CN105936691A - Flame retardant and aging resistant polyethylene plastic-wood composite board for buildings - Google Patents
Flame retardant and aging resistant polyethylene plastic-wood composite board for buildings Download PDFInfo
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- CN105936691A CN105936691A CN201610398832.2A CN201610398832A CN105936691A CN 105936691 A CN105936691 A CN 105936691A CN 201610398832 A CN201610398832 A CN 201610398832A CN 105936691 A CN105936691 A CN 105936691A
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- oleamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame retardant and aging resistant polyethylene plastic-wood composite board for buildings. The composite board is made of the following components by weight: 100-110 parts of polyethylene, 80-90 parts of willow wood flour, 12-18 parts of alkyd resin, 5-9 parts of trimethylolpropane triacrylate, 4-8 parts of potassium persulfate, 50 parts of vinyl acetate, 10-15 parts of glycerin, 2-6 parts of an acrylate copolymer, 10-14 parts of dibutyltin dilaurate, 1-3 parts of hydroxymethyl cellulose, 3-5 parts of sulfur powder, 3 parts of oleamide, 2 parts of nonylphenol polyoxyethylene ether, 6 parts of titanium dioxide, and 2 parts of octyl diphenyl phosphate. The flame retardant and aging resistant polyethylene plastic-wood composite board provided by the invention has the advantages of good toughness, rigidity and elasticity, good processing performance, low cost, flame retardance, strong environmental tolerance, stable performance, and aging resistance.
Description
Technical field
The invention belongs to building material technical field, be specifically related to a kind of for building fire-retardant ageing-resistant
Wood composite board moulded by polyethylene.
Background technology
Wood plastic composite is the novel environment friendly building materials the most just occurred, is the most also just
Starting.Raw material used by wood-plastic products can use waste or used plastics and discarded timber, agricultural Fructus Citri tangerinae bar etc.
Plant fiber makees base material, without any additional harmful components.And recyclable again with, claim
Environmental protection truly, energy-conservation, the novel products of resource regeneration must be gone up.
" plastic-wood material ", is also " wood plastic composite ", as the term suggests can be regarded as mainly with
Plastics are raw material, are mixed into new wood by adding the useless Plant fiber such as wood powder, rice husk, straw
Material, then through the plastic processings such as extruding, mold pressing, injection moulding, the sheet material produced
Or section bar.It is mainly used in the industries such as building materials, furniture, logistics packaging.By plastics and wooden powder
By a certain percentage through the sheet material of hot extrusion molding after mixing, referred to as extrude wood-plastic composite panel.
The Waterproof corrosion of plastics and two kinds of characteristics of texture of timber are had concurrently so that it becomes one owing to moulding wood
Plant function admirable the most durable outdoor building materials (floor, fence, bench, gardens or water bank
View etc.)；Also replace the Wood member that harbour, harbour etc. use, it may also be used for substitute wood
It is too numerous to enumerate that material makes various packing materials, pallet, warehouse pallet etc., and purposes is extremely wide.Mould
Wood plank, combines Plant fiber and the plurality of advantages of plastics macromolecular material, can substitute in a large number
Timber, can effectively alleviate the contradiction that China's Forest Resources is poor, wood supply is in short supply, is a kind of
The low-carbon (LC) of great development prospect, green, renewable ecological plastic-wood material capable of circulation.
Along with people's raising to environmental resource attention degree, reclaim with waste and old material and resource is combined
Close and be utilized as the circular-type economy developmental pattern of core and become the trend of development of world economy.Greatly
Power is exploited natural resources recycle utilization, will produce the national economic development and environment sustainable development
Profound influence.And utilize waste or used plastics and wood fiber to produce Wood Plastics Composite Product and fit just
Answer the good project of this requirement.
Owing to domestic market is still at the initial stage, plastic-wood products market at home does not also have large area
Promote.Chinese market is compared with North America market, and the growth of wood plastic composite and manufactured goods also has
Sizable space, it is contemplated that domestic Wood plastic composite market yield in recent years will be more than million
Ton, the output value is more than 1,000,000,000 yuan, and forms novel wood-plastic composite article system.
Plastic-wood products will become following trend trend place, for consumers, moulds wooden
Product belong to energy saving and environment friendly product, not only can well control the discharge of nuisance, additionally it is possible to
Accomplish that the waterproof and dampproof of ground waits effect.
Polyethylene (PE) is one of five big synthetic resin, be in China's synthetic resin production capacity maximum,
The kind that import volume is most.Corrosion resistance, electrical insulating property (especially high-frequency insulation) is excellent, permissible
Chlorination, radiation modification, useable glass fiber reinforcement.Therefore, research and development are a kind of with polyethylene as raw material
Wood plastic composite substitute wood raw material, not only can alleviate current timber well in short supply
Problem, and its good processability, low cost, fire-retardant, strong to environmental resistance, performance is steady
Fixed, so having important practical significance and popularizing application prospect.
Summary of the invention
To achieve these goals, the invention provides a kind of fire-retardant ageing-resistant polyethylene for building
Mould wood composite board.
It is an object of the invention to be achieved through the following technical solutions:
Wood composite board moulded by a kind of fire-retardant ageing-resistant polyethylene for building, and it is by following weight portion
The component mix and blend of number is made: polyethylene 100-110 part, willow wood powder 80-90 part, alcohol
Acid resin 12-18 part, trimethylolpropane trimethacrylate 5-9 part, potassium peroxydisulfate 4-8 part,
Vinyl acetate 50 parts, glycerol 10-15 part, acrylic acid esters co-polymer 2-6 part, two Laurels
Acid two fourth stannum fat 10-14 parts, hydroxymethyl cellulose 1-3 part, Cosan 3-5 part, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
One of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 100 parts,
Willow wood powder 80 parts, alkyd resin 12 parts, trimethylolpropane trimethacrylate 5 parts, mistake
Potassium sulfate 4 parts, vinyl acetate 50 parts, glycerol 10 parts, acrylic acid esters co-polymer 2 parts,
10 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 1 part, Cosan 3 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
The two of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 110 parts,
Willow wood powder 90 parts, alkyd resin 18 parts, trimethylolpropane trimethacrylate 9 parts, mistake
Potassium sulfate 8 parts, vinyl acetate 50 parts, glycerol 15 parts, acrylic acid esters co-polymer 6 parts,
14 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 3 parts, Cosan 5 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
The three of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 102 parts,
Willow wood powder 82 parts, alkyd resin 13 parts, trimethylolpropane trimethacrylate 6 parts, mistake
Potassium sulfate 5 parts, vinyl acetate 50 parts, glycerol 12 parts, acrylic acid esters co-polymer 3 parts,
12 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 2 parts, Cosan 4 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
The four of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 108 parts,
Willow wood powder 88 parts, alkyd resin 16 parts, trimethylolpropane trimethacrylate 8 parts, mistake
Potassium sulfate 7 parts, vinyl acetate 50 parts, glycerol 14 parts, acrylic acid esters co-polymer 5 parts,
13 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 2 parts, Cosan 4 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, obtains
Mixed material；Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.
The method have the advantages that wood moulded by the fire-retardant ageing-resistant polyethylene that the present invention provides
Composite board has good toughness, rigidity and elasticity, good processability, low cost, fire-retardant,
Strong to environmental resistance, stable performance, ageing-resistant.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention,
Although the present invention being described in detail with reference to previous embodiment, for the technology of this area
For personnel, the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it
In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention
Within the scope of.
Embodiment 1
Wood composite board moulded by a kind of fire-retardant ageing-resistant polyethylene for building, and it is by following weight portion
The component mix and blend of number is made:
Polyethylene 100 parts, willow wood powder 80 parts, alkyd resin 12 parts, trimethylolpropane
Triacrylate 5 parts, potassium peroxydisulfate 4 parts, vinyl acetate 50 parts, glycerol 10 parts, propylene
Esters of gallic acid copolymer 2 parts, 10 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 1 part,
Cosan 3 parts, oleamide 3 parts, NPE 2 parts, titanium dioxide 6 parts, Asia
Diphenyl octyl phosphate 2 parts.Its preparation method is: carry out weighing above-mentioned each component by proportioning
Mixing treatment, obtains mixed material；Then extruder is used to be extruded into by mixed material gained
Type, i.e. obtains finished product.
Embodiment 2
Wood composite board moulded by a kind of fire-retardant ageing-resistant polyethylene for building, and it is by following weight portion
The component mix and blend of number is made:
Polyethylene 110 parts, willow wood powder 90 parts, alkyd resin 18 parts, trimethylolpropane
Triacrylate 9 parts, potassium peroxydisulfate 8 parts, vinyl acetate 50 parts, glycerol 15 parts, propylene
Esters of gallic acid copolymer 6 parts, 14 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 3 parts,
Cosan 5 parts, oleamide 3 parts, NPE 2 parts, titanium dioxide 6 parts, Asia
Diphenyl octyl phosphate 2 parts.Its preparation method is: carry out weighing above-mentioned each component by proportioning
Mixing treatment, obtains mixed material；Then extruder is used to be extruded into by mixed material gained
Type, i.e. obtains finished product.
Embodiment 3
Wood composite board moulded by a kind of fire-retardant ageing-resistant polyethylene for building, and it is by following weight portion
The component mix and blend of number is made:
Polyethylene 102 parts, willow wood powder 82 parts, alkyd resin 13 parts, trimethylolpropane
Triacrylate 6 parts, potassium peroxydisulfate 5 parts, vinyl acetate 50 parts, glycerol 12 parts, propylene
Esters of gallic acid copolymer 3 parts, 12 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 2 parts,
Cosan 4 parts, oleamide 3 parts, NPE 2 parts, titanium dioxide 6 parts, Asia
Diphenyl octyl phosphate 2 parts.Its preparation method is: carry out weighing above-mentioned each component by proportioning
Mixing treatment, obtains mixed material；Then extruder is used to be extruded into by mixed material gained
Type, i.e. obtains finished product.
Embodiment 4
Wood composite board moulded by a kind of fire-retardant ageing-resistant polyethylene for building, and it is by following weight portion
The component mix and blend of number is made:
Polyethylene 108 parts, willow wood powder 88 parts, alkyd resin 16 parts, trimethylolpropane
Triacrylate 8 parts, potassium peroxydisulfate 7 parts, vinyl acetate 50 parts, glycerol 14 parts, propylene
Esters of gallic acid copolymer 5 parts, 13 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 2 parts,
Cosan 4 parts, oleamide 3 parts, NPE 2 parts, titanium dioxide 6 parts, Asia
Diphenyl octyl phosphate 2 parts.Its preparation method is: carry out weighing above-mentioned each component by proportioning
Mixing treatment, obtains mixed material；Then extruder is used to be extruded into by mixed material gained
Type, i.e. obtains finished product.
Claims (5)
1. wood composite board moulded by a fire-retardant ageing-resistant polyethylene for building, it is characterised in that it
It is to be prepared by the component of following parts by weight: polyethylene 100-110 part, willow wood powder 80-90
Part, alkyd resin 12-18 part, trimethylolpropane trimethacrylate 5-9 part, potassium peroxydisulfate
4-8 part, vinyl acetate 50 parts, glycerol 10-15 part, acrylic acid esters co-polymer 2-6 part,
Dibutyl tin dilaurate fat 10-14 part, hydroxymethyl cellulose 1-3 part, Cosan 3-5 part,
Oleamide 3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite
2 parts.
It is multiple that wood moulded by one the most according to claim 1 fire-retardant ageing-resistant polyethylene for building
Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 100 parts,
Willow wood powder 80 parts, alkyd resin 12 parts, trimethylolpropane trimethacrylate 5 parts, mistake
Potassium sulfate 4 parts, vinyl acetate 50 parts, glycerol 10 parts, acrylic acid esters co-polymer 2 parts,
10 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 1 part, Cosan 3 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
It is multiple that wood moulded by one the most according to claim 1 fire-retardant ageing-resistant polyethylene for building
Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 110 parts,
Willow wood powder 90 parts, alkyd resin 18 parts, trimethylolpropane trimethacrylate 9 parts, mistake
Potassium sulfate 8 parts, vinyl acetate 50 parts, glycerol 15 parts, acrylic acid esters co-polymer 6 parts,
14 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 3 parts, Cosan 5 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
It is multiple that wood moulded by one the most according to claim 1 fire-retardant ageing-resistant polyethylene for building
Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 102 parts,
Willow wood powder 82 parts, alkyd resin 13 parts, trimethylolpropane trimethacrylate 6 parts, mistake
Potassium sulfate 5 parts, vinyl acetate 50 parts, glycerol 12 parts, acrylic acid esters co-polymer 3 parts,
12 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 2 parts, Cosan 4 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
It is multiple that wood moulded by one the most according to claim 1 fire-retardant ageing-resistant polyethylene for building
Plywood material, it is characterised in that it is to be prepared by the component of following parts by weight: polyethylene 108 parts,
Willow wood powder 88 parts, alkyd resin 16 parts, trimethylolpropane trimethacrylate 8 parts, mistake
Potassium sulfate 7 parts, vinyl acetate 50 parts, glycerol 14 parts, acrylic acid esters co-polymer 5 parts,
13 parts of dibutyl tin dilaurate fat, hydroxymethyl cellulose 2 parts, Cosan 4 parts, oleamide
3 parts, NPE 2 parts, titanium dioxide 6 parts, octyl diphenyl phosphite 2 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398832.2A CN105936691A (en) | 2016-06-06 | 2016-06-06 | Flame retardant and aging resistant polyethylene plastic-wood composite board for buildings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398832.2A CN105936691A (en) | 2016-06-06 | 2016-06-06 | Flame retardant and aging resistant polyethylene plastic-wood composite board for buildings |
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| CN105936691A true CN105936691A (en) | 2016-09-14 |
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| CN201610398832.2A Pending CN105936691A (en) | 2016-06-06 | 2016-06-06 | Flame retardant and aging resistant polyethylene plastic-wood composite board for buildings |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629286A (en) * | 2017-08-31 | 2018-01-26 | 苏州仲勉装饰有限公司 | A kind of preparation method of electrostatic prevention plastic wood composite board |
| CN108285559A (en) * | 2018-01-29 | 2018-07-17 | 铜陵四通环境科技有限公司 | A kind of TDN Macromolecular composite plates and its manufacturing process |
| CN109203154A (en) * | 2018-09-08 | 2019-01-15 | 佛山市禅城区诺高环保科技有限公司 | A kind of forest-friendly building timbers fire retardant |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101367973A (en) * | 2008-10-09 | 2009-02-18 | 上海交通大学 | Preparation method for high-strength heat-proof polythene composite material |
| CN101418101A (en) * | 2008-12-08 | 2009-04-29 | 山东鑫海汽车配件有限公司 | Polypropylene wood-plastic slab and preparation method thereof |
| CN103333512A (en) * | 2013-06-17 | 2013-10-02 | 内蒙古亿利塑业有限责任公司 | Salix psammophila/polyethylene wood-plastic composite material and preparation method thereof |
| CN105368026A (en) * | 2015-11-24 | 2016-03-02 | 苏州市相城区明达复合材料厂 | Novel sound-insulation material |
-
2016
- 2016-06-06 CN CN201610398832.2A patent/CN105936691A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101367973A (en) * | 2008-10-09 | 2009-02-18 | 上海交通大学 | Preparation method for high-strength heat-proof polythene composite material |
| CN101418101A (en) * | 2008-12-08 | 2009-04-29 | 山东鑫海汽车配件有限公司 | Polypropylene wood-plastic slab and preparation method thereof |
| CN103333512A (en) * | 2013-06-17 | 2013-10-02 | 内蒙古亿利塑业有限责任公司 | Salix psammophila/polyethylene wood-plastic composite material and preparation method thereof |
| CN105368026A (en) * | 2015-11-24 | 2016-03-02 | 苏州市相城区明达复合材料厂 | Novel sound-insulation material |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629286A (en) * | 2017-08-31 | 2018-01-26 | 苏州仲勉装饰有限公司 | A kind of preparation method of electrostatic prevention plastic wood composite board |
| CN108285559A (en) * | 2018-01-29 | 2018-07-17 | 铜陵四通环境科技有限公司 | A kind of TDN Macromolecular composite plates and its manufacturing process |
| CN109203154A (en) * | 2018-09-08 | 2019-01-15 | 佛山市禅城区诺高环保科技有限公司 | A kind of forest-friendly building timbers fire retardant |
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| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160914 |