CN105925289B - A kind of combined vaporizing destructive distillation prepares low tar gas combustion apparatus - Google Patents

A kind of combined vaporizing destructive distillation prepares low tar gas combustion apparatus Download PDF

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Publication number
CN105925289B
CN105925289B CN201610550772.1A CN201610550772A CN105925289B CN 105925289 B CN105925289 B CN 105925289B CN 201610550772 A CN201610550772 A CN 201610550772A CN 105925289 B CN105925289 B CN 105925289B
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gas
coal
furnace
fluidized
destructive distillation
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CN105925289A (en
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曹俊刚
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Shaanxi Capitel Industry Co Ltd
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Shaanxi Capitel Industry Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/04Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of powdered coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/50Fuel charging devices
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/80Other features with arrangements for preheating the blast or the water vapour
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • C10J3/84Gas withdrawal means with means for removing dust or tar from the gas
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/095Exhaust gas from an external process for purification
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0959Oxygen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • C10J2300/0976Water as steam
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/12Heating the gasifier
    • C10J2300/123Heating the gasifier by electromagnetic waves, e.g. microwaves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/16Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603Integration of gasification processes with another plant or parts within the plant with gas treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Industrial Gases (AREA)
  • Fluidized-Bed Combustion And Resonant Combustion (AREA)

Abstract

The present invention relates to a kind of combined vaporizing destructive distillation to prepare low tar gas combustion apparatus, it includes fluidized-bed gasification furnace (3), cyclone separator (4), slag collection device (5), gasifying agent supply system, microwave heating equipment (12), second plasmatorch (17), fluidized bed dry distillation furnace (2-1), built-in gas-solid separator (2-2), synthesis gas coal gas processor (2-3) and the first plasmatorch (2-11), the device can be suitably used for coal catalyzed conversion and non-catalytic conversion preparation combustion gas, thermal efficiency is high, it is easy to enlargement, longtime running is stablized, coal conversion is high, it is low that combustion gas contains burnt dustiness, synthesis gas Exposure degree is efficient.

Description

A kind of combined vaporizing destructive distillation prepares low tar gas combustion apparatus
Technical field
The present invention relates to coal chemical technology application field, in particular to a kind of combined vaporizing destructive distillation prepares low tar combustion gas dress It sets.
Background technique
Coal chemical industry prepares solid fuel using coal as raw material, through Physical Processing, make through chemical process coal be converted into gaseous fuel, Liquid fuel, coke and chemicals include that coal gasification, liquefaction, coking etc. utilize route.Pyrolysis of coal is that coal processing turns Change, such as gasify, liquefy, the pilot process that coking technique is particularly important, the part of coal can be achieved under anoxybiotic or anoxia condition Gasification and liquefaction, are made coal gas and tar.
Coal gasification is broadly divided into fixed bed gasification, fluidized gasification and entrained flow gasification.In The Fluidized Bed Coal Gasification Technology is because of it On a large scale, efficiently, coal adaptability become the Main way of gasification technology development by force, fluidized-bed gasification furnace high-temperature synthesis gas it is aobvious Recuperation of heat is one of problem of gasification technology, and gasification furnace high-temperature synthesis gas temperature is at 1000 DEG C or more out, synthesis gas high temperature sensible heat Way of recycling mainly has waste heat boiler, water Quench and chemical recuperation of heat.Chemical recuperation of heat can by the pyrolysis of coal absorb energy come Recycle out the sensible heat of one section of high-temperature synthesis gas of gasification furnace.Two kinds of sides of dry ash extraction and slag tap can be used in fluidized-bed gasification furnace Formula, dry ash extraction efficiency of carbon con version is lower, required dreg removing system and operating cost are high;Slag tap can reduce carbon content in lime-ash, But required energy consumption is high, and system utilization efficiency of heat energy is low.Applicant is by comprehensive retrieval and in-depth study, and the prior art is not yet There is provided one kind be easy to enlargement production, stable, coal conversion is high, synthesis gas Exposure degree efficiently, system thermal efficiency it is high, Combustion gas is containing burnt Coal Gasification destructive distillation co-generation system and method low, dust is few.
Summary of the invention
In order to overcome coal thermal transition low efficiency, combustion gas in the prior art containing burnt dustiness, high, combustion gas sensible heat utilization does not conform to Reason, system thermal efficiency is low, equipment is easy to slagging, can not catalyzed conversion with same set of system suitable for coal and non-catalytic conversion The technical issues of preparing combustion gas, it is necessary to design the Coal Gasification destructive distillation combined production device and method that can solve the above problem.
Provided a kind of combined vaporizing destructive distillation of the invention prepares low tar gas combustion apparatus, including gasification system (1) With dry distillation of coal system (2).Wherein, the gasification system (1) includes: fluidized-bed gasification furnace (3), cyclone separator (4), clinker receipts Acquisition means (5) and gasifying agent supply system;The fluidized-bed gasification furnace (3) includes furnace body (6) and shell (10), and furnace body (6) is interior Conical distribution plate (7) are arranged in lower part, the burnt entrance (9) of coal charge entrance (8) and ash being arranged above conical distribution plate (7);It is described The setting of gasification furnace (3) top runs through the syngas outlet (11) of the furnace body (6) and shell (10), burner hearth (6) and shell (10) The toroidal cavity of formation, the toroidal cavity is interior to be arranged microwave heating equipment (12), and microwave heating equipment (12) setting exists Between conical distribution plate (7) and syngas outlet (11);It is opened up slag-drip opening (13) in the middle part of conical distribution plate (7), slag-drip opening (13) It is connected to by scum pipe (14) with slag collection device (5);It is formed between shell (10) lower head below conical distribution plate (7) Gas chamber (15), gasifying agent air inlet pipe (16) are arranged through the shell (10) and furnace body (6).The dry distillation of coal system (2) includes Fluidized bed dry distillation furnace (2-1), gas-solid separator (2-2) and synthesis gas coal gas processor (2-3);Fluidized bed dry distillation furnace (the 2- It 1) include the first furnace body (2-4), the first furnace body (2-4) interior lower part setting the first conical distribution plate (2-5), the first conical distribution plate The first coal charge entrance (2-6) being arranged above (2-5);Coke discharging mouth (2-7), coke discharging are opened up in the middle part of first conical distribution plate (2-5) Mouth (2-7) is connected to by the first coke discharging tube (2-8) with the burnt entrance (9) of the ash;First conical distribution plate (2-5) lower section and first Fluidizing gas distributing chamber (2-9) is formed between furnace body (2-4) inner wall;Setting and the stream on the first furnace body (2-4) outer wall Change the fluidizing gas blast pipe (2-10) of gas distributing chamber (2-9) connection;The gas-solid separator (2-2) is built in the fluidisation The top of bed gas retort (2-1), gas-solid separator (2-2) gas vent pass through pipeline and synthesis gas coal gas processor (2- 3) air inlet is connected to;Synthesis gas coal gas, which is managed, is arranged multiple first plasmatorch (2-11) at the top of device (2-3), the processing of synthesis gas coal gas Device (2-3) gas vent is sequentially connected boiler (2-12) and gas buffer-stored tank (2-13) by the first gas pipeline.It is described Cyclone separator (4) air inlet and air outlet respectively with the syngas outlet pipeline (11) and the fluidizing gas blast pipe (2-10) connection;Cyclone separator (4) the solids discharge mouth and the burnt entrance (9) of the ash.
Preferably, the gas-solid separator (2-2) includes be interconnected centrifugal deduster and filter element.It is highly preferred that Filter element (2-13) is ceramic porous material or iron aluminum metal sintered porous material.
Preferably, be additionally provided on the scum pipe (14) of the fluidized-bed gasification furnace (3) two symmetrical second it is equal from Sub- torch (17), and the second plasmatorch (17) is arranged with scum pipe (14) axis at 30-60 degree angle opening obliquely.More preferably Ground, the second plasmatorch (17) are arranged with the scum pipe (14) axis at 45 degree of angle openings obliquely.
Preferably, the quantity of multiple first plasmatorch (2-11) of setting is above synthesis gas coal gas reason device (2-3) 3-5 branch, and be arranged symmetrically at circumference.It is highly preferred that the quantity of first plasmatorch (2-11) be 4, described first etc. Ion torch (2-11) is arranged with synthesis gas coal gas reason device (2-3) vertical direction axis at 45 degree of angle openings obliquely.
Preferably, the quantity of the gasifying agent air inlet pipe (16) of the fluidized-bed gasification furnace (3) is 4-10 root and is even number, institute It is symmetrical at circumference to state more gasifying agent air inlet pipe (16), the gasifying agent air inlet pipe (16) is barrel forms, central inner pipe For by oxygen-containing gas, it is for example dry that the annular space between inner tube and outer tube is passed through not oxygenous water vapour or reducibility gas Evaporate combustion gas.It is highly preferred that 2-5 nozzle (19) is arranged through the conical distribution plate (7), the nozzle (19) is located at same circle On week and it is uniformly arranged.Nozzle (19) nozzle is tube-in-tube structure, and the central inner pipe of the nozzle (19) is used for by oxygen-containing Gas, the annular space between central inner pipe and outer tube are passed through not oxygenous water vapour;Nozzle (19) the central inner pipe front end face Distance L is 20-35mm between its outer tube front end face, i.e., protrudes into the institute in gasification furnace furnace chamber through the conical distribution plate (7) The central inner pipe front end face for stating nozzle (19) is longer than its outer tube front end face;The nozzle (19) by connecting elements such as flange with Gasifying agent air inlet pipe (16) the compartment of terrain connection.Specifically he, such as when the quantity of gasifying agent air inlet pipe (16) be 4 when, institute The quantity for stating nozzle (19) is 2, and first nozzle, second nozzle are connected to first gasifying agent air inlet pipe and third The gasifying agent that root gasifying agent air inlet pipe, second gasifying agent air inlet pipe and the 4th gasifying agent air inlet pipe are sent into enters the gas chamber (15), the gasifying agent in the gas chamber (15) is entered in furnace body (6) burner hearth by the aperture on the conical distribution plate (7).With This analogizes.
Preferably, the quantity of the fluidizing gas blast pipe (2-10) of the fluidized bed dry distillation furnace (2-1) is 4-10 root and is Even number, the fluidizing gas blast pipe (2-10) are symmetrical at circumference.It is highly preferred that running through the first conical distribution plate 2-5 the first jet pipes (2-14) are arranged in (2-5), and first jet pipe (2-14) is located on same circumference and is uniformly arranged.It is described First jet pipe (2-14) is connect by connecting elements (such as flange) with fluidizing gas blast pipe (2-10) compartment of terrain.Specifically He, such as when the quantity of fluidizing gas blast pipe (2-10) is 6, the quantity of first jet pipe (2-14) is 3,1# the One jet pipe, the first jet pipe of 2#, the first jet pipe of 3# are connected to 1# fluidizing gas blast pipe, 3# fluidizing gas blast pipe and 5# stream Change gas blast pipe;The high temperature entered through 2# fluidizing gas blast pipe, 4# fluidizing gas blast pipe and 6# fluidizing gas blast pipe Synthesis gas enters the fluidizing gas distributing chamber (2-9), and the fluidizing gas in the fluidizing gas distributing chamber (2-9) passes through described Aperture on first conical distribution plate (2-5) enters in the first furnace body (2-4) burner hearth.And so on.
Preferably, the slag collection device (5) is tube-in-tube structure, can be made of inner barrel and outer barrel, outer cylinder and inner cylinder Toroidal cavity in be arranged two groups of independent snakelike heat exchange tubes;Or be made of inner cylinder, middle cylinder and outer cylinder, between inner cylinder and middle cylinder Annular space flowing steam, annular space between outer cylinder and middle cylinder circulates oxygen.
Gasifying agent for the fluidized-bed gasification furnace (3) enters institute after flowing through the slag collection device (5) recycling heat State gasifying agent air inlet pipe (16).Preferably, the slag collection device (5) is made of inner barrel and outer barrel, tube-in-tube structure annular Two groups of coiled pipe heat exchanger tubes are set in cavity, and oxygen of first group of coiled pipe heat exchanger tube for ventilating air separation equipment to be isolated is formed The oxygen of the oxidant of preheating, the steam of water source (tap water or the sewage containing organic matter) through boiler (2-12) by-product is through second group Superheated steam is formed after the heat exchange of coiled pipe heat exchanger tube, the oxygen and superheated steam of preheating respectively enter the gasifying agent air inlet pipe (16) Central inner pipe and inner tube and outer tube between annular space.
Preferably, the scum pipe (14) is made of heat-resisting material.Preferably, the heat-resisting material includes zirconium oxide And silica.
Preferably, the scum pipe (14) is additionally provided with fine ash entrance (20), fine ash entrance (20) be located at described second it is equal from Above sub- torch (17);The vertical height of the fine ash entrance (20) and second plasmatorch (17) is 0.15-0.3m.It is more excellent (close to the second plasmatorch at the 1/3 of selection of land, second plasmatorch (17) and the slag collection device (5) spacing (17)) two jet pipes (18) for spraying water vapour are additionally provided on scum pipe (14).It is highly preferred that two jet pipes (18) circumferentially symmetrical and Open Side Down and horizontal plane is arranged at 40 degree of angles.It is highly preferred that second plasmatorch (17) scum pipe (14) long 1m between the slag collection device (5).
Preferably, the cyclone separator (4) of the gasification system (1) includes the first cyclone separator and the second whirlwind point From device, the syngas outlet (11), the first cyclone separator, the second cyclone separator are sequentially connected, the second cyclone separator Air inlet and gas outlet respectively with the fluidizing gas in the gas outlet of the first cyclone separator and dry distillation of coal system (2) into Air hose (2-10) connection;The first cyclone separator solid outlet is connected to the burnt entrance (9) of the ash, second whirlwind Separator solid fine ash discharge port is connected to the fine ash entrance (20) being arranged on the scum pipe (14), the fine ash entrance (20) it is located above second plasmatorch (17);The fine ash entrance (20) is vertical with second plasmatorch (17) Height is 0.15-0.3m.
A kind of method that combined vaporizing destructive distillation prepares low tar combustion gas, which comprises (a), be mixed with catalyst or not The coal dust for being mixed with catalyst is sent into gasification furnace (3) burner hearth, the gas of preheating through the coal charge entrance (8) of fluidized-bed gasification furnace (3) Agent is sent into gasification furnace (3) burner hearth through the conical distribution plate (7) of the fluidized-bed gasification furnace (3) and fluidizes the coal dust, coal Microwave heating equipment in furnace body (6) and shell (10) toroidal cavity of the heat needed for powder gasification by being located at gasification furnace (3) (12) it provides, the high-temperature synthesis gas formed in fluidized-bed gasification furnace (3) passes through the syngas outlet (11) on the gasification furnace (3) It draws;(b), fluidizing gas air inlet of the high-temperature synthesis gas after cyclone separator (4) processing through fluidized bed dry distillation furnace (2-1) Pipe (2-10) and the first conical distribution plate (2-5) enter fluidized bed dry distillation furnace (2-1) burner hearth for serve as fluidizing agent and Heat carrier makes to enter the stream by being located at the first coal charge entrance (2-6) being arranged above the first conical distribution plate (2-5) Powder fluidized, destructive distillation in change bed gas retort (2-1) burner hearth form combustion gas, and the combustion gas is through fluidized bed dry distillation furnace (2-1) furnace roof Synthesis gas coal gas processor (2-3) is sent into after built-in gas-solid separator (2-2) dedusting;(c), synthesis gas coal gas processor (2- 3) the first plasmatorch (2-11) that top is arranged is made in combustion gas by 2500 DEG C of arc discharge output or more of plasma Tar, the heavy hydrocarbon pyrolysis form small molecule fuel gas, and through synthesis bottle coal treatment apparatus (2-3), treated, and combustion gas is divided at least Two parts, a part introduce the fluidized-bed gasification furnace (3) for coal charge in fluidized furnace, and another part is recycled through boiler (2-12) Gas buffer storage tank (2-13) is sent into after heat byproduct steam.
Preferably, the method that above-mentioned combined vaporizing destructive distillation prepares low tar combustion gas is done using the above-mentioned combined vaporizing of the present invention It evaporates and prepares the implementation of low tar gas combustion apparatus.
Preferably, the gasifying agent of above-mentioned preheating includes oxygen and steam, and the oxygen is separated by air separation plant and is made, institute Stating steam is superheated steam.It is highly preferred that the superheated steam includes water source through boiler (2-12) heating byproduct steam again through institute The overheat formed after the interlayer cavity recycling heat of the jacket type structure of fluidized-bed gasification furnace (3) slag collection device (5) is stated to steam Vapour, the water source include tap water and/or the sewage containing organic matter.Preferably, gasification temperature is 700-850 DEG C, gasification pressure Power is 0.1-0.4MPa.It is highly preferred that gasification temperature is 780-820 DEG C, vapor pressure 0.25-0.35MPa.Preferably, gas Changing the mass ratio of steam and coal in furnace is 0.3-0.8:1, and the mass ratio of oxygen and coal is 0.3-0.6:1.It is highly preferred that gasification furnace The mass ratio of interior steam and coal is 0.5-0.7:1, and the mass ratio of oxygen and coal is 0.4-0.5:1.
Preferably, the cyclone separator (4) of the gasification system (1) includes the first cyclone separator and the second whirlwind point From device, the solid particle of the first cyclone separator separation and through the first coke discharging tube of fluidized bed dry distillation furnace (2-1) (2-8) discharge Semicoke is recycled into fluidized-bed gasification furnace (3) by the burnt entrance (9) of ash on fluidized-bed gasification furnace (3);Second cyclone separator The fine ash isolated is sent into the fine ash entrance (20) on the scum pipe (14), second be located at below the fine ash entrance (20) 3000 DEG C of output of plasmatorch (17) or more flame of centre, makes fine ash and through fluidized-bed gasification furnace (3) the conical distribution plate (7) The ash melting of slag-drip opening (13) discharge, two jet pipes (18) being equipped on the scum pipe (14) spray under water vapor acting Further gasification forms synthesis gas.
Compared with prior art coal reforming unit, of the invention is had the advantages that
(1), apparatus of the present invention are able to achieve coal gasification, destructive distillation coproduction, using independently operated fluidized-bed gasification furnace and fluidisation Bed pyrolysis oven implements gasification and retorting operation respectively, is easy to control and is suitble to enlargement production.
(2), gasification furnace uses microwave heating, enables coal from internal to external while heating, and heating efficiency is high, improves Gasification reaction accurately controls gasification reaction temperature by microwave heating, especially becomes apparent to the catalytic gasification reaction effect of coal; The device that invention provides can be suitable for coal catalytic gasification destructive distillation coproduction and coal non-catalyzed gasification destructive distillation coproduction simultaneously.
(3), apparatus of the present invention are filled using high-temperature gasification synthesis gas as the fluidizing agent of fluidized bed dry distillation furnace and heat carrier Divide the production for increasing combustion gas using the thermal energy in system, while avoiding using energy loss and formation caused by the cooling of water Quench Contaminated wastewater;It decreases using boiler recycling heat bring investment and maintenance cost.
(4), gas-solid separator built in fluidized bed pyrolysis furnace includes that interconnected centrifugal deduster and filter element can use The combustion gas dustiness of self-fluidized type bed pyrolysis oven is less than 8mg/Nm3, can be significant by fluidized bed pyrolysis furnace built in above-mentioned gas-solid separator Ground reduces tar and results in blockage in the accumulation of filter element surface, extends filter element service life, due to fluidized bed dry distillation furnace Interior top temperature is kept above 550 DEG C, and the tar in combustion gas is hardly agglomerated with fine ash.
(5), the synthesis gas coal gas processor for the first plasmatorch being equipped with by top is to by dedusting combustion gas hot tearing Solution, the plasma of first 2500 DEG C of plasmatorch arc discharge output or more form tar in combustion gas, the heavy hydrocarbon pyrolysis Small molecule fuel gas, increases fuel gases calorific value, and tar content is less than 5ppm in combustion gas after handling thermal cracking, can be directly used for Engine or generator combustion power generation.
(6), boiler byproduct steam is set after synthesis gas coal gas processor as fluidized-bed gasification furnace gasifying agent, is realized Thermal effect utilizes;Using the Partial cleansing combustion gas after recovered heat as fluidized-bed gasification furnace fluidizing agent, fluidized bed Jie is reduced The investment of matter increases combustion gas active principle concentration and improves fuel gases calorific value.
(7), the cyclone separator of fluidized-bed gasification furnace includes concatenated first cyclone separator and the second cyclone separator For depth separating high-temp synthesis gas entrained solid particle, gas solid separation operating pressure built in fluidized bed dry distillation furnace is reduced; The coke recycle of the coarse granule of first cyclone separator separation and fluidized bed dry distillation fire grate Jiao Kou discharge is sent into fluidized gasification Furnace gas improves charcoal percent conversion.More symmetrical openings are arranged on fluidized-bed gasification furnace scum pipe to be arranged obliquely The second plasmatorch can generate 3000 DEG C or more flame of centre, fine ash that the second cyclone separator is isolated is sent into fluidized bed gas The fine ash entrance changed on furnace slag discharge pipe is mixed with the clinker that slag-drip opening is discharged, and is melted under 3000 DEG C of conditions above, is passed through deslagging Jet pipe that pipe is equipped with sprays into steam, and not only to have served as coolant cooling to slag but also serve as the carbon material of gasifying agent and melting and gasify to be formed Synthesis gas.
(8), coal dust and gas in burner hearth are enhanced through the nozzle of setting tube-in-tube structure on fluidized-bed gasification furnace distribution grid The mixed effect of agent avoids distribution grid near zone from forming dead zone, causes sintering damage distribution grid.The distribution of fluidized bed dry distillation furnace Through setting jet pipe on plate, the turbulent closure scheme effect of coal dust and heat carrier in burner hearth is enhanced, homogeneous heating reduces the shape of tar At.
Detailed description of the invention
Fig. 1 is that combined vaporizing destructive distillation of the invention prepares low tar gas combustion apparatus schematic diagram.
In figure, 1, gasification system;2, dry distillation of coal system;3, fluidized-bed gasification furnace;4, cyclone separator;5, slag collection Device;6, furnace body;7, conical distribution plate;8, coal charge entrance;9, the burnt entrance of ash;10, shell;11, syngas outlet;12, microwave Heating device;13, slag-drip opening;14, scum pipe;15, gas chamber;16, gasifying agent air inlet pipe;17, the second plasmatorch;18, jet pipe; 19, nozzle;20, fine ash entrance;2-1, fluidized bed dry distillation furnace;2-2, gas-solid separator;2-3, synthesis gas coal gas processor;2-4, First furnace body;2-5 the first conical distribution plate;2-6, the first coal charge entrance;2-7, coke discharging mouth;2-8, the first coke discharging tube;2-9, stream Change gas distributing chamber;2-10, fluidizing gas blast pipe;2-11, the first plasmatorch;2-12, boiler;2-13, gas buffer are deposited Storage tank;2-14, the first jet pipe.
Specific embodiment
Below with reference to the embodiments and with reference to the accompanying drawing the technical solutions of the present invention will be further described.
Embodiment 1: feed coal (lignite, anthracite or jet coal) water content after being dried is 6-10wt%, dehydration Feed coal afterwards is crushed, sieving separating goes out to be greater than the broken coal B that 10mm is less than the broken coal A and 4-10mm of 16mm, broken coal B and catalysis Agent is mixed to form Mixture Density Networks C, wherein catalyst is alkali or alkaline earth metal catalyst, and the mass ratio of broken coal B and catalyst is 80-200:1, Mixture Density Networks C are sent into fluidized-bed gasification furnace by the coal charge entrance 8 of fluidized-bed gasification furnace 3, preheated gasifying agent (oxygen and steam) by the hole in furnace on the conical distribution plate 7 of 8 lower section of coal charge entrance and runs through through gasifying agent air inlet pipe 16 The nozzle 19 of the conical distribution plate 7 is sent into 3 burner hearth of fluidized-bed gasification furnace and fluidizes the Mixture Density Networks C, wherein control steam and coal Mass ratio be 0.3-0.8:1, the mass ratio of oxygen and coal is 0.3-0.6:1, adjusts the power control of microwave heating equipment 12 Temperature in gasification furnace 3 at 700-850 DEG C, control furnace pressure be 0.1-0.4MPa, wherein gasification furnace body 6 top, Middle part and lower part respectively set thermocouple, and the high-temperature synthesis gas that gasification is formed in gasification furnace 3 draws the furnace by syngas outlet 11 Body 6 is sent into the fluidizing gas blast pipe 2-10 of fluidized bed dry distillation furnace 2-1 after 4 dedusting of cyclone separator by pipeline, wherein Cyclone separator 4 includes the first cyclone separator and the second cyclone separator being connected in series;High-temperature synthesis gas is through the fluidisation The first conical distribution plate 2-5 of bed gas retort 2-1 and through the first conical distribution plate 2-5 jet pipe (2-14) for flowing Change, heat and be sent into broken coal A through the first coal charge entrance 2-6, the combustion gas that destructive distillation generates is through being built in the fluidized bed dry distillation furnace 2-1's It is closed after the gas-solid separator 2-2 purification at top, by being sent into the pipeline of gas-solid separator 2-2 top gas outlet connection At bottle coal treatment apparatus 2-3;Wherein, the gas-solid separator 2-2 includes interconnected centrifugal deduster 2-12 and crosses filtering element The multiple first plasmatorch 2-11 electric discharge output being arranged at the top of part 2-13, synthesis gas coal gas processor 2-3 is higher than 2500 DEG C Tar in combustion gas, the heavy hydrocarbon pyrolysis are formed small molecule fuel gas by plasma, through synthesis bottle coal treatment apparatus 2-3 processing Combustion gas afterwards is divided at least two parts, and a part of combustion gas is through pipeline to the gasification for not passing through flanged joint with the nozzle 19 Agent air inlet pipe 16 (outer tube preferably in the gasifying agent air inlet pipe 16 of cannula structure) enters the gas chamber 15 of gasification furnace 3, part combustion Gas is used to fluidize the solid material in burner hearth through the hole on the conical distribution plate 7;A part of combustion gas is changed through boiler (2-12) Gas buffer storage tank (2-13) is sent into after heat and byproduct steam.Wherein, the semicoke formed in fluidized bed dry distillation furnace 2-1 is through first The coke discharging mouth 2-7 opened up in the middle part of conical distribution plate 2-5, the first coke discharging tube 2-8 being connected to the coke discharging mouth 2-7 are sent into the stream Change the burnt entrance 9 of ash on bed gasification furnace 3;Wherein, the burnt entrance 9 of ash is to being placed in 8 lower section of coal charge entrance;Cyclone separator The coarse granule that the first cyclone separator in 4 is isolated is sent into cycle gasification in gasification furnace 3 through the burnt entrance 9 of the ash;Second rotation The fine ash that wind separator is isolated then is sent into the fine ash entrance 20 being arranged on the scum pipe 14 of fluidized-bed gasification furnace 3, fluidized bed gas Change the lime-ash that the gasification of furnace 3 generates and the scum pipe 14, the lime-ash are entered by the slag-drip opening 13 opened up in the middle part of conical distribution plate 7 And fine ash passes through multiple second plasmatorch 17 being arranged below fine ash entrance 20 under the effect of gravity and forms high-temperature area heating Melting, wherein described 3000 DEG C of second plasmatorch, 17 output or more flame of centre, a steam through boiler (2-12) by-product Jet pipe 18 through being arranged below second plasmatorch 17 on the scum pipe 14 sprays into scum pipe 14, in thermodynamic activity Under, the steam sprayed through jet pipe 18 is moved at V-type, and the steam flowed up in the lime-ash and fine ash of melting and scum pipe 14 is into one Walk gasification reaction and form synthesis gas and enter in fluidized-bed gasification furnace 3 through scum pipe 14, in scum pipe 14 through just cooling slag into Enter slag collection device 5;Wherein, the slag collection device 5 be tube-in-tube structure, can be made of inner barrel and outer barrel, outer cylinder with Two groups of independent snakelike heat exchange tubes are set in the toroidal cavity of inner cylinder;Or it is made of inner cylinder, middle cylinder and outer cylinder, inner cylinder and middle cylinder Between annular space flowing steam, annular space between outer cylinder and middle cylinder circulates oxygen;The O obtained through air-separating plant2And boiler Another steam of (2-12) by-product respectively through the gas access on slag collection device 5 enter in heat exchange component with high temperature furnace slag Heat exchange, the O after heating2It is respectively fed in the gasifying agent air inlet pipe 16 for passing through flanged joint with the nozzle 19 with superheated steam Pipe and outer tube.Through detecting, carbon content is less than 4wt% in slag collection device 5, without synthesis gas coal gas processor 2-3 processing Combustion gas tar content is greater than 1500ppm, and combustion gas tar content is less than 5ppm in gas buffer storage tank (2-13), and solid particle contains Dust quantity is less than 8mg/Nm3, for coal treating capacity greater than 180 tons/d, system thermal efficiency is greater than 80%, and continuously-running 2 years stifled without tar Plug filter element causes system shutdown.
Embodiment 2: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is identical, and difference is: broken coal B being directly sent into fluidized bed by the coal charge entrance 8 of fluidized-bed gasification furnace 3 Non-catalyzed gasification is carried out in gasification furnace, gasification temperature control is at 830-1150 DEG C.Through detecting, carbon contains in slag collection device 5 Amount is less than 3.85wt%, and the combustion gas tar content without synthesis gas coal gas processor 2-3 processing is greater than 1378ppm, gas buffer Combustion gas tar content is less than 4.8ppm in storage tank (2-13), and solid particle dustiness is less than 7.8mg/Nm3, coal treating capacity is greater than 180 tons/d, system thermal efficiency is greater than 82%, and continuous operation 2 years is without blocking system shutdown caused by filter element because of tar.
Embodiment 3: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: the gas-solid separator 2-2 built in by fluidized bed dry distillation furnace is external, that is, passes through Pipeline is connected to the outlet of fluidized bed dry distillation furnace furnace top gas, connecting tube road length 0.3-0.6m;Other technological parameters and 1 phase of embodiment Together, system shutdown caused by being blocked because of filter element tar for system continuous operation 13 months.
Embodiment 4: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: the gas-solid separator 2-2 built in fluidized bed dry distillation furnace be two it is concatenated from Heart deduster, other technological parameters are same as Example 1.Through detecting, carbon content is less than 4wt% in slag collection device 5, without The combustion gas tar content of synthesis gas coal gas processor 2-3 processing is greater than 1760ppm, and combustion gas contains in gas buffer storage tank (2-13) Tar content is less than 6.5ppm, and solid particle dustiness is greater than 169mg/Nm3, for coal treating capacity greater than 180 tons/d, system thermal efficiency is big In 80%, system shutdown is caused without tar blocking filter element within continuously-running 2 years.
Embodiment 5: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: the gas-solid separator 2-2 built in fluidized bed dry distillation furnace is two concatenated mistakes Original part is filtered, other technological parameters are same as Example 1.System shutdown caused by being blocked because of filter element for system continuous operation 6 months.
Embodiment 6: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: the fine ash that the second cyclone separator separates equally being passed through grey burnt entrance 9 and is sent into stream Change bed gasification furnace, other technological parameters are same as Example 1.Through detecting, less than 74%, system is run 11 months system thermal efficiency System shutdown caused by being blocked because of filter element;Carbon content is less than 4wt% in slag collection device 5, without the processing of synthesis gas coal gas The combustion gas tar content of device 2-3 processing is greater than 1500ppm, and combustion gas tar content is less than in gas buffer storage tank (2-13) 5ppm, solid particle dustiness are less than 8mg/Nm3, for coal treating capacity greater than 180 tons/d, system thermal efficiency, can be continuous less than 74% System shutdown is caused without tar blocking filter element within operation 2 years.
Embodiment 7: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: the second plasmatorch is not provided on fluidized-bed gasification furnace scum pipe, by the second whirlwind The fine ash of separator separation is sent into fluidized-bed gasification furnace by the burnt entrance 9 of ash, and other technological parameters are same as Example 1.Through examining It surveys, carbon content is greater than 10wt% in slag collection device 5, and carbon utilisation rate is low.
Embodiment 8: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: is not set on fluidized-bed gasification furnace conical distribution plate 7 through the conical distribution plate Nozzle 19, that is, the gasifying agent (oxygen and superheated steam) after preheating and the part circulating gas for serving as fluidizing agent pass through gas Agent air inlet pipe 16 enters gasification furnace burner hearth, other technological parameters and 1 phase of embodiment through the hole on the conical distribution plate 7 Together.Through detecting, carbon content is less than 4.5wt% in slag collection device 5, and system runs 14 months fluidized-bed gasification furnace conical distributions Hardened slag is serious, and system is caused to be forced to stop.
Embodiment 9: the embodiment carries out that combined vaporizing destructive distillation prepares the method for low tar combustion gas and embodiment 1 is carried out The device of method selection is different, and difference is: fluidized-bed gasification furnace slag collection device 5 be non-tube-in-tube structure, i.e. gasifying agent not It is sent directly into gasifying agent air inlet pipe 16 through the heat exchange recycling heat of slag collection device 5, other technological parameters are same as Example 1. Through detecting, system thermal efficiency is less than 50%, and carbon content is less than 4.1wt% in slag collection device 5, without the processing of synthesis gas coal gas The combustion gas tar content of device 2-3 processing is greater than 1700ppm, and combustion gas tar content is less than in gas buffer storage tank (2-13) 5.3ppm, solid particle dustiness are less than 10mg/Nm3, coal treating capacity is greater than 180 tons/d, and continuously-running 2 years without tar blocking Filter element causes system shutdown.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., is all included in the scope of protection of the present invention.

Claims (14)

1. a kind of combined vaporizing destructive distillation prepares low tar gas combustion apparatus, including gasification system (1) and dry distillation of coal system (2), Be characterized in that: the gasification system (1) include: fluidized-bed gasification furnace (3), cyclone separator (4), slag collection device (5) and Gasifying agent supply system;The fluidized-bed gasification furnace (3) includes the cone of furnace body (6) and the interior lower part setting of shell (10), furnace body (6) The burnt entrance (9) of coal charge entrance (8) and ash being arranged above shape distribution grid (7), the conical distribution plate (7);The fluidized bed The setting of gasification furnace (3) top runs through the syngas outlet (11) of the furnace body (6) and shell (10), furnace body (6) and shell (10) Microwave heating equipment (12) are set in the toroidal cavity of formation, the microwave heating equipment (12) is arranged in conical distribution plate (7) Between syngas outlet (11);It is opened up slag-drip opening (13) in the middle part of conical distribution plate (7), slag-drip opening (13) passes through scum pipe (14) It is connected to slag collection device (5);Gas chamber (15) are formed between shell (10) lower head below the conical distribution plate (7), Gasifying agent air inlet pipe (16) is arranged through the shell (10) and furnace body (6);
The dry distillation of coal system (2) includes fluidized bed dry distillation furnace (2-1), gas-solid separator (2-2) and synthesis gas coal gas processor (2-3);The fluidized bed dry distillation furnace (2-1) includes the first furnace body (2-4), the interior lower part setting first of the first furnace body (2-4) Conical distribution plate (2-5), the first coal charge entrance (2-6) that the first conical distribution plate (2-5) top is arranged;First taper point It is opened up coke discharging mouth (2-7) in the middle part of fabric swatch (2-5), the coke discharging mouth (2-7) passes through the first coke discharging tube (2-8) and the burnt entrance of the ash (9) it is connected to;Fluidizing gas distributing chamber (2- is formed below first conical distribution plate (2-5) between the first furnace body (2-4) inner wall 9);The fluidizing gas air inlet being connected to the fluidizing gas distributing chamber (2-9) is set on the first furnace body (2-4) outer wall It manages (2-10);The gas-solid separator (2-2) is built at the top of the fluidized bed dry distillation furnace (2-1), the gas-solid separator (2- 2) gas vent is connected to by pipeline with synthesis gas coal gas processor (2-3) air inlet;At the top of synthesis gas coal gas processor (2-3) 3-5 the first plasmatorch (2-11), place's synthesis gas coal gas processor (2-3) gas vent and gas buffer storage tank are set (2-13) connection;
Cyclone separator (4) air inlet and air outlet are entered the wind with the syngas outlet (11) and the fluidizing gas respectively Manage (2-10) connection;Cyclone separator (4) the solids discharge mouth and the burnt entrance (9) of the ash.
2. combined vaporizing destructive distillation according to claim 1 prepares low tar gas combustion apparatus, it is characterised in that: the fluidized bed Two symmetrical the second plasmatorch (17), and the second plasmatorch are additionally provided on the scum pipe (14) of gasification furnace (3) (17) it is arranged obliquely with scum pipe (14) axis at 30-60 degree angle opening.
3. combined vaporizing destructive distillation according to claim 2 prepares low tar gas combustion apparatus, it is characterised in that: described second etc. Ion torch (17) is arranged with the scum pipe (14) axis at 45 degree of angle openings obliquely.
4. combined vaporizing destructive distillation according to claim 1 prepares low tar gas combustion apparatus, it is characterised in that: the gas-solid point It include the centrifugal deduster and filter element being arranged in series from device (2-2).
5. combined vaporizing destructive distillation according to claim 4 prepares low tar gas combustion apparatus, it is characterised in that: described to cross filtering element Part is ceramic porous material or iron aluminum metal sintered porous material.
6. combined vaporizing destructive distillation according to claim 1 prepares low tar gas combustion apparatus, it is characterised in that: the synthesis gas The first plasmatorch (2-11) Cheng Yuanzhou being arranged at the top of coal gas processor (2-3) is arranged symmetrically.
7. combined vaporizing destructive distillation according to claim 6 prepares low tar gas combustion apparatus, it is characterised in that: described first etc. The quantity of ion torch (2-11) is 4, and first plasmatorch (2-11) and the synthesis gas coal gas processor (2-3) are vertical Azimuth axis is arranged obliquely at 45 degree of angle openings.
8. combined vaporizing destructive distillation described in any one of -4 claims prepares low tar gas combustion apparatus according to claim 1, special Sign is: the slag collection device (5) is the tube-in-tube structure being made of inner cylinder, middle cylinder and outer cylinder, and inner cylinder collects clinker, inner cylinder Annular space flowing steam between middle cylinder, the annular space circulation oxygen between outer cylinder and middle cylinder.
9. combined vaporizing destructive distillation according to claim 5 prepares low tar gas combustion apparatus, it is characterised in that: the whirlwind point From device (4) include the first cyclone separator and the second cyclone separator, the syngas outlet (11), the first cyclone separator, Second cyclone separator is sequentially connected, and the air inlet of the second cyclone separator and gas outlet go out with the first cyclone separator respectively Port is connected to the fluidizing gas blast pipe (2-10) in dry distillation of coal system (2);The first cyclone separator solid goes out Material mouth is connected to the burnt entrance (9) of the ash, and the second cyclone separator solid fine ash discharge port and setting are in the scum pipe (14) fine ash entrance (20) connection on, the fine ash entrance (20) are located above the second plasmatorch (17).
10. combined vaporizing destructive distillation described in any one of -7,9 claims prepares low tar gas combustion apparatus according to claim 1, Be characterized in that: the quantity of the gasifying agent air inlet pipe (16) of the fluidized-bed gasification furnace (3) is 4 and, institute symmetrical at circumference Stating gasifying agent air inlet pipe (16) is to be made of inner tube with the outer tube being set in outside inner tube, through the conical distribution plate (7) setting 2 It is a to be located on same circumference and symmetrically arranged nozzle (19), nozzle (19) nozzle are by inner tube and being set in outside inner tube The tube-in-tube structure of outer tube composition, nozzle (19) central inner pipe front end face distance L between its outer tube front end face is 20- 35mm, the nozzle (19) are connect by flange with gasifying agent air inlet pipe (16) compartment of terrain.
11. a kind of method that combined vaporizing destructive distillation prepares low tar combustion gas, it is characterised in that: the described method includes: (a), be mixed with Catalyst or the coal dust for not being mixed with catalyst are sent into gasification furnace (3) furnace through the coal charge entrance (8) of fluidized-bed gasification furnace (3) Thorax, the gasifying agent of preheating are sent into gasification furnace (3) burner hearth through the conical distribution plate (7) of the fluidized-bed gasification furnace (3) and are fluidized The coal dust, the microwave in furnace body (6) and shell (10) toroidal cavity of the heat needed for coal dust gasification by being located at gasification furnace (3) Heating device (12) provides, and the high-temperature synthesis gas formed in fluidized-bed gasification furnace (3) passes through the synthesis gas on the gasification furnace (3) (11) are exported to draw;(b), high-temperature synthesis gas fluidisation through fluidized bed dry distillation furnace (2-1) after cyclone separator (4) processing Gas blast pipe (2-10) and the first conical distribution plate (2-5) enter fluidized bed dry distillation furnace (2-1) burner hearth for serving as stream Change medium and heat carrier make by be located at the first coal charge entrance (2-6) being arranged above the first conical distribution plate (2-5) into Enter powder fluidized in fluidized bed dry distillation furnace (2-1) burner hearth, destructive distillation forms combustion gas, the combustion gas is through fluidized bed dry distillation furnace Synthesis gas coal gas processor (2-3) is sent into after gas-solid separator (2-2) dedusting built in (2-1) furnace roof;(c), synthesis gas coal gas The first plasmatorch (2-11) being arranged at the top of processor (2-3) is made by 2500 DEG C of arc discharge output or more of plasma Tar in combustion gas, the heavy hydrocarbon pyrolysis form small molecule fuel gas, through synthesis bottle coal treatment apparatus (2-3) treated combustion gas It is divided at least two parts, a part introduces the fluidized-bed gasification furnace (3) for coal charge in fluidized furnace, and another part is through boiler (2-12) is sent into gas buffer storage tank (2-13) after recycling heat byproduct steam.
12. the method that combined vaporizing destructive distillation according to claim 11 prepares low tar combustion gas, it is characterised in that: the side Method prepares low tar gas combustion apparatus using combined vaporizing destructive distillation described in any one of claim 1-10 claim and implements.
13. the method that combined vaporizing destructive distillation according to claim 12 prepares low tar combustion gas, it is characterised in that: gasification temperature Degree is 700-850 DEG C, vapor pressure 0.1-0.4MPa, and the mass ratio of steam and coal is 0.3-0.8:1 in gasification furnace, oxygen with The mass ratio of coal is 0.3-0.6:1.
14. the method that combined vaporizing destructive distillation according to claim 13 prepares low tar combustion gas, it is characterised in that: gasification temperature Degree is 780-820 DEG C, vapor pressure 0.25-0.35MPa, and the mass ratio of steam and coal is 0.5-0.7:1, oxygen in gasification furnace Mass ratio with coal is 0.4-0.5:1.
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