CN105660680B - A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof - Google Patents
A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof Download PDFInfo
- Publication number
- CN105660680B CN105660680B CN201610235964.3A CN201610235964A CN105660680B CN 105660680 B CN105660680 B CN 105660680B CN 201610235964 A CN201610235964 A CN 201610235964A CN 105660680 B CN105660680 B CN 105660680B
- Authority
- CN
- China
- Prior art keywords
- present
- agricultural
- agent
- pesticide composition
- diacloden
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 73
- 239000000575 pesticide Substances 0.000 title claims abstract description 56
- 150000001408 amides Chemical class 0.000 title claims abstract description 42
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 title abstract description 64
- 241000238631 Hexapoda Species 0.000 title abstract description 41
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract description 34
- 239000005864 Sulphur Substances 0.000 title abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 53
- 240000007594 Oryza sativa Species 0.000 claims abstract description 22
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 22
- 235000009566 rice Nutrition 0.000 claims abstract description 22
- 230000002265 prevention Effects 0.000 claims abstract description 18
- 241000218475 Agrotis segetum Species 0.000 claims abstract description 15
- 240000008042 Zea mays Species 0.000 claims abstract description 14
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims abstract description 14
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims abstract description 13
- 235000005822 corn Nutrition 0.000 claims abstract description 13
- 239000000126 substance Substances 0.000 claims description 76
- -1 alkali metal salt Chemical class 0.000 claims description 47
- 239000000375 suspending agent Substances 0.000 claims description 41
- 239000000417 fungicide Substances 0.000 claims description 39
- 239000000839 emulsion Substances 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 20
- 239000002904 solvent Substances 0.000 claims description 19
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 18
- 239000013530 defoamer Substances 0.000 claims description 18
- 239000006185 dispersion Substances 0.000 claims description 16
- 239000008187 granular material Substances 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 239000003995 emulsifying agent Substances 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 14
- 239000004530 micro-emulsion Substances 0.000 claims description 13
- 239000003381 stabilizer Substances 0.000 claims description 13
- 239000000080 wetting agent Substances 0.000 claims description 12
- 239000004094 surface-active agent Substances 0.000 claims description 11
- 239000004563 wettable powder Substances 0.000 claims description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 9
- 239000003094 microcapsule Substances 0.000 claims description 9
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 238000009472 formulation Methods 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 7
- 239000008158 vegetable oil Chemical class 0.000 claims description 7
- 229920001285 xanthan gum Polymers 0.000 claims description 7
- 241000196324 Embryophyta Species 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 239000000725 suspension Substances 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 5
- 235000010489 acacia gum Nutrition 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 5
- 244000144730 Amygdalus persica Species 0.000 claims description 4
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 4
- 150000002170 ethers Chemical class 0.000 claims description 4
- 229920000591 gum Polymers 0.000 claims description 4
- 150000002576 ketones Chemical class 0.000 claims description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- 241000416162 Astragalus gummifer Species 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- 229920001800 Shellac Polymers 0.000 claims description 3
- 229920001615 Tragacanth Polymers 0.000 claims description 3
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 229940105329 carboxymethylcellulose Drugs 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 235000010981 methylcellulose Nutrition 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000004208 shellac Substances 0.000 claims description 3
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 3
- 235000013874 shellac Nutrition 0.000 claims description 3
- 229940113147 shellac Drugs 0.000 claims description 3
- 235000010487 tragacanth Nutrition 0.000 claims description 3
- 239000000196 tragacanth Substances 0.000 claims description 3
- 229940116362 tragacanth Drugs 0.000 claims description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 claims description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 2
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 claims description 2
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 claims description 2
- 235000010413 sodium alginate Nutrition 0.000 claims description 2
- 239000000661 sodium alginate Substances 0.000 claims description 2
- 229940005550 sodium alginate Drugs 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 230000000704 physical effect Effects 0.000 claims 1
- 150000004671 saturated fatty acids Chemical class 0.000 claims 1
- 239000002917 insecticide Substances 0.000 abstract description 53
- 238000002360 preparation method Methods 0.000 abstract description 40
- 241000607479 Yersinia pestis Species 0.000 abstract description 29
- 239000003814 drug Substances 0.000 abstract description 25
- 230000000749 insecticidal effect Effects 0.000 abstract description 12
- 229940079593 drug Drugs 0.000 abstract description 5
- 235000013311 vegetables Nutrition 0.000 abstract description 5
- 230000000361 pesticidal effect Effects 0.000 abstract description 4
- 241000256247 Spodoptera exigua Species 0.000 abstract description 3
- 239000000447 pesticide residue Substances 0.000 abstract description 3
- 241000255777 Lepidoptera Species 0.000 abstract description 2
- 241000255969 Pieris brassicae Species 0.000 abstract description 2
- 241000500437 Plutella xylostella Species 0.000 abstract description 2
- 230000009931 harmful effect Effects 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 39
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Natural products O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 33
- 210000000481 breast Anatomy 0.000 description 25
- 238000012360 testing method Methods 0.000 description 24
- 239000000047 product Substances 0.000 description 22
- 230000000694 effects Effects 0.000 description 17
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical group CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- 239000007859 condensation product Substances 0.000 description 12
- 239000000843 powder Substances 0.000 description 12
- 231100000419 toxicity Toxicity 0.000 description 12
- 230000001988 toxicity Effects 0.000 description 12
- 239000002270 dispersing agent Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 10
- 239000002585 base Substances 0.000 description 10
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- 229920000056 polyoxyethylene ether Polymers 0.000 description 9
- 229940051841 polyoxyethylene ether Drugs 0.000 description 9
- 239000005995 Aluminium silicate Substances 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- 235000012211 aluminium silicate Nutrition 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000005941 Thiamethoxam Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 7
- 229940117927 ethylene oxide Drugs 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 230000003449 preventive effect Effects 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 241001498622 Cixius wagneri Species 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 6
- 239000004495 emulsifiable concentrate Substances 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 4
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical group N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- XUZHLZDRCCUWEV-UHFFFAOYSA-N formaldehyde;methyl naphthalene-1-sulfonate Chemical compound O=C.C1=CC=C2C(S(=O)(=O)OC)=CC=CC2=C1 XUZHLZDRCCUWEV-UHFFFAOYSA-N 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 4
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- AIHZDRMFOVBNAV-UHFFFAOYSA-N 3-(2-phenylethyl)phenol Chemical compound OC1=CC=CC(CCC=2C=CC=CC=2)=C1 AIHZDRMFOVBNAV-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 241001272567 Hominoidea Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 3
- 206010033799 Paralysis Diseases 0.000 description 3
- QIOZLISABUUKJY-UHFFFAOYSA-N Thiobenzamide Chemical compound NC(=S)C1=CC=CC=C1 QIOZLISABUUKJY-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000006184 cosolvent Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000012875 nonionic emulsifier Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000010452 phosphate Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 231100000572 poisoning Toxicity 0.000 description 3
- 230000000607 poisoning effect Effects 0.000 description 3
- 238000006068 polycondensation reaction Methods 0.000 description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 2
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical group CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical group [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 241001414720 Cicadellidae Species 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- 229920005682 EO-PO block copolymer Polymers 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- 244000061176 Nicotiana tabacum Species 0.000 description 2
- 241001556089 Nilaparvata lugens Species 0.000 description 2
- 241000819999 Nymphes Species 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000019483 Peanut oil Nutrition 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical group [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 241001074085 Scophthalmus aquosus Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 239000003849 aromatic solvent Substances 0.000 description 2
- 229960000892 attapulgite Drugs 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- 229940092782 bentonite Drugs 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229960005082 etohexadiol Drugs 0.000 description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 2
- 239000010903 husk Substances 0.000 description 2
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229940059904 light mineral oil Drugs 0.000 description 2
- 229920005610 lignin Polymers 0.000 description 2
- 230000010534 mechanism of action Effects 0.000 description 2
- 239000010445 mica Substances 0.000 description 2
- 229910052618 mica group Inorganic materials 0.000 description 2
- 229910052625 palygorskite Inorganic materials 0.000 description 2
- 239000000312 peanut oil Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 239000008159 sesame oil Substances 0.000 description 2
- 235000011803 sesame oil Nutrition 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000009331 sowing Methods 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 210000002784 stomach Anatomy 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 229930192474 thiophene Natural products 0.000 description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- ZITVKGIRQCDOSX-UHFFFAOYSA-N 1h-cyclopropa[a]naphthalene Chemical compound C1=CC=CC2=C3CC3=CC=C21 ZITVKGIRQCDOSX-UHFFFAOYSA-N 0.000 description 1
- RQJQQSAYDFANNM-UHFFFAOYSA-N 2,3-dibutylnaphthalene-1-sulfonic acid;formaldehyde Chemical compound O=C.C1=CC=C2C(S(O)(=O)=O)=C(CCCC)C(CCCC)=CC2=C1 RQJQQSAYDFANNM-UHFFFAOYSA-N 0.000 description 1
- DMAXMXPDVWTIRV-UHFFFAOYSA-N 2-(2-phenylethyl)phenol Chemical compound OC1=CC=CC=C1CCC1=CC=CC=C1 DMAXMXPDVWTIRV-UHFFFAOYSA-N 0.000 description 1
- RWLALWYNXFYRGW-UHFFFAOYSA-N 2-Ethyl-1,3-hexanediol Chemical compound CCCC(O)C(CC)CO RWLALWYNXFYRGW-UHFFFAOYSA-N 0.000 description 1
- 125000001340 2-chloroethyl group Chemical class [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- FNRMMDCDHWCQTH-UHFFFAOYSA-N 2-chloropyridine;3-chloropyridine;4-chloropyridine Chemical compound ClC1=CC=NC=C1.ClC1=CC=CN=C1.ClC1=CC=CC=N1 FNRMMDCDHWCQTH-UHFFFAOYSA-N 0.000 description 1
- YFDKVXNMRLLVSL-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid;sodium Chemical compound [Na].CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O YFDKVXNMRLLVSL-UHFFFAOYSA-N 0.000 description 1
- WODGMMJHSAKKNF-UHFFFAOYSA-N 2-methylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C)=CC=C21 WODGMMJHSAKKNF-UHFFFAOYSA-N 0.000 description 1
- BFFQFGGITJXTFP-UHFFFAOYSA-N 3-methyldioxetane Chemical compound CC1COO1 BFFQFGGITJXTFP-UHFFFAOYSA-N 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241001474374 Blennius Species 0.000 description 1
- QOYXIHSMOOWKSF-XXAVUKJNSA-N CNCC[Na].C(CCCCCCC\C=C/CCCCCCCC)(=O)O Chemical compound CNCC[Na].C(CCCCCCC\C=C/CCCCCCCC)(=O)O QOYXIHSMOOWKSF-XXAVUKJNSA-N 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- 240000008384 Capsicum annuum var. annuum Species 0.000 description 1
- 241000131329 Carabidae Species 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000289763 Dasygaster padockina Species 0.000 description 1
- 241001517923 Douglasiidae Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- 208000012895 Gastric disease Diseases 0.000 description 1
- 244000299507 Gossypium hirsutum Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 241000256602 Isoptera Species 0.000 description 1
- 240000007049 Juglans regia Species 0.000 description 1
- 235000009496 Juglans regia Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241000254043 Melolonthinae Species 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 241001556090 Nilaparvata Species 0.000 description 1
- 241000256259 Noctuidae Species 0.000 description 1
- 241000282376 Panthera tigris Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical group ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- OIPILFWXSMYKGL-UHFFFAOYSA-N acetylcholine Chemical compound CC(=O)OCC[N+](C)(C)C OIPILFWXSMYKGL-UHFFFAOYSA-N 0.000 description 1
- 229960004373 acetylcholine Drugs 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 125000004432 carbon atom Chemical class C* 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- PSOVNZZNOMJUBI-UHFFFAOYSA-N chlorantraniliprole Chemical compound CNC(=O)C1=CC(Cl)=CC(C)=C1NC(=O)C1=CC(Br)=NN1C1=NC=CC=C1Cl PSOVNZZNOMJUBI-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 230000008828 contractile function Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 229940099112 cornstarch Drugs 0.000 description 1
- 238000007405 data analysis Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- NHFDKKSSQWCEES-UHFFFAOYSA-N dihydrogen phosphate;tris(2-hydroxyethyl)azanium Chemical compound OP(O)(O)=O.OCCN(CCO)CCO NHFDKKSSQWCEES-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004920 integrated pest control Methods 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical group 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000011419 magnesium lime Substances 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 210000000663 muscle cell Anatomy 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000010773 plant oil Chemical class 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000003223 protective agent Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 102000042094 ryanodine receptor (TC 1.A.3.1) family Human genes 0.000 description 1
- 108091052345 ryanodine receptor (TC 1.A.3.1) family Proteins 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- JAJWGJBVLPIOOH-IZYKLYLVSA-M sodium taurocholate Chemical compound [Na+].C([C@H]1C[C@H]2O)[C@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@@H](CCC(=O)NCCS([O-])(=O)=O)C)[C@@]2(C)[C@@H](O)C1 JAJWGJBVLPIOOH-IZYKLYLVSA-M 0.000 description 1
- 239000003516 soil conditioner Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of agricultural pesticide composition containing sulphur insect amide (HY366) and Diacloden and application thereof.Sulphur insect amide and Diacloden are according to weight ratio 1~100:1~100 mixture has significant synergies prevention water rice hopper and corn black cutworm pest, not only increases insecticidal effect, also reduces drug cost, reduces environmental pollution and pesticide residue, also helps the generation for overcoming and delaying pest resistance to insecticide.Agricultural pesticide composition of the present invention can be applied to the lepidoptera pests such as vegetables prevention diamondback moth, beet armyworm, cabbage caterpillar.Agricultural pesticide composition of the present invention is all normal without obvious harmful effect, leaf color, growing way etc. to trial crops, and security is good, meets the security requirement of pesticidal preparations.
Description
【Technical field】
The invention belongs to technical field of pesticide.It is more particularly it relates to a kind of containing sulphur insect amide and Diacloden
Agricultural pesticide composition, further relates to the purposes of the agricultural pesticide composition.
【Background technology】
Lepidoptera pest with cabbage caterpillar, diamondback moth, beet armyworm etc. for representative is the weight of China most area vegetables
Want pest.The class pest influences vegetables normal growth by feeding plant leaf, can also pass through the brill moth (twill at such as advanced age
Noctuid and beet armyworm can brill moth tomato, green peppers etc.) cause harm, seriously affect the quality and market value of vegetables.Chemical prevention is
The main means for controlling above-mentioned pest to cause harm, but as the continuous of chemical agent is applied, resistance problem becomes increasingly conspicuous, and in agricultural
During produce reality, pest resistance to insecticide problem is an important factor for influencing pest controling effect.Different active ingredients are carried out
Compounding can expand prevention spectrum and improve preventive effect, be the effective measures of pest resistance treatment.
Sulphur insect amide (HY366) can be combined with ryanodine receptor, cause Ca2+The out of control and loss of release, makes muscle cell
Contractile function paralysis, be brand-new mechanism of action compound.Pest after chemicals treatment, which shows as feeding, to stop rapidly, is weary
Power, gastric disorder causing nausea and Muscle paralysis, until dead.This insecticides insecticidal spectrum is wide, the longevity of residure is long, toxicity is low, environmentally friendly, with showing
Each insecticides no interactions resistance having.Each Species of Lepidopterous Insect Pests and some coleoptera larvaes, adult can be effectively prevented, also
It can be used for preventing the pests such as ant, termite.
Diacloden (Thiamethoxam) is a kind of second generation nicotinoids high-efficient low toxicity insecticide of brand new, to pest
With stomach toxicity, tag and systemic activity, for foliar spray and soil root irrigation.Rapidly by interior suction after its dispenser, and conduct
To each position of plant, there is good preventive effect to sucking pest such as aphid, plant hopper, leafhopper, aleyrodid and subterranean pest-insect etc..Different agricultures
Medicine kind mixture is the common methods of the agriculture resistant insect of prevention.Screened by formulation of pesticide, filter out rational formula, can had
Effect improves actual prevention effect, reduces dosage, reduces cost, delay the generation of pest resistance to insecticide, and extend medicament uses the longevity
Life, is the important means of integrated pest management.
But these prior arts are not met by current agricultural production needs, therefore also need there are some technological deficiencies
New efficient prevention rice, the Pesticidal combination of vegetable insect disease are developed, this is for promoting agriculture large-scale development to have pole
Its important meaning.
【The content of the invention】
[technical problems to be solved]
The object of the present invention is to provide a kind of agricultural pesticide composition.
It is a further object to provide the purposes of the agricultural pesticide composition.
[technical solution]
The present invention is achieved through the following technical solutions.
The present invention relates to a kind of agricultural pesticide composition.
The agricultural pesticide composition is by the compound with following chemical constitution formula (I)s and with following chemical constitutions
The compound of formula (II) is according to weight ratio 1~50:1~50 composition:
A preferred embodiment of the invention, chemical constitution formula (I) compound and chemical constitution formula (II) chemical combination
The weight ratio of thing is 10~40:8~42.
Another kind preferred embodiment according to the present invention, chemical constitution formula (I) compound and chemical constitution formula (II)
The weight ratio of compound is 18~32:16~34.
The present invention relates to a kind of agricultural fungicides.The agricultural fungicides contains by weight described in 0.5~95.0%
Agricultural pesticide composition and surplus be agriculturally acceptable carrier and auxiliary agent.
A preferred embodiment of the invention, the agricultural fungicides contain by weight described in 20~70%
Agricultural pesticide composition and surplus be agriculturally acceptable carrier and auxiliary agent.
Another kind preferred embodiment, the agricultural fungicides contain 30~60% institute by weight according to the present invention
The agricultural pesticide composition and surplus stated are agriculturally acceptable carrier and auxiliary agent.
Another kind preferred embodiment according to the present invention, the agricultural fungicides are wettable powder, suspending agent, hang
The formulations such as emulsion, microemulsion, aqueous emulsion, water-dispersible granules or microcapsule suspending agent.
Another kind preferred embodiment according to the present invention, the carrier that uses of the present invention are solid carrier or liquid-carrier,
The solid carrier is selected from silicate, carbonate, sulfate, oxide, alkali metal salt, vegetalitas carrier or synthetic filling class
Carrier;The liquid-carrier is selected from water, aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, aliphatic hydrocarbon, alcohols, ethers, ketone, vegetable oil, methylate plant
Thing is oily or other special solvents.
Another kind preferred embodiment according to the present invention, the auxiliary agent are selected from surfactant, defoamer, thickening
Agent, suspending agent and antifreezing agent;The surfactant is for the surface in emulsifying agent, dispersant, stabilizer or wetting agent
Activating agent;The defoamer is selected from bubble enemy, silicone, C8~10Fatty alcohol, C10~20Saturated fatty acid or acid amides defoamer;Institute
The thickener stated is selected from carboxymethyl alcohol, polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, gum arabic, polyethylene pyrrole
Pyrrolidone, Magnesiumaluminumsilicate, polyvinyl alcohol, polyethylene glycol, phenolic resin, shellac, carboxymethyl cellulose or sodium alginate;Described
Suspending agent is selected from glycerine, Arabic gum, tragacanth, peach gum, methylcellulose, sodium carboxymethylcellulose or hydroxy propyl cellulose
Element;The antifreezing agent is selected from glycerine, urea, ethylene glycol or propane diols.
The invention further relates to the agricultural insecticidal composite or the agricultural insecticide in prevention rice hoppers or corn
Purposes in seed pelleting prevention black cutworm.
The present invention is described in more detail below.
The present invention relates to a kind of agricultural pesticide composition.
The agricultural pesticide composition by the compound sulphur insect amide with following chemical constitution formula (I)s with following
The compound Diacloden of chemical constitution formula (II) is according to weight ratio 1~50:1~50 composition:
In agricultural pesticide composition of the present invention, the chemical entitled bromo- 1- (3- of 3- of the chemical constitution formula (I) compound
Chloropyridine -2- bases)-N- [2,4- bis- chloro- 6- (isopropylamino thioformyl) phenyl] -1H- pyrazoles -5- formamides (English
Common name Thiotraniliprole) (sulphur insect amide, represented for simplicity with HY366), it is according to CN 103130770
Prepared by the method for B descriptions.Sulphur insect amide belongs to O-formammidotiazol-benzamide insecticide, its insecticidal activity and E.I.Du Pont Company
The Rynaxypyr insecticidal activity of development is essentially identical, and insecticidal spectrum is wide, the longevity of residure is long, toxicity is low, environmentally friendly, and existing
Each insecticides no interactions resistance.Each Species of Lepidopterous Insect Pests can be effectively prevented, but it is low to homoptera pest activity.They
Solubility in multi-solvents is preferable, can easily prepare water baseization such as high-content aqueous emulsion, microemulsion, suspending agent environmental protection system
Agent.
In agricultural pesticide composition of the present invention, chemical entitled 3- (chloro- 1, the 3- thiophenes of 2- of chemical constitution formula (II) compound
Azoles -5- ylmethyls) -5- methyl isophthalic acids, 3,5- oxadiazines -4- bases fork (nitro) amine (referred to as Diacloden, English common name
Thiamethoxam).Diacloden is alternative to suppress insect CNS nicotinic acetylcholine esterase acceptor, and then blocks
Insect CNS normal conduction, causes pest to occur dead during paralysis machine.It not only have tag, stomach toxicity, it is interior inhale live
Property, but also have the characteristics that more high activity, more preferable security, wider insecticidal spectrum and work fast, lasting period are long.It can
Effectively prevent various aphids, leafhopper, plant hopper, aleyrodid, chafer larva, colorado potato bug, nematode, ground beetle, leaf miner
Deng pest.It can be not only used for cauline leaf process, seed treatment, can also be used for soil treatment.It is suitable for rice class crop, beet, oil
Dish, potato, cotton, Kidney bean, fruit tree, peanut, sunflower, soybean, tobacco and citrus etc..
The Diacloden that the present invention uses is current market sales of product, such as by Syngenta Co., Ltd with trade name Acker
25% Diacloden water dispersible granules product of Thailand's sale.
In agricultural pesticide composition of the present invention, when the amount of chemical constitution formula (II) compound is in the scope, such as
The amount of fruit chemical constitution formula (I) compound is higher than the scope of the amount, then can be high because of dosage, and security declines, and poisoning easily occurs;
If the amount of chemical constitution formula (I) compound is less than the scope of the amount, can be relatively low to pest preventive effect.
When the amount of chemical constitution formula (I) compound is in the scope, if the amount of chemical constitution formula (II) compound
, also can be high because of dosage higher than the scope of the amount, security declines, and poisoning easily occurs;If chemical constitution formula (II) compound
Amount be less than the amount scope, then can be relatively low to pest preventive effect.
Therefore, in agricultural pesticide composition of the present invention, chemical constitution formula (I) compound and chemical constitution formula (II) chemical combination
The weight ratio of thing is 1~50:1~50 is rational.
Preferably, chemical constitution formula (I) compound and the weight ratio of chemical constitution formula (II) compound are 10~40:8~
42。
It is highly preferred that chemical constitution formula (I) compound and the weight ratio of chemical constitution formula (II) compound are 18~32:16
~34.
The present invention relates to a kind of agricultural fungicides.The agricultural fungicides contains by weight described in 0.5~95.0%
Agricultural pesticide composition and surplus be agriculturally acceptable carrier and auxiliary agent.
In the present invention, the carrier or auxiliary agent in Pesticide formulation or use it should be understood that be used to improve medicine
Agent physicochemical property, improve drug effect, be readily transported storage etc. performance auxiliary substances, such as wetting agent, emulsifying agent, dispersant,
Sticker, stabilizer or synergist etc..According to the present invention, it is every that there are these performances and agricultural fungicides of the present invention is not appointed
The chemical substance of what negative effect may be used to the present invention, they are all within protection scope of the present invention.
According to the present invention, can be because having if the agricultural pesticide composition content of the agricultural fungicides is less than 0.5%
Effect component is low, is unfavorable for the manufacturing of product from economic angle;If the agricultural pesticide composition of the agricultural fungicides
When content is higher than 95.0%, then because of the too high performance for being unfavorable for drug effect of content and poisoning can be also easy to produce;Therefore, the agricultural insecticidal
The agricultural pesticide composition content of agent is appropriate for 0.5~95.0%.
Preferably, the agricultural fungicides contains the agricultural pesticide composition and surplus described in 20~70% by weight
For agriculturally acceptable carrier and auxiliary agent.
It is highly preferred that the agricultural fungicides contains the agricultural pesticide composition described in 30~60% by weight and remaining
Measure as agriculturally acceptable carrier and auxiliary agent.
In the present invention, the carrier used is solid carrier or liquid-carrier.
The solid carrier is selected from silicate, carbonate, sulfate, oxide, alkali metal salt, vegetalitas carrier or conjunction
Into earthfill rockfill concrete riprap RCC carrier etc..
Wherein silicate, carbonate, sulfate and oxide carrier are mineral substance carrier.
For example, silicate carrier is kaolin, sepiolite, nacrite, montmorillonite, mica, vermiculite, pyrophyllite or talcum
Deng.
Carbonate support is calcium carbonate or dolomite etc..
Sulfate carrier is ammonium sulfate, sodium sulphate or calcium sulfate etc..
Oxide carrier is quick lime, magnesium lime or diatomite etc..
Alkali metal salt carrier is potassium chloride or sodium chloride etc..
Vegetalitas carrier is citrus pulp, corncob cellulose, rice husk powder, rice husk, big soya bean stem meal, tobacco powder, walnut shell or sawmilling
Powder etc..
Synthetic filling class carrier is winnofil hydrate, winnofil or white carbon etc..
These solid carriers that the present invention uses all are to be sold in the art known to technical staff, currently on the market
The product sold, or the accessory substance of widely known agricultural byproducts processing.
The liquid-carrier (solvent) is selected from water, aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, aliphatic hydrocarbon, alcohols, ethers, ketone, plant
Oil, methylated vegetable oils or other special solvents.
For example, aromatic hydrocarbons carrier is benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons etc..
Chlorinated aliphatic hydrocarbon carrier is vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and more chloroethanes etc..
Aliphatic hydrocarbon carrier is petroleum distillate, hexamethylene, light mineral oil or paraffin etc., such as limited by Jiangsu China human relations chemical industry
The S-200 fat hydrocarbon products being mainly made of octane and heptane of company's sale.
Alcoholic vehicle is methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol, propane diols, glycerine or fatty alcohol
Deng.
Ethers carrier is Propylene Glycol ether, ethohexadiol ether or petroleum ether etc..
Ketone is acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), cyclohexanone, isophorone or N- methyl-pyrrolidons etc..
In the present invention, the special solvent is it should be understood that the solvent being used in mixed way with one or more of solvents.It is described
Solvent in special solvent is dimethylformamide, dimethyl sulfoxide (DMSO), polyethylene glycol or nitrile etc..
Vegetable oil is soybean oil, rapeseed oil, peanut oil or sesame oil etc..
Methylated vegetable oils are methylated soya oil, rapeseed oil, peanut oil or sesame oil etc..What the present invention used methylates
Vegetable oil is all in current market sales of product.
The liquid-carrier that the present invention uses all is in the art known to technical staff, current market sales of
Product, for example, sold by Sinopec Group Hangzhou Refinery light mineral oil, by Shanghai Sheng Jun Industry investments Co., Ltd
Propylene Glycol ether, ethohexadiol ether, methyl iso-butyl ketone (MIBK), isophorone, the dimethylformamide of sale.
When using a kind of above-mentioned organic solvent when, this organic solvent can with single use, can also from it is other different
Organic solvent is used in mixed way, or is used in mixed way with water.When used as a mixture, its mixed proportion can according to actual use situation into
Row selection, this is that hell and high water is not present for those skilled in the art.
Surfactant of the auxiliary agent that the present invention uses in for emulsifying agent, dispersant, stabilizer or wetting agent, disappear
Infusion, thickener, suspending agent and antifreezing agent.
The surfactant is the surfactant used in emulsifying agent, dispersant, stabilizer or wetting agent.
The surfactant that the present invention uses can be ionic or non-ionic, such as polyacrylic acid sodium salt and calcium
Salt, lignin sulfonic acid sodium salt and calcium salt;With at least 12 carbon atom fatty acids or fatty amine and ethylene oxide and/or epoxy third
The polycondensation product of alkane;Glycerine, dodecanol -1, tetradecanol -1, sorbierite, sucrose or pentaerythritol fatty ester and they
With ethylene oxide and/or the polycondensation product of propylene oxide;The sulfate or sulfonate of the polycondensation product;With at least ten carbon
Atom alkyl sulfuric acid or sulfonate alkali metal or alkali salt, are preferably sodium salt, as lauryl sodium sulfate, secondary alkyl sulfuric acid
Sodium, sulfonated castor oil sodium salt, alkylaryl sodium sulfonate or neopelex;Ethylene oxide polymer or ethylene oxide and ring
Ethylene Oxide copolymer.
Emulsifying agent that the present invention uses is allowed to shape it should be understood that one kind can improve each phase interfacial surface tension in emulsion
Into the material of uniform and stable dispersion or emulsion.It is every that there are these performances and agricultural fungicides of the present invention is not appointed
The chemical substance of what negative effect may be used to the present invention, they are all within protection scope of the present invention.
The emulsifying agent that the present invention uses is nonionic emulsifier.For example, the nonionic emulsifier is selected from polyoxy
Ethene fatty acid ester, polyoxyethylene aliphatic alcohol ether and Polyoxyethylene fatty ammonia, as ethoxylated castor oil, polyoxyethylene (n20) benzene
Ethyl phenolic group oleic acid ester, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin polyoxyethylene ether, triphen second
Alkenyl phenol polyethenoxy (n20), ether phosphoric acid triethanolamine salt, Diphenethyl phenolic group polyoxyethylene ether (n18) formaldehyde condensation products,
Diphenyl phenol polyethenoxy (n18) polyethenoxy ether (n20) etc., these nonionic emulsifier are all current market sales of
Product, such as the polyoxyethylene (n provided by Jiangsu Kai Yuan Science and Technology Ltd.s20) phenethyl phenolic group oleic acid ester, alkylaryl
Formaldehyde resin polyoxyethylene ether, the diphenyl phenol polyethenoxy (n of sale18) polyethenoxy ether (n20).The emulsification that the present invention uses
Agent can be commercial emulsifier, such as agriculture breast 0201B, agriculture breast 0203B, agriculture breast 100#, agriculture breast 500#, agriculture breast 600#, agriculture breast 600-
2#, agriculture breast 1601, agriculture breast 2201, agriculture breast NP-10, agriculture breast NP-15, agriculture breast 507#, agriculture breast OX-635, agriculture breast OX-622, agriculture breast
OX-653, agriculture breast OX-667, agriculture breast CS-7 or peaceful breasts 36#。
Dispersant that the present invention uses is it should be understood that a kind of in the molecule while have a lipophilic fraction and hydrophily portion
Point interfacial agent, it be it is a kind of will can be difficult to be dissolved in solid in liquid dispersed with liquid particles, at the same time and also
It can be prevented to settle and agglomerate, form the material of stable suspension.It is every to there are these performances and to agricultural fungicides of the present invention
The chemical substance for not having any negative effect may be used to the present invention, they are all within protection scope of the present invention.
The dispersant that the present invention uses is, for example, sodium lignin sulfonate, pull open powder, calcium lignosulfonate, methyl naphthalene sulfonic acid first
Aldehyde condensate, naphthalene sulfonic acid-formaldehyde condensation product, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to uncle
Butyl ether, dibutyl naphthalenesulfonic acid formaldehyde condensation products, phosphate such as calgon, alkylphenol-polyethenoxy based phosphates, alkyl
Phenol polyethenoxy base ether formaldehyde condensation products sulfate, the contracting of N- methyl-fatty acyl group-sodium taurocholate alkylphenol polyoxyethylene ether formaldehyde
Compound, aralkyl phenol polyethenoxy ether phosphate alkylphenol polyoxyethylene ether, castor oil ethylene oxide adduct, ethylene oxide-
Propylene oxide block copolymer APES formaldehyde condensation product, alkylphenol-polyethenoxy polyethenoxy ether and methyl are fine
Dimension element.
The dispersant that the present invention uses all is current market sales of product, such as by Nanjing Teva-Chem. Co., Ltd.
N- methyl-fatty acyl groups-sodium taurocholate the APES formaldehyde condensation product of sale, castor oil ethyleneoxide addition
Thing, ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation product, alkylphenol-polyethenoxy Ji Mijia
Aldehyde condensate sulfate.
The stabilizer that the present invention uses is, for example, sodium lignin sulfonate.The stabilizer that the present invention uses all is currently on the market
The product of sale, such as the lignin series of products sold by virtue Visco Co..
Wetting agent that the present invention uses it should be understood that one kind can reduce solid material surface tension or interfacial tension,
The material that water easily spreads out and soaks solid material in its surface.It is every to there are these performances and to agricultural insecticidal of the present invention
The chemical substance that agent does not have any negative effect may be used to the present invention, they are all within protection scope of the present invention.
The wetting agent that the present invention uses is selected from sldium lauryl sulfate, alkylol polyoxyethylene base ether sodium sulfate, octylphenol polyethylene
Oxyethylene group ether sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, sodium alkyl sulfonate, dodecyl benzene sulfonic acid
Sodium, Negel, dialkyl succinylsuccinate sulfonate, lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium, alkyl amide sodium taurocholate, fat
Fat alcohol polyoxyethylene ether, alkylphenol-polyethenoxy base ether, polyoxyethylene polyoxypropylene block polymer, sorbitan fatty
Acid esters polyoxyethylene ether etc..
The wetting agent that the present invention uses all is current market sales of product, such as is sold by Xing Fei Chemical Co., Ltd.s
Alkylol polyoxyethylene base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulfate, lauryl alcohol polyethylene glycol oxide
Base ether sulfonic acid sodium, sorbitan fatty acid ester polyoxyethylene ether.
In addition to above-mentioned surfactant, the auxiliary agent that the present invention uses also has defoamer, thickener, suspending agent and antifreezing agent.
The defoamer that the present invention uses is it should be understood that a kind of material with chemistry and surface chemistry defoaming effect.It is every
It may be used to the present invention with these performances and the chemical substance that does not have any negative effect to agricultural fungicides of the present invention, it
All within protection scope of the present invention.
The defoamer is selected from bubble enemy, silicone, C8~10Fatty alcohol, C10~20Saturated fatty acid or acid amides defoamer;
The defoamer that the present invention uses all is current market sales of product, such as is sold by Nanjing Jie Run Co., Ltds
Bubble enemy, C10~20Saturated fatty acid, acid amides defoamer.
The thickener that the present invention uses is it should be understood that one kind can emulsify agricultural fungicides of the present invention, it is possible to increase kill
Worm agent viscosity simultaneously reaches stable material.It is every that there are these performances and do not have any negative shadow to agricultural fungicides of the present invention
Loud chemical substance may be used to the present invention, they are all within protection scope of the present invention.
The thickener is selected from carboxymethyl alcohol, polyvinyl alcohol, polyvinyl acetate, xanthans, gelatin, Arabic tree
Glue, polyvinylpyrrolidone, Magnesiumaluminumsilicate, polyvinyl alcohol, polyethylene glycol, phenolic resin, shellac, carboxymethyl cellulose or seaweed
Sour sodium;
The thickener that the present invention uses all is current market sales of product, such as by Beijing Green Tai Mu Co., Ltds
Carboxymethyl alcohol, the polyvinylpyrrolidone of sale.
The suspending agent that the present invention uses is it should be understood that one kind can increase agricultural fungicides viscosity of the present invention to reduce
Wherein particulate sinking speed or the increase hydrophilic material of particulate.It is every that there are these performances and do not have to agricultural fungicides of the present invention
The chemical substance for having any negative effect may be used to the present invention, they are all within protection scope of the present invention.
The suspending agent is selected from glycerine, Arabic gum, tragacanth, peach gum, methylcellulose, sodium carboxymethylcellulose
Or hydroxypropyl cellulose.
The suspending agent that the present invention uses all is current market sales of product, such as by Nanjing Guan Hua trade Co., Ltds
Xanthans, peach gum, the sodium carboxymethylcellulose of sale.
The antifreezing agent that the present invention uses is it should be understood that one kind can prevent agricultural fungicides of the present invention in microthermal climate ring
The material freezed under border.It is every that there are these performances and do not have the chemistry of any negative effect to agricultural fungicides of the present invention
Material may be used to the present invention, they are all within protection scope of the present invention.
The antifreezing agent is selected from glycerine, urea, ethylene glycol or propane diols.
The antifreezing agent that the present invention uses all is current market sales of product.
According to the present invention, the agricultural fungicides for wettable powder, suspending agent, suspension emulsion, microemulsion, aqueous emulsion,
The formulation such as water dispersion granule or microcapsule suspending agent.
When agricultural fungicides of the present invention is wettable powder, its preparation method is as follows:To 0.5%~80% institute by weight
Agricultural pesticide composition, 2%~10% wetting agent, 5%~10% dispersant and the filler of surplus to 100% stated are fully mixed
Close, reuse ultrafine crusher or airslide disintegrating mill commonly used in the art and crushed, obtain the wettable powder.
The filler that the present invention uses is kaolin, diatomite, mica powder, bentonite, attapulgite or precipitated calcium carbonate;The present invention uses
Other raw materials it is as previously described, similarly hereinafter, therefore repeat no more.
When agricultural fungicides of the present invention is suspending agent, its preparation method is as follows:By by weight described in 0.5%~50%
Agricultural pesticide composition, 1%~5% wetting agent, 1%~8% dispersant, 0.1%~1% thickener, 2%~5% antifreezing agent
It is uniformly mixed with the water for being supplemented to 100%, then is sanded in sand mill to 2~5 microns of particle diameter, filtering, then toward in its filtrate
Thickener is added, shear agitation is uniform, obtains the suspending agent.
When agricultural fungicides of the present invention is microemulsion, its preparation method is as follows:By by weight described in 0.5%~40%
Agricultural pesticide composition, 1%~12% emulsifying agent, 0%~10% cosolvent, 0%~5% stabilizer, 0%~40% solvent with
It is supplemented to 100% water to be added in reaction kettle, stirs evenly and be completely dissolved, be slowly added into pure water, stirring while adding, mixing
Uniformly, the microemulsion is obtained.The cosolvent that is used when preparing microemulsion of the present invention is, for example, isopropanol, cyclohexanone, under
Together, therefore repeat no more.They are all current market sales of products, such as are sold by Jinan, Shandong Province Guo Tai Chemical Co., Ltd.s
The isopropanol product sold or the cyclohexanone product sold by Nanjing Royal DSM company.
When agricultural fungicides of the present invention is aqueous emulsion, its preparation method is as follows:By by weight described in 0.5%~80%
Agricultural pesticide composition, 1%~20% emulsifying agent, 0%~15% cosolvent, 0%~5% stabilizer, 10%~40% solvent
Water with being supplemented to 100% is added in reaction kettle, is stirred evenly and is completely dissolved, and is slowly added into pure water, stirring while adding, is mixed
Close and uniformly, obtain the aqueous emulsion.
When agricultural fungicides of the present invention is suspension emulsion, its preparation method is as follows:Take by weight described in 0.5%~90%
Agricultural pesticide composition, 1%~5% solvent, 1%~5% dispersant, 1%~10% emulsifying agent, 1%~5% wetting agent, 1%
~5% stabilizer, 0%~5% antifreezing agent, 0%~5% thickener, 0%~5% defoamer and the water for being supplemented to 100%, so
Sulphur insect amide is prepared into aqueous emulsion according to the preparation method of above-mentioned aqueous emulsion afterwards, while according to the preparation method of above-mentioned suspending agent
Diacloden is prepared into suspending agent, then, the aqueous emulsion and the suspending agent are uniformly mixed, is obtained described
Suspension emulsion.Alternatively, Diacloden is prepared into aqueous emulsion according to the preparation method of above-mentioned aqueous emulsion, while according to above-mentioned suspending agent
Sulphur insect amide is prepared into suspending agent by preparation method, then, the aqueous emulsion and the suspending agent is uniformly mixed, obtained
The suspension emulsion.
When agricultural fungicides of the present invention is water dispersion granule, its preparation method is as follows:Will by weight 0.5%~80%
The agricultural pesticide composition, 0%~2% surfactant, 1%~15% wetting agent, 1%~15% dispersant, 1%~
10% disintegrant, 0%~5% stabilizer, the filler co-grinding with being supplemented to 100%, add water kneading, are made in comminutor
Grain, dry, screening, obtain the water dispersion granule.The disintegrant that the present invention uses is ammonium sulfate or carboxymethyl cellulose
Sodium;The filler that the present invention uses is kaolin, diatomite or cornstarch.
When agricultural fungicides of the present invention is microcapsule suspending agent, its preparation method is as follows:Take 0.5%~70% institute by weight
It is the agricultural pesticide composition stated, 1%~20% emulsifying agent, 1%~20% solvent, 0%~10% thickener, 0%~10% anti-
Freeze agent, 0%~5% stabilizer, 0%~5% defoamer, 1%~10% microcapsules carrier and the water for being supplemented to 100%;Use
Sulphur insect amide, Diacloden, emulsifying agent, solvent and stabilizer are encapsulated in the microcapsules of particle diameter D90≤50 μm by microcapsules carrier, are used
Carrier is made in water, antifreezing agent, thickener and defoamer, they are uniformly mixed, and microcapsule suspending agent is made.The present invention uses micro-
Capsule carrier is isocyanates.
The invention further relates to the agricultural insecticidal composite or the agricultural insecticide in prevention rice hoppers or corn
Purposes in seed pelleting prevention black cutworm.
The active component application dosage of agricultural pesticide composition and agricultural fungicides of the present invention is 50ga.i./hm2~200g
a.i./hm2.Agricultural pesticide composition and agricultural fungicides of the present invention can use conventional method to apply, such as injection, spraying.
Its amount of application can change according to weather conditions or crop growthing state, can be applied before or after pest damage generation
With.The duration of protective effect is usually related with the content of single compound in composition, also related to extraneous factor, such as
Weather, but the influence of weather can be slowed down by using appropriate formulation.
Agricultural pesticide composition and agricultural fungicides of the present invention can also be with other compounds with weeding, bactericidal property
It is used in mixed way, can also be used in mixed way with nematicide, protective agent, growth regulator, nutrient for plants or soil conditioner.
[beneficial effect]
Agricultural pesticide composition of the present invention has following beneficial effects:
Agricultural pesticide composition of the present invention containing sulphur insect amide (HY366) and Diacloden is to prevention water rice hopper and corn
Black cutworm pest has significant synergies, and not only increases insecticidal effect, also reduces drug cost, and it is dirty to reduce environment
Dye and pesticide residue, also help the generation for overcoming and delaying pest resistance to insecticide.Agricultural pesticide composition of the present invention can be applied to
Rice and corn prevention planthopper and corn black cutworm pest.Agricultural pesticide composition of the present invention is to trial crops without obvious
Harmful effect, leaf color, growing way etc. is all normal, and security is good, meets the security requirement of pesticidal preparations.
【Embodiment】
The present invention is will be better understood that by following embodiments.
First, the preparation of agricultural fungicides of the present invention
Embodiment 1:Prepare 50%HY366 Diacloden wettable powders
Weigh with 40% chemical constitution formula (I) sulphur insect amide of this insecticide wettable powder gross weight meter, 10% chemistry knot
Structure formula (II) Diacloden, 2% lauryl sodium sulfate, 5% White Carbon black, 10% sodium lignin sulfonate be supplemented to 100% it is light
Matter calcium carbonate, insecticide wettable powder of the present invention is obtained according to the preparation method described in present specification.
Embodiment 2:Prepare 60%HY366 Diacloden wettable powders
Weigh with 38% chemical constitution formula (I) sulphur insect amide of this insecticide wettable powder gross weight meter, 22% chemistry knot
Structure formula (II) Diacloden, 2% lauryl sodium sulfate, 5% naphthalene sulfonic acid-formaldehyde condensation product, 4% sodium lignin sulfonate, 6% white carbon
The black precipitated calcium carbonate with being supplemented to 100%, insecticide of the present invention is obtained according to the preparation method described in present specification
Wettable powder.
Embodiment 3:Prepare 74%HY366 Diacloden wettable powders
Weigh with 34% chemical constitution formula (I) sulphur insect amide of this insecticide wettable powder gross weight meter, 40% chemistry knot
Structure formula (II) Diacloden, 8% sodium lignin sulfonate, 6% methyl naphthalene sulfonate formaldehyde condensate, 2% lauryl sodium sulfate,
5% White Carbon black and be supplemented to 100% kaolin, obtain desinsection of the present invention according to the preparation method described in present specification
Agent wettable powder.
Embodiment 4:Prepare 56%HY366 Diacloden water dispersion granules
Weigh with 8% chemical constitution formula (I) sulphur insect amide of this insecticide water dispersion granule gross weight meter, 48% chemistry knot
Structure formula (II) Diacloden, 13% sodium lignin sulfonate, 5% methyl naphthalene sulfonate formaldehyde condensate, 9% ammonium sulfate are with being supplemented to
100% kaolin, insecticide water dispersion granule of the present invention is obtained according to the preparation method described in present specification.
Embodiment 5:Prepare 95%HY366 Diacloden water dispersion granules
Weigh with 45% chemical constitution formula (I) sulphur insect amide of this insecticide water dispersion granule gross weight meter, 50% chemistry
Structure formula (II) Diacloden, 2% naphtholsulfonic acid formaldehyde condensation products, 1%N- methyl-oleoyl-sodium taurocholate, 1% soluble shallow lake
Powder and be supplemented to 100% kaolin, obtain insecticide moisture of the present invention according to the preparation method described in present specification
Scattered seed agent.
Embodiment 6:Prepare 84%HY366 Diacloden water dispersion granules
Weigh with 44% chemical constitution formula (I) sulphur insect amide of this insecticide water dispersion granule gross weight meter, 40% chemistry
Structure formula (II) Diacloden, 3% naphtholsulfonic acid formaldehyde condensation products, 4%N- methyl-oleoyl-sodium taurocholate, 6% soluble shallow lake
Powder, 2% sodium sulphate and the kaolin for being supplemented to 100%, the present invention is obtained according to the preparation method described in present specification
Insecticide water dispersion granule.
Embodiment 7:Prepare 58%HY366 Diacloden water dispersion granules
Weigh with 36% chemical constitution formula (I) sulphur insect amide of this insecticide water dispersion granule gross weight meter, 22% chemistry
Structure formula (II) Diacloden, 6% methyl naphthalene sulfonate formaldehyde condensate, 10% sodium lignin sulfonate, 8% ammonium sulfate are with being supplemented to
100% kaolin, insecticide water dispersion granule of the present invention is obtained according to the preparation method described in present specification.
Embodiment 8:Prepare 42%HY366 Diacloden suspending agents
Weigh with 12% chemical constitution formula (I) sulphur insect amide of this insecticide suspending agent gross weight meter, 30% chemical structural formula
(II) Diacloden, 2% pull open powder, 3%Soproplot SC, 0.05% xanthans, 1% aluminium-magnesium silicate, 0.3%418G, 0.1%
BIT and be supplemented to 100% water, obtain insecticide suspending agent of the present invention according to the preparation method described in present specification.
Embodiment 9:Prepare 26%HY366 Diacloden suspending agents
Weigh with 21% chemical constitution formula (I) sulphur insect amide of this insecticide suspending agent gross weight meter, 5% chemical structural formula
(II) Diacloden, 2% pull open powder, 3%Soproplot SC, 0.12% xanthans, 1% aluminium-magnesium silicate, 0.2%418G, 0.1%
BIT and be supplemented to 100% water, obtain insecticide suspending agent of the present invention according to the preparation method described in present specification.
Embodiment 10:Prepare 22%HY366 Diacloden suspending agents
Weigh with 16% chemical constitution formula (I) sulphur insect amide of this insecticide suspending agent gross weight meter, 6% chemical structural formula
(II) Diacloden, 5% polycarboxylate, 1% White Carbon black, 1% attapulgite, 0.4% potassium dihydrogen phosphate, 4% ethylene glycol, 0.4%
Tributyl phosphate and be supplemented to 100% water, obtain insecticide of the present invention according to the preparation method described in present specification
Suspending agent.
Embodiment 11:Prepare 14%HY366 Diacloden suspending agents
Weigh with 6% chemical constitution formula (I) sulphur insect amide of this insecticide suspending agent gross weight meter, 8% chemical structural formula
(II) Diacloden, 3% methyl naphthalene sulfonate formaldehyde condensate, 1% bentonite, 4% agriculture breast OX-656,4% glycerine, 0.3%
Tributyl phosphate and be supplemented to 100% water, obtain insecticide of the present invention according to the preparation method described in present specification
Suspending agent.
Embodiment 12:Prepare 0.5%HY366 Diacloden suspending agents
Weigh with 0.25% chemical constitution formula (I) sulphur insect amide of this insecticide suspending agent gross weight meter, 0.25% chemistry knot
Structure formula (II) Diacloden, 4% phenethyl phenol polyoxyethylene poly-oxygen propylene aether, 1.8% Magnesiumaluminumsilicate, 0.3% xanthans, 3% the third
Glycol polyoxyethylene poly-oxygen propylene aether and be supplemented to 100% water, obtained according to the preparation method described in present specification
Insecticide suspending agent of the present invention.
Embodiment 13:Prepare 45%HY366 Diacloden missible oil
Weigh with 28% chemical constitution formula (I) sulphur insect amide of this insecticide emulsifiable concentrate gross weight meter, 17% chemical structural formula
(II) Diacloden, 7% agriculture breast 2201#, 4% agriculture breast 600#, 20% dimethylformamide and the S-200 aromatic hydrocarbons that is supplemented to 100% it is molten
Agent, insecticide emulsifiable concentrate of the present invention is obtained according to the preparation method described in present specification.
Embodiment 14:Prepare 15%HY366 Diacloden missible oil
Weigh with 9% chemical constitution formula (I) sulphur insect amide of this insecticide emulsifiable concentrate gross weight meter, 6% chemical constitution formula (II)
Diacloden, 3% agriculture breast 500#, 8% agriculture breast 0201B, 10% dimethylformamide and be supplemented to 100% S-200 aromatic solvents,
Insecticide emulsifiable concentrate of the present invention is obtained according to the preparation method described in present specification.
Embodiment 15:Prepare 29%HY366 Diacloden missible oil
Weigh with 11% chemical constitution formula (I) sulphur insect amide of this insecticide emulsifiable concentrate gross weight meter, 18% chemical structural formula
(II) Diacloden, 6% agriculture breast 0203B, 8% agriculture breast 0201B, 15% cyclohexanone and the S-200 aromatic solvents for being supplemented to 100%,
Insecticide emulsifiable concentrate of the present invention is obtained according to the preparation method described in present specification.
Embodiment 16:Prepare 45%HY366 Diacloden aqueous emulsions
Weigh with 25% chemical constitution formula (I) sulphur insect amide of this insecticide aqueous emulsion gross weight meter, 20% chemical structural formula
(II) Diacloden, 12%N- methyl pyrrolidones, 15% solvent naphtha, 6% dodecyl sodium sulfate, 4% polyvinyl alcohol, 4% breast
Agent 500#, 0.5% defoamer and be supplemented to 100% deionized water, according to the preparation method described in present specification
Obtain insecticide aqueous emulsion of the present invention.
Embodiment 17:Prepare 50%HY366 Diacloden aqueous emulsions
Weigh with 35% chemical constitution formula (I) sulphur insect amide of this insecticide aqueous emulsion gross weight meter, 15% chemical structural formula
(II) Diacloden, 13%N- methyl pyrrolidones, 15% solvent naphtha, 5% dodecyl sodium sulfate, 4% polyvinyl alcohol, 5.0%
Emulsifying agent 500#, 0.5% defoamer and be supplemented to 100% deionized water, according to the preparation side described in present specification
Method obtains insecticide aqueous emulsion of the present invention.
Embodiment 18:Prepare 42%HY366 Diacloden aqueous emulsions
Weigh with 13% chemical constitution formula (I) sulphur insect amide of this insecticide aqueous emulsion gross weight meter, 29% chemical structural formula
(II) Diacloden, 12%N- methyl pyrrolidones, 14% solvent naphtha, 3% 3 phenethyl phenol polyoxyethylene ether phosphate, 5% 3
Phenethyl phenol polyoxyethylene poly-oxygen propylene aether block copolymer, 0.5% defoamer, 4% ethylene glycol and be supplemented to 100% go from
Sub- water, insecticide aqueous emulsion of the present invention is obtained according to the preparation method described in present specification.
Embodiment 19:Prepare 39%HY366 thiamethoxam micro-emulsions
Weigh with 14% chemical constitution formula (I) sulphur insect amide of this insecticide microemulsion gross weight meter, 25% chemical structural formula
(II) Diacloden, 8% isopropanol, 24% trimethylbenzene, 18% propane diols polyoxyethylene poly-oxygen propylene aether and it is supplemented to 100%
Water, insecticide microemulsion of the present invention is obtained according to the preparation method described in present specification.
Embodiment 20:Prepare 34%HY366 thiamethoxam micro-emulsions
Weigh with 30% chemical constitution formula (I) sulphur insect amide of this insecticide microemulsion gross weight meter, 4% chemical structural formula
(II) Diacloden, 10% cyclohexanone, 20% solvent naphtha, 5% calcium dodecyl benzene sulfonate, 9% 3 phenethyl phenol polyoxyethylene gather
Oxypropylene ether block copolymers and be supplemented to 100% deionized water, obtained according to the preparation method described in present specification
To insecticide microemulsion of the present invention.
2nd, the measure of bioactivity
In order to further appreciate that the virulence of sulphur insect amide and Diacloden composition, a large amount of formulation screening tests have been carried out.
Agricultural pesticide composition biological activity determination of the present invention is as follows:
According to farm-chemical indoor determination test rule (agricultural industry criteria NY/T1154.7-2006, NY/T1154.14-
2008) carried out with initiative pesticide bioactivity evaluation SOP (insecticide volume).The preparation method system described according to present specification
The standby test medicine containing HY366 and Diacloden.
Brown Planthopper (Nilaparvata legen) raises worm kind (in temperature 27 with rice seedling throughout the year using indoor
Receive illumination according to 14h/d at DEG C).Selection indoor feeding to the consistent nymph of 3 age mid-terms is for experiment.Using spray-on process.
Experiment rice seedling selects water culture to cultivate to the rice seedling of 2 leaf, 1 heart (being about 3~4cm), is cleaned with clear water spare.By 4~
6 rice seedlings are fixed on crystobalite sand in the culture dish of Φ 7cm, meet CO2The Brown Planthopper 3 age mid-term nymph 30 of anesthesia
Left and right, is placed under Potter spray towers quantitative (2.5mL) spraying treatment (pressure 5Ib/iW2, settling amount 4.35mg/cm2).
Experiment sets the corresponding organic solvent without medicament and handles as control.Each processing is repeated 4 times, and transparent plastic cup cover is used after spraying
Firmly, be put in observation ward the inspection result after illumination 14h, 3d at 27 DEG C of temperature, polypide touched with writing brush, it is reactionless be considered as it is dead
Worm.
Black cutworm experiment is carried out using leaf dipping method.Appropriate maize leaf is submerged into 15s in liquid is tested, is taken out in logical
Dry in the shade, be put in the culture dish of diameter 9cm naturally at wind, connect 3 instar larvae of black cutworm according to 15/ware, one filter paper of upper cover, adds
Lid, mark.Experiment sets clear water processing control, and often processing is repeated 4 times.It is put in observation ward after illumination 14h, 3d at 27 DEG C of temperature
Inspection result, polypide is touched with writing brush, reactionless to be considered as dead worm.
The work borer population of each processing and total borer population are counted, calculates the death rate and corrected mortality (Abbott ' s of each processing
Formula);Data analysis statistical is carried out with " DPS data handling systems " V14.50 professional versions, obtains regression straight line, LC50Value.Use grandson
Yun Peifa (Sun etc., 1960) calculates toxicity index, and co-toxicity coefficient is calculated by following formula:
Contents (%) of the toxicity index × A of mixed toxicity index (the TTI)=A of theory in mixed
Contents (%) of the toxicity index × B of+B in mixed
When co-toxicity coefficient is more than 120, show that this mixture has synergistic effect;And co-toxicity coefficient be less than 80 when, show
This mixture has antagonism;And co-toxicity coefficient be more than 80 less than 120 when, show that this mixture has summation action.
HY366 and Diacloden different ratio mixture the Toxicity Determination of planthopper and black cutworm the results are shown in Table 1 to
In table 2.
Table 1:Toxicity Determination results of the HY366 with Thiamethoxam compound to planthopper
Medicament | LC50(mg/L) | ATI | TTI | Co-toxicity coefficient CTC |
HY366(A) | 9.77 | 42.07 | - | - |
Diacloden (B) | 4.11 | 100.00 | - | - |
A:B(1:100) | 3.22 | 127.64 | 99.43 | 128.38 |
A:B(1:50) | 3.05 | 134.75 | 98.86 | 136.30 |
A:B(1:20) | 2.91 | 141.24 | 97.24 | 145.24 |
A:B(1:10) | 2.68 | 153.36 | 94.73 | 161.88 |
A:B(1:5) | 2.70 | 152.22 | 90.34 | 168.49 |
A:B(1:1) | 3.44 | 119.48 | 71.03 | 168.20 |
A:B(5:1) | 4.81 | 85.45 | 51.72 | 165.20 |
A:B(10:1) | 5.14 | 79.96 | 47.33 | 168.93 |
A:B(20:1) | 5.72 | 71.85 | 44.83 | 160.29 |
A:B(50:1) | 6.82 | 60.26 | 43.20 | 139.49 |
A:B(100:1) | 7.31 | 56.22 | 42.64 | 131.85 |
Table 2:Toxicity Determination results of the HY366 with Thiamethoxam compound to black cutworm
Medicament | LC50(mg/L) | ATI | TTI | Co-toxicity coefficient CTC |
HY366(A) | 8.28 | 283.45 | - | - |
Diacloden (B) | 23.47 | 100.00 | - | - |
A:B(1:100) | 17.45 | 134.50 | 101.82 | 132.10 |
A:B(1:50) | 16.52 | 142.07 | 103.60 | 137.14 |
A:B(1:20) | 14.01 | 167.52 | 108.74 | 154.06 |
A:B(1:10) | 12.52 | 187.46 | 116.68 | 160.66 |
A:B(1:5) | 11.36 | 206.60 | 130.58 | 158.22 |
A:B(1:1) | 7.15 | 328.25 | 191.73 | 171.21 |
A:B(5:1) | 5.96 | 393.79 | 252.88 | 155.72 |
A:B(10:1) | 5.61 | 418.36 | 266.78 | 156.82 |
A:B(20:1) | 5.32 | 441.17 | 274.72 | 160.59 |
A:B(50:1) | 5.92 | 396.45 | 279.86 | 141.66 |
A:B(100:1) | 6.71 | 349.78 | 281.64 | 124.19 |
The Toxicity Determination result listed from table 1 and table 2 can be seen that thiobenzamide with Diacloden mixture in matter
Amount is than being 1:100~100:Its co-toxicity coefficient is all higher than 120 in the range of 1, these are the result shows that thiobenzamide and thiophene worm
Piperazine mixture has significant synergistic effect to planthopper and black cutworm.Its result is also shown that thiobenzamide and Diacloden
Mixture, which prevents above-mentioned pest, has reasonability and feasibility.
3rd, Field information is tested
1st, water rice hopper field control effectiveness test is prevented
Test medicine:The test medicine listed in table 3 is prepared according to the preparation method described in this specification.
Comparison medicament:Comparison medicament is prepared according to the method identical with test medicine preparation method, simply using single work
Property component HY366 or single-activity component Diacloden.
According to medicine inspecting institute of the Ministry of Agriculture " GB-T 17980.4-2000 pesticide field efficacy medicine tests criterions (one) --- insecticide
The regulation of prevention water rice hopper " carries out experiment.
Test site:Five small towns Ming Lun villages of Ningbo City, Zhejiang Province Yinzhou District.
Test period:8 days~the September of September in 2014 22 days.
Test method:Once, rice hoppers are based on low instar larvae for dispenser during Rise's boot period.Formulation rate is 750kg/
hm2, plant blade face even spraying.Plot area 25m2, 4 repetitions, random district's groups arrangement.Per the parallel jump method 10 in experimental plot
Point sampling, every is investigated 2 clumps, investigates 20 clumps altogether, investigates every 2 clumps of work borer populations taken.
According to investigation result, (1), (2) calculate Revision insect recluced rate and preventive effect according to the following equation.Test data uses Duncan
Family name's duncan's new multiple range method (DMRT) carries out statistical analysis, and prevention water rice hopper Field information result of the test is listed in Table 3 below.
Prevention water rice hopper field control effectiveness test result is listed in Table 3 below.
Table 3:Prevent water rice hopper field control effectiveness test result
2nd, corn black cutworm field control effectiveness test is prevented
Test medicine:The test medicine listed in table 4 is prepared according to the preparation method described in this specification.
Comparison medicament:Comparison medicament is prepared according to the method identical with test medicine preparation method, simply using single work
Property component HY366 or single-activity component Diacloden.
Test method:
Corn seed is coated according to conventional pharmacopoeia weight ratio.
Experiment selection soil fertility etc. is preferable, has the plot that cutworm is caused harm to a certain degree in recent years.Scientific arrangement experiment is small
Area, is accustomed to rationally sowing according to sowing, blank control is used as using uncoated seed.Cell is arranged using random district's groups, repeats 4
It is secondary.According to《Pesticide field efficacy medicine test criterion》Related request carries out field control effectiveness test and result investigation.Prevent corn smallly
Tiger field test results are listed in Table 4 below.
Table 4:Prevent corn black cutworm field control effectiveness test result
By HY366 it can be seen from the field control effectiveness test result of table 3 and table 4 and energy effectively preventing after Thiamethoxam compound
Water rice hopper and corn black cutworm, preventive effect are substantially better than comparison medicament.To trial crops safety in scope of medication.
Summary, indoor biometrics and field control effectiveness test result show, compared with single dose, agricultural insecticidal combination of the present invention
Thing has pest significant synergistic effect, improves effect;Times for spraying is reduced at the same time, lowers drug cost, and it is dirty to reduce environment
Dye and pesticide residue;Agricultural pesticide composition of the present invention is made of the active ingredient of different mechanism of action, and action site increase, has
Beneficial to the generation for overcoming and delaying pest resistance to insecticide.Agricultural pesticide composition of the present invention is to trial crops without obvious bad shadow
Ring, leaf color, growing way etc. are all normal, and security is good, meets the security requirement of pesticidal preparations.
Agricultural pesticide composition of the present invention has good preventive effect to water rice hopper and corn black cutworm.
Claims (9)
1. a kind of agricultural pesticide composition, it is characterised in that it is by the compound with following chemical constitution formula (I)s and with
The compound of chemical constitution formula (II) is stated according to weight ratio 1~50:1~50 composition:
2. agricultural pesticide composition according to claim 1, it is characterised in that chemical constitution formula (I) compound is tied with chemistry
The weight ratio of structure formula (II) compound is 10~40:8~42.
3. agricultural pesticide composition according to claim 1, it is characterised in that chemical constitution formula (I) compound is tied with chemistry
The weight ratio of structure formula (II) compound is 18~32:16~34.
4. a kind of agricultural fungicides, it is characterised in that it contains any one of 0.5~95.0% claim 1-3 power by weight
Profit requires the agricultural pesticide composition and surplus as agriculturally acceptable carrier and auxiliary agent;Its formulation is wettable powder
Agent, suspending agent, suspension emulsion, microemulsion, aqueous emulsion, water dispersion granule or microcapsule suspending agent.
5. agricultural fungicides according to claim 4, it is characterised in that it contains 20~70% claim by weight
Agricultural pesticide composition and surplus described in any one of 1-3 claims are agriculturally acceptable carrier and auxiliary agent.
6. agricultural fungicides according to claim 4, it is characterised in that it contains 30~60% claim by weight
Agricultural pesticide composition and surplus described in any one of 1-3 claims are agriculturally acceptable carrier and auxiliary agent.
7. according to the agricultural fungicides described in any one of claim 4-6 claim, it is characterised in that the carrier is
Solid carrier or liquid-carrier, the solid carrier are selected from silicate, carbonate, sulfate, oxide, alkali metal salt, plant
Physical property carrier or synthetic filling class carrier;The liquid-carrier is selected from water, aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, aliphatic hydrocarbon, alcohols, ether
Class, ketone, vegetable oil, methylated vegetable oils or other special solvents.
8. according to the agricultural fungicides described in any one of claim 4-6 claim, it is characterised in that the auxiliary agent choosing
From surfactant, defoamer, thickener, suspending agent and antifreezing agent;The surfactant is for emulsifying agent, disperses
Surfactant in agent, stabilizer or wetting agent;The defoamer is selected from bubble enemy, silicone, C8~10Fatty alcohol, C10~20
Saturated fatty acid or acid amides defoamer;The thickener be selected from carboxymethyl alcohol, polyvinyl alcohol, polyvinyl acetate, xanthans,
Gelatin, gum arabic, polyvinylpyrrolidone, Magnesiumaluminumsilicate, polyethylene glycol, phenolic resin, shellac, carboxymethyl cellulose or
Sodium alginate;The suspending agent is selected from glycerine, Arabic gum, tragacanth, peach gum, methylcellulose, carboxymethyl cellulose
Sodium or hydroxypropyl cellulose;The antifreezing agent is selected from glycerine, urea, ethylene glycol or propane diols.
9. appoint according to agricultural pesticide composition described in any one of claim 1-3 claim or according in claim 4-6
Purposes of the agricultural fungicides described in one claim in prevention rice hoppers or corn seed coating prevention black cutworm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610235964.3A CN105660680B (en) | 2016-04-15 | 2016-04-15 | A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610235964.3A CN105660680B (en) | 2016-04-15 | 2016-04-15 | A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105660680A CN105660680A (en) | 2016-06-15 |
CN105660680B true CN105660680B (en) | 2018-05-01 |
Family
ID=56309770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610235964.3A Active CN105660680B (en) | 2016-04-15 | 2016-04-15 | A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105660680B (en) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101589722A (en) * | 2009-06-26 | 2009-12-02 | 南开大学 | Insecticides of a kind of chloride worm benzamide and its production and use |
CN101755812A (en) * | 2009-09-24 | 2010-06-30 | 张志高 | Insecticidal composition having chlorantraniliprole and thiamethoxam |
CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
CN102657175A (en) * | 2012-04-12 | 2012-09-12 | 广西田园生化股份有限公司 | Chlorantraniliprole-containing hot fogging concentrate |
CN104206405B (en) * | 2014-08-26 | 2016-06-08 | 青海省农林科学院 | A kind of pesticide preventing and treating Fructus Foeniculi thin wing open country snout moth's larva and method thereof |
-
2016
- 2016-04-15 CN CN201610235964.3A patent/CN105660680B/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN105660680A (en) | 2016-06-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN102217639A (en) | Insecticidal composition containing dinotefuran and chlorantraniliprole | |
CN101669472A (en) | Synergistic pesticide combination | |
CN105638715B (en) | A kind of agricultural pesticide composition and application thereof | |
CN105831147B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and lambda-cyhalothrin and application thereof | |
CN103875701A (en) | Insecticidal composition for preventing and treating soil insects | |
CN105613511B (en) | A kind of agricultural pesticide composition and application thereof | |
CN105660680B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and Diacloden and application thereof | |
CN103125496A (en) | Novel insecticide composition compounding pymetrozine | |
CN102475087A (en) | Chlorfenapyr-containing insecticidal composition | |
CN105707119B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and chlopyrifos and application thereof | |
CN106577709A (en) | Pesticide compound containing cyhalodiamide and hexaflumuron | |
CN105746567B (en) | A kind of agricultural pesticide composition and application thereof | |
CN105766989B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and cyfloxylate and application thereof | |
CN105613562B (en) | A kind of agricultural pesticide composition and application thereof containing sulphur insect amide and dinotefuran | |
CN105794789B (en) | A kind of agricultural pesticide composition containing sulphur insect amide and Nylar and application thereof | |
CN105660649B (en) | A kind of agricultural pesticide composition and application thereof | |
CN101708009A (en) | Disinsection composition containing indoxacarb | |
CN105685067B (en) | A kind of agricultural pesticide composition and application thereof | |
CN105660681A (en) | Agricultural insecticide composition containing insect sulfamide and fenpropathrin and application thereof | |
CN105685050B (en) | A kind of agricultural pesticide composition and application thereof | |
CN104255751A (en) | Mite-killing composition containing etoxazole and vermectin | |
CN105746560A (en) | Agricultural insecticidal composition and application thereof | |
CN105941424A (en) | Agricultural insecticidal composition capable of preventing and treating rice planthopper | |
CN103461371A (en) | Methoxyfenozide and dinotefuran pesticidal composition | |
CN102217634A (en) | Insecticidal composition containing sulfoxaflor and pymetozine or indoxacarb |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: 311106 No. 172, Zhangjiadun Road, Tangqi Town, Linping District, Hangzhou, Zhejiang Patentee after: Zhejiang Yulong Pharmaceutical Co.,Ltd. Address before: No. 172, zhangjiadun Road, Tangqi Town, Yuhang District, Hangzhou City, Zhejiang Province, 311106 Patentee before: Hangzhou Udragon Chemical Co.,Ltd. |
|
CP03 | Change of name, title or address |