CN105936838A - Biogas circulation desulfurization system - Google Patents

Biogas circulation desulfurization system Download PDF

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Publication number
CN105936838A
CN105936838A CN201610472562.5A CN201610472562A CN105936838A CN 105936838 A CN105936838 A CN 105936838A CN 201610472562 A CN201610472562 A CN 201610472562A CN 105936838 A CN105936838 A CN 105936838A
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CN
China
Prior art keywords
desulfurizing tower
biogas
gas outlet
air inlet
desulfurization
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
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CN201610472562.5A
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Chinese (zh)
Inventor
吴松林
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Gongan County Forward Technology Energy Co Ltd
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Gongan County Forward Technology Energy Co Ltd
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Application filed by Gongan County Forward Technology Energy Co Ltd filed Critical Gongan County Forward Technology Energy Co Ltd
Priority to CN201610472562.5A priority Critical patent/CN105936838A/en
Publication of CN105936838A publication Critical patent/CN105936838A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The invention relates to the technical field of biogas desulfurization, and especially relates to a biogas circulation desulfurization system. The biogas circulation desulfurization system comprises a first desulfurization tower and a second desulfurization tower. The lateral walls of the lower ends of the first desulfurization tower and the second desulfurization tower are both provided with a gas inlet. The tops of the first desulfurization tower and the second desulfurization tower are both provided with a gas outlet. The gas inlet of the first desulfurization tower is communicated with the gas outlet of the second desulfurization tower through a pipeline, the gas outlet of the first desulfurization tower is communicated with the gas inlet of the second desulfurization tower through a pipeline; and the first desulfurization tower and the second desulfurization tower are filled with a desulfurizer. The biogas circulation desulfurization system has the advantages that the structure is simple, the operation and using are convenient, biogas can be fully circulated and desulfurized in the desulfurization towers, the sulfur content of desulfurized biogas is low, the utilization rate of desulfurizer is high, the desulfurization cost is saved, and the raw material loss is reduced.

Description

A kind of biogas recirculation desulphurization system
Technical field
The present invention relates to a kind of biogas desulfurization technical field, particularly to a kind of biogas recirculation desulphurization system.
Background technology
At present, when biogas desulfurization is carried out desulfurization, it is biogas to be passed through single or each lead into many mostly Oxidation sweetening is carried out, when, after desulfurization certain time length, the desulfurizing agent within tower body effectively becomes in individual desulfurizing tower Dividing content to be gradually lowered, this allows for being passed through the biogas within tower body can not sufficiently carry out desulfurization, thus Causing to be met actual demand by sulfur content in the biogas out of tower body gas outlet, now, it is right to be necessary for Desulfurizing agent in tower body is replaced, and refills, and this sorbent utilization allowed in tower body is relatively low, And cause a large amount of of desulfurizing agent to waste, meanwhile, change desulfurizing agent frequently and make biogas desulfurization inefficient, Production cost is the highest.
Summary of the invention
The technical problem to be solved is to provide a kind of biogas recirculation desulphurization system, effectively solves The biogas desulfurization equipment of prior art is during to biogas desulfurization, and sorbent utilization is relatively low, easily Causing the waste of desulfurizing agent, change desulfurizing agent frequently and make biogas desulfurization inefficient, production cost is also Higher defect.
The technical scheme is that a kind of biogas recirculation desulphurization system, bag Include the first desulfurizing tower and the second desulfurizing tower, on the lower end sidewall of above-mentioned first desulfurizing tower and the second desulfurizing tower all Being provided with air inlet, its top is equipped with gas outlet, and the air inlet of above-mentioned first desulfurizing tower passes through pipeline communication The gas outlet of above-mentioned second desulfurizing tower, pipeline communication above-mentioned second is passed through in the gas outlet of above-mentioned first desulfurizing tower The air inlet of desulfurizing tower, is separately filled with desulfurizing agent in above-mentioned first desulfurizing tower and the second desulfurizing tower.
The invention has the beneficial effects as follows: simple in construction, easy to operate, when within one of them desulfurizing tower During desulfurizing agent active ingredient deficiency, continue in the biogas after this tower body desulfurization is imported another one desulfurizing tower Desulfurization, until its purity meets demand, it is ensured that the desulfurizing agent in desulfurizing tower fully reacts with biogas, Make sorbent utilization higher, effectively reduce production cost.
On the basis of technique scheme, the present invention can also do following improvement.
Further, also include that biogas air inlet is responsible for, above-mentioned first desulfurizing tower and the air inlet of the second desulfurizing tower It is responsible for by pipeline communication above-mentioned biogas air inlet respectively, and is respectively equipped with electromagnetism on two pipelines of correspondence Valve.
The beneficial effect using above-mentioned further scheme is easy for two desulfurizing towers are carried out central gas supply, and The flow direction of biogas can be controlled by electromagnetic valve, operate more convenient.
Further, also include that biogas is given vent to anger supervisor, above-mentioned first desulfurizing tower and the gas outlet of the second desulfurizing tower Given vent to anger by the above-mentioned biogas of pipeline communication respectively and be respectively equipped with electromagnetism on supervisor, and two pipelines of correspondence Valve.
The beneficial effect using above-mentioned further scheme is easy for carrying out concentrating aerofluxus to two desulfurizing towers, and The exhaust condition of biogas in single tower body can be controlled by electromagnetic valve, operate more convenient.
Further, the air inlet of above-mentioned first desulfurizing tower connects the gas outlet of above-mentioned second desulfurizing tower On the pipeline of the air inlet that the gas outlet of pipeline and above-mentioned first desulfurizing tower connects above-mentioned second desulfurizing tower It is respectively equipped with electromagnetic valve.
The beneficial effect using above-mentioned further scheme is easy for being controlled two pipelines respectively by electromagnetic valve In upper, the circulation status of biogas, operates more convenient.
Further, it is respectively equipped with at the gas outlet of above-mentioned first desulfurizing tower and the gas outlet of the second desulfurizing tower Gas concentration detector.
Use above-mentioned further scheme to provide the benefit that can the biogas of two desulfurizing tower gas outlets be included Some concentration of hydrogen sulfide detect.
Further, the bottom of above-mentioned first desulfurizing tower and the second desulfurizing tower is respectively communicated with and is provided with drain pipe 6, And on drain pipe, it is equipped with water check valve.
The beneficial effect using above-mentioned further scheme is easy for controlling two desulfurizing tower inside deposition moisture Discharge.
Further, above-mentioned desulfurizing agent is magnetic iron oxide.
Above-mentioned further scheme is used to provide the benefit that desulfurized effect is preferable.
Accompanying drawing explanation
Fig. 1 is the structural representation of the biogas recirculation desulphurization system of the present invention.
In accompanying drawing, the list of parts representated by each label is as follows:
1, the first desulfurizing tower, the 2, second desulfurizing tower, 3, biogas air inlet supervisor, 4, biogas give vent to anger supervisor, 5, gas concentration detector, 6, drain pipe.
Detailed description of the invention
Being described principle and the feature of the present invention below in conjunction with accompanying drawing, example is served only for explaining this Invention, is not intended to limit the scope of the present invention.
Embodiment one: as it is shown in figure 1, the biogas recirculation desulphurization system of the present embodiment includes the first desulfurizing tower 1 and second desulfurizing tower 2, the lower end sidewall of above-mentioned first desulfurizing tower 1 and the second desulfurizing tower 2 is equipped with Air inlet, its top is equipped with gas outlet, and the air inlet of above-mentioned first desulfurizing tower 1 is by pipeline communication Stating the gas outlet of the second desulfurizing tower 2, the gas outlet of above-mentioned first desulfurizing tower 1 is by pipeline communication above-mentioned the The air inlet of two desulfurizing towers 2, is separately filled with desulfurization in above-mentioned first desulfurizing tower 1 and the second desulfurizing tower 2 Agent.
Also including biogas air inlet supervisor 3, the air inlet of above-mentioned first desulfurizing tower 1 and the second desulfurizing tower 2 divides Tong Guo not be respectively equipped with electromagnetic valve on pipeline communication above-mentioned biogas air inlet supervisor 3, and two pipelines of correspondence.
Also including that biogas is given vent to anger supervisor 4, the gas outlet of above-mentioned first desulfurizing tower 1 and the second desulfurizing tower 2 is divided Do not given vent to anger by the above-mentioned biogas of pipeline communication and be respectively equipped with electromagnetic valve on supervisor 4, and two pipelines of correspondence.
The air inlet of above-mentioned first desulfurizing tower 1 connects the pipeline of the gas outlet of above-mentioned second desulfurizing tower 2 And on the pipeline of the gas outlet of above-mentioned first desulfurizing tower 1 air inlet that connects above-mentioned second desulfurizing tower 2 point It is not provided with electromagnetic valve.
It is respectively equipped with gas at the gas outlet of above-mentioned first desulfurizing tower 1 and the gas outlet of the second desulfurizing tower 2 Concentration detector 5.
During use, when being used alone the first desulfurizing tower 1, close biogas air inlet supervisor 3 and second Electromagnetic valve on pipeline between desulfurizing tower 2 air inlet, simultaneously closes off the air inlet and of the first desulfurizing tower 1 Electromagnetic valve on pipeline between the gas outlet of two desulfurizing towers 2, and close at the first desulfurizing tower 1 gas outlet Electromagnetic valve, biogas is responsible for 3 communication conduits by biogas air inlet and is entered the first desulfurizing tower 1 inside, with therein Desulfurizing agent reacts, and after question response certain time length, opens the electromagnetic valve at the first desulfurization 1 gas outlet, Biogas after desulfurization is entered biogas by pipeline and gives vent to anger supervisor 4, and afterwards, output is to follow-up package system i.e. Can.
After the first desulfurizing tower 1 is used alone certain time length, its interior desulfurizing agent active ingredient is gradually lowered, The biogas desulfurization being passed through it interior can be made insufficient, and examined by the gas concentration detector 5 of its gas outlet Measure it and include sulphur concentration, when detecting that in the biogas at gas outlet, sulfur content is higher, close it and give vent to anger The electromagnetic valve that mouth and biogas are given vent to anger between supervisor 4 on pipeline, and open its gas outlet and the second desulfurizing tower 2 Air inlet between electromagnetic valve on pipeline so that imported by the first desulfurizing tower 1 gas outlet biogas out Carry out secondary desulfuration in second desulfurizing tower 2, and carry out sulfur content detection in the second desulfurizing tower 2 gas outlet, After detecting that sulfur content is up to standard in biogas, open the second desulfurizing tower 2 gas outlet and biogas give vent to anger supervisor 4 it Between electromagnetic valve on pipeline, biogas is expelled to follow-up package system by the biogas supervisor 4 that gives vent to anger.
In said process, it is continually fed into biogas in the first desulfurizing tower 1, desulfurizing agent in it is made full use of, Until its effective ingredient is down to minimum, closes the first desulfurizing tower 1 air inlet afterwards and be responsible for 3 with biogas air inlet Between pipeline solenoid, and close the first desulfurizing tower 1 gas outlet and the second desulfurizing tower 2 air inlet successively Between electromagnetic valve on pipeline, stop the use of the first desulfurizing tower 1, and its interior desulfurizing agent carried out more Change.
Example two in real time: be used alone the second desulfurizing tower 2 and biogas is carried out desulfurization process, it is away from implementing Example one.
Embodiment three: simultaneously use the first desulfurizing tower 1 and the second desulfurizing tower 2 that biogas is carried out high-efficiency desulfurization Process, during this, close pipeline between the first desulfurizing tower 1 gas outlet and the second desulfurizing tower 2 air inlet On electromagnetic valve, and close between the first desulfurizing tower 1 air inlet and the second desulfurizing tower 2 gas outlet on pipeline Electromagnetic valve, be directed respectively into the first desulfurizing tower 1 He after making to be passed through the biogas shunting in biogas air inlet supervisor 3 Carry out desulfurization process in second desulfurizing tower 2 respectively, pending after, respectively by both gas outlets by pipe Road converges to biogas and gives vent to anger in supervisor 4, concentrates afterwards and discharges the package system that importing is follow-up.
When carrying out in biogas desulfurization processing procedure, in biogas in the first desulfurizing tower 1 or the second desulfurizing tower 2 The moisture contained can be deposited in desulfurizing agent, and gradually ooze and drop down onto bottom tower body, therefore in above-mentioned first desulfurization The bottom of tower 1 and the second desulfurizing tower 2 is respectively communicated with and is provided with drain pipe 6, and sets on drain pipe 6 respectively Put water check valve, it is simple to the deposit moisture in cleaning tower body in time, it is ensured that being normally carried out of desulfurization work.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all in the present invention Spirit and principle within, any modification, equivalent substitution and improvement etc. made, should be included in this Within bright protection domain.

Claims (7)

1. a biogas recirculation desulphurization system, it is characterised in that: include the first desulfurizing tower (1) and second Desulfurizing tower (2), the lower end sidewall of described first desulfurizing tower (1) and the second desulfurizing tower (2) is all provided with Having air inlet, its top is equipped with gas outlet, and the air inlet of described first desulfurizing tower (1) passes through pipeline Connecting the gas outlet of described second desulfurizing tower (2), the gas outlet of described first desulfurizing tower (1) is by pipe Road connects the air inlet of described second desulfurizing tower (2), described first desulfurizing tower (1) and the second desulfurizing tower (2) desulfurizing agent it is separately filled with in.
A kind of biogas recirculation desulphurization system the most according to claim 1, it is characterised in that: also wrap Include biogas air inlet supervisor (3), described first desulfurizing tower (1) and the air inlet of the second desulfurizing tower (2) Respectively by being respectively equipped with on biogas air inlet supervisor (3), and two pipelines of correspondence described in pipeline communication Electromagnetic valve.
A kind of biogas recirculation desulphurization system the most according to claim 1 and 2, it is characterised in that: Also include that biogas is given vent to anger supervisor (4), going out of described first desulfurizing tower (1) and the second desulfurizing tower (2) QI KOU is given vent to anger on supervisor (4), and two pipelines of correspondence respectively by biogas described in pipeline communication respectively It is provided with electromagnetic valve.
A kind of biogas recirculation desulphurization system the most according to claim 3, it is characterised in that: described The air inlet of described first desulfurizing tower (1) connect the pipeline of the gas outlet of described second desulfurizing tower (2) with And the gas outlet of described first desulfurizing tower (1) connects the pipeline of air inlet of described second desulfurizing tower (2) On be respectively equipped with electromagnetic valve.
A kind of biogas recirculation desulphurization system the most according to claim 3, it is characterised in that: described It is respectively equipped with gas dense at the gas outlet of the first desulfurizing tower (1) and the gas outlet of the second desulfurizing tower (2) Degree detector (5).
A kind of biogas recirculation desulphurization system the most according to claim 1 and 2, it is characterised in that: The bottom of described first desulfurizing tower (1) and the second desulfurizing tower (2) is respectively communicated with and is provided with drain pipe (6), And it is equipped with water check valve on drain pipe (6).
A kind of biogas recirculation desulphurization system the most according to claim 1 and 2, it is characterised in that: Described desulfurizing agent is magnetic iron oxide.
CN201610472562.5A 2016-06-24 2016-06-24 Biogas circulation desulfurization system Pending CN105936838A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610472562.5A CN105936838A (en) 2016-06-24 2016-06-24 Biogas circulation desulfurization system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610472562.5A CN105936838A (en) 2016-06-24 2016-06-24 Biogas circulation desulfurization system

Publications (1)

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CN105936838A true CN105936838A (en) 2016-09-14

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201643959U (en) * 2010-04-19 2010-11-24 颜京文 Desulfuration device
CN202610236U (en) * 2012-05-29 2012-12-19 潍坊明硕环保设备有限公司 Methane production system
CN205687882U (en) * 2016-06-24 2016-11-16 公安县前锋科技能源有限公司 A kind of biogas recirculation desulphurization system

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201643959U (en) * 2010-04-19 2010-11-24 颜京文 Desulfuration device
CN202610236U (en) * 2012-05-29 2012-12-19 潍坊明硕环保设备有限公司 Methane production system
CN205687882U (en) * 2016-06-24 2016-11-16 公安县前锋科技能源有限公司 A kind of biogas recirculation desulphurization system

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Application publication date: 20160914

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