CN105967579A - Self-cleaning water permeable brick containing Chinese herbal medicines and manufacturing method thereof - Google Patents
Self-cleaning water permeable brick containing Chinese herbal medicines and manufacturing method thereof Download PDFInfo
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- CN105967579A CN105967579A CN201610152136.3A CN201610152136A CN105967579A CN 105967579 A CN105967579 A CN 105967579A CN 201610152136 A CN201610152136 A CN 201610152136A CN 105967579 A CN105967579 A CN 105967579A
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- CN
- China
- Prior art keywords
- permeable brick
- water permeable
- water
- chinese herbal
- containing chinese
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/24—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
- C04B18/248—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork from specific plants, e.g. hemp fibres
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a self-cleaning water permeable brick containing Chinese herbal medicines. After carbonization treatment, carbonized grapefruit peel, clove and pericarpium granati are ground at room temperature; the pore surface adsorbs a photocatalytic material nanometer titania; and light irradiation is conducted to generate hydroxyl radical, super-oxygen ion free radical and H2O free radical which have strong capacity of oxidization and decomposition to directly oxidize various organic matter into inorganic micomolecules such as CO2 and H2O, etc. By applying the above product into a water permeable brick, the obtained water permeable brick can degrade automobile exhaust and the like in the atmosphere. In addition, the water permeable brick also has strong antibacterial purification effects and can effectively remove pollutants in sewage. Modified sugar filter mud is used as a pore-forming agent, and high bauxite, aventurine feldspar and furnace kiln dust are used as aggregate. The water permeable brick prepared after high-temperature sintering of the materials has large porosity, excellent self-cleaning effect, high strength, high density and environmental protection performance of purification and sterilization, etc.
Description
Technical field
The present invention relates to building material technical field, particularly relate to a kind of automatically cleaning water-permeable brick containing Chinese herbal medicine and preparation method thereof.
Background technology
Along with the continuous plaque of city water resource is weary, and the pursuit of urban environment hommization, the research and development of water-permeable brick cause material, environment and the extensive concern of municipal works expert.Water-permeable brick has good seepage of water and moisture retention, can well alleviate city and cover, owing to being mated formation by non-pervious surface, " the city desertification " and " tropical island effect " caused, urban waterlogging can also be alleviated to a certain extent, supplement urban groundwater, regulation urban environment, is conducive to keeping city water balance.Existing water-permeable brick develops to high compact, high intensity direction, its comprcssive strength is higher, but still there is many defects, on the one hand it is that water penetration is excessively poor, even if there being the fragment of brick that water permeability is good, but its comprcssive strength does not reaches paving requirement, water-permeable brick is through life-time service simultaneously, surface and hole are easy to fall into various dirt and form blocking and can not automatically remove, weakening permeable effect, ecological effect is poor, and higher to the requirement of pumping equipment in use, occur as run into the situation of impeded drainage after rain, be then easily generated hydrops problem.The water-permeable brick function that the most existing technology produces is the most single, and they are simply to make precipitation pass through brick body to permeate the ground, it is impossible to effectively remove contained pollutant in water, the sewage through brick body is not had purification.For solving these problems, need to develop a kind of novel while there is permeable and purification function automatically cleaning water-permeable brick.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of automatically cleaning water-permeable brick containing Chinese herbal medicine and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of automatically cleaning water-permeable brick containing Chinese herbal medicine, is prepared by the raw materials in: alumine 32-34, sunstone 22-24, stove ash 27-29, cement 9-11, sugar filter mud 17-19, para arrowroot slurry 7-9, BBP(Butyl Benzyl Phthalate 4-6, chitosan 1.8-2.1, nano titanium oxide 0.4-0.6, carbon fiber 2-4, ammonium sulfite 0.7-0.9, Citrua paradiai skin 6-8, Flos Caryophylli 2-3, Pericarpium Granati 1-3, suitable quantity of water.
The manufacture method of described a kind of automatically cleaning water-permeable brick containing Chinese herbal medicine, comprises the following steps:
(1) Citrua paradiai skin, Flos Caryophylli, Pericarpium Granati are dried and put in retort at a temperature of 450-500 DEG C, isolation air carbonization 20-30 minute, it is cooled to that room temperature adds nano titanium oxide, chitosan, carbon fiber grind 40-50 minute;
(2) dry at a temperature of 50-60 DEG C after sugar filter mud being washed, send into and high-speed mixer adds para arrowroot slurry, BBP(Butyl Benzyl Phthalate, ammonium sulfite and appropriate water, turning/speed high-speed stirred 15-20 minute of min with 1400-1500, be dried, ultrasonic grinding becomes powder to dry;
(3) alumine, sunstone, stove ash are crushed to 120-140 mesh after 750-820 DEG C of high-temperature calcination processes, add step (1), (2) material and the mixing of other residual componentss, putting into ball milling 2-3 hour in ball mill, water spray pelletize, ageing are pressed into raw adobe after 2 days;
(4) life adobe natural drying is air-dried, sinter 1-2 hour in 1060-1100 DEG C in chamber type electric resistance furnace, naturally cool to room temperature discharging.
The invention have the advantage that the present invention after Citrua paradiai skin, Flos Caryophylli, Pericarpium Granati carbonization are processed through grinding at room temperature, pore surface adsorption photochemical catalysis material nano titanium dioxide, generation hydroxyl radical free radical, Superoxide anion free radical and H when light irradiates2O free radical is respectively provided with the strongest oxidation, capacity of decomposition, is CO by various Organic substance direct oxidations2And H2The inorganic molecules such as O, it is applied in water-permeable brick be possible not only to the vehicle exhaust etc. in air of degrading, also there is stronger antibacterial purifying effect, effectively remove the pollutant in sewage, with modified sugars filter mud as pore former, alumine, sunstone, stove ash are aggregate, and the water-permeable brick porosity big automatically cleaning effect prepared after high temperature sintering is excellent, has the environmental-protecting performances such as high intensity, high density, purification and sterilization.
Detailed description of the invention
A kind of automatically cleaning water-permeable brick containing Chinese herbal medicine, is prepared by the raw materials in: alumine 32, sunstone 22, stove ash 27, cement 9, sugar filter mud 17, para arrowroot slurry 7, BBP(Butyl Benzyl Phthalate 4, chitosan 1.8, nano titanium oxide 0.4, carbon fiber 2, ammonium sulfite 0.7, Citrua paradiai skin 6, Flos Caryophylli 2, Pericarpium Granati 1, suitable quantity of water.
The manufacture method of described a kind of automatically cleaning water-permeable brick containing Chinese herbal medicine, comprises the following steps:
(1) Citrua paradiai skin, Flos Caryophylli, Pericarpium Granati are dried and put in retort at a temperature of 450 DEG C, isolation air carbonization 20 minutes, it is cooled to that room temperature adds nano titanium oxide, chitosan, carbon fiber grind 40 minutes;
(2) drying at a temperature of 50 DEG C after being washed by sugar filter mud, send into and add para arrowroot slurry, BBP(Butyl Benzyl Phthalate, ammonium sulfite and appropriate water in high-speed mixer, with the speed high-speed stirred 15 minutes of 1400 turns/min, be dried, ultrasonic grinding becomes powder to dry;
(3) alumine, sunstone, stove ash are crushed to 120 mesh after 750 DEG C of high-temperature calcinations process, add step (1), (2) material and the mixing of other residual componentss, putting into ball milling 2 hours in ball mill, water spray pelletize, ageing are pressed into raw adobe after 2 days;
(4) life adobe natural drying is air-dried, sinter 1 hour in 1060 DEG C in chamber type electric resistance furnace, naturally cool to room temperature discharging.
The technical parameter index using the automatically cleaning water-permeable brick of present invention production is as follows: the comprcssive strength of water-permeable brick is up to 35.5 MPa, and rupture strength reaches 3.55MPa, and coefficient of permeability is 0.55cm/s.
Claims (2)
1. the automatically cleaning water-permeable brick containing Chinese herbal medicine, it is characterized in that, be prepared by the raw materials in: alumine 32-34, sunstone 22-24, stove ash 27-29, cement 9-11, sugar filter mud 17-19, para arrowroot slurry 7-9, BBP(Butyl Benzyl Phthalate 4-6, chitosan 1.8-2.1, nano titanium oxide 0.4-0.6, carbon fiber 2-4, ammonium sulfite 0.7-0.9, Citrua paradiai skin 6-8, Flos Caryophylli 2-3, Pericarpium Granati 1-3, suitable quantity of water.
The manufacture method of a kind of automatically cleaning water-permeable brick containing Chinese herbal medicine the most according to claim 1, it is characterised in that comprise the following steps:
(1) Citrua paradiai skin, Flos Caryophylli, Pericarpium Granati are dried and put in retort at a temperature of 450-500 DEG C, isolation air carbonization 20-30 minute, it is cooled to that room temperature adds nano titanium oxide, chitosan, carbon fiber grind 40-50 minute;
(2) dry at a temperature of 50-60 DEG C after sugar filter mud being washed, send into and high-speed mixer adds para arrowroot slurry, BBP(Butyl Benzyl Phthalate, ammonium sulfite and appropriate water, turning/speed high-speed stirred 15-20 minute of min with 1400-1500, be dried, ultrasonic grinding becomes powder to dry;
(3) alumine, sunstone, stove ash are crushed to 120-140 mesh after 750-820 DEG C of high-temperature calcination processes, add step (1), (2) material and the mixing of other residual componentss, putting into ball milling 2-3 hour in ball mill, water spray pelletize, ageing are pressed into raw adobe after 2 days;
(4) life adobe natural drying is air-dried, sinter 1-2 hour in 1060-1100 DEG C in chamber type electric resistance furnace, naturally cool to room temperature discharging.
Priority Applications (1)
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CN201610152136.3A CN105967579A (en) | 2016-03-17 | 2016-03-17 | Self-cleaning water permeable brick containing Chinese herbal medicines and manufacturing method thereof |
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CN201610152136.3A CN105967579A (en) | 2016-03-17 | 2016-03-17 | Self-cleaning water permeable brick containing Chinese herbal medicines and manufacturing method thereof |
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CN105967579A true CN105967579A (en) | 2016-09-28 |
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CN201610152136.3A Pending CN105967579A (en) | 2016-03-17 | 2016-03-17 | Self-cleaning water permeable brick containing Chinese herbal medicines and manufacturing method thereof |
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Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102535725A (en) * | 2012-02-17 | 2012-07-04 | 大连工业大学 | Permeable bricks inlaid with nanometer titanium dioxide and preparation method thereof |
CN104841394A (en) * | 2015-04-22 | 2015-08-19 | 马鞍山市顺达环保设备有限公司 | Adsorbent for recovering carbon monoxide by modified straw and preparation method thereof |
-
2016
- 2016-03-17 CN CN201610152136.3A patent/CN105967579A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102535725A (en) * | 2012-02-17 | 2012-07-04 | 大连工业大学 | Permeable bricks inlaid with nanometer titanium dioxide and preparation method thereof |
CN104841394A (en) * | 2015-04-22 | 2015-08-19 | 马鞍山市顺达环保设备有限公司 | Adsorbent for recovering carbon monoxide by modified straw and preparation method thereof |
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Application publication date: 20160928 |
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