CN105945435A - Laser machining device of annular micropore and laser machining method of annular micropore - Google Patents

Laser machining device of annular micropore and laser machining method of annular micropore Download PDF

Info

Publication number
CN105945435A
CN105945435A CN201610409601.7A CN201610409601A CN105945435A CN 105945435 A CN105945435 A CN 105945435A CN 201610409601 A CN201610409601 A CN 201610409601A CN 105945435 A CN105945435 A CN 105945435A
Authority
CN
China
Prior art keywords
workpiece
laser
nano
energy
particle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610409601.7A
Other languages
Chinese (zh)
Other versions
CN105945435B (en
Inventor
佟艳群
石琳
任旭东
张永康
吴笑漪
黄建宇
王昭
周武超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu University
Original Assignee
Jiangsu University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu University filed Critical Jiangsu University
Priority to CN201610409601.7A priority Critical patent/CN105945435B/en
Publication of CN105945435A publication Critical patent/CN105945435A/en
Application granted granted Critical
Publication of CN105945435B publication Critical patent/CN105945435B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/36Removing material
    • B23K26/38Removing material by boring or cutting
    • B23K26/382Removing material by boring or cutting by boring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/04Automatically aligning, aiming or focusing the laser beam, e.g. using the back-scattered light
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/062Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
    • B23K26/0622Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/08Devices involving relative movement between laser beam and workpiece
    • B23K26/082Scanning systems, i.e. devices involving movement of the laser beam relative to the laser head
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/70Auxiliary operations or equipment
    • B23K26/702Auxiliary equipment

Abstract

The invention provides a laser machining device of an annular micropore. The laser machining device of the annular micropore comprises a pulse laser, a polarization control system, a scanning mirror, an aperture, a focusing lens, a confinement layer, single-layer nano-particles, a three-dimensional moving platform and a computer control system. The pulse laser, the polarization control system and the scanning mirror are distributed along the same optical axis center in order. The aperture and the focusing lens are arranged right below the scanning mirror and the three-dimensional moving platform is arranged right below the focusing lens. The pulse laser, the focusing lens and the three-dimensional moving platform are connected with the computer control system. The creating of the annular micropore is realized in the way of depositing the single-layer nano-particles on the surface of a workpiece by the pretreatment of the surface of the workpiece, then determining the energy strengthening multiple, and machining the surface of the workpiece by the output energy of the pulse laser. According to the device, the laser machining of the annular micropore can be realized. The device has the characteristics of being high in accuracy, controllable in size, high in machining efficiency, simple in equipment and like.

Description

The laser processing device of a kind of annular micropore and method
Technical field
The invention belongs to field of laser processing, the laser processing device of a kind of annular micropore and method.
Background technology
The progress of industrial technology so that laser processing technology is developed rapidly, wherein laser boring is to reach practical the earliest Laser processing technology.Owing to laser boring has speed soon, the advantages such as efficiency is high, good in economic efficiency, have become as laser and add One of main application fields of work.
Laser drilling is the laser beam irradiation target utilizing high power density, makes the temperature of target material surface be quickly ramped up to vaporization temperature Degree, evaporation forms hole, and beam of laser single effect can be only formed a hole.And when laser drilling is applied at micro-nano Time in manufacture field, just face a lot of problem.Mainly have: 1. can not large-area manufacturing micropore, carry out micro-at micro-nano technology yardstick When hole makes, efficiency is substantially reduced;2. laser micropore size is limited by laser beam spot diameter, and swashs by adjusting processing The spot diameter of light is processed the mode in various micro/nano-scale aperture and is realized difficulty very greatly, pore size the most controlled requirement; 3. micro-pore shape is single, is circle, it is impossible to process unusual hole, such as annular micropore.
For in overcoming laser micropore to make can not the technological deficiency of large-area manufacturing micropore, the patent No.: CN201310007951 is open A kind of device that by optics, laser beam is split shaping, it is achieved that the technique effect that beam of laser is porous, shaped, The microwell array of multiple combination can be processed.But this device has multiple optical system to constitute, building cost high, operation easier is big. And pore size is uncontrollable and shape is single etc., and problem is the most effectively solved.When research sight is focused on micro-nano technology by people During field, the requirement to laser boring technique is more and more higher, and especially at laser micro/nano manufacture field, urgent needs one swashs Light cheesing techniques, it is possible to solve the problems referred to above.
Summary of the invention
There is the deficiencies such as working (machining) efficiency is low, pore size is uncontrollable, shape is single for laser micropore technology in prior art, this Invention provides a kind of laser processing device and the method for annular micropore, utilizes noble metal nano particles to make laser energy processed Surface of the work forms circular power and strengthens region, it is achieved that the Laser Processing of annular micropore, has high accuracy, size is controlled, add The features such as work efficiency rate is high, equipment is simple.
The present invention realizes above-mentioned technical purpose by techniques below means.
The laser processing device of a kind of annular micropore, including pulse laser, polarization control system, scanning galvanometer, aperture, gathers Focus lens, restraint layer, monolayer nano-particle, three-dimensional mobile platform and computerized control system;Described pulse laser, polarization control System processed and scanning galvanometer are arranged successively along same optical axis center;Described scanning galvanometer is arranged right below aperture;Described aperture just under Side is provided with condenser lens;Described condenser lens is arranged right below three-dimensional mobile platform;Described three-dimensional mobile platform upper surface places work Part;Described workpiece surface covers monolayer nano-particle;Described monolayer nano-particle upper surface covers restraint layer;Described pulse swashs Light device, condenser lens and three-dimensional mobile platform all electrically connect with computerized control system.Preferably, described monolayer nano-particle is expensive Metal nanoparticle.
Preferably, the one during described noble metal nano particles is gold nano grain or silver nano-grain.
Preferably, a diameter of a of described monolayer nano-particle, the wavelength of described pulse laser is λ, then it meets relational expression: λ/10<a<λ。
Preferably, described restraint layer is transparent material;Described polarization control system is made up of linear polarizer and 1/4 slide;Described Aperture is low pass circular hole wave filter.
The laser processing of a kind of annular micropore, comprises the steps:
S1: put up the laser processing device of annular micropore: adjust pulse laser, polarization control system and scanning galvanometer and be in Same optical axis center;Adjust aperture, condenser lens, the focal point of three-dimensional mobile platform to scanning galvanometer;By pulse laser, Condenser lens, three-dimensional mobile platform and computerized control system electrical connection;
S2: pre-treated workpiece surface: monolayer nano-particle is configured to nano granule suspension, and suspension is deposited on workpiece Surface, obtains surface and has deposited the workpiece of monolayer nano-particle;
S3: determine energy intensification factor A: according to workpiece, pulse laser and the characteristic parameter of monolayer nano-particle, solve work The normalization Laser beam energy distribution on part surface, draws out energy Enhanced feature curve;According to the annular processing internal diameter d of micropore or add Work outer diameter D determines energy intensification factor A;
S4: determine laser export energy parameter: energy intensification factor A determined according to step S3, open computerized control system, Output energy density J of pulse laser, J=J are set0/ A, wherein J0For workpiece damage energy density threshold;
S5: adjust light polarization and the location of workpiece: adjust polarization control system so that the laser beam of outgoing is circularly polarized light; The workpiece that surface described in step S2 has deposited monolayer nano-particle is positioned in three-dimensional mobile platform;At monolayer nano-particle Upper surface covers one layer of restraint layer;
S6: processing workpiece: computerized control system Output of laser, is processed surface of the work, it is achieved the making of annular micropore.
Preferably, pre-treated workpiece surface process described in step S2 is as follows: to surface of the work sanding and polishing, ultrasonic waves for cleaning, And the solvent comprising hydrophilic group is smeared at surface of the work;The described surface that obtains has deposited the processing workpiece mistake of monolayer nano-particle Journey is as follows: monolayer nano-particle is configured to the nano granule suspension of 5% solid content, nano granule suspension is placed in ultrasound wave Ultrasonic 10-15min in cleaning machine;Use micropipettor, take out 500 μ L every time, carefully drop in the work having carried out pretreatment Part surface;There is the titanium alloy of nanoparticles solution to be placed on inclination 9 ° standing 12h in the dustless kitchen of ventilation by dripping, steam completely to solvent Send out, obtain surface and deposited the processing workpiece of monolayer nano-particle.
Preferably, determine described in step S3 that energy intensification factor A process is as follows: normalization incident pulse laser energy density Being 1, set the contact point zero o as abscissa of nano-particle and processing surface of the work, transverse axis is the position of surface of the work Point, vertical coordinate is energy intensification factor, and then builds coordinate system;The peak A of energy intensification factormaxCorresponding transverse axis location point Being respectively+h and-h, coordinate corresponding in a coordinate system is (± h, Amax);Peak is risen to by contact point o in energy intensification factor Value AmaxSegment, if laser energy density is the location point at 1 is respectively+p and-p, coordinate corresponding in a coordinate system be (± p, 1);In energy intensification factor A by peak AmaxDrop to 0 segment, be respectively if laser energy density is the location point at 1 + q and-q, coordinate corresponding in a coordinate system is (± q, 1).Wherein the value of p, h, q meets: 0 < p < h < q;
When requiring that the internal diameter processing workpiece is d, it is desirable to op < d/2 < oh, determine that+d or-d location point is corresponding according to d size Energy intensification factor Ad;When require process workpiece external diameter be D time, it is desirable to oh≤D/2 < oq, according to D size determine+D or Energy intensification factor A that-D location point is correspondingD
Preferably, the material of workpiece described in step S4 is metal material or semi-conducting material.
Preferably, any one during the material of described workpiece is steel, copper, titanium alloy, monocrystal silicon, polysilicon.
Beneficial effects of the present invention:
(1) a kind of annular laser processing device of micropore of the present invention and method, utilize and be coated in by noble metal nano particles The surface of the work of pretreatment, forms monolayer nano-particle, to strengthen laser emission energy, and laser energy is constrained in nanometer Bottom Li, form circular power on workpiece to be machined surface and strengthen region, by rationally selecting machined parameters, produce annular micro- Hole array.
(2) precision is high.Annular capillary processing yardstick is micro-nano magnitude, uses noble metal nano particles near field optic field, Form Localized field enhancement effect, it is possible to break through the diffraction limit of laser beam;Pore size is controlled.Owing to pore size depends on receiving Choosing of rice grain and laser energy, strengthens curve according to energy and can predict the characteristic size of annular micropore, it is achieved controlled skill Art effect.
(3) heat effect is low, and capacity usage ratio is high.Can greatly strengthen the energy of incident laser so that the course of processing can make Obtain the micropore of micro/nano level with relatively low energy, there is the highest precision;Working (machining) efficiency is high.After surface of the work hydrophilic treated, Nano-particle can be with extensive deposition at surface of the work, thus the method can the micropore of large-area manufacturing micro/nano level.
(4) device is simple, easily operates.The laser drilling device that the present invention proposes does not has the optical system device of complexity, processing During there is no unnecessary regulation and control step, simple to operation.
Accompanying drawing explanation
Fig. 1 is the structural representation of the laser processing device of described annular micropore.
Fig. 2 is embodiment 1 laser energy cross-sectional distribution figure, and white dashed line part is the gold nano grain of diameter 200nm.
Fig. 3 is the energy profile that embodiment 1 processes surface of the work.
Fig. 4 is the energy enhancing curve that Fig. 3 processes surface of the work white dashed line part.
Fig. 5 is that the energy of embodiment 1 and 2 titanium alloy surface strengthens curve chart and the data point of correspondence.
Reference is as follows: 1-pulse laser, 2-polarization control system, 3-pulse laser, 4-scanning galvanometer, 5-aperture, 6- Condenser lens, 7-restraint layer, 8-monolayer nano-particle, 9-workpiece, 10-three-dimensional mobile platform, 11-computerized control system.
Detailed description of the invention
Below in conjunction with the accompanying drawings and specific embodiment the present invention is further illustrated, but protection scope of the present invention is not limited to This.
As it is shown in figure 1, the laser processing device of a kind of annular micropore, including pulse laser 1, polarization control system 2, scanning Galvanometer 4, aperture 5, condenser lens 6, restraint layer 7, monolayer nano-particle 8, three-dimensional mobile platform 10 and computerized control system 11;Described pulse laser 1, polarization control system 2 and scanning galvanometer 4 are arranged successively along same optical axis center;Described polarization Control system 2 is made up of linear polarizer and 1/4 slide, and adjustment pulse laser is circularly polarized light, acts on workpiece 9 surface;Institute State scanning galvanometer 4 and be arranged right below aperture 5;Described aperture 5 is low pass circular hole wave filter, act as filtering restraint layer 7 and reflects Light, prevent reflect photodoping processing laser in;Described aperture 5 is arranged right below condenser lens 6;Described condenser lens 6 Pulse laser is converged and vertical incidence is on workpiece 9 surface.The energy density that described pulse laser 1 is chosen in the course of processing Should be less than the damage energy density threshold of workpiece 9.
Described condenser lens 6 is arranged right below three-dimensional mobile platform 10, and described three-dimensional mobile platform 10 upper surface places workpiece 9, The focal position of laser beam it is positioned at for adjusting workpiece 9.Described workpiece 9 upper surface covers monolayer nano-particle 8, monolayer nanometer Granule 8 is noble metal nano particles, such as the one in gold nano grain or silver nano-grain;Table on described monolayer nano-particle 8 Face covers restraint layer 7, and restraint layer 7 is transparent material, such as glass;A diameter of a of described monolayer nano-particle 8, described pulse The wavelength of laser instrument 1 is λ, then it meets relational expression: λ/10 < a < λ.Described pulse laser 1, condenser lens 6 and three-dimensional shifting Moving platform 10 all electrically connects with computerized control system 11.
The course of processing of whole device is as follows:
The pulse laser that described pulse laser 1 is launched, obtains circularly polarized light through described polarization control system 2, scanning shakes Mirror 4 controls scanning pattern, is filled into veiling glare by aperture 5, is focused lens 6 and converges and be radiated workpiece 9 surface.Monolayer Nano-particle 8 forms Localized field enhancement effect under laser emission effect on workpiece 9 surface, and then realizes the micro-of workpiece 9 surface Hole machined.In the range of near field optic, laser can continue to propagate by cut-through thing in communication process, arrives workpiece 9 surface, Multiple reflections bottom granule.Noble metal nano particles has abundant electron outside nucleus, is easily formed under the excitation of laser energy Surface plasmons, and then form Localized field enhancement effect.In conjunction with Finite-Difference Time-Domain Method and Mie theory, can be in the hope of Solve the laser energy field distribution on workpiece 9 surface, and then the energy obtaining workpiece 9 surface strengthens curve, it was predicted that the work after processing Part surface annular cell morphology feature.
Embodiment 1
S1: put up the laser processing device of annular micropore: adjust pulse laser 1, polarization control system 2 and scanning galvanometer 4 It is in same optical axis center;Adjust aperture 5, condenser lens 6, the focal point of three-dimensional mobile platform 10 to scanning galvanometer 4;Will Pulse laser 1, condenser lens 6, three-dimensional mobile platform 10 and computerized control system 11 electrically connect.Wherein, noble metal is selected Nano-particle material is gold;The laser instrument used is IPG series of pulses optical fiber laser, centre wavelength 1064nm, repeats frequency Rate 10KHz-100KHz is adjustable, spot diameter 50 μm, maximum impulse energy 1mJ;
S2: choose workpiece 9, material is titanium alloy, a size of 20mm*20mm*5mm, and its damage threshold is J0=30.5 mJ/cm2;Pre-treated workpiece 9 surface: roughness is followed successively by the sand paper of 120,600,1200,3000 mesh and enters titanium alloy surface Row polishing, removes the obvious cut in surface;Polished titanium alloy is utilized dehydrated alcohol as solvent, at ultrasonic washing unit Middle cleaning 5 minutes.Not there is due to titanium alloy surface hydrophilic, cleaning the dried use suds rich in hydrophilic group Smear its surface so that it is there is hydrophilic;
Select the gold nano grain suspension of the diameter a=200nm of 5% solid content, meet λ/10 < a < λ, i.e. 106.4 nm<a<1064nm.Suspension is placed in ultrasonic 15min in ultrasonic washing unit so that nano-particle is fully dispersed to be opened;Use Micropipettor, takes out 500 μ L every time, carefully drops in the titanium alloy surface having carried out hydrophilic treated so that nano-particle is molten Liquid is fully dispersed to titanium alloy surface;The titanium alloy of nanoparticles solution is had to be placed on inclination 9 ° standing 12 in the dustless kitchen of ventilation by dripping H, evaporates completely to solvent, obtains surface and has deposited the processing workpiece of monolayer nano-particle.Need the processing workpiece prepared to protect Exist in culture dish, in order to avoid the contaminated surfaces such as dust foreign material.Fig. 2 is that the gold grain of single diameter a=200nm is at 1064nm ripple Long pulsed laser energy distribution sectional view, the polarization state of laser beam is circular.Laser energy is constrained at the bottom of granule by nano-particle Portion, forms Localized field enhancement effect.As shown in Figure 2, strengthen energy and concentrate on workpiece 9 surface and nano-particle contact area. In order to more clearly observe the Energy distribution of processing surface of the work, Fig. 3 is the energy profile on workpiece 9 surface corresponding for Fig. 2. The laser energy that nano-particle bottom formed can be clearly seen by Fig. 3 and strengthen region, the enhancing region, field that workpiece 9 surface is formed is Annular.
S3: determine energy intensification factor A: according to workpiece 9, pulse laser 1 and the characteristic parameter of monolayer nano-particle 8, Solve the normalization Laser beam energy distribution on workpiece 9 surface, draw out energy Enhanced feature curve;In processing according to annular micropore Footpath d or processing outer diameter D determine energy intensification factor A;As shown in Figure 4, penetrate pulsed laser energy density when normalizing dissolves be 1, set the contact point zero o as abscissa of nano-particle and processing surface of the work, transverse axis is the location point of surface of the work, Vertical coordinate is energy intensification factor A.According to Fig. 5, the peak A of energy intensification factormaxThe location point of=154.33 correspondences Being respectively+h and-h, h=15nm herein, the coordinate in respective coordinates system is (± 15,154.33).Require that processing annular is micro- Outer diameter D=the 100nm in hole, now q=50, meet oh≤D/2 < oq, according to energy Enhanced feature curve, corresponding in coordinate system In coordinate be (50,9.01323), it is determined that go out energy intensification factor AD=9.01323.
S4: energy intensification factor A determined according to step S3, opens computerized control system 11, arranges the defeated of pulse laser Go out energy density J, J=J0/ A, wherein J0Energy density threshold is damaged for workpiece 9;The spot diameter of known laser bundle is 50 μm, Being calculated laser energy and be chosen as 0.015mJ, arranging repetition rate is 20KHz, and scanning speed is 10m/s.
S5: adjust polarization control system 2 so that the laser beam of outgoing is circularly polarized light;Surface described in step S2 is deposited The processing workpiece of complete monolayer nano-particle is positioned in three-dimensional mobile platform 10;One layer is covered about at monolayer nano-particle 8 upper surface Bundle layer 7;
S6: computerized control system 11 Output of laser, is processed processing surface of the work, it is achieved the making of annular micropore.
The annular micropore using scanning electron microscope to process this embodiment is observed, and the outer diameter D of the annular micropore that discovery is processed is equal Value is 95.6nm, meets very well with processing request.
Embodiment 2
Require internal diameter d=20nm, the now p=10 of processing annular micropore, meet op < d/2 < oh.Such as Fig. 5, obtain according to solving Energy Enhanced feature curve, determine energy intensification factor Ad=24.5.Open computerized control system, it is known that the hot spot of laser beam A diameter of 50 μm, are calculated laser energy and are chosen as 0.019mJ, and arranging repetition rate is 50KHz, and scanning speed is 25 m/s.The step of other processing, parameter are identical with embodiment 1.
Use scanning electron microscope that the annular micropore of processing is observed, find that the internal diameter d average of the annular micropore processed is 18.78 Nm, meets very well with processing request.
Described embodiment be the present invention preferred embodiment, but the present invention is not limited to above-mentioned embodiment, without departing substantially from this In the case of the flesh and blood of invention, any conspicuously improved, replacement or modification that those skilled in the art can make are equal Belong to protection scope of the present invention.

Claims (10)

1. the laser processing device of an annular micropore, it is characterised in that include pulse laser (1), polarization control system (2), Scanning galvanometer (4), aperture (5), condenser lens (6), restraint layer (7), monolayer nano-particle (8), three-dimensional mobile platform And computerized control system (11) (10);Described pulse laser (1), polarization control system (2) and scanning galvanometer (4) edge Same optical axis center is arranged successively;Described scanning galvanometer (4) is arranged right below aperture (5);Set immediately below described aperture (5) There is condenser lens (6);Described condenser lens (6) is arranged right below three-dimensional mobile platform (10);Described three-dimensional mobile platform (10) Upper surface places workpiece (9);Described workpiece (9) upper surface covers monolayer nano-particle (8);Described monolayer nano-particle (8) Upper surface covers restraint layer (7);Described pulse laser (1), condenser lens (6) and three-dimensional mobile platform (10) are equal and electric Brain control system (11) electrically connects.
The laser processing device of a kind of annular micropore the most according to claim 1, it is characterised in that described monolayer nanometer Grain (8) is noble metal nano particles.
The laser processing device of a kind of annular micropore the most according to claim 2, it is characterised in that described noble metal nano Granule is the one in gold nano grain or silver nano-grain.
The laser processing device of a kind of annular micropore the most according to claim 1 and 2, it is characterised in that described monolayer is received A diameter of a of rice grain (8), the wavelength of described pulse laser (1) is λ, then it meets relational expression: λ/10 < a < λ.
The laser processing device of a kind of annular micropore the most according to claim 1 and 2, it is characterised in that described restraint layer (7) it is transparent material, such as glass;Described polarization control system (2) is made up of linear polarizer and 1/4 slide;Described aperture (5) it is low pass circular hole wave filter.
6. the laser processing of an annular micropore, it is characterised in that comprise the steps:
S1: put up the laser processing device of annular micropore: adjust pulse laser (1), polarization control system (2) and scanning Galvanometer (4) is in same optical axis center;Adjust the extremely scanning of aperture (5), condenser lens (6), three-dimensional mobile platform (10) to shake The focal point of mirror (4);By pulse laser (1), condenser lens (6), three-dimensional mobile platform (10) and computerized control system (11) electrical connection;
S2: pre-treated workpiece (9) surface: monolayer nano-particle (8) is configured to nano granule suspension, and by suspension It is deposited on workpiece (9) surface, obtains surface and deposited the workpiece of monolayer nano-particle;
S3: determine energy intensification factor A: according to workpiece (9), pulse laser (1) and the spy of monolayer nano-particle (8) Levy parameter, solve the normalization Laser beam energy distribution on workpiece (9) surface, draw out energy Enhanced feature curve;Micro-according to annular Processing internal diameter d or the processing outer diameter D in hole determine energy intensification factor A;
S4: determine laser export energy parameter: energy intensification factor A determined according to step S3, open computerized control system (11), output energy density J of pulse laser, J=J are set0/ A, wherein J0Energy density threshold is damaged for workpiece (9);
S5: adjust light polarization and the location of workpiece: adjust polarization control system (2) so that the laser beam of outgoing is circular polarization Light;The workpiece that surface described in step S2 has deposited monolayer nano-particle is positioned in three-dimensional mobile platform (10);At list Layer nano-particle (8) upper surface covers one layer of restraint layer (7);
S6: processing workpiece: computerized control system (11) Output of laser, is processed surface of the work, it is achieved annular micropore Make.
The laser processing of a kind of annular micropore the most according to claim 6, it is characterised in that described in step S2 Pre-treated workpiece (9) surface process is as follows: to workpiece (9) surface sanding and polishing, ultrasonic waves for cleaning, and at workpiece (9) table Topcoating smears the solvent comprising hydrophilic group;
Described obtain surface to have deposited the processing workpiece fabrication of monolayer nano-particle as follows: monolayer nano-particle (8) is configured to The nano granule suspension of 5% solid content, is placed in ultrasonic 10-15min in ultrasonic washing unit by nano granule suspension;Use Micropipettor, takes out 500 μ L every time, carefully drops in workpiece (9) surface having carried out pretreatment;To drip and have nanometer The titanium alloy of grain solution is placed in the dustless kitchen of ventilation and tilts 9 ° of standing 12h, evaporates completely to solvent, obtains surface and deposit The processing workpiece of complete monolayer nano-particle.
The laser processing of a kind of annular micropore the most according to claim 6, it is characterised in that described in step S3 Determine that energy intensification factor A process is as follows:
Normalization incident pulse laser energy density is 1, sets the contact point of nano-particle and processing surface of the work as abscissa Zero o, transverse axis is the location point of surface of the work, and vertical coordinate is energy intensification factor, and then builds coordinate system;Energy increases The peak A of strong multiplemaxCorresponding transverse axis location point is respectively+h and-h, and coordinate corresponding in a coordinate system is (± h, Amax); Peak A is risen to by contact point o in energy intensification factormaxSegment, is respectively if laser energy density is the location point at 1 + p and-p, coordinate corresponding in a coordinate system is (± p, 1);0th district is dropped to by peak A max in energy intensification factor A Between section, if laser energy density is the location point at 1 is respectively+q and-q, coordinate corresponding in a coordinate system is (± q, 1); Wherein the value of p, h, q meets: 0 < p < h < q;
When requiring that the internal diameter processing workpiece is d, it is desirable to op < d/2 < oh, determine that+d or-d location point is corresponding according to d size Energy intensification factor Ad;When require process workpiece external diameter be D time, it is desirable to oh≤D/2 < oq, according to D size determine+D or Energy intensification factor A that-D location point is correspondingD
The laser processing of a kind of annular micropore the most according to claim 6, it is characterised in that described in step S4 The material of workpiece (9) is metal material or semi-conducting material.
The laser processing of a kind of annular micropore the most according to claim 9, it is characterised in that described workpiece (9) Material be any one in steel, copper, titanium alloy, monocrystal silicon, polysilicon.
CN201610409601.7A 2016-06-12 2016-06-12 A kind of laser processing device and method of annular micropore Active CN105945435B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610409601.7A CN105945435B (en) 2016-06-12 2016-06-12 A kind of laser processing device and method of annular micropore

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610409601.7A CN105945435B (en) 2016-06-12 2016-06-12 A kind of laser processing device and method of annular micropore

Publications (2)

Publication Number Publication Date
CN105945435A true CN105945435A (en) 2016-09-21
CN105945435B CN105945435B (en) 2018-02-27

Family

ID=56908050

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610409601.7A Active CN105945435B (en) 2016-06-12 2016-06-12 A kind of laser processing device and method of annular micropore

Country Status (1)

Country Link
CN (1) CN105945435B (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106181025A (en) * 2016-08-29 2016-12-07 桂林电子科技大学 The up-down vibration auxiliary device of a kind of laser ablation and using method
CN106501946A (en) * 2017-01-10 2017-03-15 青岛镭创光电技术有限公司 Optical lens module
CN108145312A (en) * 2018-01-30 2018-06-12 江苏微纳激光应用技术研究院有限公司 A kind of laser welding system and its welding method
CN109676245A (en) * 2018-09-30 2019-04-26 湖北工业大学 A method of super hydrophilic glass surface is prepared using pulse laser
CN114654116A (en) * 2022-04-22 2022-06-24 武汉大学 Fixed-point machining device and method for nanometer holes of optical drive nanoparticles
CN116727900A (en) * 2023-08-11 2023-09-12 中国人民解放军空军工程大学 Laser hole making and opening method and device for aviation composite material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09223456A (en) * 1996-02-16 1997-08-26 Canon Inc Manufacture of surface conductive type electron emission element using laser beam
CN101239418A (en) * 2008-02-19 2008-08-13 江苏大学 Flying plate driving type laser micro-welding method and device
CN101249590A (en) * 2008-02-29 2008-08-27 深圳市大族激光科技股份有限公司 Ultraviolet laser cutting machine tool
CN101519184A (en) * 2008-02-29 2009-09-02 财团法人工业技术研究院 Method for manufacturing application substrate through photo-thermal effect
CN102601529A (en) * 2012-03-27 2012-07-25 北京理工大学 Method for improving machining efficiency of micro-channel preparation through femtosecond laser

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09223456A (en) * 1996-02-16 1997-08-26 Canon Inc Manufacture of surface conductive type electron emission element using laser beam
CN101239418A (en) * 2008-02-19 2008-08-13 江苏大学 Flying plate driving type laser micro-welding method and device
CN101249590A (en) * 2008-02-29 2008-08-27 深圳市大族激光科技股份有限公司 Ultraviolet laser cutting machine tool
CN101519184A (en) * 2008-02-29 2009-09-02 财团法人工业技术研究院 Method for manufacturing application substrate through photo-thermal effect
CN102601529A (en) * 2012-03-27 2012-07-25 北京理工大学 Method for improving machining efficiency of micro-channel preparation through femtosecond laser

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106181025A (en) * 2016-08-29 2016-12-07 桂林电子科技大学 The up-down vibration auxiliary device of a kind of laser ablation and using method
CN106181025B (en) * 2016-08-29 2018-01-23 桂林电子科技大学 The up-down vibration servicing unit and application method of a kind of laser ablation
CN106501946A (en) * 2017-01-10 2017-03-15 青岛镭创光电技术有限公司 Optical lens module
CN106501946B (en) * 2017-01-10 2023-02-14 青岛镭创光电技术有限公司 Optical lens assembly
CN108145312A (en) * 2018-01-30 2018-06-12 江苏微纳激光应用技术研究院有限公司 A kind of laser welding system and its welding method
CN109676245A (en) * 2018-09-30 2019-04-26 湖北工业大学 A method of super hydrophilic glass surface is prepared using pulse laser
CN114654116A (en) * 2022-04-22 2022-06-24 武汉大学 Fixed-point machining device and method for nanometer holes of optical drive nanoparticles
CN114654116B (en) * 2022-04-22 2023-02-03 武汉大学 Fixed-point machining device and method for nanometer holes of optical drive nanoparticles
CN116727900A (en) * 2023-08-11 2023-09-12 中国人民解放军空军工程大学 Laser hole making and opening method and device for aviation composite material
CN116727900B (en) * 2023-08-11 2023-10-20 中国人民解放军空军工程大学 Laser hole making and opening method and device for aviation composite material

Also Published As

Publication number Publication date
CN105945435B (en) 2018-02-27

Similar Documents

Publication Publication Date Title
CN105945435A (en) Laser machining device of annular micropore and laser machining method of annular micropore
CN107243697B (en) A method of the femtosecond laser of no exposure mask manufactures super-hydrophobic and anti-reflecting surface
Nolte et al. Femtosecond waveguide writing: a new avenue to three-dimensional integrated optics
CN108015410A (en) One kind is based on femtosecond laser induction amorphous gemSbnTekThe method of film preparation crystalline state nanostructured
Ding et al. One-step fabrication of multifunctional fusiform hierarchical micro/nanostructures on copper by femtosecond laser
CN109434289B (en) Femtosecond laser manufacturing method for tunable phase-change nano-structure super surface
CN106583930A (en) Method for achieving reversible wettability of titanium sheet based on femtosecond laser direct writing
CN103627883A (en) Method of regulating and controlling light absorption property of metal surface by picosecond pulse laser
CN105728945A (en) Method for preparing surface-enhanced Raman substrate through femtosecond laser double pulses with one-step method
JP2016517962A (en) Surface enhanced Raman scattering (SERS) sensor and method of manufacturing the same
CN108213718A (en) A kind of femtosecond laser regulates and controls GemSbnTekCrystalline state nanostructured geometric shape method
CN109277692B (en) Femtosecond laser double-pulse regulation and control method for polydimethylsiloxane surface micro-nano structure
CN108620728A (en) Semiconductor silicon surface large area regular distribution nano-pore array structure preparation method
CN109576640A (en) One kind preparing TiO in titanium substrate2The method of multiple dimensioned micro-nano compound structure
CN111318053B (en) Super-hydrophobic aluminum alloy filter screen and preparation method and application thereof
Garcell et al. Comparative study of femtosecond laser-induced structural colorization in water and air
Ding et al. Bioinspired near-full transmittance MgF2 window for infrared detection in extremely complex environments
CN109365995A (en) A kind of preparation method of highly homogeneous microtip arrays structure
CN113118633B (en) Method for preparing periodic microstructure on surface of titanium alloy through nanosecond laser irradiation
CN103738915B (en) The preparation method of three-dimensional crystal optics Echo Wall microcavity
CN107378231A (en) The method for preparing metal structure in transparent material surface using metal nano prepared Chinese ink
CN108296230B (en) A kind of dynamic range laser cleaning method
CN110116273A (en) The method that femtosecond laser synergistic oxidation reaction prepares broad band anti-reflection structure
CN112894143B (en) Method for regulating and controlling surface wettability of stainless steel based on femtosecond laser direct writing scanning
CN105112860B (en) A kind of cavitation method for implantation and device based on induced with laser shock wave focusing

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CP02 Change in the address of a patent holder
CP02 Change in the address of a patent holder

Address after: 212013 No. 3 Tieta Road, Guyang Town, Dantu District, Zhenjiang City, Jiangsu Province

Patentee after: Jiangsu University

Address before: No. 301, Xuefu Road, Jingkou District, Zhenjiang, Jiangsu Province

Patentee before: Jiangsu University