitol. The obtained product can improve a fiber structure of paper pulp, the use amount of paper pulp raw materials is reduced, the mechanical strength of paper is improved, and the cost of enterprises can be reduced.
Description
Technical field
The present invention relates to paper making additive field, particularly relate to paper making auxiliary agent composition and preparation method thereof.
Background technology
Along with the raising of people's living standard, the requirement to paper is more and more higher, paper be write, print, paint or
The sheet-like fiber goods of packaging etc., paper rapping off, transmission of culture, develop science and technology and in terms of production, be that one has by force
The instrument of power and material.But there is its deficiency in paper, such as intensity is less, the most mouldy, it is difficult to preserve for a long time.Existing
Although paper technology also relative maturity, but owing to preparation technology is more complicated, and plus the scarcity of needlebush resource and right
The requirement of environmental conservation, the factor that the above is complicated, new requirement is proposed for paper making additive.
Application publication number CN 104695258 A(application number 201310638918.4) Chinese patent literature disclose one
Plant paper making additive mixture, be made up of the composition of raw materials component of following mass percent: 100-200 part terphenyl quinone, 100-200
Part iso-amylene naphthoquinone, 100-200 part anthrol, 100-200 part anthracene nucleus ketone, 20-50 part OPEO, 20-50 part pair
Phenol a polyoxyethylene ether, 20-50 part polyoxyethylene lauryl ether, 20-50 part alkylphenol polyoxyethylene, 50-80 part dodecyl
Benzenesulfonic acid calcium, 50-80 part sodium tripolyphosphate, 50-80 part sodium laurate, 10-20 part waterproofing agent of organosilicon, 10-20 part stabilizer.
Publication No. CN 104343051 A(application number 201410511132.0) Chinese patent literature disclose a kind of attapulgite clay level papermaking
Auxiliary agent, it is made up of the raw material of following weight parts: attapulgite 60-70, aluminum trifluoride 2-3, sepiolite powder 10-20, swollen
Profit soil 20-30, polyoxyethylene glycerol ether 2-3, Flos Inulae soak oil 0.3-1, sodium borohydride 1-2,1-hydroxy ethylidene-1,1-diphosphonic acid 3-4,
Silver nitrate 0.3-0.5, DBDMH 0.5-2, hexadecyltrimethylammonium chloride 1-2, ammonium metavanadate 0.4-1, casein 1-2,
Calcium lignosulfonate 3-4, cetomacrogol 1000 2-3.Publication No. CN 103882771 A(application number 201410065585.5)
Chinese patent literature discloses a kind of paper making auxiliary agent composition and preparation method thereof, and this paper making auxiliary agent composition is following heavy by comprising
Amount part component make: polyoxyethyl propyl glycerin ether 30-35 part, tristerin 20-30 part, glass fibre 20-30 part,
Calcium carbonate crystal whisker 10-15 part, polyhexamethylene guanidine hydrochloride 10-15 part, 4,4 '-diphenyl methane-diisocyanate 3-5 part
With hydrogen sulfate disodium 2-5 part.
At present paper making additive the most on the market, its practical effect is poor, especially keeping effect, become paper at paper pulp
The aspects such as intensity, it is impossible to be effectively improved, therefore also need to strengthen research in this respect.
Summary of the invention
For problem of the prior art, it is an object of the invention to provide a kind of paper making auxiliary agent composition and preparation method thereof,
To improve paper pulp drainage effect and to reduce useless foam, and strengthen the mechanical strength of paper, improve quality.
The technical scheme is that
Paper making auxiliary agent composition, is mainly prepared from by following raw materials according, is mass parts: carboxymethyl chitosan 10-14, dolomite
20-30, Borax 10-18, Polyethylene Glycol 2-6, single hard fatty acids glyceride 1-5, hydroxypropyl starch 2-4, DBSA
Sodium 1-3, higher alcohols fatty acid ester compounded thing 2-4, hydroquinone 1-1.6, white beeswax 2-4, Ammonium persulfate. 1-1.8, sodium hexameta phosphate
1-3, mannitol 3-6.
Preferred version is, carboxymethyl chitosan 11-13, dolomite 23-27, Borax 12-16, Polyethylene Glycol 3-5, single stearic
Fatty acid glyceride 2-4, hydroxypropyl starch 2.5-3.5, dodecylbenzene sodium sulfonate 1.5-2.5, the fatty acid ester compounded thing of higher alcohols
2.5-3.5, hydroquinone 1.2-1.4, white beeswax 2.5-3.5, Ammonium persulfate. 12-1.6, sodium hexameta phosphate 1.5-2.5, mannitol
4-5。
It is more preferable that carboxymethyl chitosan 12, dolomite 25, Borax 14, Polyethylene Glycol 4, single hard fatty acids glycerol
Ester 3, hydroxypropyl starch 3, dodecylbenzene sodium sulfonate 2, the fatty acid ester compounded thing of higher alcohols 3, hydroquinone 1.3, white beeswax 3, mistake
Ammonium sulfate 1.4, sodium hexameta phosphate 2, mannitol 4.5.
The preparation method of described paper making auxiliary agent composition, step is as follows:
(1) taking dolomite and Borax grinds, add water stirring mixing, removes impurity, dries and pulverize；
(2) carboxymethyl chitosan, Polyethylene Glycol, dodecylbenzene sodium sulfonate, Ammonium persulfate. and sodium hexameta phosphate are mixed, be placed in
In stirring container, it is dissolved in water, at the uniform velocity stirs 15-35 minute (preferably: at the uniform velocity stirring 20-30 minute；More preferably: even
Speed stirring 25 minutes)；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch and stir 30-40 minute, be continuously heating to
80-110 DEG C, it is sequentially added into single hard fatty acids glyceride, the fatty acid ester compounded thing of higher alcohols, hydroquinone, white beeswax and mannose
Alcohol, high-speed stirred 60-80 minute is (preferably: high-speed stirred 65-75 minute；More preferably: high-speed stirred 70 minutes), stand
10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under heated at constant temperature state, dispersion stirs, spraying drying powder-forming
End, obtains paper making auxiliary agent composition.
The preparation method of described paper making auxiliary agent composition, step (1) is dried and was pulverized 200-400 mesh sieve (preferably: dry
250-350 mesh sieve is crossed in dry grinding；More preferably: dry and pulverized 300 mesh sieves).
The preparation method of described paper making auxiliary agent composition, step (2) amount of water be 8-12 times of raw materials quality (preferably
: amount of water is 9-11 times of raw materials quality；More preferably: amount of water is 10 times of raw materials quality).
The preparation method of described paper making auxiliary agent composition, step (3) stirs 33-37 minute (preferably: stir 35 points
Clock).
The preparation method of described paper making auxiliary agent composition, step (3) is continuously heating to 90-100 DEG C (preferably: continue
It is warming up to 95 DEG C).
The preparation method of described paper making auxiliary agent composition, the speed of step (3) high-speed stirred is 400-600 rev/min
(preferably: the speed of high-speed stirred is 450-550 rev/min；More preferably: the speed of high-speed stirred is 500 revs/min
Clock).
The preparation method of described paper making auxiliary agent composition, step (4) heated at constant temperature is to 75-85 DEG C (preferably: constant temperature adds
Heat is to 80 DEG C).
The paper making auxiliary agent composition preparation science that the present invention provides, technique is simple.In addition, the excellent results of the present invention
It is also manifested by: products obtained therefrom of the present invention can improve the fibre structure of paper pulp, reduces paper pulp raw material consumption, and the mechanics improving paper is strong
Degree, it is possible to decrease entreprise cost.
Detailed description of the invention
Describe technical scheme in detail below in conjunction with embodiment and experimental example, but protection domain is not limited to this.
Embodiment 1 paper making auxiliary agent composition, is mainly prepared from (every part of 5kg) by following raw materials according: carboxymethyl chitosan 10
Part, dolomite 20 parts, Borax 10 parts, Polyethylene Glycol 2 parts, single hard fatty acids glyceride 1 part, hydroxypropyl starch 2 parts, dodecyl
Benzene sulfonic acid sodium salt 1 part, the fatty acid ester compounded thing of higher alcohols 2 parts, hydroquinone 1 part, white beeswax 2 parts, Ammonium persulfate. 1 part, hexa metaphosphoric acid
1 part of sodium, mannitol 3 parts.The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) taking dolomite and Borax grinds, add water stirring mixing, removes impurity, dries and pulverized 200 mesh sieves；
(2) carboxymethyl chitosan, Polyethylene Glycol, dodecylbenzene sodium sulfonate, Ammonium persulfate. and sodium hexameta phosphate are mixed, be placed in
In stirring container, add the water dissolution of raw materials quality 8 times, at the uniform velocity stirring 15 minutes；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch and stir 30 minutes, be continuously heating to 80
DEG C, it is sequentially added into single hard fatty acids glyceride, the fatty acid ester compounded thing of higher alcohols, hydroquinone, white beeswax and mannitol, with
The speed high-speed stirred of 400 revs/min 60 minutes, stands 10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under the state of heated at constant temperature to 75 DEG C, dispersion stirs, spray dried
Dry one-tenth powder, obtains paper making auxiliary agent composition.
Embodiment 2 paper making auxiliary agent composition, is mainly prepared from (every part of 5kg) by following raw materials according: carboxymethyl chitosan 14
Part, dolomite 30 parts, Borax 18 parts, Polyethylene Glycol 6 parts, single hard fatty acids glyceride 5 parts, hydroxypropyl starch 4 parts, dodecyl
Benzene sulfonic acid sodium salt 3 parts, the fatty acid ester compounded thing of higher alcohols 4 parts, hydroquinone 1.6 parts, white beeswax 4 parts, Ammonium persulfate. 1.8 parts, six is inclined
Sodium phosphate 3 parts, mannitol 6 parts.The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) taking dolomite and Borax grinds, add water stirring mixing, removes impurity, dries and pulverized 400 mesh sieves；
(2) carboxymethyl chitosan, Polyethylene Glycol, dodecylbenzene sodium sulfonate, Ammonium persulfate. and sodium hexameta phosphate are mixed, be placed in
In stirring container, add the water dissolution of raw materials quality 12 times, at the uniform velocity stirring 35 minutes；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch and stir 40 minutes, be continuously heating to 110
DEG C, it is sequentially added into single hard fatty acids glyceride, the fatty acid ester compounded thing of higher alcohols, hydroquinone, white beeswax and mannitol, with
The speed high-speed stirred of 600 revs/min 80 minutes, stands 10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under the state of heated at constant temperature to 85 DEG C, dispersion stirs, spray dried
Dry one-tenth powder, obtains paper making auxiliary agent composition.
Embodiment 3 paper making auxiliary agent composition, is mainly prepared from (every part of 5kg) by following raw materials according: carboxymethyl chitosan 11
Part, dolomite 23 parts, Borax 12 parts, Polyethylene Glycol 3 parts, single hard fatty acids glyceride 2 parts, hydroxypropyl starch 2.5 parts, dodecane
Base benzene sulfonic acid sodium salt 1.5 parts, the fatty acid ester compounded thing of higher alcohols 2.5 parts, hydroquinone 1.2 parts, white beeswax 2.5 parts, Ammonium persulfate. 12
Part, sodium hexameta phosphate 1.5 parts, mannitol 4 parts.The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) taking dolomite and Borax grinds, add water stirring mixing, removes impurity, dries and pulverized 250 mesh sieves；
(2) carboxymethyl chitosan, Polyethylene Glycol, dodecylbenzene sodium sulfonate, Ammonium persulfate. and sodium hexameta phosphate are mixed, be placed in
In stirring container, add the water dissolution of raw materials quality 9 times, at the uniform velocity stirring 20 minutes；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch and stir 33 minutes, be continuously heating to 90
DEG C, it is sequentially added into single hard fatty acids glyceride, the fatty acid ester compounded thing of higher alcohols, hydroquinone, white beeswax and mannitol, with
The speed high-speed stirred of 450 revs/min 65 minutes, stands 10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under the state of heated at constant temperature to 75 DEG C, dispersion stirs, spray dried
Dry one-tenth powder, obtains paper making auxiliary agent composition.
Embodiment 4 paper making auxiliary agent composition, is mainly prepared from (every part of 5kg) by following raw materials according: carboxymethyl chitosan 13
Part, dolomite 27 parts, Borax 16 parts, Polyethylene Glycol 5 parts, single hard fatty acids glyceride 4 parts, hydroxypropyl starch 3.5 parts, dodecane
Base benzene sulfonic acid sodium salt 2.5 parts, the fatty acid ester compounded thing of higher alcohols 3.5 parts, hydroquinone 1.4 parts, white beeswax 3.5 parts, Ammonium persulfate. 1.6
Part, sodium hexameta phosphate 2.5 parts, mannitol 5 parts.The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) taking dolomite and Borax grinds, add water stirring mixing, removes impurity, dries and pulverized 350 mesh sieves；
(2) carboxymethyl chitosan, Polyethylene Glycol, dodecylbenzene sodium sulfonate, Ammonium persulfate. and sodium hexameta phosphate are mixed, be placed in
In stirring container, add the water dissolution of raw materials quality 11 times, at the uniform velocity stirring 30 minutes；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch and stir 37 minutes, be continuously heating to 100
DEG C, it is sequentially added into single hard fatty acids glyceride, the fatty acid ester compounded thing of higher alcohols, hydroquinone, white beeswax and mannitol, with
The speed high-speed stirred of 550 revs/min 75 minutes, stands 10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under the state of heated at constant temperature to 85 DEG C, dispersion stirs, spray dried
Dry one-tenth powder, obtains paper making auxiliary agent composition.
Embodiment 5 paper making auxiliary agent composition, is mainly prepared from (every part of 5kg) by following raw materials according: carboxymethyl chitosan 12
Part, dolomite 25 parts, Borax 14 parts, Polyethylene Glycol 4 parts, single hard fatty acids glyceride 3 parts, hydroxypropyl starch 3 parts, dodecyl
Benzene sulfonic acid sodium salt 2 parts, the fatty acid ester compounded thing of higher alcohols 3 parts, hydroquinone 1.3 parts, white beeswax 3 parts, Ammonium persulfate. 1.4 parts, six is inclined
Sodium phosphate 2 parts, mannitol 4.5 parts.The preparation method of above-mentioned paper making auxiliary agent composition is:
(1) take dolomite (purchased from Hubei Ju Sheng Science and Technology Ltd.) and Borax (purchased from Jinan spring Lu rich merchant trade company limited) grinds
Mill, add water stirring mixing, removes impurity, dries and pulverized 300 mesh sieves；
(2) by carboxymethyl chitosan (purchased from Feng Tai bio tech ltd, Shandong), Polyethylene Glycol (purchased from open country, Shanghai side chemical industry
Company limited), dodecylbenzene sodium sulfonate (purchased from Zhengzhou Kang Yuan chemical products company limited), Ammonium persulfate. (remote purchased from Shanghai
Admire bio tech ltd) and sodium hexameta phosphate (purchased from Shanghai Fu Sheng Industrial Co., Ltd.) mixing, it is placed in stirring container,
Add the water dissolution of raw materials quality 10 times, at the uniform velocity stirring 25 minutes；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch (limited purchased from Xi'an Yuhua biotechnology
Company) stir 35 minutes, it is continuously heating to 95 DEG C, is sequentially added into single hard fatty acids glyceride (purchased from the Central-South biotechnology in Anhui
Company limited), the fatty acid ester compounded thing of higher alcohols (purchased from Hubei Ju Sheng Science and Technology Ltd.), hydroquinone (remote purchased from Wuhan
Become to create Science and Technology Ltd.), white beeswax (purchased from Wuhan great achievement medication chemistry company limited of big China) and mannitol be (purchased from Hebei
Yuan Chuan bio tech ltd), with the speed high-speed stirred 70 minutes of 500 revs/min, stand 10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under the state of heated at constant temperature to 80 DEG C, dispersion stirs, spray dried
Dry one-tenth powder, obtains paper making auxiliary agent composition.
Primary raw material used by the present invention:
Carboxymethyl chitosan: be a chitosan analog derivative after carboxy methylation, have good film property, rust inhibition,
Antibiotic property, ionic adsorption, water solublity and flocculability, can be widely applied to the every field such as medicine, chemical industry, environmental protection and agricultural
In.
Dolomite: belonging to the carbonate mineral of trigonal system, chemical composition is CaMg(CO3)2, aggregation is the most in pelletized form.Ash
White, sometimes micro-strip brown, light green color pale yellow, shallow.Glassy lustre.In metallurgical industry, refine as basic refractory and blast furnace
Ferrum flux;Part is in order to extraction of metal magnesium;May further be used to manufacture calcium magnesium phosphate, magnesium sulfate etc.;In addition, pottery, glass can also be made
Dispensing.
Borax: for semi-transparent clear crystal or white crystalline powder.Odorless, salty in the mouth.It is to extract boron and the master of boron compound
Want raw mineral materials.In metallurgical industry, Borax is used for forging, welding and metallographictest, is again good flux.Additionally, the most extensively
For industry such as glass, pottery, medicine, fertilizer, weavings.
Polyethylene Glycol: character is nontoxic, nonirritant, mildly bitter flavor, has a good water solublity, and with many Organic substance groups
Part has good intermiscibility.Also there are excellent lubricity, moisture retention, dispersibility, bonding agent, antistatic additive and softening agent etc..
Physico-chemical property is nonionic ethylene oxide condensate, ethanol equal solvent soluble in water, be widely used in medicine, cosmetics, chemical industry,
The fields such as rubber, intermetallic composite coating, pesticide `, pigment, weaving, are also the primary raw materials of ester type surfactant.
Single hard fatty acids glyceride: White waxy thin slice or beadlet solid, water insoluble, mix through intense oscillations with hot water
It is dispersed among in water, for water-in-oil emulsifier.Purposes: for emulsifying agent and the additive of food;In cosmetics and medicine unguentum
As emulsifying agent, make mastic fine and smooth, lubricious；Emulsifying agent and the lubricant of textile for industrial yarn oil preparation；At plastic sheeting
In be used as drip agent and antifoggant；In plastic processing, make lubricant and antistatic additive, in other respects can as defoamer, point
Powder, thickening agent, wetting agent etc..
Hydroxypropyl starch: a kind of white or pale and the powder without special odor.Insoluble in cold water, can be at heating condition
Under be pasted into thickness there is the colloid of certain transparency, good stability.Can be used for paper industry, as paper internal sizing or table
Face applying glue, makes printing-ink distinct, makes uniformly, to make glued membrane smooth, and reduce ink consumption, also have and necessarily do plucking ability.
Dodecylbenzene sodium sulfonate: white or faint yellow powdery or chip solid.Difficult volatilization, soluble in water, be dissolved in water and
Become translucent solution.To alkali, diluted acid, hard water stable chemical nature, micro-poison.There is cleaning function, can be as emulsifying dispersant, anti-
Electrostatic agent, also frequently as cotton fabric refining agent, desizing auxiliary agent, levelling agent during dyeing, metal deposition processes is used as metal
Degreasing agent；Pitch dispersant, felt detergent, deinking agent it is used as in paper industry；Leather industry is used as infiltration defat
Agent；Anticaking agent it is used as in fertilizer industry；In cement industry, it is used as all many-sides such as air-entrainment or is used alone or makees to join
Synthesis point uses.
The fatty acid ester compounded thing of higher alcohols: for white or light yellow viscous liquid, non-corrosiveness, nonflammable, non-explosive, no
Volatilization, stable in properties.Easily flowing under room temperature and when heating, when-25 ~-30 DEG C, viscosity increases, poor fluidity.Pacify as defoamer
Complete reliable.
Hydroquinone: be two para-position hydrogen of benzene compounds of being optionally substituted by a hydroxyl group formation, for white crystals.Meet naked light, height
Heat is flammable.Contact with strong oxidizer and chemical reaction can occur.Be mainly used in producing black-and-white development agent, anthraquinone dye, azo dye,
Rubber antioxidant, stabilizer and antioxidant.
White beeswax: white or faint yellow solid.Glossy, density 0.950-0.970.Fusing point 80-85 DEG C.Water insoluble, second
Alcohol and ether.It is soluble in benzene.Mainly ceryl alcohol and the esters of white beeswax alcohol.Can be used for wax candle processed, paraffin paper, ointment and glazing agent etc..
Ammonium persulfate.: white crystals or powder.Odorlessness.Soluble in water, aqueous solution is acidity, and the most gradually divides
Solve, quickly decompose to give off oxygen when higher temperature, and generate ammonium hydrogen sulfate.Main uses: make oxidant and preparation peroxidating
Hydrogen, potassium peroxydisulfate and other persulfate.It can dissociate initiator as macromolecular polymerization reaction, and oils and fats, soap industry are used as bleaching
Agent.In the oxidation preparing aniline dyes and dyestuff and electroplating industry, photography and chemical analysis.Food stage is used as Semen Tritici aestivi
Modification agent, beer yeast antifungus agent.Also can make the etchant of metal.
Sodium hexameta phosphate: be by phosphorus pentoxide and soda hybrid reaction by a certain percentage, and heat and make it de-poly-, generate
Sodium hexameta phosphate melt through quenching film-making, cooling, obtain industry sodium hexameta phosphate finished product.Purposes: as boiler feed water and work
Industry water (including DYE PRODUCTION water, titanium white production water, size mixing and dyeing water, cleans cinecolour copy and uses by printing and dyeing
Water, and chemical industry water, medicine, reagent industrial water etc.) water softener, the water treatment agent of industrial circulating cooling water；Also serve as
Corrosion inhibiter, flotation agent, dispersant, high temperature adhesives, dyeing assistant, Treatment of Metal Surface, antirust agent, detergent builders, cement
Hardening accelerator.
Mannitol: a kind of polyhydric alcohol or sugar alcohol, can be prepared through catalytic hydrogenation by fructose, and character is colourless to white needles
Or rhombic prism shape crystal or crystalline powder.Hygroscopicity is low, is the anti-of a kind of good low calorie sweetener, chewing gum and confection
Glutinous agent, nutritional supplement and texturizing agents, wetting agent, also serve as Plasticising system component so that it is keep soft characteristic.
The performance test of test example 1 gained of the present invention paper making auxiliary agent composition (embodiment 5):
Choose gained paper making auxiliary agent composition of the present invention, add the water dilution of 5 times, after stirring, then mix with paper pulp, as
Experimental group, matched group adds other multi-functional paper making additives, and is measured two groups, its technical specification testing result such as table 1
Shown in:
The testing result of 1 liang of table group
As shown in Table 1, experimental group is compared with matched group, and greyness of paper improves 5.2%, and degree of sizing improves 0.25mm, and fracture length improves
432m, illustrates that products obtained therefrom of the present invention can be effectively improved the retention of fiber fines and filler, reinforcing fiber adhesion, improves into
The quality of paper.
It should be pointed out that, the detailed description of the invention more representational example that is the present invention, it is clear that the skill of the present invention
Art scheme is not limited to above-described embodiment, it is also possible to have many variations.Those of ordinary skill in the art, the most public with present invention institute
What what that open or according to file written description was undoubted obtained, all it is considered as this patent scope of the claimed.
Claims (10)
1. paper making auxiliary agent composition, it is characterised in that be mainly prepared from by following raw materials according, be mass parts: carboxymethyl chitosan
Sugar 10-14, dolomite 20-30, Borax 10-18, Polyethylene Glycol 2-6, single hard fatty acids glyceride 1-5, hydroxypropyl starch 2-4,
Dodecylbenzene sodium sulfonate 1-3, higher alcohols fatty acid ester compounded thing 2-4, hydroquinone 1-1.6, white beeswax 2-4, Ammonium persulfate. 1-
1.8, sodium hexameta phosphate 1-3, mannitol 3-6.
2. paper making auxiliary agent composition as claimed in claim 1, it is characterised in that carboxymethyl chitosan 11-13, dolomite 23-
27, Borax 12-16, Polyethylene Glycol 3-5, single hard fatty acids glyceride 2-4, hydroxypropyl starch 2.5-3.5, DBSA
Sodium 1.5-2.5, higher alcohols fatty acid ester compounded thing 2.5-3.5, hydroquinone 1.2-1.4, white beeswax 2.5-3.5, Ammonium persulfate. 12-
1.6, sodium hexameta phosphate 1.5-2.5, mannitol 4-5.
3. paper making auxiliary agent composition as claimed in claim 1, it is characterised in that carboxymethyl chitosan 12, dolomite 25, Borax
14, Polyethylene Glycol 4, single hard fatty acids glyceride 3, hydroxypropyl starch 3, dodecylbenzene sodium sulfonate 2, higher alcohols fatty acid ester is multiple
Compound 3, hydroquinone 1.3, white beeswax 3, Ammonium persulfate. 1.4, sodium hexameta phosphate 2, mannitol 4.5.
4. the preparation method of the paper making auxiliary agent composition as described in claim 1-3 is arbitrary, it is characterised in that step is as follows:
(1) taking dolomite and Borax grinds, add water stirring mixing, removes impurity, dries and pulverize；
(2) carboxymethyl chitosan, Polyethylene Glycol, dodecylbenzene sodium sulfonate, Ammonium persulfate. and sodium hexameta phosphate are mixed, be placed in
In stirring container, it is dissolved in water, at the uniform velocity stirs 15-35 minute (preferably: at the uniform velocity stirring 20-30 minute；More preferably: even
Speed stirring 25 minutes)；
(3) take the water of total raw material quality 5 times, be heated to 65 DEG C, add hydroxypropyl starch and stir 30-40 minute, be continuously heating to
80-110 DEG C, it is sequentially added into single hard fatty acids glyceride, the fatty acid ester compounded thing of higher alcohols, hydroquinone, white beeswax and mannose
Alcohol, high-speed stirred 60-80 minute is (preferably: high-speed stirred 65-75 minute；More preferably: high-speed stirred 70 minutes), stand
10 minutes；
(4) being mixed by step (1) (2) (3) products therefrom, under heated at constant temperature state, dispersion stirs, spraying drying powder-forming
End, obtains paper making auxiliary agent composition.
5. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (1) is dried and pulverized
200-400 mesh sieve is (preferably: dry and pulverized 250-350 mesh sieve；More preferably: dry and pulverized 300 mesh sieves).
6. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (2) amount of water is former
8-12 times of material quality (preferably: amount of water is 9-11 times of raw materials quality；More preferably: amount of water is raw materials quality
10 times).
7. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (3) stirring 33-37 divides
Clock (preferably: stir 35 minutes).
8. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (3) is continuously heating to
90-100 DEG C (preferably: be continuously heating to 95 DEG C).
9. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (3) high-speed stirred
Speed is 400-600 rev/min (preferably: the speed of high-speed stirred is 450-550 rev/min；More preferably: high-speed stirring
The speed mixed is 500 revs/min).
10. the preparation method of paper making auxiliary agent composition as claimed in claim 4, it is characterised in that step (4) heated at constant temperature is extremely
75-85 DEG C (preferably: heated at constant temperature to 80 DEG C).
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106638135A (en) * | 2016-12-09 | 2017-05-10 | 苏州艾博迈尔新材料有限公司 | Paper fiber dispersing agent and preparation method thereof |
| CN106702808A (en) * | 2016-12-09 | 2017-05-24 | 张日龙 | Wear-proof plain-color decoration body paper and preparation method thereof |
| CN112663385A (en) * | 2020-12-28 | 2021-04-16 | 冠宏化工（扬州）有限公司 | Paper pulp papermaking auxiliary agent and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1875150A (en) * | 2003-10-27 | 2006-12-06 | 巴斯福股份公司 | Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion |
| CN103882771A (en) * | 2014-02-25 | 2014-06-25 | 苏州恒康新材料有限公司 | Papermaking additive composition and preparation method thereof |
| CN104343051A (en) * | 2014-09-29 | 2015-02-11 | 安徽博硕科技有限公司 | Attapulgite-level paper-making additive |
| CN104695258A (en) * | 2013-12-04 | 2015-06-10 | 郑辉安 | Papermaking auxiliary agent mixture |
-
2016
- 2016-04-27 CN CN201610267740.0A patent/CN105970721A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1875150A (en) * | 2003-10-27 | 2006-12-06 | 巴斯福股份公司 | Method of making a paper coating using a blend of a vinyl aromatic-acrylic polymer dispersion with a vinyl aromatic-diene polymer dispersion |
| CN104695258A (en) * | 2013-12-04 | 2015-06-10 | 郑辉安 | Papermaking auxiliary agent mixture |
| CN103882771A (en) * | 2014-02-25 | 2014-06-25 | 苏州恒康新材料有限公司 | Papermaking additive composition and preparation method thereof |
| CN104343051A (en) * | 2014-09-29 | 2015-02-11 | 安徽博硕科技有限公司 | Attapulgite-level paper-making additive |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106638135A (en) * | 2016-12-09 | 2017-05-10 | 苏州艾博迈尔新材料有限公司 | Paper fiber dispersing agent and preparation method thereof |
| CN106702808A (en) * | 2016-12-09 | 2017-05-24 | 张日龙 | Wear-proof plain-color decoration body paper and preparation method thereof |
| CN112663385A (en) * | 2020-12-28 | 2021-04-16 | 冠宏化工（扬州）有限公司 | Paper pulp papermaking auxiliary agent and preparation method thereof |
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Address after: 744300 Gansu, Dingxi Anding District, No. 8, Yu Yuan Garden District, building 2-401, 1, Applicant after: Shang Xiaoxia Address before: Ying Shi Xi Jie, Huaiyin District of Ji'nan city of Shandong Province, No. 5 250000 Applicant before: Shang Xiaoxia |
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