CN105941424A - Agricultural insecticidal composition capable of preventing and treating rice planthopper - Google Patents
Agricultural insecticidal composition capable of preventing and treating rice planthopper Download PDFInfo
- Publication number
- CN105941424A CN105941424A CN201610375302.6A CN201610375302A CN105941424A CN 105941424 A CN105941424 A CN 105941424A CN 201610375302 A CN201610375302 A CN 201610375302A CN 105941424 A CN105941424 A CN 105941424A
- Authority
- CN
- China
- Prior art keywords
- present
- agricultural
- agent
- pymetrozine
- pesticide composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an agricultural insecticidal composition. The agricultural insecticidal composition is prepared from an N-(cyano alkyl)benzamide compound and pymetrozine at the weight ratio from (1: 1) to (1: 20), preferably (1: 2) to (1: 8). The invention further relates to application of the agricultural insecticidal composition to prevention and treatment of the rice planthopper, and the agricultural insecticidal composition definitely has a good synergistic effect.
Description
[technical field]
The invention belongs to technical field of pesticide.More particularly it relates to an containing N-(cyanoalkyl) Benzoylamide
Compounds and the agricultural pesticide composition of pymetrozine, further relate to the purposes of described agricultural pesticide composition.
[background technology]
Planthopper is the main insect of Oryza sativa L., and its harm occurred has hiding, fulminant and destructive feature.
Planthopper is a kind of migratory pest, usually causes the significant loss of crop, the Rice Production of serious harm China.Along with chemistry
Constantly using of medicament, resistance problem becomes increasingly conspicuous, and in agricultural production real process, pest resistance to insecticide problem is impact evil
The key factor of worm prevention effect.Being carried out by difference effective ingredient compounding can be that insect resists with expanding prevention spectrum and raising preventive effect
Property administer effective measures.
N-(cyanoalkyl) benzamide compound has good prevention effect to Oryza sativa L. rice leaf roller, striped rice borer, but
The prevention effect of water rice hopper can not be reached preferable effect.Chinese patent application CN 201010293074.0, denomination of invention
" preparation method of a kind of N-(cyanoalkyl) benzamide compound " discloses a kind of N-(cyanoalkyl) benzamides chemical combination
The preparation method of thing, in its general structure I, R1Selected from H, halogen or methyl;R2Selected from H or halogen;R3Selected from H or C1-C6Alkyl;
R4Selected from C1-C6Alkyl;Or R3And R4C is formed together with the carbon connected3-C6Cycloalkyl;R5Selected from halogen, C1-C6Alkyl,
C1-C6Alkylhalide group or C1-C6Alkyl groups in the halogenalkoxy;R6Selected from halogen;R7Selected from H, halogen, C1-C3Alkyl, C1-C3Haloalkyl;X is selected from
CH, CF, CCl or N;Y is selected from Cl or Br.This compounds has high insecticidal activity and bactericidal activity.
Pymetrozine (Pymetrozine), No. CAS [123312-89-0], chemical name (E)-4,5-dihydro-6-methyl-4-
(3-pyridine methylene amino)-1,2,4-3 (2H)-one, belongs to pyridines or Triazinone insecticide, is former Novartis Co., Ltd of Switzerland
The Novel heterocyclic pesticide of exploitation in 1988.Its model of action is unique, as long as aphid or plant hopper one touch pymetrozine almost
Produce lancet blocking effect immediately, stop at once taking food, and final hungry lethal, and also this process is irreversible.Therefore,
Pymetrozine has the blocking-up insecticide of excellence and passes poison function.Pymetrozine is the most effective to larva and adult.This medicament can quickly penetrate into
In plant tissue, residual effect reaches 1 month.Pymetrozine is to the aphid of crop, plant hopper, leaves such as Oryza sativa L., vegetable, Cotton Gossypii, Semen Tritici aestivi and fruit trees
Cicadae, aleyrodid etc. have the highest preventive effect.
[summary of the invention]
[solving the technical problem that]
It is an object of the invention to provide a kind of agricultural containing N-(cyanoalkyl) benzamide compound and pymetrozine to kill
Worm compositions.
It is a further object to provide the purposes of described agricultural pesticide composition.
[technical scheme]
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of agricultural pesticide composition, described agricultural pesticide composition is by having following chemical structural formula
(I) compound forms according to weight ratio 1:1~1:20 with pymetrozine:
A preferred embodiment of the invention, chemical constitution formula (I) compound is 1:2 with the weight ratio of pymetrozine
~1:8.
The present invention relates to a kind of agricultural fungicides, described agricultural fungicides contains by weight described in 0.5~95.0%
Agricultural pesticide composition and surplus be agriculturally acceptable carrier and auxiliary agent.
A preferred embodiment of the invention, described agricultural fungicides contains by weight described in 20~70%
Agricultural pesticide composition and surplus be agriculturally acceptable carrier and auxiliary agent.
According to a kind of detailed description of the invention of the present invention, described agricultural fungicides is wettable powder, suspending agent, outstanding breast
The dosage forms such as agent, microemulsion, aqueous emulsion, water dispersion granule or microcapsule suspending agent.
The invention still further relates to described agricultural pesticide composition or described agricultural fungicides in preventing and treating rice hoppers
Purposes.
The present invention will be described in detail belows.
The present invention relates to a kind of agricultural pesticide composition, described agricultural pesticide composition is by having following chemical structural formula
(I) compound forms according to weight ratio 1:1~1:20 with pymetrozine:
This compound is equivalent to previously mentioned Chinese patent application CN201010293074.0, invention entitled " one
The preparation method of N-(cyanoalkyl) benzamide compound " disclosed in No. 18 compound, wherein R1=Cl, R2=Cl, R3
=CH3、R4=CH3、R5=Br, R6=Cl, R7=H and X=N is (in the present invention in order to simplify description, with active component 419 generation
Table, or referred to as " 419 ").The bromo-1-of its chemical name 3-(3-chloropyridine-2-base)-N-[the chloro-6-of 2,4-bis-(2-cyanopropyl-2-
Base formamido) phenyl]-1H-pyrazoles-5-Methanamide.It is the method described according to patent application CN201010293074.0
Preparation.
In agricultural pesticide composition of the present invention, when the amount of pymetrozine is in described scope, if active component 419
Amount exceedes the scope of described amount, then can be high because of consumption, and safety declines, and poisoning easily occurs.
When the amount of 419 is in described scope, if the amount of pymetrozine exceedes the scope of described amount, also can be high because of consumption,
Safety declines, and poisoning easily occurs.
Therefore, in agricultural pesticide composition of the present invention, active component 419 is 1:1~1:20 with the weight ratio of pymetrozine
It is rational.
Preferably, 419 is 1:2~1:8 with the weight ratio of pymetrozine.
The present invention relates to a kind of agricultural fungicides.Described agricultural fungicides contains by weight described in 0.5~95.0%
Agricultural pesticide composition and surplus be agriculturally acceptable carrier and auxiliary agent.
In the present invention, described carrier or auxiliary agent are it should be understood that be used for improving medicine in Pesticide formulation or use
Agent physicochemical property, improves drug effect, it is simple to the auxiliary substances of the transport performances such as storage, such as wetting agent, emulsifying agent, dispersant,
Sticker, stabilizer or synergist etc..According to the present invention, every have these performances and not appoint agricultural fungicides of the present invention
The chemical substance of what negative effect may be used to the present invention, and they are all within protection scope of the present invention.
According to the present invention, if the agricultural pesticide composition content of described agricultural fungicides is less than 0.5%, then can be because having
Effect composition is low, is unfavorable for the manufacturing of product from economic angle;If the agricultural pesticide composition of described agricultural fungicides
When content is higher than 95.0%, then can be unfavorable for the performance of drug effect because content is the highest and be easily generated poisoning;Therefore, described agricultural insecticidal
The agricultural pesticide composition content of agent is 0.5~95.0% to be appropriate.
Preferably, described agricultural fungicides contains agricultural pesticide composition described in 20~70% and surplus by weight
For agriculturally acceptable carrier and auxiliary agent.
In the present invention, the carrier of use is solid carrier or liquid-carrier.
Described solid carrier is selected from silicate, carbonate, sulfate, oxide, alkali metal salt, vegetalitas carrier or conjunction
Become earthfill rockfill concrete riprap RCC carrier etc..
Wherein silicate, carbonate, sulfate are mineral substance carrier with oxide carrier.
Such as, silicate carrier is Kaolin, meerschaum, nacrite, montmorillonite, Muscovitum, Vermiculitum, pyrophyllite or Talcum
Deng.
Carbonate support is calcium carbonate or dolomite etc..
Sulfate carrier is ammonium sulfate, sodium sulfate or calcium sulfate etc..
Oxide carrier is quick lime, magnesium lime or kieselguhr etc..
Alkali metal salt carrier is potassium chloride or sodium chloride etc..
Vegetalitas carrier is citrus pulp, corncob cellulose, rice husk powder, rice husk, big soybean stem meal, tobacco powder, Endocarpium Juglandis or sawmilling
Powder etc..
Synthetic filling class carrier is winnofil hydrate, winnofil or white carbon etc..
The present invention use these solid carriers be all in the art known to technical staff, sell in the market
The product sold, or the by-product of widely known agricultural byproducts processing.
Described liquid-carrier (solvent) is selected from water, aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, aliphatic hydrocarbon, alcohols, ethers, ketone, plant
Oil, methylated vegetable oils or other special solvent.
Such as, aromatic hydrocarbons carrier is benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons etc..
Chlorinated aliphatic hydrocarbon carrier is vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and many ethyl chloride etc..
Aliphatic hydrocarbon carrier is petroleum distillate, hexamethylene, light mineral oil or paraffin etc., such as limited by Jiangsu China human relations chemical industry
The main S-200 aliphatic hydrocarbon product being made up of octane and heptane of Company.
Alcoholic vehicle is methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol, propylene glycol, glycerol or fatty alcohol
Deng.
Ethers carrier is Propylene Glycol ether, ethohexadiol ether or petroleum ether etc..
Ketone is acetone, butanone, methyl iso-butyl ketone (MIBK), Ketohexamethylene, isophorone or N-methyl-pyrrolidon etc..
In the present invention, described special solvent is it should be understood that the solvent that is used in mixed way with one or more solvents.Described
Solvent in special solvent is dimethylformamide, dimethyl sulfoxide, Polyethylene Glycol or nitrile etc..
Vegetable oil is soybean oil, Oleum Brassicae campestris, Oleum Arachidis hypogaeae semen or Oleum sesami etc..
Methylated vegetable oils is methylated soya oil, Oleum Brassicae campestris, Oleum Arachidis hypogaeae semen or Oleum sesami etc..What the present invention used methylates
Vegetable oil is all at product sold in the market.
The present invention use liquid-carrier be all in the art known to technical staff, sell in the market
Product, the light mineral oil such as sold by SINOPEC's Hangzhou Refinery, by Shanghai Sheng Jun Industry investment company limited
The Propylene Glycol ether of sale, ethohexadiol ether, methyl iso-butyl ketone (MIBK), isophorone, dimethylformamide.
When using a kind of above-mentioned organic solvent, this organic solvent can single use, it is also possible to different from other
Organic solvent is used in mixed way, or is used in mixed way with water.When used as a mixture, its mixed proportion can be entered according to actually used situation
Row selects, and this is to there is not hell and high water for those skilled in the art.
The auxiliary agent that the present invention uses is selected from the surfactant in emulsifying agent, dispersant, stabilizer or wetting agent, disappears
Infusion, thickening agent, binding agent, suspending agent and antifreezing agent.
Described surfactant is the surfactant used in emulsifying agent, dispersant, stabilizer or wetting agent.
The surfactant that the present invention uses can be ion-type or nonionic, such as polyacrylic acid sodium salt and calcium
Salt, lignin sulfonic acid sodium salt and calcium salt;There is at least 12 carbon atom fatty acids or fatty amine and oxirane and/or epoxy third
The polycondensation product of alkane;Glycerol, dodecanol-1, tetradecanol-1, sorbitol, sucrose or pentaerythritol fatty ester and they
With oxirane and/or the polycondensation product of expoxy propane;The sulfate of described polycondensation product or sulfonate;There are at least 10 carbon
Atom alkyl sulphuric acid or sulfonate alkali metal or alkali salt, preferably sodium salt, as sodium lauryl sulphate, secondary alkylsurfuric acid
Sodium, sulfonated castor oil sodium salt, alkylaryl sodium sulfonate or dodecylbenzene sodium sulfonate;Ethylene oxide polymer or oxirane and ring
Ethylene Oxide copolymer.
The emulsifying agent that the present invention uses, it should be understood that one can improve each phase interfacial surface tension in emulsion, is allowed to shape
The most stable dispersion or the material of emulsion.Every have these performances and not appoint agricultural fungicides of the present invention
The chemical substance of what negative effect may be used to the present invention, and they are all within protection scope of the present invention.
The emulsifying agent that the present invention uses is nonionic emulsifier.Such as, described nonionic emulsifier is selected from polyoxy
Ethylene fatty acid ester, polyoxyethylene aliphatic alcohol ether and Polyoxyethylene fatty ammonia, as ethoxylated castor oil, polyoxyethylene (n20) benzene
Ethyl phenolic group oleic acid ester, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin polyoxyethylene ether, triphen second
Thiazolinyl phenol polyethenoxy (n20), ether phosphoric acid triethanolamine salt, Diphenethyl phenolic group polyoxyethylene ether (n18) formaldehyde condensation products,
Diphenyl phenol polyethenoxy (n18) polyethenoxy ether (n20) etc., these nonionic emulsifier are sold the most in the market
Product, the polyoxyethylene (n such as provided by Jiangsu Kai Yuan Science and Technology Ltd.20) phenethyl phenol ether through reaction oleate, alkylaryl
Formaldehyde resin polyoxyethylene ether, the diphenyl phenol polyethenoxy (n of sale18) polyethenoxy ether (n20).The emulsifying that the present invention uses
Agent can be commercial emulsifier, such as agriculture breast 0201B, agriculture breast 0203B, agriculture breast 100#, agriculture breast 500#, agriculture breast 600#, agriculture breast 600-
2#, agriculture breast 1601, agriculture breast 2201, agriculture breast NP-10, agriculture breast NP-15, agriculture breast 507#, agriculture breast OX-635, agriculture breast OX-622, agriculture breast
OX-653, agriculture breast OX-667, agriculture breast CS-7 or peaceful breast 36#。
The dispersant that the present invention uses is it should be understood that one has lipophilic fraction and hydrophilic portion in intramolecular simultaneously
Point interfacial agent, it be a kind of can be dispersed with liquid particles by the solid being difficult to be dissolved in liquid, simultaneously and also
Its sedimentation and cohesion can be stoped, form the material of stable suspension.Every have these performances and to agricultural fungicides of the present invention
The chemical substance not having any negative effect may be used to the present invention, and they are all within protection scope of the present invention.
The present invention use dispersant e.g. sodium lignin sulfonate, pull open powder, calcium lignosulfonate, methyl naphthalene sulfonic acid first
Aldehyde condensate, naphthalene sulfonic acid-formaldehyde condensation product, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to uncle
Butyl ether, dibutyl naphthalenesulfonic acid formaldehyde condensation products, phosphate such as sodium hexameta phosphate, alkylphenol-polyethenoxy based phosphates, alkyl
Phenol polyethenoxy base ether formaldehyde condensation products sulfate, N-methyl-fatty acyl group-sodium taurocholate alkylphenol polyoxyethylene formaldehyde contracting
Compound, aralkyl phenol polyethenoxy ether phosphate alkylphenol polyoxyethylene, Oleum Ricini ethylene oxide adduct, oxirane-
Propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products, alkylphenol-polyethenoxy polyethenoxy ether and methyl are fine
Dimension element.
The dispersant that the present invention uses is all product sold in the market, such as by Nanjing Teva-Chem. Co., Ltd.
N-methyl-fatty acyl group-sodium taurocholate alkylphenol polyoxyethylene the formaldehyde condensation products of sale, Oleum Ricini ethyleneoxide addition
Thing, ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products, alkylphenol-polyethenoxy Ji Mijia
Aldehyde condensate sulfate.
The stabilizer e.g. sodium lignin sulfonate that the present invention uses.The stabilizer that the present invention uses is all in the market
Product sold, the lignin series of products such as sold by virtue Visco Co..
The wetting agent that the present invention uses it should be understood that solid material surface tension or interfacial tension can be reduced by one,
Water easily spreads out and in its surface by the material of solid material moistening.Every have these performances and to agricultural insecticidal of the present invention
Agent does not has the chemical substance of any negative effect to may be used to the present invention, and they are all within protection scope of the present invention.
The wetting agent that the present invention uses is selected from sodium laurylsulfate, alkylol polyoxyethylene groups ether sodium sulfate, octylphenol polyethylene
Oxyethylene group ether sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, sodium alkyl sulfonate, DBSA
Sodium, Negel, dialkyl succinylsuccinate sulfonate, lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium, alkyl amide sodium taurocholate, fat
Fat alcohol polyoxyethylene ether, alkylphenol-polyethenoxy base ether, polyoxyethylene polyoxypropylene block polymer, sorbitan fatty
Acid esters polyoxyethylene ether etc..
The wetting agent that the present invention uses is all product sold in the market, such as, sold by Xing Fei Chemical Co., Ltd.
Alkylol polyoxyethylene groups ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, lauryl alcohol polyethylene glycol oxide
Base ether sulfonic acid sodium, sorbitan fatty acid ester polyoxyethylene ether.
In addition to above-mentioned surfactant, the present invention use auxiliary agent also have defoamer, thickening agent, binding agent, suspending agent and
Antifreezing agent.
Defoamer that the present invention uses is it should be understood that a kind of have chemistry and the material of surface chemistry froth breaking effect.Every
There are these performances and do not have the chemical substance of any negative effect to may be used to the present invention agricultural fungicides of the present invention, it
All within protection scope of the present invention.
Described defoamer is selected from bubble enemy, silicone, C8~10Fatty alcohol, C10~20Satisfied fatty acid or amide defoamer;This
The defoamer that invention uses is all product sold in the market, the bubble enemy that such as sold by Nanjing Jie Run company limited,
C10~20Satisfied fatty acid, amide defoamer.
The thickening agent that the present invention uses is it should be understood that one can make agricultural fungicides emulsifying of the present invention, it is possible to increase kill
Worm agent viscosity also reaches stable material.Every have these performances and do not have any negative shadow to agricultural fungicides of the present invention
The chemical substance rung may be used to the present invention, and they are all within protection scope of the present invention.
Described thickening agent is selected from carboxymethyl alcohol, polyvinyl alcohol, polyvinyl acetate, xanthan gum, gelatin, Arabic tree
Glue, polyvinylpyrrolidone, Magnesiumaluminumsilicate, polyvinyl alcohol, Polyethylene Glycol, phenolic resin, Lac, carboxymethyl cellulose or Sargassum
Acid sodium;The thickening agent that the present invention uses is all product sold in the market, such as, sold by Beijing Green Tai Mu company limited
The carboxymethyl alcohol sold, polyvinylpyrrolidone.
The binding agent that the present invention uses is it should be understood that one can make agricultural fungicides of the present invention more easy-formation, it is possible to carry
High insecticide caking ability also reaches the material of slow release.Every have these performances and do not have agricultural fungicides of the present invention any negative
The chemical substance that face rings may be used to the present invention, and they are all within protection scope of the present invention.
Described binding agent is that one or more are selected from soluble starch, natural gum, xanthan gum, carboxymethyl cellulose, dextrin
Or polyvinyl alcohol.
The suspending agent that the present invention uses is it should be understood that one can increase agricultural fungicides viscosity of the present invention to reduce
Wherein microgranule sedimentation velocity or the increase hydrophilic material of microgranule.Every have these performances and do not have agricultural fungicides of the present invention
The chemical substance having any negative effect may be used to the present invention, and they are all within protection scope of the present invention.
Described suspending agent is selected from glycerol, arabic gum, tragakanta, Resina persicae, methylcellulose, sodium carboxymethyl cellulose
Or hydroxypropyl cellulose.
The suspending agent that the present invention uses is all product sold in the market, such as by Nanjing Guan Hua trade Co., Ltd
The xanthan gum of sale, Resina persicae, sodium carboxymethyl cellulose.
The antifreezing agent that the present invention uses is it should be understood that one is prevented from agricultural fungicides of the present invention at microthermal climate ring
The material freezed under border.Every chemistry that there are these performances and agricultural fungicides of the present invention is not had any negative effect
Material may be used to the present invention, and they are all within protection scope of the present invention.
Described antifreezing agent is selected from glycerol, carbamide, ethylene glycol or propylene glycol.
The antifreezing agent that the present invention uses is all product sold in the market.
According to the present invention, described agricultural fungicides be wettable powder, suspending agent, suspension emulsion, microemulsion, aqueous emulsion,
The dosage form such as water dispersion granule or microcapsule suspending agent.
When agricultural fungicides of the present invention is wettable powder, its preparation method is as follows: by 0.5%~80% institute by weight
The agricultural pesticide composition stated, 2%~10% wetting agent, 5%~10% dispersant the most mixed with the filler of surplus to 100%
Close, re-use ultrafine crusher commonly used in the art or jet mill is pulverized, obtain described wettable powder.
The filler that the present invention uses is Kaolin, kieselguhr, mica powder, bentonite, attapulgite or precipitated calcium carbonate;The present invention uses
Other raw material as previously described, lower with, therefore repeat no more.
When agricultural fungicides of the present invention is suspending agent, its preparation method is as follows: described in by weight 0.5%~50%
Agricultural pesticide composition, 1%~5% wetting agent, 1%~8% dispersant, 0.1%~1% thickening agent, 2%~5% antifreezing agent
Mix homogeneously with the water being supplemented to 100%, then be milled to particle diameter 2~5 microns at sand mill medium sand, filter, then toward in its filtrate
Adding thickening agent, shear agitation is uniform, obtains described suspending agent.
When agricultural fungicides of the present invention is microemulsion, its preparation method is as follows: described in by weight 0.5%~40%
Agricultural pesticide composition, 1%~12% emulsifying agent, 0%~10% cosolvent, 0%~5% stabilizer, 0%~40% solvent with
It is supplemented to the water of 100% be added in reactor, stirs and be completely dissolved, being slowly added into pure water, stirring while adding, mixing
Uniformly, described microemulsion is obtained.The cosolvent that the present invention uses when preparing microemulsion e.g. isopropanol, cyclohexanone, under
With, therefore repeat no more.They are all product solds in the market, such as by Jinan, Shandong Province Guo Tai Chemical Co., Ltd. pin
The isopropanol product sold or by the cyclohexanone product of Nanjing DSM company Company.
When agricultural fungicides of the present invention is aqueous emulsion, its preparation method is as follows: described in by weight 0.5%~80%
Agricultural pesticide composition, 1%~20% emulsifying agent, 0%~15% cosolvent, 0%~5% stabilizer, 10%~40% solvent
It is added in reactor with the water being supplemented to 100%, stirs and be completely dissolved, be slowly added into pure water, stirring while adding, mixed
Close uniformly, obtain described aqueous emulsion.
When agricultural fungicides of the present invention is suspension emulsion, its preparation method is as follows: take by weight described in 0.5%~90%
Agricultural pesticide composition, 1%~5% solvent, 1%~5% dispersant, 1%~10% emulsifying agent, 1%~5% wetting agent, 1%
~5% stabilizer, 0%~5% antifreezing agent, 0%~5% thickening agent, 0%~5% defoamer be supplemented to 100% water, so
After be prepared as aqueous emulsion by 419 according to the preparation method of above-mentioned aqueous emulsion, simultaneously according to the preparation method of above-mentioned suspending agent by pyrrole
Aphid ketone is prepared as suspending agent, then, is uniformly mixed with described suspending agent by described aqueous emulsion, obtains described outstanding breast
Agent.Or, pymetrozine is prepared as aqueous emulsion, simultaneously according to the preparation of above-mentioned suspending agent according to the preparation method of above-mentioned aqueous emulsion
Method is prepared as suspending agent by 419, then, is uniformly mixed with described suspending agent by described aqueous emulsion, obtains described hanging
Emulsion.
When agricultural fungicides of the present invention is water dispersion granule, its preparation method is as follows: by by weight 0.5%~80%
Described agricultural pesticide composition, 0%~2% surfactant, 1%~15% wetting agent, 1%~15% dispersant, 1%~
10% disintegrating agent, 0%~5% stabilizer, be supplemented to 100% filler co-grinding, add water kneading, make in comminutor
Grain, dry, screening, obtain described water dispersion granule.The disintegrating agent that the present invention uses is ammonium sulfate or carboxymethyl cellulose
Sodium;The filler that the present invention uses is Kaolin, kieselguhr or corn starch.
When agricultural fungicides of the present invention is microcapsule suspending agent, its preparation method is as follows: take 0.5%~70% institute by weight
The agricultural pesticide composition stated, 1%~20% emulsifying agent, 1%~20% solvent, 0%~10% thickening agent, 0%~10% prevent
Freeze agent, 0%~5% stabilizer, 0%~5% defoamer, 1%~10% microcapsule carrier and the water being supplemented to 100%;Use
419, pymetrozine, emulsifying agent, solvent and stabilizer are encapsulated in the μm microcapsule of particle diameter D90≤50 by microcapsule carrier, with water, prevent
Freeze agent, thickening agent makes carrier with defoamer, by they mix homogeneously, makes microcapsule suspending agent.The microcapsule that the present invention uses
Carrier is isocyanates.
When agricultural fungicides of the present invention is granule, its preparation method is as follows: take by weight described in 0.5%~80%
Agricultural pesticide composition, 0%~2% surfactant, 1%~15% wetting agent, 1%~15% dispersant, 1%~10% collapse
Solve agent, 0%~5% stabilizer, 1%~10% binding agent, be supplemented to 100% filler co-grinding, add water kneading,
Pelletize in comminutor, dry, screening, obtain described granule.The disintegrating agent that the present invention uses is ammonium sulfate or carboxymethyl fibre
Dimension element sodium;The filler that the present invention uses is Kaolin, kieselguhr or white carbon.
The invention still further relates to described agricultural insecticidal composite or described agricultural insecticide use in preventing and treating rice hoppers
On the way.Planthopper belongs to Homoptera Delphacidae.Mainly brown paddy plant hopper, white backed planthopper and the small brown rice planthopper of hazard rice.Harm is seriously
Brown paddy plant hopper and white backed planthopper, in early rice growth early stage based on white backed planthopper harm, endanger with brown paddy plant hopper at early rice Later growth
It is main;Middle late rice is then based on brown paddy plant hopper harm.Brown paddy plant hopper the most directly endangers water, but can propagate paddy and wheat, seeding corn and other crops
Virus.
It is 50g a.i./hm that Pesticidal combination of the present invention and insecticide impose on the application dosage in rice field2~200g a.i./
hm2.Pesticidal combination of the present invention and insecticide can use conventional method to use, such as, spray, spray.Its amount of application can root
Change according to weather conditions or crop growthing state, can use before or after pest damage occurs.Holding of protective effect
The content of generally compound individualized with compositions of continuous time is relevant, also relevant to extraneous factor, such as weather, but by using
Suitable dosage form can slow down the impact of weather.
Pesticidal combination of the present invention and insecticide can also have weeding with other, the compound of bactericidal property mixes makes
With, it is also possible to it is used in mixed way with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner.
[beneficial effect]
Pesticidal combination of the present invention has a following beneficial effect:
1, active component 419 compounds the composition that pymetrozine is good to planthopper prevention effect, solves 419 independent medications pair
Water rice hopper is double controls the problem that effect is poor, can reach Oryza sativa L. rice leaf roller, striped rice borer, the most double effect controlled of plant hopper;
2, reduce times for spraying, lower drug cost, reduce environmental pollution and pesticide residues;
3, compositions is made up of the effective ingredient of different mechanism of action, and action site increases, and is conducive to overcoming and delay evil
The drug-fast generation of worm.The present composition is equal without obvious harmful effect to trial crops, and leaf color, growing way etc. are all normal, safety
Property is good, meets the security requirement of pesticidal preparations.
[detailed description of the invention]
Below in conjunction with embodiment, the present invention will be further described, but is not limited to embodiment.
In the present invention, if no special instructions, for illustrating that " % " of consumption or ratio is all weight percentage, ": " or
" compare " and be weight ratio.
One, the preparation of agricultural fungicides of the present invention
Embodiment 1: prepare 40%419 pymetrozine wettable powders (effective ingredient 1:1)
Weigh in terms of this insecticide wettable powder gross weight 20% chemical constitution formula (I) 419,20% pymetrozine, 2%
Sodium lauryl sulphate, 5% White Carbon black, 10% sodium lignin sulfonate be supplemented to 100% precipitated calcium carbonate, according to the application
Preparation method described in description obtains insecticide wettable powder of the present invention.
Embodiment 2: prepare 48%419 pymetrozine wettable powders (effective ingredient 1:5)
Weigh in terms of this insecticide wettable powder gross weight 8% chemical constitution formula (I) 419,40% pymetrozine, 2%0
Sodium dialkyl sulfate, 5% naphthalene sulfonic acid-formaldehyde condensation product, 4% sodium lignin sulfonate, 6% White Carbon black and the lightweight being supplemented to 100%
Calcium carbonate, obtains insecticide wettable powder of the present invention according to the preparation method described in present specification.
Embodiment 3: prepare 77%419 pymetrozine water dispersion granules (effective ingredient 1:10)
Weigh in terms of this insecticide water dispersion granule gross weight 7% chemical constitution formula (I) 419,70% pymetrozine, 2%
Naphtholsulfonic acid formaldehyde condensation products, 1%N-methyl-oleoyl-sodium taurocholate, 1% soluble starch and the kaolinite being supplemented to 100%
Soil, obtains insecticide water dispersion granule of the present invention according to the preparation method described in present specification.
Embodiment 4: prepare 56%419 pymetrozine water dispersion granules (effective ingredient 1:3)
Weigh in terms of this insecticide water dispersion granule gross weight 14% chemical constitution formula (I) 419,42% pymetrozine, 3%
Naphtholsulfonic acid formaldehyde condensation products, 4%N-methyl-oleoyl-sodium taurocholate, 3% soluble starch, 2% sodium sulfate be supplemented to
The Kaolin of 100%, obtains insecticide water dispersion granule of the present invention according to the preparation method described in present specification.
Embodiment 5: prepare 20%419 pymetrozine water dispersion granules (effective ingredient 1:1)
Weigh in terms of gross weight 10% chemical constitution formula (I) 419,10% pymetrozine, 3% naphtholsulfonic acid formaldehyde condensation products,
4%N-methyl-oleoyl-sodium taurocholate, 3% soluble starch, 2% sodium sulfate be supplemented to 100% Kaolin, according to this
Preparation method described in application specification obtains insecticide water dispersion granule of the present invention.
Embodiment 6: prepare 48%419 pymetrozine suspension agents (effective ingredient 1:3)
Weigh in terms of this insecticide suspending agent gross weight 12% chemical constitution formula (I) 419,36% pymetrozine, 2% pull open
Powder, 3%Soproplot SC, 0.1% xanthan gum, 1% aluminium-magnesium silicate, 0.3%418G, 0.1%BIT and be supplemented to 100%
Water, obtains insecticide suspending agent of the present invention according to the preparation method described in present specification.
Embodiment 7: prepare 30%419 pymetrozine suspension agents (effective ingredient 1:9)
Weigh in terms of gross weight 3% chemical constitution formula (I) 419,27% pymetrozine, 2% pull open powder, 3%Soproplot
SC, 0.1% xanthan gum, 1% aluminium-magnesium silicate, 0.3%418G, 0.1%BIT and be supplemented to 100% water, illustrate according to the application
Preparation method described in book obtains insecticide suspending agent of the present invention.
Embodiment 8: prepare 42%419 pymetrozine suspension agents (effective ingredient 1:20)
Weigh in terms of this insecticide suspending agent gross weight 2% chemical constitution formula (I) 419,40% pymetrozine, 2% pull open powder,
3%Soproplot SC, 0.15% xanthan gum, 1% aluminium-magnesium silicate, 0.2%418G, 0.1%BIT and be supplemented to 100% water,
Insecticide suspending agent of the present invention is obtained according to the preparation method described in present specification.
Embodiment 9: prepare 52%419 pymetrozine cream (effective ingredient 1:12)
Weigh in terms of this insecticide emulsifiable concentrate gross weight 4% chemical constitution formula (I) 419,48% pymetrozine, 7% agriculture breast
2201#, 4% agriculture breast 600#, 15% dimethylformamide be supplemented to 100% S-200 aromatic solvent, illustrate according to the application
Preparation method described in book obtains insecticide emulsifiable concentrate of the present invention.
Embodiment 10: prepare 60%419 pymetrozine cream (effective ingredient 1:11)
Weigh in terms of this insecticide emulsifiable concentrate gross weight 5% chemical constitution formula (I) 419,55% pymetrozine, 3% agriculture breast 500#,
8% agriculture breast 0201B, 10% dimethylformamide be supplemented to 100% S-200 aromatic solvent, according in present specification
The preparation method described obtains insecticide emulsifiable concentrate of the present invention.
Embodiment 11: prepare 9%419 pymetrozine water emulsion (effective ingredient 1:8)
Weigh in terms of this insecticide aqueous emulsion gross weight 1% chemical constitution formula (I) 419,8% pymetrozine, 12%N-methyl
Ketopyrrolidine, 6% dodecyl sodium sulfate, 4% polyvinyl alcohol, 4% emulsifying agent 500#, 0.5% defoamer be supplemented to 100%
Deionized water, obtain insecticide aqueous emulsion of the present invention according to the preparation method described in present specification.
Embodiment 12: prepare 30%419 pymetrozine water emulsion (effective ingredient 1:2)
Weigh in terms of this insecticide aqueous emulsion gross weight 10% chemical constitution formula (I) 419,20% pymetrozine, 11%N-first
Base ketopyrrolidine, 5% dodecyl sodium sulfate, 4% polyvinyl alcohol, 5.0% emulsifying agent 500#, 0.5% defoamer be supplemented to
The deionized water of 100%, obtains insecticide aqueous emulsion of the present invention according to the preparation method described in present specification.
Embodiment 13: prepare 15%419 pymetrozine water emulsion (effective ingredient 1:5)
Weigh in terms of this insecticide aqueous emulsion gross weight 2.5% chemical constitution formula (I) active component 419,12.5% pyrrole aphid
Ketone, 11%N-methyl pyrrolidone, 5% dodecyl sodium sulfate, 4% polyvinyl alcohol, 5.0% emulsifying agent 500#, 0.5% froth breaking
Agent be supplemented to 100% deionized water, obtain insecticide water of the present invention according to the preparation method described in present specification
Emulsion.
Embodiment 14: prepare 25%419 pymetrozine micron emulsion (effective ingredient 1:4)
Weigh in terms of this insecticide microemulsion gross weight 5% chemical constitution formula (I) 419,20% pymetrozine, 8% isopropanol,
24% trimethylbenzene, 18% propylene glycol polyoxyethylene poly-oxygen propylene aether be supplemented to 100% water, retouch according in present specification
The preparation method stated obtains insecticide microemulsion of the present invention.
Embodiment 15: prepare 18%419 pymetrozine micron emulsion (effective ingredient 1:5)
Weigh in terms of this insecticide microemulsion gross weight 3% chemical constitution formula (I) 419,15% pymetrozine, 4% Ketohexamethylene,
9% solvent naphtha, 5% calcium dodecyl benzene sulfonate, 9% triphen ethyl phenol polyoxyethylene poly-oxygen propylene aether block copolymer are with supplementary
To the deionized water of 100%, obtain insecticide microemulsion of the present invention according to the preparation method described in present specification.
Embodiment 16: prepare 7%419 pymetrozine granules (effective ingredient 1:6)
Weigh in terms of this insecticide water dispersion granule gross weight 1% chemical constitution formula (I) 419,7% pymetrozine, 2% naphthalene
Phenol sulfonic formaldehyde condensation compound, 1%N-methyl-oleoyl-sodium taurocholate, 1% soluble starch and the kaolinite being supplemented to 100%
Soil, obtains insecticide water dispersion granule of the present invention according to the preparation method described in present specification.
Embodiment 17: prepare 4%419 pymetrozine granules (effective ingredient 1:3)
Weigh in terms of this insecticide water dispersion granule gross weight 1% chemical constitution formula (I) 419,3% pymetrozine, 3% naphthalene
Phenol sulfonic formaldehyde condensation compound, 4%N-methyl-oleoyl-sodium taurocholate, 3% soluble starch, 2% sodium sulfate be supplemented to
The Kaolin of 100%, obtains insecticide water dispersion granule of the present invention according to the preparation method described in present specification.
Two, bioactive mensuration
In order to further appreciate that the virulence of active component 419 and pymetrozine composition, carry out a large amount of formulation screening test.
Pesticidal combination biological activity determination of the present invention is as follows:
According to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.6-2006 and agricultural
Industry standard NY/T1154.7-2006), measure single dose LC50With mixture LC50。
Select indoor throughout the year with rice seedling raising worm kind (27 DEG C, 14h illumination/d).Select indoor feeding low age, size
Consistent Brown Planthopper (Nilaparvata lugens (Stal)) nymph is for experiment.Use dip method.By target insect
After immersing medicinal liquid 5~10s, sucking unnecessary medicinal liquid with filter paper, go to examination worm raise under normal condition, test sets without medicament
Corresponding organic solvent is processed as comparison, often processes and is repeated 4 times, and often repeats to soak worm 20~30, checks result, with brush pen after 24h
Touch polypide, reactionless be considered as dead worm.Add up each borer population alive processed and total borer population, calculate mortality rate and the correction of each process
Mortality rate (Abbott ' s formula);Carry out data analysis statistical by " DPS data handling system " V14.50 professional version, obtain recurrence
Straight line, LC50Value.Calculate toxicity index by the abundant method of Sun Yun (Sun etc., 1960), following formula be calculated co-toxicity coefficient:
Toxicity index × the A of theoretical mixed toxicity index (TTI)=A content (%) in mixed
Toxicity index × the B of+B content (%) in mixed
When co-toxicity coefficient is more than 120, show that this mixture has potentiation;And co-toxicity coefficient less than 80 time, show
This mixture has antagonism;And co-toxicity coefficient more than 80 less than 120 time, show that this mixture has summation action.
Active component 419 and pymetrozine different ratio mixture see table 1 to the Toxicity Determination result of planthopper.
Table 1:419 and the Pyraphione compound Toxicity Determination result to planthopper
From above-mentioned Toxicity Determination result it can be seen that 419 answer in the range of weight ratio 1:1~1:20 with pymetrozine
Timing, its co-toxicity coefficient (CTC) is all higher than 120, illustrates that water rice hopper is had significantly by active component 419 and pymetrozine mixture
Potentiation.
Three, preventing and treating water rice hopper Field information test
According to medicine inspecting institute of the Ministry of Agriculture " GB-T 17980.4-2000 pesticide field efficacy medicine test criterion (one) insecticide
Preventing and treating water rice hopper " regulation carry out test.
Test method: Rise's boot period dispenser is once.Rice hoppers is based on low instar nymphs.
Formulation rate is 750kg/hm2, plant blade face even spraying.Plot area 25m2, repeating for 4 times, random district group arranges.
Every experimental plot 10 samplings of parallel jump method, investigate 2 clumps at every, and investigation 20 clumps, investigates every 2 clumps of borer populations alive taken altogether.
According to survey result, calculate Revision insect recluced rate and preventive effect according to formula below (1) with (2).Test data uses Deng
Ken Shi duncan's new multiple range method (DMRT) carries out statistical analysis.
Water rice hopper field control effectiveness test result prevented and treated by table 2
From above-mentioned field control effectiveness test result it can be seen that can effectively preventing after active component 419 and Pyraphione compound
Water rice hopper, preventive effect is better than compareing medicament, shows the reduction of on the one hand effective ingredient consumption, on the other hand 7 days preventive effects after medicine
All it is significantly increased with 14 days preventive effects.To trial crops safety in scope of medication.
In sum, under indoor biometrics and field control effectiveness test result show that agricultural pesticide composition of the present invention has
State beneficial effect:
1, compared with single dose, this Pesticidal combination has significant potentiation to preventing and treating planthopper, extends the lasting period, carries
High effect;
2, reduce times for spraying, lower drug cost, reduce environmental pollution and pesticide residues;
3, compositions is made up of the effective ingredient of different mechanism of action, and action site increases, and is conducive to overcoming and delay evil
The drug-fast generation of worm.The present composition is equal without obvious harmful effect to trial crops, and leaf color, growing way etc. are all normal, safety
Property is good, meets the security requirement of pesticidal preparations.
Pesticidal combination of the present invention has good preventive effect to water rice hopper.
Claims (7)
1. an agricultural pesticide composition, it is characterised in that described agricultural pesticide composition is by having following chemical constitution formula (I)
Compound and pymetrozine form according to weight ratio 1:1~1:20:
Agricultural pesticide composition the most according to claim 1, it is characterised in that chemical constitution formula (I) compound and pymetrozine
Weight ratio be 1:2~1:8.
3. an agricultural fungicides, it is characterised in that it contains 0.5~95.0% agriculture described in claim 1 or 2 by weight
Industry Pesticidal combination and surplus are agriculturally acceptable carrier and auxiliary agent.
Agricultural fungicides the most according to claim 3, it is characterised in that it contains by weight 20~70% claim 1
Or agricultural pesticide composition described in 2 and surplus are agriculturally acceptable carrier and auxiliary agent.
5. according to the agricultural fungicides described in claim 3 or 4, it is characterised in that it is wettable powder, suspending agent, outstanding breast
The dosage forms such as agent, suspension emulsion, microemulsion, aqueous emulsion, water dispersion granule or microcapsule suspending agent.
Agricultural pesticide composition the most according to claim 1 and 2 or according to claim institute any one of claim 3-5
The agricultural fungicides stated purposes in preventing and treating rice insect pest.
Agricultural pesticide composition the most according to claim 1 and 2 or according to claim institute any one of claim 3-5
The agricultural fungicides stated purposes in preventing and treating rice hoppers.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610375302.6A CN105941424A (en) | 2016-05-31 | 2016-05-31 | Agricultural insecticidal composition capable of preventing and treating rice planthopper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610375302.6A CN105941424A (en) | 2016-05-31 | 2016-05-31 | Agricultural insecticidal composition capable of preventing and treating rice planthopper |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105941424A true CN105941424A (en) | 2016-09-21 |
Family
ID=56907339
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610375302.6A Pending CN105941424A (en) | 2016-05-31 | 2016-05-31 | Agricultural insecticidal composition capable of preventing and treating rice planthopper |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105941424A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106614632A (en) * | 2016-11-17 | 2017-05-10 | 河北博嘉农业有限公司 | Agricultural insecticidal composition containing isotianil and pymetrozine |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008134969A1 (en) * | 2007-04-30 | 2008-11-13 | Sinochem Corporation | Benzamide compounds and applications thereof |
CN101720769A (en) * | 2010-01-08 | 2010-06-09 | 张志高 | Insecticidal composition containing pymetrozine and chlorantraniliprole |
CN104412991A (en) * | 2013-09-06 | 2015-03-18 | 沈阳化工研究院有限公司 | Binary insecticide composition and application thereof |
-
2016
- 2016-05-31 CN CN201610375302.6A patent/CN105941424A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008134969A1 (en) * | 2007-04-30 | 2008-11-13 | Sinochem Corporation | Benzamide compounds and applications thereof |
CN101720769A (en) * | 2010-01-08 | 2010-06-09 | 张志高 | Insecticidal composition containing pymetrozine and chlorantraniliprole |
CN104412991A (en) * | 2013-09-06 | 2015-03-18 | 沈阳化工研究院有限公司 | Binary insecticide composition and application thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106614632A (en) * | 2016-11-17 | 2017-05-10 | 河北博嘉农业有限公司 | Agricultural insecticidal composition containing isotianil and pymetrozine |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103271074B (en) | Insecticide composition containing cycolxylidin and pymetrozine | |
CN102217638B (en) | Pesticide composition for preventing and treating plant virus diseases | |
CN105010315B (en) | It is a kind of containing Acetamiprid and the dispersible oil-suspending agent of carbosulfan and application | |
CN105638715B (en) | A kind of agricultural pesticide composition and application thereof | |
CN103125496A (en) | Novel insecticide composition compounding pymetrozine | |
CN105941424A (en) | Agricultural insecticidal composition capable of preventing and treating rice planthopper | |
CN105831147B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and lambda-cyhalothrin and application thereof | |
CN107743967A (en) | Composition pesticide and its application containing flumioxazin and flufenacet | |
CN105746567B (en) | A kind of agricultural pesticide composition and application thereof | |
CN104824011A (en) | Insecticidal composition containing pyridine quinazoline and guadipyr | |
CN108651514A (en) | A kind of composition pesticide containing fosthiazate and fluxapyroxad | |
CN105660649B (en) | A kind of agricultural pesticide composition and application thereof | |
CN107517990A (en) | Composition pesticide and its application containing metamitron, desmedipham and phenmedipham | |
CN105766989B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and cyfloxylate and application thereof | |
CN105707119B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and chlopyrifos and application thereof | |
CN105660681A (en) | Agricultural insecticide composition containing insect sulfamide and fenpropathrin and application thereof | |
CN105746560A (en) | Agricultural insecticidal composition and application thereof | |
CN105685050B (en) | A kind of agricultural pesticide composition and application thereof | |
CN105613562B (en) | A kind of agricultural pesticide composition and application thereof containing sulphur insect amide and dinotefuran | |
CN105660680B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof | |
CN101502268B (en) | Pesticide composition containing Thiamethoxam and Pyridaben and use thereof | |
CN105794789B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and Nylar and application thereof | |
CN105165859B (en) | Insecticide acaricide composition and its application | |
CN105794790A (en) | Agricultural pesticidal composition containing sulfamide and ethofenprox and application of agricultural pesticidal composition | |
CN105432642A (en) | Prothioconazole and cyhalodiamide-containing insecticidal sterilization composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160921 |