CN105951442B - A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof - Google Patents
A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof Download PDFInfo
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- CN105951442B CN105951442B CN201610437462.9A CN201610437462A CN105951442B CN 105951442 B CN105951442 B CN 105951442B CN 201610437462 A CN201610437462 A CN 201610437462A CN 105951442 B CN105951442 B CN 105951442B
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- bib
- hydrophobic
- air
- fabric
- base fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 104
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 57
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000835 fiber Substances 0.000 claims abstract description 36
- 229920000742 Cotton Polymers 0.000 claims abstract description 22
- -1 polypropylene Polymers 0.000 claims abstract description 22
- 108010022355 Fibroins Proteins 0.000 claims abstract description 20
- 239000004743 Polypropylene Substances 0.000 claims abstract description 18
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920001155 polypropylene Polymers 0.000 claims abstract description 18
- 102000014171 Milk Proteins Human genes 0.000 claims abstract description 16
- 108010011756 Milk Proteins Proteins 0.000 claims abstract description 16
- 235000021239 milk protein Nutrition 0.000 claims abstract description 16
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 16
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 12
- 238000001035 drying Methods 0.000 claims abstract description 10
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims abstract 6
- 239000010408 film Substances 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 230000004048 modification Effects 0.000 claims description 16
- 238000012986 modification Methods 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 230000009471 action Effects 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 8
- 238000009941 weaving Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010409 thin film Substances 0.000 claims description 2
- 235000012054 meals Nutrition 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 2
- 230000003385 bacteriostatic effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 11
- PZJJKWKADRNWSW-UHFFFAOYSA-N trimethoxysilicon Chemical compound CO[Si](OC)OC PZJJKWKADRNWSW-UHFFFAOYSA-N 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 235000013305 food Nutrition 0.000 description 4
- 230000003115 biocidal effect Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 241001116389 Aloe Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 235000011399 aloe vera Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000774 hypoallergenic effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000002355 dual-layer Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/20—Protein-derived artificial fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin, including bib base fabric and nano finishing layer, bib base fabric is two-sided tissue, the upper surface of the bib base fabric is made of hydrophobic, air-permeability polypropylene fibre and cotton fiber, the lower surface of the bib base fabric is made of milk protein fiber and cotton fiber, nano finishing layer is covered in the upper surface of bib base fabric, the nano finishing layer includes the upper and lower, upper strata is made of octyl group trimethoxy silane and fibroin, and lower floor is made of nano-titanium dioxide and nano silicon dioxide.Bib fabric prepared by the present invention has the effect of hydroscopic fast-drying, hydrophobic, air-permeability, antibacterial bacteriostatic, pro-skin skin care, can solve the problems, such as at the same time various when children have a meal, and feature is good.
Description
Technical field
The invention belongs to textile material technical field, and in particular to a kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and its
Preparation method.
Background technology
Swill can be always stained with clothes, eat one by children when just starting and having a meal or learned to have a meal
Meal will change body clothes, very increase the burden of adult.Children splash swill on clothes in order to prevent on the market at present,
Will more there is the Seereo bib directly using silica gel or plastic material to cloth bib is placed on the neck of children.Silica gel or
The Seereo bib of plastic material does not absorb water, easy to clean, can catch the splashing that food reduces food, but weight weight, aggravates baby
The burden of youngster's nose, the food that the liquids such as gap, soup are left at bib and neckline are easily fallen into and airtight, food
Meeting long-time and skin contact, be easy to cause the discomfort of the tender and lovely skin of children.
A kind of manufacture craft of bib disclosed in Chinese patent CN 1923070B, non-woven fabrics, wood pulp paper and PE films are utilized
Hot melt adhesive is once-combined to be sticked together, forms bib composite material, then be fabricated to through cutting out and installing self-adhesive paper or parting compound adhesive
Bib.A kind of baby bibs disclosed in Chinese patent CN 103082426A, bib use three shell fabrics, are respectively that bamboo charcoal is fine
Dimension, flexible film plastics and non-woven fabrics are formed, and trilaminate material is combined using sewing process.Chinese patent CN
Antibacterial skin-care bib for babies disclosed in 102885409A, contains base fabric, aloe vitamin skin care cloth and antibacterial in the Baby bibs
Anti-mite hypo-allergenic cloth, aloe vitamin skin care cloth are located at neckline, and the hypo-allergenic cloth of antibiosis anti-acarien is located at the upper surface of base fabric.By upper
State the prior art to understand, in order to increase the feature of bib, bib water repellency is assigned by adding hydrophobic film, by compound anti-
Bacterium skin-protecting function fabric assigns the performance of bib antibiotic skin-care, but the feature of the bib prepared is more single, it is difficult at the same time
Solve the problems, such as various when children have a meal.
The present invention prepares double-layer fabric by regarding the improved polypropylene of hydrophobic, air-permeability and cotton fiber as raw material, and to dual-layer face
Material carries out nano-functional material modification, obtains a kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin.
The content of the invention
Bib fabric and its preparation side the technical problem to be solved in the present invention is to provide a kind of hydrophobic, air-permeability antibacterial pro-skin
Method, base fabric is formed using hydrophobic, air-permeability polypropylene fibre, milk protein fiber and cotton fiber as raw material through two-sided weave, then through receiving
The arrangement successively of rice titanium dioxide and nano silicon dioxide, octyl group trimethoxy silane and fibroin, obtains hydrophobic, air-permeability and resists
The bib fabric of bacterium pro-skin.Bib fabric prepared by the present invention can disposably solve the problems, such as it is various when children have a meal, it is light, dredge
Water, oleophylic, quick-drying of breathing freely, pro-skin skin care.
In order to solve the above technical problems, the technical scheme is that：
A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin, the bib fabric of the hydrophobic, air-permeability antibacterial pro-skin include bib
Base fabric and nano finishing layer, the bib base fabric are made of hydrophobic, air-permeability polypropylene fibre, milk protein fiber and cotton fiber, the nanometer
Finish layer includes nano-titanium dioxide, nano silicon dioxide, octyl group trimethoxy silane and fibroin.
As the preferred of above-mentioned technical proposal, the bib base fabric is two-sided tissue, the upper surface of the bib base fabric by
Hydrophobic, air-permeability polypropylene fibre and cotton fiber are formed, and the lower surface of the bib base fabric is made of milk protein fiber and cotton fiber, described
Nano finishing layer is covered in the upper surface of bib base fabric, and the nano finishing layer includes the upper and lower, and upper strata is by octyl group front three
Oxysilane and fibroin are formed, and lower floor is made of nano-titanium dioxide and nano silicon dioxide.
The present invention also provides a kind of preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin, comprise the following steps：
(1) adopted hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn
With the two-sided setup action institutional framework of six pieces of satin weaves, weaving obtains bib base fabric；
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source and irradiates, in bib base fabric
The solution of upper surface coated with nano titanium dioxide and nano silicon dioxide, then be placed under ultraviolet source and irradiate, take out, washing, from
So dry, obtain modified bib base fabric；
(3) the bib scrim surfaces coating octyl group trimethoxy silane for the modification for preparing step (2) and fibroin are molten
Liquid, stands, is cleaned with being impregnated in ethanol solution, washes, and drying, obtains the bib fabric of hydrophobic, air-permeability antibacterial pro-skin.
As the preferred of above-mentioned technical proposal, in the step (1), the arrangement ratio of upper warp thread and lower warp thread in bib base fabric
For 1:1.
As the preferred of above-mentioned technical proposal, in the step (1), bib base fabric through it is close be 480-520 roots/10cm,
Filling density is 580-600 roots/10cm.
As the preferred of above-mentioned technical proposal, in the step (2), the irradiation intensity of ultraviolet source is 180-250W/m2,
Irradiation time is 20-50min.
As the preferred of above-mentioned technical proposal, in the step (2), the solution of nano-titanium dioxide and nano silicon dioxide
The mass fraction of middle nano-titanium dioxide is 2-6%, and the mass fraction of nano silicon dioxide is 3-5%.
As the preferred of above-mentioned technical proposal, in the step (2), modified bib scrim surfaces nano-titanium dioxide and
The thickness of nanometer titanium dioxide silicon thin film is 0.5-1mm.
As the preferred of above-mentioned technical proposal, in the step (3), in octyl group trimethoxy silane and fibroin solutions
The mass fraction of octyl group trimethoxy silane is 1-3%, and the mass fraction of fibroin is 3-7%.
As the preferred of above-mentioned technical proposal, in the step (3), the bib web surface of hydrophobic, air-permeability antibacterial pro-skin is thin
The gross thickness of film is 2-2.5mm.
Compared with prior art, the invention has the advantages that：
(1) base fabric of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin prepared by the present invention includes the polypropylene fibre fibre of hydrophobic, air-permeability
Dimension, milk protein fiber and cotton fiber, the soft texture of the polypropylene fiber of hydrophobic, air-permeability, fluffy plentiful, nontoxicity are hydrophobic
Gas, can prevent spoon meat from permeating, and keep the neat and tidy of children's skin, contain amino acid, pro-skin in milk protein fiber
Skin care performance is good, but also breathes freely, leads wet, refreshing body, and cotton fiber is bibulous natural fiber, and the polypropylene fibre of hydrophobic, air-permeability is fine
Peacekeeping cotton fiber woven can prevent runny immersion skin as upper surface, by under milk fibre and cotton fiber woven
Surface and skin contact, skin are dry and comfortable comfortable.
(2) the nano finishing layer of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin prepared by the present invention includes nanometer titanium dioxide
Titanium-silica finish layer and octyl group trimethoxy silane and fibroin finish layer, nano-titanium dioxide-silica arrange
Layer can assign bib fabric antibiotic property, ultraviolet-resistent property and water lock, and octyl group trimethoxy silane and fibroin finish layer can
To assign bib fabric oleophylic performance and skin-friendly.
(3) oil and water can be firmly attached to fabric by the bib fabric of hydrophobic, air-permeability antibacterial pro-skin prepared by the present invention
Surface, prevent low, but fabric inner layer will not be infiltrated through, keep the dry and comfortable of skin, and bib fabric is thoroughly soft, pro-skin,
Nontoxic, ventilative, wearing comfort is good.
Embodiment
Below in conjunction with specific embodiment, the present invention will be described in detail, herein illustrative examples and explanation of the invention
For explaining the present invention, but it is not as a limitation of the invention.
Embodiment 1：
(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn, on
The arrangement of warp thread and lower warp thread is compared for 1:1, using the two-sided setup action institutional framework of six pieces of satin weaves, with 480/10cm through close
With the filling density of 580/10cm, weaving obtains bib base fabric.
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source, in 180W/m2Lower irradiation
20min, the nanometer that the nano-titanium dioxide and mass fraction for being 2% in the upper surface coating quality fraction of bib base fabric are 3%
The solution of silica, then in 180W/m2Lower irradiation 20min, takes out, and washing, naturally dry, it is 0.5mm to obtain film thickness
Modification bib base fabric.
(3) the bib scrim surfaces coating quality fraction for the modification for preparing step (2) is 1% octyl group trimethoxy silicon
Alkane and the fibroin solutions that mass fraction is 3%, stand, are cleaned with being impregnated in ethanol solution, washed, drying, obtains thin
The gross thickness of film is the bib fabric of the hydrophobic, air-permeability antibacterial pro-skin of 2mm.
Embodiment 2：
(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn, on
The arrangement of warp thread and lower warp thread is compared for 1:1, using the two-sided setup action institutional framework of six pieces of satin weaves, with 520/10cm through close
With the filling density of 600/10cm, weaving obtains bib base fabric.
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source, in 250W/m2Lower irradiation
50min, the nanometer that the nano-titanium dioxide and mass fraction for being 6% in the upper surface coating quality fraction of bib base fabric are 5%
The solution of silica, then in 1250W/m2Lower irradiation 50min, takes out, washing, naturally dry, and it is 1mm's to obtain film thickness
Modified bib base fabric.
(3) the bib scrim surfaces coating quality fraction for the modification for preparing step (2) is 3% octyl group trimethoxy silicon
Alkane and the fibroin solutions that mass fraction is 7%, stand, are cleaned with being impregnated in ethanol solution, washed, drying, obtains thin
The gross thickness of film is the bib fabric of the hydrophobic, air-permeability antibacterial pro-skin of 2.5mm.
Embodiment 3：
(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn, on
The arrangement of warp thread and lower warp thread is compared for 1:1, using the two-sided setup action institutional framework of six pieces of satin weaves, with 500/10cm through close
With the filling density of 590/10cm, weaving obtains bib base fabric.
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source, in 200W/m2Lower irradiation
30min, the nanometer that the nano-titanium dioxide and mass fraction for being 3% in the upper surface coating quality fraction of bib base fabric are 4%
The solution of silica, then in 2000W/m2Lower irradiation 30min, takes out, and washing, naturally dry, it is 0.6mm to obtain film thickness
Modification bib base fabric.
(3) the bib scrim surfaces coating quality fraction for the modification for preparing step (2) is 2% octyl group trimethoxy silicon
Alkane and the fibroin solutions that mass fraction is 4%, stand, are cleaned with being impregnated in ethanol solution, washed, drying, obtains thin
The gross thickness of film is the bib fabric of the hydrophobic, air-permeability antibacterial pro-skin of 2.2mm.
Embodiment 4：
(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn, on
The arrangement of warp thread and lower warp thread is compared for 1:1, using the two-sided setup action institutional framework of six pieces of satin weaves, with 510/10cm through close
With the filling density of 595/10cm, weaving obtains bib base fabric.
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source, in 230W/m2Lower irradiation
40min, the nano-titanium dioxide and mass fraction that are 5% in the upper surface coating quality fraction of bib base fabric are 3.5% to receive
The solution of rice silica, then in 230W/m2Lower irradiation 40min, takes out, and washing, naturally dry, obtaining film thickness is
The bib base fabric of the modification of 0.7mm.
(3) the bib scrim surfaces coating quality fraction for the modification for preparing step (2) is 2.5% octyl group trimethoxy
Silane and the fibroin solutions that mass fraction is 5.5%, stand, are cleaned with being impregnated in ethanol solution, washed, drying, obtains
The bib fabric for the hydrophobic, air-permeability antibacterial pro-skin that gross thickness to film is 2.4mm.
Embodiment 5：
(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn, on
The arrangement of warp thread and lower warp thread is compared for 1:1, using the two-sided setup action institutional framework of six pieces of satin weaves, with 520/10cm through close
With the filling density of 580/10cm, weaving obtains bib base fabric.
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source, in 220W/m2Lower irradiation
20min, the nanometer that the nano-titanium dioxide and mass fraction for being 5% in the upper surface coating quality fraction of bib base fabric are 5%
The solution of silica, then in 220W/m2Lower irradiation 20min, takes out, and washing, naturally dry, it is 0.8mm to obtain film thickness
Modification bib base fabric.
(3) the bib scrim surfaces coating quality fraction for the modification for preparing step (2) is 1.5% octyl group trimethoxy
Silane and the fibroin solutions that mass fraction is 6%, stand, are cleaned with being impregnated in ethanol solution, washed, drying, obtains
The gross thickness of film is the bib fabric of the hydrophobic, air-permeability antibacterial pro-skin of 2.3mm.
Embodiment 6：
(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber as lower warp thread, cotton fiber as weft yarn, on
The arrangement of warp thread and lower warp thread is compared for 1:1, using the two-sided setup action institutional framework of six pieces of satin weaves, with 510/10cm through close
With the filling density of 588/10cm, weaving obtains bib base fabric.
(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source, in 250W/m2Lower irradiation
20min, the nanometer that the nano-titanium dioxide and mass fraction for being 6% in the upper surface coating quality fraction of bib base fabric are 3%
The solution of silica, then in 180W/m2Lower irradiation 50min, takes out, and washing, naturally dry, it is 0.8mm to obtain film thickness
Modification bib base fabric.
(3) the bib scrim surfaces coating quality fraction for the modification for preparing step (2) is 2% octyl group trimethoxy silicon
Alkane and the fibroin solutions that mass fraction is 6%, stand, are cleaned with being impregnated in ethanol solution, washed, drying, obtains thin
The gross thickness of film is the bib fabric of the hydrophobic, air-permeability antibacterial pro-skin of 2.5mm.
After testing, the result of the wearability of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin prepared by embodiment 1-6 is as follows
It is shown：
As seen from the above table, the bib fabric of hydrophobic, air-permeability antibacterial pro-skin that prepared by the present invention is hydrophobic, ventilative, moisture absorption, heat conduction,
Take comfortable.
The above-described embodiments merely illustrate the principles and effects of the present invention, not for the limitation present invention.It is any ripe
Know the personage of this technology all can carry out modifications and changes under the spirit and scope without prejudice to the present invention to above-described embodiment.Cause
This, those of ordinary skill in the art is complete without departing from disclosed spirit and institute under technological thought such as
Into all equivalent modifications or change, should by the present invention claim be covered.
Claims (9)
- A kind of 1. bib fabric of hydrophobic, air-permeability antibacterial pro-skin, it is characterised in that：The bib face of the hydrophobic, air-permeability antibacterial pro-skin Material includes bib base fabric and nano finishing layer, and the bib base fabric is by hydrophobic, air-permeability polypropylene fibre, milk protein fiber and cotton fiber structure Into the nano finishing layer includes nano-titanium dioxide, nano silicon dioxide, octyl group trimethoxy silane and fibroin, institute It is two-sided tissue to state bib base fabric, and the upper surface of the bib base fabric is made of hydrophobic, air-permeability polypropylene fibre and cotton fiber, the bib The lower surface of base fabric is made of milk protein fiber and cotton fiber, and the nano finishing layer is covered in the upper surface of bib base fabric, The nano finishing layer includes the upper and lower, and upper strata is made of octyl group trimethoxy silane and fibroin, and lower floor is by nanometer Titanium dioxide and nano silicon dioxide are formed.
- A kind of 2. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin, it is characterised in that：Comprise the following steps：(1) using hydrophobic, air-permeability polypropylene fibre as upper warp thread, milk protein fiber is as lower warp thread, and cotton fiber is as weft yarn, using six Piece two-sided setup action institutional framework of satin weave, weaving obtain bib base fabric；(2) after the bib base fabric for preparing step (1) is fully dried, it is placed under ultraviolet source and irradiates, in the upper table of bib base fabric The solution of face coated with nano titanium dioxide and nano silicon dioxide, then be placed under ultraviolet source and irradiate, take out, washing, dries in the air naturally It is dry, obtain modified bib base fabric；(3) the bib scrim surfaces coating octyl group trimethoxy silane and fibroin solutions for the modification for preparing step (2), it is quiet Put, cleaned with being impregnated in ethanol solution, washed, drying, obtains the bib fabric of hydrophobic, air-permeability antibacterial pro-skin.
- A kind of 3. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (1), above the arrangement of warp thread and lower warp thread is compared for 1 in bib base fabric:1.
- A kind of 4. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (1), bib base fabric through it is close be 480-520 roots/10cm, filling density is 580-600 roots/10cm.
- A kind of 5. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (2), the irradiation intensity of ultraviolet source is 180-250W/m2, irradiation time 20-50min.
- A kind of 6. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (2), the mass fraction of nano-titanium dioxide is 2- in the solution of nano-titanium dioxide and nano silicon dioxide 6%, the mass fraction of nano silicon dioxide is 3-5%.
- A kind of 7. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (2), the thickness of modified bib scrim surfaces nano-titanium dioxide and nanometer titanium dioxide silicon thin film is 0.5- 1mm。
- A kind of 8. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (3), the mass fraction of octyl group trimethoxy silane is 1- in octyl group trimethoxy silane and fibroin solutions 3%, the mass fraction of fibroin is 3-7%.
- A kind of 9. preparation method of the bib fabric of hydrophobic, air-permeability antibacterial pro-skin according to claim 2, it is characterised in that： In the step (3), the gross thickness of the bib web surface film of hydrophobic, air-permeability antibacterial pro-skin is 2-2.5mm.
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| CN201610437462.9A CN105951442B (en) | 2016-06-16 | 2016-06-16 | A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof |
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| CN201610437462.9A CN105951442B (en) | 2016-06-16 | 2016-06-16 | A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof |
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| WO2019194146A1 (en) | 2018-04-03 | 2019-10-10 | Ｓｐｉｂｅｒ株式会社 | Molded article and method for production thereof |
| CN109137508A (en) * | 2018-07-18 | 2019-01-04 | 圣华盾防护科技股份有限公司 | Cotton fabric antibacterial and hydroscopic fast-drying method for sorting based on electronic beam irradiation technology |
| CN115821456A (en) * | 2022-12-23 | 2023-03-21 | 常州丁丁纺织科技有限公司 | Hydrophobic fabric |
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| CN2750681Y (en) * | 2004-10-13 | 2006-01-11 | 梁和凤 | Disposable bibs |
| CN101279103A (en) * | 2008-05-27 | 2008-10-08 | 徐国文 | Fibroin composite coating liquid and method of preparing the same and applications |
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| CN105951442A (en) | 2016-09-21 |
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