CN105967666A - Nanometer ceramic paint for pre-painting of metal printing plates with rollers and preparation method thereof - Google Patents
Nanometer ceramic paint for pre-painting of metal printing plates with rollers and preparation method thereof Download PDFInfo
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- CN105967666A CN105967666A CN201610302301.9A CN201610302301A CN105967666A CN 105967666 A CN105967666 A CN 105967666A CN 201610302301 A CN201610302301 A CN 201610302301A CN 105967666 A CN105967666 A CN 105967666A
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- ceramic coating
- metal printing
- roller coat
- printing card
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/14—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62222—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products obtaining ceramic coatings
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention relates to the field of preparation technology of paint with scratch-resistance and wear-resistance, and especially relates to nanometer ceramic paint for pre-painting of metal printing plates with rollers and a preparation method thereof. The paint comprises the following components in parts by weight: 70-80 parts of nanometer ceramic resin, 10-15 parts of a curing agent, 2-4 parts of a matting agent, 0.5-3 parts of a fluorocarbon surfactant, 25-35 parts of a solvent, and 1-5 parts of an additive. A special Si/O structure in the components has binding energy which reaches 101 kilocalorie/mol, a vitrescent three-dimensional net structure can be formed after high temperature roast during a later period, so that hardness of a paint film on the surface of a coating is equal to or higher than 6H; the paint film is not easy to scratch or wear, and has excellent incombustibility and insulating properties; application limitation of the prior printing decorative plates which are prepainted with rollers is broken, good compatibility to a fluorocarbon coating layer is formed, and the paint is suitable for coating metal base materials or base materials with the fluorocarbon coating layer.
Description
Technical field
The present invention relates to the preparing technical field of anti-scratching wearproof coating, particularly a kind of pre-roller of metal printing card
It is coated with ceramic coating and preparation method thereof.
Background technology
Metal stamp decorative panel is gradually widely used in building, transportation and medical and health industry in recent years,
This kind of metal printing card is integrated type warming plate, has alternative tradition wood grain and the new mounting means of bag,
It is applicable to build the public spheres such as interior trim, decoration of exterior wall, airport, subway, market.General metal stamp
Plate includes metallic plate basic unit and the stamp composite bed being arranged in metallic plate basic unit, and this kind of metal printing card has
The problem that face coat hardness is inadequate, in transport, installs and during later stage maintenance easily by pointed object
Scratching and form abrasion, thus affect outward appearance and service life, the replacing installation for single damage face is also held
Easily peripheral part is produced unnecessary printing, and then increases use cost.For the problems referred to above, develop one
Planting metal printing card is that those skilled in the art are to be solved with pre-roller coat ceramic coating and preparation method thereof
Technical problem.
Summary of the invention
The technical problem to be solved in the present invention is: for above-mentioned technical problem, it is provided that a kind of metal printing card is used
Pre-roller coat ceramic coating and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of metal printing card is received with pre-roller coat
Rice ceramic coating, counts by weight, and this coating includes following component: nano ceramics resin 70-80 part,
Firming agent 10-15 part, delustering agent 2-4 part, fluorocarbon surfactant 0.5-3 part, solvent 25-35 part,
Additive 1-5 part；Described nano ceramics resin includes following component: nanometer grade powder 10-20, inorganic silicon
Hydrochlorate water and thing 20-40, aqueous silicone acrylic emulsion 5-12；Inorganic silicic acid saline and thing are by hydro-thermal legal system
The mean diameter become is at the water of 50-100nm and thing；Described firming agent is beta-hydroxy alkylamide class or three shrinks
Glyceryl chlorinated isocyanurates；Additive be levelling agent and defoamer according to weight ratio (0.7-1): (0.8-1)
The complex formed.
Further, nanometer grade powder described in technique scheme be nano titanium oxide, nano silicon,
One in nano-aluminium oxide, calcium carbonate superfine powder, magnesium carbonate, magnesium silicate or Pulvis Talci, two kinds or many
The compositions planted, preferably nano silicon, nano-aluminium oxide and calcium carbonate superfine powder are according to mass ratio
1:(0.4-0.8): the compound that (0.3-0.6) is formed；Described inorganic silicate be modulus be 1.5-2.8
Sodium silicate or modulus be the potassium silicate of 1.5-2.5.
Further, fluorocarbon surfactant described in technique scheme is 3-tetra-polycyclic oxygen nine fluorine butane amide
Base propyl group (2-sulfurous acid) ethosulfate or 3-tetra-polycyclic oxygen nine fluorine butane amide base CAB；Institute
State aqueous silicone acrylic emulsion to be the 378 of Shanghai Li Bang Chemical Industry Science Co., Ltd or be the group including following weight portion
Become: methyl silicon resin 20-30 part, Isooctyl acrylate monomer 22-32 part, deionized water 25-35 part, nonyl
Phenol polyethenoxy ether 1-2 part, silane coupler 0.2-0.5 part, methyl o-benzoylbenzoate 2.5-5 part,
Propylene glycol methyl ether acetate 3-6 part.
Further, delustering agent described in technique scheme is aerosil, solvent be isophorone or
Isopropanol；Described levelling agent is polyurethane 2020, PW50C, BYK-358, MFPE, BYK358N or polyethers
One in modified dimethyl polysiloxane copolymer, defoamer be polyvinyl, polysiloxanes or
One in W-082 type organic silicon defoamer, TEGO Foamex K3, BYK066 or BEK-760.
A kind of metal printing card preparation method of pre-roller coat ceramic coating, is characterized in that: this preparation side
Method includes following preparation process:
(1) count by weight, prepare following component: nano ceramics resin 70-80 part, firming agent 10-15
Part, delustering agent 2-4 part, fluorocarbon surfactant 0.5-3 part, solvent 25-35 part, additive 1-5 part；
(2) dispersion machine is used to disperse, at rotating speed in the reactor nano ceramics resin and solvent
800-1000 turns/min, dispersed with stirring 15-20min；
(3) in step (2) product, add fluorocarbon surfactant, delustering agent and additive to be sequentially added into
Mix and blend 30-40min in reactor, is subsequently adding firming agent, and reduction of speed 20% stirs 20-30min, uses
180-200 eye mesh screen filters, and obtains pre-roller coat ceramic coating.
Beneficial effect: compared with prior art, in the component of the present invention, distinctive Si-O structure has up to
The combination energy of 101 kilocalories/mol, can form vitrescence space network after later stage high-temperature baking, from
And make coating surface hardness of paint film reach the >=effect of 6H, be difficult to scratch or formed abrasion, have outstanding not
Combustion property and insulating properties, broken the application limitation of conventional pre-roller coat printing ornament plate, it is possible to and fluorocarbon coating
Layer forms good compatibility, it is adaptable to coat metal substrates or have the base material of fluorocarbon coating layer.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited to following enforcement
Example.
Embodiment one
A kind of metal printing card preparation method of pre-roller coat ceramic coating, this preparation method includes as follows
Preparation process:
(1) count by weight, prepare following component: nano ceramics resin 80 parts, 15 parts of firming agent,
Aerosil 4 parts, fluorocarbon surfactant 2.5 parts, isophorone 35 parts, additive 4 parts；
(2) dispersion machine is used to disperse, at rotating speed in the reactor nano ceramics resin and solvent
800-1000 turns/min, dispersed with stirring 15-20min；
(3) in step (2) product, add fluorocarbon surfactant, delustering agent and additive to be sequentially added into
Mix and blend 30-40min in reactor, is subsequently adding firming agent, and reduction of speed 20% stirs 20-30min, with 200
Eye mesh screen filters, and obtains pre-roller coat ceramic coating.
Wherein, in step (1), nano ceramics resin is by nanometer grade powder 20, inorganic silicic acid saline and thing
40, aqueous silicone acrylic emulsion 12 is according to aqueous silicone acrylic emulsion, inorganic silicic acid saline and thing, nanometer grade powder
Order of addition stirs formation in the reactor；Inorganic silicic acid saline and thing are the average particle made by hydro-thermal method
Footpath is at the sodium silicate water that modulus is 1.8 of 80nm and thing, and nanometer grade powder is nano silicon, nanometer three
The compound that Al 2 O and calcium carbonate superfine powder are formed according to mass ratio 1:0.6:0.5, aqueous silicone acrylic emulsion
It is the 378 of Shanghai Li Bang Chemical Industry Science Co., Ltd；
Firming agent is beta-hydroxy alkylamide class；Fluorocarbon surfactant is 3-tetra-polycyclic oxygen nine fluorine butane amide
Base propyl group (2-sulfurous acid) ethosulfate, additive is levelling agent BYK-358 and defoamer polysiloxanes
The complex formed according to weight ratio 0.8:0.9.
Embodiment two
A kind of metal printing card preparation method of pre-roller coat ceramic coating, this preparation method includes as follows
Preparation process:
(1) count by weight, prepare following component: nano ceramics resin 75 parts, 13 parts of firming agent,
Aerosil 3 parts, fluorocarbon surfactant 2.0 parts, isophorone 30 parts, additive 4 parts；Its
Remaining step is with embodiment one.
Wherein, in step (1), nano ceramics resin is by nanometer grade powder 15, inorganic silicic acid saline and thing
30, aqueous silicone acrylic emulsion 8 is according to aqueous silicone acrylic emulsion, inorganic silicic acid saline and thing, nanometer grade powder
Order of addition stirs formation in the reactor；Inorganic silicic acid saline and thing are the average particle made by hydro-thermal method
Footpath is at the sodium silicate water that modulus is 1.8 of 80nm and thing, and nanometer grade powder is nano silicon, nanometer three
The compound that Al 2 O and magnesium silicate are formed according to mass ratio 1:0.7:0.6, on aqueous silicone acrylic emulsion is
The 378 of Hai Libang Chemical Industry Science Co., Ltd；
Firming agent is beta-hydroxy alkylamide class；Fluorocarbon surfactant is 3-tetra-polycyclic oxygen nine fluorine butane amide
Base CAB, additive is levelling agent polyether-modified Dimethicone Copolyol body and defoamer
The complex that BYK066 is formed according to weight ratio 0.7:0.8.
Embodiment three
A kind of metal printing card preparation method of pre-roller coat ceramic coating, this preparation method includes as follows
Preparation process:
(1) count by weight, prepare following component: nano ceramics resin 75 parts, 12 parts of firming agent,
Aerosil 3 parts, fluorocarbon surfactant 2.5 parts, isopropanol 30 parts, additive 4 parts；Remaining
Step is with embodiment one.
Wherein, in step (1), nano ceramics resin is by nanometer grade powder 13, inorganic silicic acid saline and thing
30, aqueous silicone acrylic emulsion 8 is according to aqueous silicone acrylic emulsion, inorganic silicic acid saline and thing, nanometer grade powder
Order of addition stirs formation in the reactor；Inorganic silicic acid saline and thing are the average particle made by hydro-thermal method
Footpath is at the potassium silicate water that modulus is 1.8 of 70nm and thing, and nanometer grade powder is nano silicon, nanometer three
The compound that Al 2 O and nano titanium oxide are formed according to mass ratio 1:0.75:0.5, aqueous silicon the third breast
Liquid includes following component: methyl silicon resin 25 parts, Isooctyl acrylate monomer 24 parts, deionized water 30 parts, nonyl
Base phenol polyethenoxy ether 1.5 parts, silane coupler 0.3 part, methyl o-benzoylbenzoate 3.0 parts, third
Glycol methyl ether acetate 4 parts, the preparation method of this aqueous silicone acrylic emulsion is: by methyl silicon resin and deionization
Water adds dispersed with stirring in reactor and, to uniformly, is then sequentially added into acrylic acid at stirring condition interval 10min
Different monooctyl ester, NPE, methyl o-benzoylbenzoate, silane coupler and propylene glycol monomethyl ether
Acetate, 300-500 turns/and min stirs 30-40min；Firming agent is triglycidyl group isocyanuric acid
Ester；Fluorocarbon surfactant is 3-tetra-polycyclic oxygen nine fluorine butane amide base CAB, and additive is levelling
The complex that agent MFPE and defoamer polyvinyl are formed according to weight ratio 0.7:0.8.
The pre-roller coat ceramic coating of above-described embodiment one, two, three gained roller coat respectively is covered at fluorine carbon
The metal substrate surface of PVDF coating, toasts PMT240 DEG C, toasts the same time, treat water-cooled cooling, respectively
Three pieces of metal bases are carried out face coat hardness determination, 180 ° of bend tests and reverse impact test, test
Result is as follows:
The metal stamp decorative panel of the present invention is with pre-roller coat ceramic coating as can be seen from the above table, can be at gold
Belong to surface of bottom material and form the nano coating of continuous-stable, through high-temperature baking, can reach >=superpower the hardness of 6H,
Apparently higher than F, H level of color coated steel sheet national standard in pencil hardness test, physical property processing characteristics refers to simultaneously
Mark is also apparently higher than national standard, and suitable further genralrlization is applied.
Above-described embodiment only for technology design and the feature of the present invention are described, its object is to allow and is familiar with this skill
The personage of art will appreciate that present disclosure and is carried out, and can not limit the protection model of the present invention with this
Enclose, all equivalence changes made according to spirit of the invention or modification, all should contain the protection in the present invention
In the range of.
Claims (8)
1. metal printing card is with a pre-roller coat ceramic coating, it is characterized in that: count by weight, should
Coating includes following component: nano ceramics resin 70-80 part, firming agent 10-15 part, delustering agent 2-4 part,
Fluorocarbon surfactant 0.5-3 part, solvent 25-35 part, additive 1-5 part；
Described nano ceramics resin includes following component: nanometer grade powder 10-20, inorganic silicic acid saline and thing
20-40, aqueous silicone acrylic emulsion 5-12；Inorganic silicic acid saline and thing are the mean diameter made by hydro-thermal method
Water and thing at 50-100nm；Described firming agent is beta-hydroxy alkylamide class or triglycidyl group isocyanide urine
Acid esters；Additive be levelling agent and defoamer according to weight ratio (0.7-1): the complex that (0.8-1) is formed.
A kind of metal printing card pre-roller coat ceramic coating, its feature the most according to claim 1
It is: described nanometer grade powder is nano titanium oxide, nano silicon, nano-aluminium oxide, ultra-fine
One in calcium carbonate, magnesium carbonate, magnesium silicate or Pulvis Talci, the compositions of two or more.
A kind of metal printing card pre-roller coat ceramic coating, its feature the most according to claim 1
It is: described inorganic silicate is that modulus is the sodium silicate of 1.5-2.8 or modulus is the potassium silicate of 1.5-2.5.
A kind of metal printing card pre-roller coat ceramic coating, its feature the most according to claim 1
It is: described fluorocarbon surfactant is 3-tetra-polycyclic oxygen nine fluorine butane amide base propyl group (2-sulfurous acid) ethyl two
Ammonium methyl or 3-tetra-polycyclic oxygen nine fluorine butane amide base CAB.
A kind of metal printing card pre-roller coat ceramic coating, its feature the most according to claim 1
It is: described aqueous silicone acrylic emulsion includes that following weight portion forms: methyl silicon resin 20-30 part, acrylic acid are different
Monooctyl ester 22-32 part, deionized water 25-35 part, NPE 1-2 part, silane coupler 0.2-0.5
Part, methyl o-benzoylbenzoate 2.5-5 part, propylene glycol methyl ether acetate 3-6 part.
A kind of metal printing card pre-roller coat ceramic coating, its feature the most according to claim 1
Being: described delustering agent is aerosil, solvent is isophorone or isopropanol.
A kind of metal printing card pre-roller coat ceramic coating, its feature the most according to claim 1
It is: described levelling agent is polyurethane 2020, PW50C, BYK-358, MFPE, BYK358N or polyether-modified
One in Dimethicone Copolyol body, defoamer is polyvinyl, polysiloxanes or W-082
One in type organic silicon defoamer, TEGO Foamex K3, BYK066 or BEK-760.
A kind of metal printing card the most according to claim 1 preparation side of pre-roller coat ceramic coating
Method, is characterized in that: this preparation method includes following preparation process:
(1) count by weight, prepare following component: nano ceramics resin 70-80 part, firming agent 10-15
Part, delustering agent 2-4 part, fluorocarbon surfactant 0.5-3 part, solvent 25-35 part, additive 1-5 part；
(2) dispersion machine is used to disperse, at rotating speed in the reactor nano ceramics resin and solvent
800-1000 turns/min, dispersed with stirring 15-20min；
(3) in step (2) product, add fluorocarbon surfactant, delustering agent and additive to be sequentially added into
Mix and blend 30-40min in reactor, is subsequently adding firming agent, and reduction of speed 20% stirs 20-30min, uses
180-200 eye mesh screen filters, and obtains pre-roller coat ceramic coating.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610302301.9A CN105967666B (en) | 2016-05-09 | 2016-05-09 | Metal printing plate pre- roller coating ceramic coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610302301.9A CN105967666B (en) | 2016-05-09 | 2016-05-09 | Metal printing plate pre- roller coating ceramic coating and preparation method thereof |
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| CN105967666A true CN105967666A (en) | 2016-09-28 |
| CN105967666B CN105967666B (en) | 2018-10-12 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603399A (en) * | 2017-09-20 | 2018-01-19 | 阜南县中泰工艺品有限公司 | A kind of high attachment coating in rattan wicker plaiting article surface |
| CN108047909A (en) * | 2017-12-06 | 2018-05-18 | 曹结宾 | A kind of processing technology of ground glass |
| CN109943108A (en) * | 2019-03-18 | 2019-06-28 | 广东欧涂新材料有限公司 | A kind of outer wall inorganic coating and preparation method thereof that lasting uvioresistant is extra-weather-proof |
| CN111906006A (en) * | 2020-06-28 | 2020-11-10 | 广东顺德铁业实业有限公司 | Manufacturing method of precoated metal plate and precoated metal plate |
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| CN102417761A (en) * | 2011-12-20 | 2012-04-18 | 浙江美浓丝网印刷有限公司 | Silk-screening printing ink with high flexibility and high brightness |
| US20140221565A1 (en) * | 2013-02-06 | 2014-08-07 | Chemical Physics Technologies Ltd | Alkyd resin based paint work composition and a method for preparing the same |
| CN104356826A (en) * | 2014-11-14 | 2015-02-18 | 珠海市澜诺新材料科技有限公司 | Surface self-cleaning coating and preparation method thereof |
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2016
- 2016-05-09 CN CN201610302301.9A patent/CN105967666B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102417761A (en) * | 2011-12-20 | 2012-04-18 | 浙江美浓丝网印刷有限公司 | Silk-screening printing ink with high flexibility and high brightness |
| US20140221565A1 (en) * | 2013-02-06 | 2014-08-07 | Chemical Physics Technologies Ltd | Alkyd resin based paint work composition and a method for preparing the same |
| CN104356826A (en) * | 2014-11-14 | 2015-02-18 | 珠海市澜诺新材料科技有限公司 | Surface self-cleaning coating and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107603399A (en) * | 2017-09-20 | 2018-01-19 | 阜南县中泰工艺品有限公司 | A kind of high attachment coating in rattan wicker plaiting article surface |
| CN108047909A (en) * | 2017-12-06 | 2018-05-18 | 曹结宾 | A kind of processing technology of ground glass |
| CN109943108A (en) * | 2019-03-18 | 2019-06-28 | 广东欧涂新材料有限公司 | A kind of outer wall inorganic coating and preparation method thereof that lasting uvioresistant is extra-weather-proof |
| CN111906006A (en) * | 2020-06-28 | 2020-11-10 | 广东顺德铁业实业有限公司 | Manufacturing method of precoated metal plate and precoated metal plate |
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| Publication number | Publication date |
|---|---|
| CN105967666B (en) | 2018-10-12 |
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