CN105936662A - Polyethylene plastic-wood composite board for buildings - Google Patents
Polyethylene plastic-wood composite board for buildings Download PDFInfo
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- CN105936662A CN105936662A CN201610398344.1A CN201610398344A CN105936662A CN 105936662 A CN105936662 A CN 105936662A CN 201610398344 A CN201610398344 A CN 201610398344A CN 105936662 A CN105936662 A CN 105936662A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/002—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers modified by after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
The invention discloses a polyethylene plastic-wood composite board for buildings. The composite board is made of the following components by weight: 80-88 parts of polyethylene, 80-90 parts of willow wood flour, 14-20 parts of butyl etherified melamine formaldehyde resin, 12-18 parts of triallylisocyanurate, 20-30 parts of ethyl acetate, 3-7 parts of BPO, 16-20 parts of acrylic acid, 3-5 parts of an antioxidant 264, 2-4 parts of alkylphenol polyoxyethylene ether, 2-4 parts of alumina, 5-9 parts of diisooctyl phenyl phosphate, and 3-5 parts of carbon nanotube. The polyethylene plastic-wood composite board provided by the invention has excellent mechanical properties and corrosion resistance, also has good fireproof performance, is suitable for high temperature and high humidity areas, is solid and durable, and has long service life. Also, the board has the advantages of environmental protection and no pollution, strong wood texture and the like.
Description
Technical field
The invention belongs to building material technical field, be specifically related to a kind of polyethylene and mould wood composite board
Material.
Background technology
Wood plastic composite is the novel environment friendly building materials the most just occurred, is the most also just
Starting.Raw material used by wood-plastic products can use waste or used plastics and discarded timber, agricultural Fructus Citri tangerinae bar etc.
Plant fiber makees base material, without any additional harmful components.And recyclable again with, claim
Environmental protection truly, energy-conservation, the novel products of resource regeneration must be gone up.
" plastic-wood material ", is also " wood plastic composite ", as the term suggests can be regarded as mainly with
Plastics are raw material, are mixed into new wood by adding the useless Plant fiber such as wood powder, rice husk, straw
Material, then through the plastic processings such as extruding, mold pressing, injection moulding, the sheet material produced
Or section bar.It is mainly used in the industries such as building materials, furniture, logistics packaging.By plastics and wooden powder
By a certain percentage through the sheet material of hot extrusion molding after mixing, referred to as extrude wood-plastic composite panel.
The Waterproof corrosion of plastics and two kinds of characteristics of texture of timber are had concurrently so that it becomes one owing to moulding wood
Plant function admirable the most durable outdoor building materials (floor, fence, bench, gardens or water bank
View etc.)；Also replace the Wood member that harbour, harbour etc. use, it may also be used for substitute wood
It is too numerous to enumerate that material makes various packing materials, pallet, warehouse pallet etc., and purposes is extremely wide.Mould
Wood plank, combines Plant fiber and the plurality of advantages of plastics macromolecular material, can substitute in a large number
Timber, can effectively alleviate the contradiction that China's Forest Resources is poor, wood supply is in short supply, is a kind of
The low-carbon (LC) of great development prospect, green, renewable ecological plastic-wood material capable of circulation.
Along with people's raising to environmental resource attention degree, reclaim with waste and old material and resource is combined
Close and be utilized as the circular-type economy developmental pattern of core and become the trend of development of world economy.Greatly
Power is exploited natural resources recycle utilization, will produce the national economic development and environment sustainable development
Profound influence.And utilize waste or used plastics and wood fiber to produce Wood Plastics Composite Product and fit just
Answer the good project of this requirement.
Owing to domestic market is still at the initial stage, plastic-wood products market at home does not also have large area
Promote.Chinese market is compared with North America market, and the growth of wood plastic composite and manufactured goods also has
Sizable space, it is contemplated that domestic Wood plastic composite market yield in recent years will be more than million
Ton, the output value is more than 1,000,000,000 yuan, and forms novel wood-plastic composite article system.
Plastic-wood products will become following trend trend place, for consumers, moulds wooden
Product belong to energy saving and environment friendly product, not only can well control the discharge of nuisance, additionally it is possible to
Accomplish that the waterproof and dampproof of ground waits effect.
Polyethylene (PE) is one of five big synthetic resin, be in China's synthetic resin production capacity maximum,
The kind that import volume is most.Corrosion resistance, electrical insulating property (especially high-frequency insulation) is excellent, permissible
Chlorination, radiation modification, useable glass fiber reinforcement.Therefore, it is necessary to research and development are a kind of with polyethylene
There is the Wood plastic composite of excellent mechanical performance and decay resistance for raw material.
Summary of the invention
To achieve these goals, the invention provides a kind of polyethylene and mould wood composite board.
It is an object of the invention to be achieved through the following technical solutions:
Wood composite board moulded by a kind of polyethylene for building, and it is to be mixed by the component of following parts by weight
Conjunction stirring is made: polyethylene 80-88 part, willow wood powder 80-90 part, butyl ether melamine
Formaldehyde resin 14-20 part, triallyl isocyanate 12-18 part, ethyl acetate 20-30 part,
BPO 3-7 part, acrylic acid 16-20 part, antioxidant 264 3-5 part, alkyl phenol polyoxy second
Alkene ether 2-4 part, aluminium oxide 2-4 part, phosphorous acid benzene di-isooctyl 5-9 part, CNT
3-5 part.
One of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 80 parts,
Willow wood powder 80 parts, butyl ether melamine formaldehyde resin 14 parts, triallyl isocyanate
12 parts, ethyl acetate 20 parts, BPO 3 parts, 16 parts of acrylic acid, antioxidant 264 3 parts,
Alkylphenol polyoxyethylene 2 parts, aluminium oxide 2 parts, phosphorous acid benzene di-isooctyl 5 parts, carbon are received
Mitron 3 parts.
The two of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 88 parts,
Willow wood powder 90 parts, butyl ether melamine formaldehyde resin 20 parts, triallyl isocyanate
18 parts, ethyl acetate 30 parts, BPO 7 parts, 20 parts of acrylic acid, antioxidant 264 5 parts,
Alkylphenol polyoxyethylene 4 parts, aluminium oxide 4 parts, phosphorous acid benzene di-isooctyl 9 parts, carbon are received
Mitron 5 parts.
The three of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 82 parts,
Willow wood powder 82 parts, butyl ether melamine formaldehyde resin 15 parts, triallyl isocyanate
14 parts, ethyl acetate 22 parts, BPO 5 parts, 18 parts of acrylic acid, antioxidant 264 4 parts,
Alkylphenol polyoxyethylene 3 parts, aluminium oxide 3 parts, phosphorous acid benzene di-isooctyl 6 parts, carbon are received
Mitron 4 parts.
The four of preferred version: it is to be prepared by the component of following parts by weight: polyethylene 86 parts,
Willow wood powder 86 parts, butyl ether melamine formaldehyde resin 18 parts, triallyl isocyanate
16 parts, ethyl acetate 27 parts, BPO 6 parts, 18 parts of acrylic acid, antioxidant 264 4 parts,
Alkylphenol polyoxyethylene 3 parts, aluminium oxide 3 parts, phosphorous acid benzene di-isooctyl 8 parts, carbon are received
Mitron 4 parts.
Its preparation method is: carries out mixing treatment by weighing above-mentioned each component by proportioning, obtains
Mixed material；Then gained uses extruder by mixed material extrusion molding, i.e. obtains finished product.
The method have the advantages that wood composite board tool moulded by the polyethylene that the present invention provides
Have and there is excellent mechanical performance and decay resistance, and fire protecting performance is good, it is adaptable to high temperature is high
Humid Area, durable, service life is long；And this kind of sheet material is environment friendly and pollution-free, woodiness touch is strong
Etc. advantage.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention,
Although the present invention being described in detail with reference to previous embodiment, for the technology of this area
For personnel, the technical scheme described in foregoing embodiments still can be modified by it,
Or wherein portion of techniques feature is carried out equivalent.All the spirit and principles in the present invention it
In, any modification, equivalent substitution and improvement etc. made, should be included in the protection of the present invention
Within the scope of.
Embodiment 1
Wood composite board moulded by a kind of polyethylene for building, and it is to be mixed by the component of following parts by weight
Conjunction stirring is made:
Polyethylene 80 parts, willow wood powder 80 parts, butyl ether melamine formaldehyde resin 14 parts,
Triallyl isocyanate 12 parts, ethyl acetate 20 parts, BPO 3 parts, 16 parts of acrylic acid,
Antioxidant 264 3 parts, alkylphenol polyoxyethylene 2 parts, aluminium oxide 2 parts, phosphorous acid benzene
Di-isooctyl 5 parts, CNT 3 parts.Its preparation method is: above-mentioned by weighing by proportioning
Each component carries out mixing treatment, obtains mixed material；Then gained use extruder will mix
Material extrusion molding, i.e. obtains finished product.
Embodiment 2
Wood composite board moulded by a kind of polyethylene for building, and it is to be mixed by the component of following parts by weight
Conjunction stirring is made:
Polyethylene 88 parts, willow wood powder 90 parts, butyl ether melamine formaldehyde resin 20 parts,
Triallyl isocyanate 18 parts, ethyl acetate 30 parts, BPO 7 parts, 20 parts of acrylic acid,
Antioxidant 264 5 parts, alkylphenol polyoxyethylene 4 parts, aluminium oxide 4 parts, phosphorous acid benzene
Di-isooctyl 9 parts, CNT 5 parts.Its preparation method is: above-mentioned by weighing by proportioning
Each component carries out mixing treatment, obtains mixed material；Then gained use extruder will mix
Material extrusion molding, i.e. obtains finished product.
Embodiment 3
Wood composite board moulded by a kind of polyethylene for building, and it is to be mixed by the component of following parts by weight
Conjunction stirring is made:
Polyethylene 82 parts, willow wood powder 82 parts, butyl ether melamine formaldehyde resin 15 parts,
Triallyl isocyanate 14 parts, ethyl acetate 22 parts, BPO 5 parts, 18 parts of acrylic acid,
Antioxidant 264 4 parts, alkylphenol polyoxyethylene 3 parts, aluminium oxide 3 parts, phosphorous acid benzene
Di-isooctyl 6 parts, CNT 4 parts.Its preparation method is: above-mentioned by weighing by proportioning
Each component carries out mixing treatment, obtains mixed material；Then gained use extruder will mix
Material extrusion molding, i.e. obtains finished product.
Embodiment 4
Wood composite board moulded by a kind of polyethylene for building, and it is to be mixed by the component of following parts by weight
Conjunction stirring is made:
Polyethylene 86 parts, willow wood powder 86 parts, butyl ether melamine formaldehyde resin 18 parts,
Triallyl isocyanate 16 parts, ethyl acetate 27 parts, BPO 6 parts, 18 parts of acrylic acid,
Antioxidant 264 4 parts, alkylphenol polyoxyethylene 3 parts, aluminium oxide 3 parts, phosphorous acid benzene
Di-isooctyl 8 parts, CNT 4 parts.Its preparation method is: above-mentioned by weighing by proportioning
Each component carries out mixing treatment, obtains mixed material；Then gained use extruder will mix
Material extrusion molding, i.e. obtains finished product.
Claims (5)
1. wood composite board moulded by a polyethylene for building, it is characterised in that it is by weighing as follows
The component of amount number prepares: polyethylene 80-88 part, willow wood powder 80-90 part, butyl etherization three
Paracyanogen ammonia formaldehyde resin 14-20 part, triallyl isocyanate 12-18 part, ethyl acetate
20-30 part, BPO 3-7 part, acrylic acid 16-20 part, antioxidant 264 3-5 part, alkyl
Phenol polyethenoxy ether 2-4 part, aluminium oxide 2-4 part, phosphorous acid benzene di-isooctyl 5-9 part, carbon
Nanotube 3-5 part.
Wood composite board moulded by one the most according to claim 1 polyethylene for building, its
It is characterised by that it is to be prepared by the component of following parts by weight: polyethylene 80 parts, willow wood powder
80 parts, butyl ether melamine formaldehyde resin 14 parts, triallyl isocyanate 12 parts,
Ethyl acetate 20 parts, BPO 3 parts, 16 parts of acrylic acid, antioxidant 264 3 parts, alkyl
Phenol polyethenoxy ether 2 parts, aluminium oxide 2 parts, phosphorous acid benzene di-isooctyl 5 parts, CNT
3 parts.
Wood composite board moulded by one the most according to claim 1 polyethylene for building, its
It is characterised by that it is to be prepared by the component of following parts by weight: polyethylene 88 parts, willow wood powder
90 parts, butyl ether melamine formaldehyde resin 20 parts, triallyl isocyanate 18 parts,
Ethyl acetate 30 parts, BPO 7 parts, 20 parts of acrylic acid, antioxidant 264 5 parts, alkyl
Phenol polyethenoxy ether 4 parts, aluminium oxide 4 parts, phosphorous acid benzene di-isooctyl 9 parts, CNT
5 parts.
Wood composite board moulded by one the most according to claim 1 polyethylene for building, its
It is characterised by that it is to be prepared by the component of following parts by weight: polyethylene 82 parts, willow wood powder
82 parts, butyl ether melamine formaldehyde resin 15 parts, triallyl isocyanate 14 parts,
Ethyl acetate 22 parts, BPO 5 parts, 18 parts of acrylic acid, antioxidant 264 4 parts, alkyl
Phenol polyethenoxy ether 3 parts, aluminium oxide 3 parts, phosphorous acid benzene di-isooctyl 6 parts, CNT
4 parts.
Wood composite board moulded by one the most according to claim 1 polyethylene for building, its
It is characterised by that it is to be prepared by the component of following parts by weight: polyethylene 86 parts, willow wood powder
86 parts, butyl ether melamine formaldehyde resin 18 parts, triallyl isocyanate 16 parts,
Ethyl acetate 27 parts, BPO 6 parts, 18 parts of acrylic acid, antioxidant 264 4 parts, alkyl
Phenol polyethenoxy ether 3 parts, aluminium oxide 3 parts, phosphorous acid benzene di-isooctyl 8 parts, CNT
4 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398344.1A CN105936662A (en) | 2016-06-06 | 2016-06-06 | Polyethylene plastic-wood composite board for buildings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398344.1A CN105936662A (en) | 2016-06-06 | 2016-06-06 | Polyethylene plastic-wood composite board for buildings |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105936662A true CN105936662A (en) | 2016-09-14 |
Family
ID=57151787
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610398344.1A Pending CN105936662A (en) | 2016-06-06 | 2016-06-06 | Polyethylene plastic-wood composite board for buildings |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333512A (en) * | 2013-06-17 | 2013-10-02 | 内蒙古亿利塑业有限责任公司 | Salix psammophila/polyethylene wood-plastic composite material and preparation method thereof |
| CN103509361A (en) * | 2013-09-13 | 2014-01-15 | 临沂康亿家生态木业有限公司 | PE wood/plastic composite sectional material and manufacturing method thereof |
| CN103602088A (en) * | 2013-10-25 | 2014-02-26 | 安徽工贸职业技术学院 | Polyethylene wood plastic composite material |
| CN104327527A (en) * | 2014-10-16 | 2015-02-04 | 嘉兴思达木塑科技有限公司 | Wood plastic composite and preparation method thereof |
| CN104725705A (en) * | 2015-03-24 | 2015-06-24 | 湖州国信物资有限公司 | Method for preparing novel polyethylene wood-plastic composite material |
| CN105440399A (en) * | 2015-12-04 | 2016-03-30 | 沈阳化工大学 | Polyvinyl wood-plastic composite and preparation method thereof |
-
2016
- 2016-06-06 CN CN201610398344.1A patent/CN105936662A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333512A (en) * | 2013-06-17 | 2013-10-02 | 内蒙古亿利塑业有限责任公司 | Salix psammophila/polyethylene wood-plastic composite material and preparation method thereof |
| CN103509361A (en) * | 2013-09-13 | 2014-01-15 | 临沂康亿家生态木业有限公司 | PE wood/plastic composite sectional material and manufacturing method thereof |
| CN103602088A (en) * | 2013-10-25 | 2014-02-26 | 安徽工贸职业技术学院 | Polyethylene wood plastic composite material |
| CN104327527A (en) * | 2014-10-16 | 2015-02-04 | 嘉兴思达木塑科技有限公司 | Wood plastic composite and preparation method thereof |
| CN104725705A (en) * | 2015-03-24 | 2015-06-24 | 湖州国信物资有限公司 | Method for preparing novel polyethylene wood-plastic composite material |
| CN105440399A (en) * | 2015-12-04 | 2016-03-30 | 沈阳化工大学 | Polyvinyl wood-plastic composite and preparation method thereof |
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Application publication date: 20160914 |
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