CN105951442A - Hydrophobic, breathable, antibacterial and skin-friendly bib fabric and preparation method thereof - Google Patents
Hydrophobic, breathable, antibacterial and skin-friendly bib fabric and preparation method thereof Download PDFInfo
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- CN105951442A CN105951442A CN201610437462.9A CN201610437462A CN105951442A CN 105951442 A CN105951442 A CN 105951442A CN 201610437462 A CN201610437462 A CN 201610437462A CN 105951442 A CN105951442 A CN 105951442A
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- Prior art keywords
- bib
- hydrophobic
- skin
- fabric
- permeability
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- 239000004744 fabric Substances 0.000 title claims abstract description 100
- 230000002209 hydrophobic effect Effects 0.000 title claims abstract description 58
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920000742 Cotton Polymers 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 22
- -1 polypropylene Polymers 0.000 claims abstract description 18
- 239000004743 Polypropylene Substances 0.000 claims abstract description 17
- 229920001155 polypropylene Polymers 0.000 claims abstract description 17
- 102000014171 Milk Proteins Human genes 0.000 claims abstract description 16
- 108010011756 Milk Proteins Proteins 0.000 claims abstract description 16
- 235000021239 milk protein Nutrition 0.000 claims abstract description 16
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 6
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 108010022355 Fibroins Proteins 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 16
- 238000005406 washing Methods 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 14
- 239000010409 thin film Substances 0.000 claims description 9
- 230000009471 action Effects 0.000 claims description 8
- 238000009941 weaving Methods 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 235000012054 meals Nutrition 0.000 abstract description 6
- 241000894006 Bacteria Species 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 230000002401 inhibitory effect Effects 0.000 abstract 1
- 235000018102 proteins Nutrition 0.000 abstract 1
- 102000004169 proteins and genes Human genes 0.000 abstract 1
- 108090000623 proteins and genes Proteins 0.000 abstract 1
- NMEPHPOFYLLFTK-UHFFFAOYSA-N trimethoxy(octyl)silane Chemical compound CCCCCCCC[Si](OC)(OC)OC NMEPHPOFYLLFTK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 23
- 239000000463 material Substances 0.000 description 13
- 239000010408 film Substances 0.000 description 10
- 235000013305 food Nutrition 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 4
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 4
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 241001116389 Aloe Species 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 2
- 235000011399 aloe vera Nutrition 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000774 hypoallergenic effect Effects 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 230000000680 avirulence Effects 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 235000013372 meat Nutrition 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000012460 protein solution Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D13/00—Woven fabrics characterised by the special disposition of the warp or weft threads, e.g. with curved weft threads, with discontinuous warp threads, with diagonal warp or weft
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2211/00—Protein-based fibres, e.g. animal fibres
- D10B2211/20—Protein-derived artificial fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
The invention provides a hydrophobic, breathable, antibacterial and skin-friendly bib fabric which comprises a bib base cloth and a nano finishing layer. The bib base cloth is of a double weave structure, the upper surface of the bib base cloth is composed of hydrophobic and breathable polypropylene fibers and cotton fibers, the lower surface of the bib base cloth is composed of milk protein fibers and cotton fibers, and the upper surface of the bib base cloth is covered with the nano finishing layer; the nano finishing layer comprises an upper layer and a lower layer, the upper layer is composed of trimethoxyoctylsilane and silk protein, and the lower layer is composed of nano-titanium dioxide and nano-silicon dioxide. The prepared bib fabric has the effects of being hydroscopic and fast dry, hydrophobic and breathable, capable of inhibiting and resisting bacteria, friendly to the skin and capable of protecting the skin, can solve various problems generated when a child has a meal and is good in functionality.
Description
Technical field
The invention belongs to textile material technical field, be specifically related to the bib face of the antibacterial pro-skin of a kind of hydrophobic, air-permeability
Material and preparation method thereof.
Background technology
Child, when just starting and having a meal or learned to have a meal, always can be stained with clothes food debris,
Eat a meal and will change body clothes, extremely increase the burden of adult.At present on the market in order to prevent child from will eat
Thing residue splashes on clothes, all can give on the neck of child and place cloth bib, more have directly use silica gel or
The Seereo bib of plastic material.The Seereo bib of silica gel or plastic material does not absorbs water, and easily cleans, and can connect
The firmly splashing of food minimizing food, but Heavy Weight, increase the weight of the burden of baby's nose, stay at bib and neckline
Have gap, the food of the liquid such as soup easily fall into into, and airtight, food can connect with skin for a long time
Touch, easily cause the discomfort of the tender and lovely skin of child.
The processing technology of a kind of bib disclosed in Chinese patent CN 1923070B, by non-woven fabrics, wood pulp paper and
PE film utilize PUR once-combined glutinous together, form bib composite, more do not do through cutting out and installing
Gummed paper or parting compound adhesive are fabricated to bib.A kind of baby bibs disclosed in Chinese patent CN 103082426A,
Bib uses three shell fabrics, respectively bamboo carbon fiber, flexible film plastics and non-woven fabrics to constitute, trilaminate material
Employing sewing process is composited.Antibacterial skin-care bib for babies disclosed in Chinese patent CN 102885409A,
Containing base fabric, Aloe vitamin skin protection cloth and the hypo-allergenic cloth of antibiosis anti-acarien, Aloe vitamin in this Baby bibs
Skin protection cloth is positioned at neckline, and the hypo-allergenic cloth of antibiosis anti-acarien is positioned at the upper surface of base fabric.Can by above-mentioned prior art
Know, in order to increase the functional of bib, give bib water repellency by adding hydrophobic film, by compound anti-
Bacterium skin-protecting function fabric gives the performance of bib antibiotic skin-care, but the bib of preparation is functional the most single
One, it is difficult to solve various problems when child has a meal simultaneously.
The present invention is by preparing double-layer fabric using the improved polypropylene of hydrophobic, air-permeability and cotton fiber as raw material and right
Double-layer fabric carries out nano-functional material modification, obtains the bib face of the antibacterial pro-skin of a kind of hydrophobic, air-permeability
Material.
Summary of the invention
The technical problem to be solved in the present invention is to provide bib fabric and the system thereof of the antibacterial pro-skin of a kind of hydrophobic, air-permeability
Preparation Method, uses hydrophobic, air-permeability polypropylene, milk protein fiber and cotton fiber as raw material through two-sided weave
Form base fabric, then through nano titanium oxide and nano silicon, octyl group trimethoxy silane and fibroin
Arrangement successively, obtain the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability.Bib fabric energy one prepared by the present invention
Various problems when secondary property solution child has a meal, light weight, hydrophobic, oleophylic, ventilative quick-drying, pro-skin skin protection.
For solving above-mentioned technical problem, the technical scheme is that
A kind of bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability, the bib fabric bag of the antibacterial pro-skin of described hydrophobic, air-permeability
Including bib base fabric and nano finishing layer, described bib base fabric is by hydrophobic, air-permeability polypropylene, milk protein fiber and cotton
Fiber is constituted, and described nano finishing layer includes nano titanium oxide, nano silicon, octyl group trimethoxy
Silane and fibroin.
Preferred as technique scheme, described bib base fabric is two-sided tissue, described bib base fabric upper
Surface is made up of hydrophobic, air-permeability polypropylene and cotton fiber, the lower surface of described bib base fabric by milk protein fiber and
Cotton fiber is constituted, and described nano finishing layer is covered in the upper surface of bib base fabric, and described nano finishing layer includes
The upper and lower, upper strata is made up of octyl group trimethoxy silane and fibroin, and lower floor is by nano titanium oxide
Constitute with nano silicon.
The present invention also provides for the preparation method of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability, including following step
Rapid:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, uses six pieces of satin weave two-sided setup action organizational structuries, weaving to obtain bib base fabric；
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source irradiation,
The upper surface coated with nano titanium dioxide of bib base fabric and the solution of nano silicon, then it is placed in ultraviolet source
Lower irradiation, takes out, and washing is dried naturally, obtains the bib base fabric of modification；
(3) the modified bib scrim surfaces coating octyl group trimethoxy silane prepared by step (2) and silkworm
Silk protein solution, stands, and cleans with impregnated in ethanol solution, and washing is dried, and obtains hydrophobic, air-permeability and resists
The bib fabric of bacterium pro-skin.
Preferred as technique scheme, in described step (1), upper warp thread and lower warp thread in bib base fabric
Arrangement than for 1:1.
Preferred as technique scheme, in described step (1), the end count of bib base fabric is 480-520
Root/10cm, filling density is 580-600 root/10cm.
Preferred as technique scheme, in described step (2), the irradiation intensity of ultraviolet source is
180-250W/m2, irradiation time is 20-50min.
Preferred as technique scheme, in described step (2), nano titanium oxide and nanometer titanium dioxide
In the solution of silicon, the mass fraction of nano titanium oxide is 2-6%, and the mass fraction of nano silicon is
3-5%.
Preferred as technique scheme, in described step (2), modified bib scrim surfaces nanometer two
The thickness of titanium oxide and nanometer titanium dioxide silicon thin film is 0.5-1mm.
Preferred as technique scheme, in described step (3), octyl group trimethoxy silane and silkworm silk egg
In white solution, the mass fraction of octyl group trimethoxy silane is 1-3%, and the mass fraction of fibroin is 3-7%.
Preferred as technique scheme, in described step (3), the bib face of the antibacterial pro-skin of hydrophobic, air-permeability
The gross thickness of material surface film is 2-2.5mm.
Compared with prior art, the method have the advantages that
(1) base fabric of the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability that prepared by the present invention includes the third of hydrophobic, air-permeability
Synthetic fibre fiber, milk protein fiber and cotton fiber, the quality of the polypropylene fiber of hydrophobic, air-permeability is soft, fluffy rich
Full, avirulence, hydrophobic, air-permeability, it is possible to prevent spoon meat to permeate, keeps the neat and tidy of child's skin,
Containing aminoacid in milk protein fiber, pro-skin skin protection performance is good, but also breathes freely, leads body wet, refreshing, cotton
Fiber is bibulous natural fiber, using the polypropylene fiber of hydrophobic, air-permeability and cotton fiber woven as upper surface
It is possible to prevent runny immersion skin, the lower surface of milk fibre and cotton fiber woven is connect with skin
Touching, skin is dry and comfortable comfortable.
(2) the nano finishing layer of the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability that prepared by the present invention includes nanometer two
Titania-silica finish layer and octyl group trimethoxy silane and fibroin finish layer, nanometer titanium dioxide
Titanium-silicon dioxide finish layer can give bib fabric antibiotic property, ultraviolet-resistent property and lock aqueous, octyl group front three
TMOS and fibroin finish layer can give bib fabric oleophylic performance and skin-friendly.
(3) oil and water can firmly be adhered to by the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability that prepared by the present invention
In the surface of fabric, prevent low, but fabric nexine will not be infiltrated through, keep the dry and comfortable of skin, and
Bib fabric is the softest, pro-skin, and nontoxic, ventilative, wearing comfort is good.
Detailed description of the invention
Describe the present invention in detail below in conjunction with specific embodiment, this present invention illustrative examples with
And explanation is used for explaining the present invention, but not as a limitation of the invention.
Embodiment 1:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, the arrangement of upper warp thread and lower warp thread, than for 1:1, uses six pieces of satin weave two-sided setup action knot of tissue
Structure, with end count and the filling density of 580/10cm of 480/10cm, weaving obtains bib base fabric.
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source, at 180W/m2
Lower irradiation 20min, in nano titanium oxide and the quality that upper surface coating quality mark is 2% of bib base fabric
Mark is the solution of the nano silicon of 3%, then at 180W/m2Lower irradiation 20min, takes out, washing, from
So dry, obtain the modified bib base fabric that film thickness is 0.5mm.
(3) the modified octyl group three that bib scrim surfaces coating quality mark is 1% prepared by step (2)
Methoxy silane and mass fraction are the fibroin solutions of 3%, stand, clear with impregnated in ethanol solution
Wash, washing, dry, obtain the bib fabric of the antibacterial pro-skin of the hydrophobic, air-permeability that gross thickness is 2mm of thin film.
Embodiment 2:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, the arrangement of upper warp thread and lower warp thread, than for 1:1, uses six pieces of satin weave two-sided setup action knot of tissue
Structure, with end count and the filling density of 600/10cm of 520/10cm, weaving obtains bib base fabric.
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source, at 250W/m2
Lower irradiation 50min, in nano titanium oxide and the quality that upper surface coating quality mark is 6% of bib base fabric
Mark is the solution of the nano silicon of 5%, then at 1250W/m2Lower irradiation 50min, takes out, washing,
Naturally dry, obtain the modified bib base fabric that film thickness is 1mm.
(3) the modified octyl group three that bib scrim surfaces coating quality mark is 3% prepared by step (2)
Methoxy silane and mass fraction are the fibroin solutions of 7%, stand, clear with impregnated in ethanol solution
Wash, washing, dry, obtain the bib face of the antibacterial pro-skin of the hydrophobic, air-permeability that gross thickness is 2.5mm of thin film
Material.
Embodiment 3:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, the arrangement of upper warp thread and lower warp thread, than for 1:1, uses six pieces of satin weave two-sided setup action knot of tissue
Structure, with end count and the filling density of 590/10cm of 500/10cm, weaving obtains bib base fabric.
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source, at 200W/m2
Lower irradiation 30min, in nano titanium oxide and the quality that upper surface coating quality mark is 3% of bib base fabric
Mark is the solution of the nano silicon of 4%, then at 2000W/m2Lower irradiation 30min, takes out, washing,
Naturally dry, obtain the modified bib base fabric that film thickness is 0.6mm.
(3) the modified octyl group three that bib scrim surfaces coating quality mark is 2% prepared by step (2)
Methoxy silane and mass fraction are the fibroin solutions of 4%, stand, clear with impregnated in ethanol solution
Wash, washing, dry, obtain the bib face of the antibacterial pro-skin of the hydrophobic, air-permeability that gross thickness is 2.2mm of thin film
Material.
Embodiment 4:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, the arrangement of upper warp thread and lower warp thread, than for 1:1, uses six pieces of satin weave two-sided setup action knot of tissue
Structure, with end count and the filling density of 595/10cm of 510/10cm, weaving obtains bib base fabric.
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source, at 230W/m2
Lower irradiation 40min, in nano titanium oxide and the quality that upper surface coating quality mark is 5% of bib base fabric
Mark is the solution of the nano silicon of 3.5%, then at 230W/m2Lower irradiation 40min, takes out, washing,
Naturally dry, obtain the modified bib base fabric that film thickness is 0.7mm.
(3) modified bib scrim surfaces coating quality mark step (2) prepared is the octyl group of 2.5%
Trimethoxy silane and mass fraction are the fibroin solutions of 5.5%, stand, with impregnated in ethanol solution
Clean, washing, dry, obtain the bib face of the antibacterial pro-skin of the hydrophobic, air-permeability that gross thickness is 2.4mm of thin film
Material.
Embodiment 5:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, the arrangement of upper warp thread and lower warp thread, than for 1:1, uses six pieces of satin weave two-sided setup action knot of tissue
Structure, with end count and the filling density of 580/10cm of 520/10cm, weaving obtains bib base fabric.
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source, at 220W/m2
Lower irradiation 20min, in nano titanium oxide and the quality that upper surface coating quality mark is 5% of bib base fabric
Mark is the solution of the nano silicon of 5%, then at 220W/m2Lower irradiation 20min, takes out, washing, from
So dry, obtain the modified bib base fabric that film thickness is 0.8mm.
(3) modified bib scrim surfaces coating quality mark step (2) prepared is the octyl group of 1.5%
Trimethoxy silane and mass fraction are the fibroin solutions of 6%, stand, clear with impregnated in ethanol solution
Wash, washing, dry, obtain the bib face of the antibacterial pro-skin of the hydrophobic, air-permeability that gross thickness is 2.3mm of thin film
Material.
Embodiment 6:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber conduct
Weft yarn, the arrangement of upper warp thread and lower warp thread, than for 1:1, uses six pieces of satin weave two-sided setup action knot of tissue
Structure, with end count and the filling density of 588/10cm of 510/10cm, weaving obtains bib base fabric.
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source, at 250W/m2
Lower irradiation 20min, in nano titanium oxide and the quality that upper surface coating quality mark is 6% of bib base fabric
Mark is the solution of the nano silicon of 3%, then at 180W/m2Lower irradiation 50min, takes out, washing, from
So dry, obtain the modified bib base fabric that film thickness is 0.8mm.
(3) the modified octyl group three that bib scrim surfaces coating quality mark is 2% prepared by step (2)
Methoxy silane and mass fraction are the fibroin solutions of 6%, stand, clear with impregnated in ethanol solution
Wash, washing, dry, obtain the bib face of the antibacterial pro-skin of the hydrophobic, air-permeability that gross thickness is 2.5mm of thin film
Material.
After testing, the knot of the wearability of the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability that prepared by embodiment 1-6
The most as follows:
As seen from the above table, the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability that prepared by the present invention is hydrophobic, ventilative, suction
Wet, heat conduction, takes comfortable.
The principle of above-described embodiment only illustrative present invention and effect thereof, not for limiting the present invention.
Above-described embodiment all can be entered by any person skilled in the art under the spirit and the scope of the present invention
Row is modified or changes.Therefore, art has usually intellectual such as without departing from institute of the present invention
All equivalences completed under the spirit disclosed and technological thought are modified or change, must be by the right of the present invention
Require to be contained.
Claims (10)
1. the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability, it is characterised in that: described hydrophobic, air-permeability
The bib fabric of antibacterial pro-skin includes bib base fabric and nano finishing layer, and described bib base fabric is by hydrophobic
Gas polypropylene, milk protein fiber and cotton fiber are constituted, and described nano finishing layer includes nanometer titanium dioxide
Titanium, nano silicon, octyl group trimethoxy silane and fibroin.
The bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 1, its feature
Being: described bib base fabric is two-sided tissue, the upper surface of described bib base fabric is by hydrophobic, air-permeability polypropylene
Constituting with cotton fiber, the lower surface of described bib base fabric is made up of milk protein fiber and cotton fiber, institute
State nano finishing layer and be covered in the upper surface of bib base fabric, described nano finishing layer include upper strata and under
Layer, upper strata is made up of octyl group trimethoxy silane and fibroin, and lower floor is by nano titanium oxide and receives
Rice silicon dioxide is constituted.
3. the preparation method of the bib fabric of the antibacterial pro-skin of hydrophobic, air-permeability, it is characterised in that: bag
Include following steps:
(1) using hydrophobic, air-permeability polypropylene as upper warp thread, milk protein fiber is as lower warp thread, cotton fiber
As weft yarn, six pieces of satin weave two-sided setup action organizational structuries, weaving are used to obtain bib base fabric；
(2) bib base fabric step (1) prepared is fully dried, is placed under ultraviolet source irradiation,
At upper surface coated with nano titanium dioxide and the solution of nano silicon of bib base fabric, then it is placed in purple
Irradiate under outer light source, take out, washing, naturally dry, obtain the bib base fabric of modification；
(3) the modified bib scrim surfaces coating octyl group trimethoxy silane prepared by step (2)
And fibroin solutions, standing, cleaning with impregnated in ethanol solution, washing, dry, dredged
The bib fabric of water air-permeable anti-bacterial pro-skin.
The preparation side of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (1), bib base fabric goes up the arrangement ratio of warp thread and lower warp thread
For 1:1.
The preparation side of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (1), the end count of bib base fabric is 480-520 root/10cm,
Filling density is 580-600 root/10cm.
The preparation side of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (2), the irradiation intensity of ultraviolet source is 180-250W/m2,
Irradiation time is 20-50min.
The preparation side of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (2), nano titanium oxide and the solution of nano silicon
The mass fraction of middle nano titanium oxide is 2-6%, and the mass fraction of nano silicon is 3-5%.
The preparation side of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (2), modified bib scrim surfaces nano titanium oxide and
The thickness of nanometer titanium dioxide silicon thin film is 0.5-1mm.
The preparation side of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (3), in octyl group trimethoxy silane and fibroin solutions
The mass fraction of octyl group trimethoxy silane is 1-3%, and the mass fraction of fibroin is 3-7%.
The preparation of the bib fabric of the antibacterial pro-skin of a kind of hydrophobic, air-permeability the most according to claim 3
Method, it is characterised in that: in described step (3), the bib web surface of the antibacterial pro-skin of hydrophobic, air-permeability
The gross thickness of thin film is 2-2.5mm.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610437462.9A CN105951442B (en) | 2016-06-16 | 2016-06-16 | A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof |
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| CN201610437462.9A CN105951442B (en) | 2016-06-16 | 2016-06-16 | A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof |
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| CN105951442B CN105951442B (en) | 2018-05-15 |
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| CN201610437462.9A Expired - Fee Related CN105951442B (en) | 2016-06-16 | 2016-06-16 | A kind of bib fabric of hydrophobic, air-permeability antibacterial pro-skin and preparation method thereof |
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| CN112135881A (en) * | 2018-04-03 | 2020-12-25 | 丝芭博株式会社 | Molded body and method for producing same |
| CN115821456A (en) * | 2022-12-23 | 2023-03-21 | 常州丁丁纺织科技有限公司 | Hydrophobic fabric |
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|---|---|
| CN105951442B (en) | 2018-05-15 |
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