CN107502078A - Application aluminium weather resistant luminescent coating and its application method - Google Patents
Application aluminium weather resistant luminescent coating and its application method Download PDFInfo
- Publication number
- CN107502078A CN107502078A CN201710593865.7A CN201710593865A CN107502078A CN 107502078 A CN107502078 A CN 107502078A CN 201710593865 A CN201710593865 A CN 201710593865A CN 107502078 A CN107502078 A CN 107502078A
- Authority
- CN
- China
- Prior art keywords
- parts
- aluminium
- coating
- phosphorescent pigment
- earth metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
It is 10~25 parts of modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.3~0.8 part of fluorescent pigment, 30~40 parts of fluorocarbon resin, 1~3 part of ethylene glycol, calcium carbonate, 1~7 part of silicone oil, 10~15 parts of titanium dioxide, 10~25 parts of curing agent, 1~3 part of anti-settling agent, 1~5 part of dispersant and 1~2 part of the defoamer of 1~2 part of 12,5~10 parts of coalescents alcohol ester the invention discloses application aluminium weather resistant luminescent coating, including parts by weight；Its application method is also disclosed, this luminescent coating good weatherability, hardness are high, and the addition of fluorescent pigment can take into account coating apparent colour and illumination effect；The reflective bottom layer of white substrate is advantageous to improve the illumination effect of noctilucent coating；Solvent is made using harmless volatile materials, heat is harmless to operating personnel during applying, also more environmentally friendly.
Description
Technical field
The present invention relates to application aluminium weather resistant luminescent coating and its application method.
Background technology
Application aluminium also known as spraying aluminium, application aluminium volume, spraying aluminium volume.Its preparation process, which is generally cleaned, (to be removed aluminium volume rolling
One layer of lubricating oil, anti-oxidation grease and the various dirts of surface attachment when processed) → chemical conversion (add industrial chemicals with aluminium roll up surface shape
Into oxide-film) → application → baking.All it is pigment or oil according to the requirement brushing respective color of client in coating process
Paint, some noctilucence application aluminium obtain the favor of businessman at present, therefore are increasingly becoming stream in chemical conversion aluminium volume surface coating luminescent coating
OK, and on the market phosphorescent pigment water resistance (weatherability) is bad, and hydrolabil, the moisture even if in air can also make them
Luminosity and persistence substantially reduce.In addition, noctilucent coating hardness is not high, its service life is reduced；In addition, noctilucence
Pigment coated luminous intensity, luminosity be not high, causes its coating apparent colour and illumination effect bad.
Application publication number is the A of CN 105349003 patent：The luminescent coating of metallic article, its raw material is matched somebody with somebody by weight
Than for：56~90 parts of polyester；4.2~7 parts of curing agent；1 part of levelling agent；25~35 parts of titanium dioxide；10 parts of pigment；Filler 20~30
Part；10~15 parts of luminous agent.It fails solve the problems, such as that weatherability and apparent colour and illumination effect are bad.Authorization Notice No. is
The B of CN 102533037 patent：A kind of colorful noctilucent paint, including consisting of composition, deionized water 30%, dispersant
0.5%, wetting agent 0.3%, F111 defoamers 0.3%, preservative 0.3%, ethylene glycol 1.2%, coalescents 1%, hydroxypropyl
Methylcellulose 0.2%, photo-induced energy storage type luminescent powder 26%, pure-acrylic emulsion 40%, thickener 0.2%.Its usage time is grown, in vain
Four hours of its extinction, night can light 8 hours, also the problem of unresolved apparent colour and bad illumination effect.
The content of the invention
Present invention mainly solves technical problem be, there is provided application aluminium weather resistant luminescent coating, good weatherability, hardness
Height, apparent colour are good with illumination effect；Solvent is made using harmless volatile materials, to operating personnel during heat painting
It is harmless, it is also more environmentally friendly.
The technical solution adopted for the present invention to solve the technical problems is：Application aluminium weather resistant luminescent coating, including weight
Measure modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.3~0.8 part of fluorescent pigment, 30~40 parts of fluorine that part is 10~25 parts
Carbon resin, 1~3 part of ethylene glycol, the calcium carbonate of 1~2 part of 12,5~10 parts of coalescents alcohol ester, 1~7 part of silicone oil,
10~15 parts of titanium dioxide, 10~25 parts of curing agent, 1~3 part of anti-settling agent, 1~5 part of dispersant and 1~2 part of defoaming
Agent.Using ethylene glycol as diluent, when being so directed to application (temperature can typically reach 120 DEG C) also do not pollute ring even if volatilization
Border, substantially harmless to operating personnel, modified aluminic acid alkaline-earth metal system phosphorescent pigment water resistance is improved, but intensity is substantially not
Become；Dispersant mainly makes pigment be dispersed in base-material, and the molecule of dispersant can be adsorbed in surface of pigments, so that around pigment all
With identical electric charge, and it is mutually exclusive, make granules of pigments keep isolation to reach dispersed, not aggregate and precipitate.It is glimmering
The addition one of delustering pigment is to improve the dull color of script phosphorescent pigment, and two be due to the granularity of fluorescent pigment compared with phosphorescent pigment
Thin many, fluorescent pigment has stronger covering to act on the luminous of phosphorescent pigment, after tested fluorescent pigment and noctilucence in the present invention
The ratio of pigment can preferably take into account coating apparent colour and illumination effect.Aluminic acid alkaline-earth metal system phosphorescent pigment is by 1300
High-temperature heating more than DEG C and the sintered body formed, then by mechanical crushing, manufactured through 200 mesh sieves point, its particle is basic
For 10 μm or so.From the point of view of coating processability, finer particles are better, if but general phosphorescent pigment crushes thinner, its hair
Light function just have it is impaired incline, therefore phosphorescent pigment particle fineness control be advisable at 10~20 μm.
Further improvement as application aluminium of the present invention with weather resistant luminescent coating, modified aluminium acid alkaline earth metal system noctilucence face
Preparing for material is as follows：After 10ml tetraethyl orthosilicates are well mixed with 100ml absolute ethyl alcohols, 1.8ml deionized waters are added, are continued
Stirring, make it well mixed；0.2-1.0ml concentrated hydrochloric acids are added after 20min, stir 60min, obtain clarifying silica sol；
Clarify and aluminic acid alkaline-earth metal system phosphorescent pigment is added in silica sol, continue to stir 60min, obtain colored colloidal sol；Wherein, often
Dyestuff addition is 0.1-1.0g in 110ml clarification silica sols；In the modified aluminium acid alkaline earth metal system phosphorescent pigment
Aluminic acid alkaline-earth metal system phosphorescent pigment is SrAl2O4:Eu, Dy or SrAl2O4:Eu or Sr4Al14O25:Eu、Dy.Phosphorescent pigment is entered
After row surface modification treatment, its water resistance is greatly improved, and its relative luminous intensity is substantially unchanged, because positive silicic acid
Chain polymer is formd after the ageing of ethyl ester hydrolyzate, one layer of reticular membrane is formd on phosphorescent pigment surface；During heating, with
Water and the further evaporation of alcohol and the decomposition of organic matter, have passed through and be condensed to polymerization process, structure is gradually closely knit, and finally turns
It is changed into corresponding SiO2Melten glass.And this film layer is higher to light transmission rate, the luminous intensity of phosphorescent pigment is influenceed compared with
It is small.
Further improvement as application aluminium of the present invention with weather resistant luminescent coating, anti-settling agent is organo montmorillonite, described
Dispersant is polycarboxylate, and the defoamer is organic silicon defoamer；The curing agent is the isocyanic acid of aliphatic hexa-methylene two
Ester or biuret,.
The application method of application aluminium weather resistant luminescent coating, by 1~3 part of ethylene glycol, 1~2 part of coalescents alcohol
The calcium carbonate that 12,5~10 part of ester, 1~7 part of silicone oil, 10~15 parts of titanium dioxide agitation grinding are configured to the bottom of white
Use coating；It is 10~25 parts of modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.3~0.8 part of fluorescent pigment, 30 by parts by weight
~40 parts of fluorocarbon resin, 10~25 parts of curing agent, 1~3 part of anti-settling agent, 1~5 part of dispersant and 1~2 part of defoaming
Noctilucent coating is made in agent agitation grinding；The bottom coating application prepared is rolled up into surface in stand-by aluminium, after drying, then brushes night
Light coating.The reflective bottom layer of white substrate is advantageous to improve the illumination effect of noctilucent coating, therefore the first aluminium volume table after chemical conversion
Face coats white priming coat, is coated with noctilucent coating, can improve the illumination effect of noctilucent coating.
Beneficial effects of the present invention have：
1st, good weatherability, hardness are high, and the addition of fluorescent pigment can take into account coating apparent colour and illumination effect；
2nd, solvent is made using harmless volatile materials, heat is harmless to operating personnel during applying, also more environmentally friendly；
3rd, after carrying out surface modification treatment to phosphorescent pigment, its water resistance is greatly improved, and its relative luminous
Intensity is substantially unchanged；
4th, the reflective bottom layer of white substrate is advantageous to improve the illumination effect of noctilucent coating, therefore the first aluminium volume after chemical conversion
Surface coats white priming coat, is coated with noctilucent coating, can improve the illumination effect of noctilucent coating.
Embodiment
With reference to embodiment, the embodiment of the present invention is further described.Following examples are only used for more
Add and clearly demonstrate technical scheme, and can not be limited the scope of the invention with this.
Embodiment one：
Application aluminium weather resistant luminescent coating, including parts by weight be 10 parts modified aluminium acid alkaline earth metal system phosphorescent pigment,
0.3 part of fluorescent pigment, 30 parts of fluorocarbon resin, 1 part of ethylene glycol, 1 part of 12,5 parts of coalescents alcohol ester calcium carbonate,
1 part of silicone oil, 10 parts of titanium dioxide, 10 parts of curing agent, 1 part of anti-settling agent, 1 part of dispersant and 1 part of defoamer.
Preparing for modified aluminium acid alkaline earth metal system phosphorescent pigment is as follows：By 10ml tetraethyl orthosilicates and 100ml absolute ethyl alcohols
After well mixed, 1.8ml deionized waters are added, lasting stirring, make it well mixed；0.2ml concentrated hydrochloric acids are added after 20min, are stirred
60min is mixed, obtains clarifying silica sol；Aluminic acid alkaline-earth metal system phosphorescent pigment is added in silica sol is clarified, is continued
60min is stirred, obtains colored colloidal sol；Wherein, per 110ml, dyestuff addition is 0.1g in clarification silica sol；The modification
Aluminic acid alkaline-earth metal system phosphorescent pigment in aluminic acid alkaline-earth metal system phosphorescent pigment is SrAl2O4:Eu、Dy。
Anti-settling agent is organo montmorillonite, and the dispersant is polycarboxylate, and the defoamer is organic silicon defoamer；It is described
Curing agent is aliphatic hexamethylene diisocyanate,.
Method using application aluminium with weather resistant luminescent coating, by 1 part of ethylene glycol, 1 part of coalescents alcohol ester 12,
5 parts of calcium carbonate, 1 part of silicone oil, 10 parts of titanium dioxide agitation grinding are configured to the bottom coating of white；It is 10 by parts by weight
Part modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.3 part of fluorescent pigment, 30 parts of fluorocarbon resin, 10 parts of curing agent, 1
Noctilucent coating is made in the anti-settling agent, 1 part of dispersant and 1 part of defoamer agitation grinding of part；The bottom prepared is applied with coating
Brush and roll up surface in stand-by aluminium, after drying, then brushing noctilucent coating.
Embodiment two：
It is with the difference of embodiment one：Application aluminium weather resistant luminescent coating, including the modified aluminium that parts by weight are 25 parts
Acid alkaline earth metal system phosphorescent pigment, 0.8 part of fluorescent pigment, 40 parts of fluorocarbon resin, 3 parts of ethylene glycol, 2 parts of coalescents
The calcium carbonate that 12,10 part of alcohol ester, 7 parts of silicone oil, 15 parts of titanium dioxide, 25 parts of curing agent, 3 parts of anti-settling agent, 5 parts of point
Powder and 2 parts of defoamer.
Concentrated hydrochloric acid dosage 1.0ml in the preparation of modified aluminium acid alkaline earth metal system phosphorescent pigment；Per 110ml, clarification silica is molten
Dyestuff addition is 1.0g in glue；Aluminic acid alkaline-earth metal system phosphorescent pigment in the modified aluminium acid alkaline earth metal system phosphorescent pigment
For SrAl2O4:Eu。
Method using application aluminium with weather resistant luminescent coating, by 3 parts of ethylene glycol, 2 parts of coalescents alcohol ester 12,
10 parts of calcium carbonate, 7 parts of silicone oil, 15 parts of titanium dioxide agitation grinding are configured to the bottom coating of white；It is by parts by weight
25 parts of modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.8 part of fluorescent pigment, 40 parts of fluorocarbon resin, 25 parts of curing agent,
Noctilucent coating is made in 3 parts of anti-settling agent, 5 parts of dispersant and 2 parts of defoamer agitation grinding；The bottom prepared is applied with coating
Brush and roll up surface in stand-by aluminium, after drying, then brushing noctilucent coating.
Embodiment three：
It is with the difference of embodiment one, application aluminium weather resistant luminescent coating, including the modified aluminium that parts by weight are 17 parts
Acid alkaline earth metal system phosphorescent pigment, 0.5 part of fluorescent pigment, 35 parts of fluorocarbon resin, 2 parts of ethylene glycol, 1.5 parts of film forming help
The calcium carbonate that 12,7 part of agent alcohol ester, 4 parts of silicone oil, 12 parts of titanium dioxide, 17 parts of curing agent, 2 parts of anti-settling agent, 3 parts
Dispersant and 1.5 parts of defoamer.
Concentrated hydrochloric acid dosage 0.6ml in the preparation of modified aluminium acid alkaline earth metal system phosphorescent pigment；Per 110ml, clarification silica is molten
Dyestuff addition is 0.6g in glue；Aluminic acid alkaline-earth metal system phosphorescent pigment in the modified aluminium acid alkaline earth metal system phosphorescent pigment
For Sr4Al14O25:Eu、Dy。
Method using application aluminium with weather resistant luminescent coating, by 2 parts of ethylene glycol, 1.5 parts of coalescents alcohol ester ten
2nd, 7 parts of calcium carbonate, 4 parts of silicone oil, 12 parts of titanium dioxide agitation grinding are configured to the bottom coating of white；By parts by weight
For 17 parts of modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.5 part of fluorescent pigment, 35 parts of fluorocarbon resin, 17 parts of solidification
Noctilucent coating is made in agent, 2 parts of anti-settling agent, 3 parts of dispersant and 1.5 parts of defoamer agitation grinding；The bottom prepared is used
Coating application rolls up surface in stand-by aluminium, after drying, then brushing noctilucent coating.
Example IV：
It is with the difference of embodiment one, application aluminium weather resistant luminescent coating, including the modified aluminium that parts by weight are 17 parts
Acid alkaline earth metal system phosphorescent pigment, 0.8 part of fluorescent pigment, 30 parts of fluorocarbon resin, 1 part of ethylene glycol, 1.5 parts of film forming help
The calcium carbonate that 12,10 part of agent alcohol ester, 4 parts of silicone oil, 12 parts of titanium dioxide, 10 parts of curing agent, 2 parts of anti-settling agent, 1 part
Dispersant and 1.5 parts of defoamer.
Concentrated hydrochloric acid dosage 1.0ml in the preparation of modified aluminium acid alkaline earth metal system phosphorescent pigment；Per 110ml, clarification silica is molten
Dyestuff addition is 0.5g in glue；Aluminic acid alkaline-earth metal system phosphorescent pigment in the modified aluminium acid alkaline earth metal system phosphorescent pigment
For SrAl2O4:Eu。
Method using application aluminium with weather resistant luminescent coating, by 1 part of ethylene glycol, 1.5 parts of coalescents alcohol ester ten
2nd, 10 parts of calcium carbonate, 4 parts of silicone oil, 12 parts of titanium dioxide agitation grinding are configured to the bottom coating of white；By parts by weight
For 17 parts of modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.8 part of fluorescent pigment, 30 parts of fluorocarbon resin, 10 parts of solidification
Noctilucent coating is made in agent, 2 parts of anti-settling agent, 1 part of dispersant and 1.5 parts of defoamer agitation grinding；The bottom prepared is used
Coating application rolls up surface in stand-by aluminium, after drying, then brushing noctilucent coating.
Embodiment five：
It is with the difference of example IV, application aluminium weather resistant luminescent coating, including the modified aluminium that parts by weight are 20 parts
Acid alkaline earth metal system phosphorescent pigment, 0.5 part of fluorescent pigment, 30 parts of fluorocarbon resin, 3 parts of ethylene glycol, 1.5 parts of film forming help
The calcium carbonate that 12,7 part of agent alcohol ester, 5 parts of silicone oil, 13 parts of titanium dioxide, 19 parts of curing agent, 2 parts of anti-settling agent, 3 parts
Dispersant and 1.8 parts of defoamer.
Concentrated hydrochloric acid dosage 0.8ml in the preparation of modified aluminium acid alkaline earth metal system phosphorescent pigment；Per 110ml, clarification silica is molten
Dyestuff addition is 0.6g in glue；Aluminic acid alkaline-earth metal system phosphorescent pigment in the modified aluminium acid alkaline earth metal system phosphorescent pigment
For Sr4Al14O25:Eu、Dy。
Method using application aluminium with weather resistant luminescent coating, by 3 parts of ethylene glycol, 1.5 parts of coalescents alcohol ester ten
2nd, 7 parts of calcium carbonate, 5 parts of silicone oil, 13 parts of titanium dioxide agitation grinding are configured to the bottom coating of white；By parts by weight
For 20 parts of modified aluminium acid alkaline earth metal system phosphorescent pigment, 0.5 part of fluorescent pigment, 30 parts of fluorocarbon resin, 19 parts of solidification
Noctilucent coating is made in agent, 2 parts of anti-settling agent, 3 parts of dispersant and 1.8 parts of defoamer agitation grinding；The bottom prepared is used
Coating application rolls up surface in stand-by aluminium, after drying, then brushing noctilucent coating.
The performance of embodiment one to five such as following table：
For the performance of luminescent coating, covering power requirement≤300g/m2, solids content >=45%, drying time≤2 are small
When, in a reservoir without caking, after stirring uniformly, resistance to congealing property reach without foaming peelings, crackle, powder phenomenon-tion be for 20 times it is qualified,
It can be seen that using luminescent coating made of the manner on property indices it is qualified.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (4)
1. application aluminium weather resistant luminescent coating, it is characterised in that including the modification alkali aluminate soil gold that parts by weight are 10~25 parts
Category system phosphorescent pigment, 0.3~0.8 part of fluorescent pigment, 30~40 parts of fluorocarbon resin, 1~3 part of ethylene glycol, 1~2 part
The calcium carbonate that 12,5~10 part of coalescents alcohol ester, 1~7 part of silicone oil, 10~15 parts of titanium dioxide, 10~25 parts of solidification
Agent, 1~3 part of anti-settling agent, 1~5 part of dispersant and 1~2 part of defoamer.
2. application aluminium weather resistant luminescent coating according to claim 1, it is characterised in that the modified alkali aluminate soil gold
Preparing for category system phosphorescent pigment is as follows：After 10ml tetraethyl orthosilicates are well mixed with 100ml absolute ethyl alcohols, add 1.8ml and go
Ionized water, lasting stirring, make it well mixed；0.2-1.0ml concentrated hydrochloric acids are added after 20min, stir 60min, obtain clarifying oxygen
SiClx colloidal sol；Aluminic acid alkaline-earth metal system phosphorescent pigment is added in silica sol is clarified, continues to stir 60min, obtains colour
Colloidal sol；Wherein, per 110ml, dyestuff addition is 0.1-1.0g in clarification silica sol；The modified aluminium acid alkaline earth metal system
Aluminic acid alkaline-earth metal system phosphorescent pigment in phosphorescent pigment is SrAl2O4:Eu, Dy or SrAl2O4:Eu or Sr4Al14O25:Eu、Dy。
3. application aluminium weather resistant luminescent coating according to claim 1, it is characterised in that the anti-settling agent is organic illiteracy
De- soil, the dispersant is polycarboxylate, and the defoamer is organic silicon defoamer；The curing agent is aliphatic hexa-methylene
Diisocyanate or biuret.
4. the application method of a kind of application aluminium weather resistant luminescent coating as described in Claims 1-4, it is characterised in that by 1
~3 parts of ethylene glycol, the calcium carbonate of 1~2 part of 12,5~10 parts of coalescents alcohol ester, 1~7 part of silicone oil, 10~15 parts
Titanium dioxide agitation grinding be configured to white bottom coating；By the modified aluminium acid alkaline earth metal system that parts by weight are 10~25 parts
Phosphorescent pigment, 0.3~0.8 part of fluorescent pigment, 30~40 parts of fluorocarbon resin, 10~25 parts of curing agent, 1~3 part anti-
Noctilucent coating is made in heavy agent, 1~5 part of dispersant and 1~2 part of defoamer agitation grinding；The bottom prepared is applied with coating
Brush and roll up surface in stand-by aluminium, after drying, then brushing noctilucent coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710593865.7A CN107502078A (en) | 2017-07-20 | 2017-07-20 | Application aluminium weather resistant luminescent coating and its application method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710593865.7A CN107502078A (en) | 2017-07-20 | 2017-07-20 | Application aluminium weather resistant luminescent coating and its application method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502078A true CN107502078A (en) | 2017-12-22 |
Family
ID=60679895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710593865.7A Pending CN107502078A (en) | 2017-07-20 | 2017-07-20 | Application aluminium weather resistant luminescent coating and its application method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107502078A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108335799A (en) * | 2018-04-17 | 2018-07-27 | 温州大学 | It is a kind of to utilize electrified wire made of phosphor material powder |
| CN112679999A (en) * | 2020-12-29 | 2021-04-20 | 长沙族兴新材料股份有限公司 | Aluminum pigment for fluorocarbon powder coating and preparation method thereof |
| CN113845804A (en) * | 2021-11-18 | 2021-12-28 | 广东电网有限责任公司 | Energy storage type luminous paint and preparation method thereof |
| CN113956753A (en) * | 2021-11-25 | 2022-01-21 | 广东电网有限责任公司 | Energy-storage environment-friendly water-based luminescent coating and preparation method thereof |
| CN113999561A (en) * | 2021-11-19 | 2022-02-01 | 广东电网有限责任公司 | Double-layer energy-storage luminescent coating and preparation method thereof |
| CN114591643A (en) * | 2020-12-07 | 2022-06-07 | Oppo广东移动通信有限公司 | Luminescent coating, preparation method thereof, shell assembly and electronic equipment |
| CN115216183A (en) * | 2022-08-25 | 2022-10-21 | 杭州映山花颜料化工有限公司 | Storage-stable organic yellow pigment and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845217A (en) * | 2010-05-11 | 2010-09-29 | 陕西科技大学 | Preparation method of water-based polyurethane/nano-silicon dioxide composite emulsion |
| CN104845463A (en) * | 2015-05-20 | 2015-08-19 | 浙江万丰摩轮有限公司 | Luminous safety hub and manufacturing method for same |
| CN106854410A (en) * | 2016-12-08 | 2017-06-16 | 安徽省阜阳闽安建材有限公司 | A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping |
-
2017
- 2017-07-20 CN CN201710593865.7A patent/CN107502078A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101845217A (en) * | 2010-05-11 | 2010-09-29 | 陕西科技大学 | Preparation method of water-based polyurethane/nano-silicon dioxide composite emulsion |
| CN104845463A (en) * | 2015-05-20 | 2015-08-19 | 浙江万丰摩轮有限公司 | Luminous safety hub and manufacturing method for same |
| CN106854410A (en) * | 2016-12-08 | 2017-06-16 | 安徽省阜阳闽安建材有限公司 | A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108335799A (en) * | 2018-04-17 | 2018-07-27 | 温州大学 | It is a kind of to utilize electrified wire made of phosphor material powder |
| CN114591643A (en) * | 2020-12-07 | 2022-06-07 | Oppo广东移动通信有限公司 | Luminescent coating, preparation method thereof, shell assembly and electronic equipment |
| CN114591643B (en) * | 2020-12-07 | 2023-03-24 | Oppo广东移动通信有限公司 | Luminescent coating, preparation method thereof, shell assembly and electronic equipment |
| CN112679999A (en) * | 2020-12-29 | 2021-04-20 | 长沙族兴新材料股份有限公司 | Aluminum pigment for fluorocarbon powder coating and preparation method thereof |
| CN112679999B (en) * | 2020-12-29 | 2022-07-19 | 长沙族兴新材料股份有限公司 | Aluminum pigment for fluorocarbon powder coating and preparation method thereof |
| CN113845804A (en) * | 2021-11-18 | 2021-12-28 | 广东电网有限责任公司 | Energy storage type luminous paint and preparation method thereof |
| CN113999561A (en) * | 2021-11-19 | 2022-02-01 | 广东电网有限责任公司 | Double-layer energy-storage luminescent coating and preparation method thereof |
| CN113956753A (en) * | 2021-11-25 | 2022-01-21 | 广东电网有限责任公司 | Energy-storage environment-friendly water-based luminescent coating and preparation method thereof |
| CN113956753B (en) * | 2021-11-25 | 2022-08-12 | 广东电网有限责任公司 | Energy-storage environment-friendly water-based luminescent coating and preparation method thereof |
| CN115216183A (en) * | 2022-08-25 | 2022-10-21 | 杭州映山花颜料化工有限公司 | Storage-stable organic yellow pigment and preparation method thereof |
| CN115216183B (en) * | 2022-08-25 | 2023-11-07 | 杭州映山花颜料化工有限公司 | Storage-stable organic yellow pigment and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107502078A (en) | Application aluminium weather resistant luminescent coating and its application method | |
| CN101067062B (en) | High performance outer wall paint preparation method | |
| CN102786229B (en) | There is glass or the crystallized glass article of decorative coveringn | |
| CN107573845B (en) | A kind of extra-weather-proof type cracking resistance anticorrosive paint of organosilicon | |
| WO2003102091A1 (en) | Photocatalytic coating material, photocatalytic composite material and process for producing the same, self-cleaning water-based coating compositions, and self-cleaning member | |
| CN108822604A (en) | A kind of coating composition, automatically cleaning water nano coating and structural body | |
| JP4058822B2 (en) | Selective permeable membrane coating solution, selective permeable membrane and selective permeable multilayer membrane | |
| CN1696219A (en) | Environmental protection type Nano Coating | |
| WO2010018852A1 (en) | Coating compositions and articles with formed coating films | |
| CN105754381B (en) | A kind of nanometer anti-reflection coating liquid and its preparation method and application | |
| TW201141968A (en) | Improved low titanium dioxide coatings | |
| WO2013065801A1 (en) | Method for producing article with low reflection film | |
| CN103436249A (en) | Organic silicon wrapped fluorescent powder for light emitting coating and preparation method and application thereof | |
| CN101240135B (en) | Simple painted metal imitation fluorocarbon paint | |
| CN101845254B (en) | Elastic aqueous fluorocarbon paint for external walls | |
| WO2021200135A9 (en) | Method for producing zirconia-coated titanium oxide microparticles, zirconia-coated titanium oxide microparticles and use thereof | |
| CN104845463B (en) | Luminous safety hub and manufacturing method for same | |
| DE102012022731A1 (en) | Highly abrasion-resistant anti-limestone layers with high chemical resistance | |
| CN114479528B (en) | Ceramic coating capable of being constructed at normal temperature and low in unit consumption and preparation and application methods thereof | |
| CN111138112B (en) | Natural stone imitation layer, photovoltaic building material and preparation method thereof | |
| CN107828323B (en) | Metal-like coating for building exterior wall and preparation method thereof | |
| WO2005063645A1 (en) | Substrates with a transparent, reflecting metal oxide partial coating, production and use thereof | |
| CN115895425B (en) | White camouflage paint, preparation method thereof and application thereof in snow camouflage | |
| CN108587334B (en) | High-adhesion and static-conducting water-based reflective heat-insulating coating for storage tank and preparation method thereof | |
| CN109504203B (en) | Color-light water-based functional coating suitable for indoor entertainment and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171222 |