CN105924753A - Plastic alloy composition - Google Patents

Plastic alloy composition Download PDF

Info

Publication number
CN105924753A
CN105924753A CN201610529554.XA CN201610529554A CN105924753A CN 105924753 A CN105924753 A CN 105924753A CN 201610529554 A CN201610529554 A CN 201610529554A CN 105924753 A CN105924753 A CN 105924753A
Authority
CN
China
Prior art keywords
plastic cement
alloy composite
ethylene
alloy composition
plastic alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610529554.XA
Other languages
Chinese (zh)
Inventor
***
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Siphon Plastic Product Co Ltd
Original Assignee
Suzhou Siphon Plastic Product Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Siphon Plastic Product Co Ltd filed Critical Suzhou Siphon Plastic Product Co Ltd
Priority to CN201810459355.5A priority Critical patent/CN108485039B/en
Priority to CN201610529554.XA priority patent/CN105924753A/en
Publication of CN105924753A publication Critical patent/CN105924753A/en
Priority to JP2019521177A priority patent/JP6871371B2/en
Priority to AU2017294210A priority patent/AU2017294210B2/en
Priority to PCT/CN2017/091216 priority patent/WO2018006758A1/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/06—Polymer mixtures characterised by other features having improved processability or containing aids for moulding methods
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2310/00—Masterbatches

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a plastic alloy composition which comprises the following raw materials: 10-68% of high density polyethylene, 10-68% of polypropylene, 1-13% of triallyl isocyanurate, 5-28% of polysulfone, 10-25% of ethylene-vinyl acetate, 8-20% of ethylene propylene diene monomer, 0.5-2.5% of ethylenebis stearamide and 10-25% of color master batch. The ring stiffness of a siphon tube made of the plastic alloy composition is 7-8, the break elongation of the siphon tube is 100-500%, and the retraction rate of the siphon tube is 0.5-1%.

Description

Plastic cement alloy composite
Technical field
The present invention relates to a kind of plastic cement alloy composite, plastic cement alloy is combined by the three big technology of employing, and one, employing connects Branch copolymerization technique.Two, block copolymerization technology is used.Three, Interpenetrating Polymer Network Technology is used.Belong to new material technology field.
Background technology
Plastic alloy (also referred to as plastics mixed thing) is the method utilizing physical blending or chemical graft, to existing plastics It is modified, is allowed to realize high performance, functionalization, customizations.Plastic alloy product can be widely applied to automobile, electronics, essence The fields such as close instrument, office equipment, packaging material, construction material.And can improve or improve plastics performance, reduce cost, send out Generated is one of kind the most active in plastics industry, consumption rapid development.Research and the production of external modifying plastics are sent out The most quickly, the plastic raw materials of international market supply is much through the modified PP Pipe Compound trade mark in exhibition, these PP Pipe Compound are easy to use, Stable performance, the market competitiveness is the strongest.Along with the development of national economy, Industry Structure there occurs great change, automobile, logical News, building, electronics, the pillar industry development such as electrically, wide market has been opened up in the application for plastic alloy.Development plastics The production of alloy, for improving competitiveness and the level of Plastics in China processing industry of domestic resin, meets domestic every profession and trade needs The most significant.
Summary of the invention
It is an object of the present invention to provide a kind of plastic cement alloy composite.
For reaching above-mentioned purpose, the technical solution used in the present invention is: a kind of plastic cement alloy composite, described plastic cement alloy The composition of raw materials of compositions includes the material of following masses percentage:
High density polyethylene (HDPE) 10 ~ 68%；
Polypropylene 10 ~ 68%；
Triallyl isocyanurate 1 ~ 13%；
Polysulfones 5 ~ 28%；
Ethylene-vinyl acetate 10 ~ 25%；
Ethylene propylene diene rubber 8 ~ 20%；
Ethylene bis stearamide 0.5 ~ 2.5%；
Masterbatch 10 ~ 25%.
Preferably technical scheme is: described Masterbatch by black wood charcoal black or/and white carbon mix with pigment after form.
Owing to technique scheme is used, the present invention compared with prior art has following advantages and an effect:
1, the siphonal ring stiffness that the present invention prepares is 7 ~ 8, and shore hardness D is 77 ~ 80, and elongation at break is 100 ~ 500%, Relaxation shrinkage is 0.5 ~ 1%.
2, the operating temperature of the present invention reach 150 DEG C and more than, and strong alkali-acid resistance.
3, impact resistance of the present invention and anti-negative pressure excellent.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described:
Embodiment one: plastic cement alloy composite
A kind of plastic cement alloy composite, the composition of raw materials of described plastic cement alloy composite includes the material of following masses percentage Material:
High density polyethylene (HDPE) 60%；
Polypropylene 10%；
Triallyl isocyanurate 1%；
Polysulfones 5%；
Ethylene-vinyl acetate 10%；
Masterbatch 14%.
Masterbatch is the black mixture being mixed to get with black pigment of black wood charcoal.
Using this plastic cement alloy composite to prepare anti-negative-pressure siphon pipe, after testing, its technical specification is: ring stiffness (8.0) Reach SR5 and above, longitudinal welds: 0.5 ~ 1%, oxidation induction time is more than or equal to 30 minutes, elongation at break: 400%, Negative pressure is tested :-0.0946MPa, at a temperature of 23 degree, and 5 mitron materials changes in a hour are less than 10%.This stage and external SDR26 Siphon tubing is compared, and not only meets international standard IS08770:2003, Australia standard AS/NZS4401:2006 and AS/ NZS5065:2005, and have the most external standard used of a lot of key index.Tubing flexibility controls within 0.5. Testing through combustion toxicity index, test by standard GJB1916 regulation, siphon tubing is the tubing of environmental protection.
Embodiment two: plastic cement alloy composite
High density polyethylene (HDPE) 20%；
Polypropylene 55%；
Triallyl isocyanurate 1%；
Polysulfones 5%；
Ethylene propylene diene rubber 8%；
Ethylene bis stearamide 1%；
Masterbatch 10%.
Use this plastic cement alloy composite to prepare bumper, by Qingtao Chemical Engineering College's Testing index be: fat melting: 0.2284, hot strength: 25.21, elongation at break: 126%, Shao D:77, longitudinal contraction rate: 1.5%(contrast with mould), laterally Shrinkage factor: be not changed in (contrasting with mould), bending strength: 12.45, the modulus of elasticity in static bending: 520.And the conjunction of Longshan, Jiangyin City One-tenth Materials Co., Ltd by Europe iso standard detection data is: hot strength: 25.36MPa, elongation at break: 197%, bending Intensity: 17.59MPa, bending modulus: 429.77MPa, cantilever beam impact strength (breach): 20.76KJ/m2, Chalpy impact Intensity (non-notch): 55.72 KJ/m2, heat distortion temperature (1.82MPa): 41.1, melt flow rate (MFR) (190 degree/12160g): 1.32g/10min。
As can be seen from the above data, bumper product and reaches high level (this on relaxation shrinkage in intensity especially Injecting products is even more important by point), can be equally matched with external product in product quality, 12 pounds used for injection product can be accomplished Hammer is rotten.Further, this formula can need according to client and different product demand is prepared plastic formula and produced Cheap and good-quality bumper and Related product.
Embodiment three: plastic cement alloy composite
High density polyethylene (HDPE) 10%；
Polypropylene 56%；
Triallyl isocyanurate 1%；
Polysulfones 5%；
Ethylene-vinyl acetate 15%；
Ethylene bis stearamide 1%；
Masterbatch 12%.
Described Masterbatch is white carbon and white pigment mixture.
Use this plastic cement alloy composite to prepare high-temperature resistant optical fiber protection set, through Qingtao Chemical Engineering College's Testing index be: molten Fat: 0.523, hot strength: 28.21, elongation at break: 100%, Shao D:77, bending strength: 25.5, the modulus of elasticity in static bending: 2650, impact strength: 15.9.Pilot scale is high temperature resistant: 180 DEG C, 96 hours.
After the elastomers such as EVA, EPDM are blended with PP, the elastomer fine particle in material can absorb part buckles, and makees Concentrate agent induce and suppress crack growth for stress, make PP be changed into ductile fracture by brittle fracture so that it is impact strength is big Amplitude promotes, and is effectively improved the toughness of PP.PSF rigid polymer is blended with PP then can ensure the strong of material while toughness reinforcing Degree and rigidity, and thermostability.
Above-described embodiment, only for technology design and the feature of the explanation present invention, its object is to allow person skilled in the art Scholar will appreciate that present disclosure and implements according to this, can not limit the scope of the invention with this.All according to the present invention The equivalence that spirit is made changes or modifies, and all should contain within protection scope of the present invention.

Claims (2)

1. a plastic cement alloy composite, it is characterised in that: the composition of raw materials of described plastic cement alloy composite includes following masses The material of percentage:
High density polyethylene (HDPE) 10 ~ 68%；
Polypropylene 10 ~ 68%；
Triallyl isocyanurate 1 ~ 13%；
Polysulfones 5 ~ 28%；
Ethylene-vinyl acetate 10 ~ 25%；
Ethylene propylene diene rubber 8 ~ 20%；
Ethylene bis stearamide 0.5 ~ 2.5%；
Masterbatch 10 ~ 25%.
Plastic cement alloy composite the most according to claim 1, it is characterised in that: described Masterbatch is black or/and white by black wood charcoal White carbon black forms after mixing with pigment.
CN201610529554.XA 2016-07-07 2016-07-07 Plastic alloy composition Pending CN105924753A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201810459355.5A CN108485039B (en) 2016-07-07 2016-07-07 Plastic alloy composition and plastic alloy product
CN201610529554.XA CN105924753A (en) 2016-07-07 2016-07-07 Plastic alloy composition
JP2019521177A JP6871371B2 (en) 2016-07-07 2017-06-30 Plastic alloy compositions and plastic alloy products
AU2017294210A AU2017294210B2 (en) 2016-07-07 2017-06-30 Plastic alloy composition
PCT/CN2017/091216 WO2018006758A1 (en) 2016-07-07 2017-06-30 Plastic alloy composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610529554.XA CN105924753A (en) 2016-07-07 2016-07-07 Plastic alloy composition

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201810459355.5A Division CN108485039B (en) 2016-07-07 2016-07-07 Plastic alloy composition and plastic alloy product

Publications (1)

Publication Number Publication Date
CN105924753A true CN105924753A (en) 2016-09-07

Family

ID=56827645

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201810459355.5A Active CN108485039B (en) 2016-07-07 2016-07-07 Plastic alloy composition and plastic alloy product
CN201610529554.XA Pending CN105924753A (en) 2016-07-07 2016-07-07 Plastic alloy composition

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201810459355.5A Active CN108485039B (en) 2016-07-07 2016-07-07 Plastic alloy composition and plastic alloy product

Country Status (4)

Country Link
JP (1) JP6871371B2 (en)
CN (2) CN108485039B (en)
AU (1) AU2017294210B2 (en)
WO (1) WO2018006758A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018006758A1 (en) * 2016-07-07 2018-01-11 苏州虹吸塑胶制品有限公司 Plastic alloy composition
CN108219284A (en) * 2018-02-09 2018-06-29 苏州虹吸塑胶制品有限公司 Plastic alloy composition, vehicle structure reinforcing member and vehicle
CN108299733A (en) * 2018-02-09 2018-07-20 苏州虹吸塑胶制品有限公司 Plastic alloy composition, automotive interior part and vehicle
CN108329591A (en) * 2018-02-09 2018-07-27 苏州虹吸塑胶制品有限公司 Plastic alloy composition, vehicle structural members and vehicle
CN108329592A (en) * 2018-02-09 2018-07-27 苏州虹吸塑胶制品有限公司 Plastic alloy composition, body panels component and vehicle
CN114456488A (en) * 2022-01-19 2022-05-10 中北大学 Tear-resistant PBSeT/PP/HDPE composite material and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844043A (en) * 2010-05-25 2010-09-29 东华大学 Co-mixing film of ethylene-acetic acid ethylene copolymer and polysulfone and method for preparing same
CN103739946A (en) * 2013-12-07 2014-04-23 天津市华鑫达投资有限公司 High-impact high-stiffness polypropylene rotational molding material and preparation method thereof
CN104448513A (en) * 2014-10-28 2015-03-25 中国石油天然气集团公司 Low-temperature resistant toughening modifier, outer protective material, thermal insulation pipe and preparation method

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101127435B1 (en) * 2009-08-03 2012-03-23 이창호 The tpe composites
EP2612889A4 (en) * 2010-09-03 2014-01-08 Sekisui Chemical Co Ltd Resin composite material and method for producing resin composite material
KR101344726B1 (en) * 2011-10-25 2013-12-24 박종순 Method of high stregth and light weight polymer alloy with forming epoxy resin
CN103360670B (en) * 2013-06-03 2016-05-04 广东波斯科技股份有限公司 A kind of general high light black masterbatch
JP6126524B2 (en) * 2013-12-16 2017-05-10 旭化成株式会社 Organic-inorganic composite composition, molded body and sheet
CN103772820A (en) * 2014-01-21 2014-05-07 江苏力达塑料托盘制造有限公司 Antistatic polyolefin composite material tray and preparation method thereof
CN105602116A (en) * 2016-03-24 2016-05-25 叶青 PP plastic alloy
CN108485039B (en) * 2016-07-07 2021-02-05 苏州虹吸塑胶制品有限公司 Plastic alloy composition and plastic alloy product

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844043A (en) * 2010-05-25 2010-09-29 东华大学 Co-mixing film of ethylene-acetic acid ethylene copolymer and polysulfone and method for preparing same
CN103739946A (en) * 2013-12-07 2014-04-23 天津市华鑫达投资有限公司 High-impact high-stiffness polypropylene rotational molding material and preparation method thereof
CN104448513A (en) * 2014-10-28 2015-03-25 中国石油天然气集团公司 Low-temperature resistant toughening modifier, outer protective material, thermal insulation pipe and preparation method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018006758A1 (en) * 2016-07-07 2018-01-11 苏州虹吸塑胶制品有限公司 Plastic alloy composition
CN108219284A (en) * 2018-02-09 2018-06-29 苏州虹吸塑胶制品有限公司 Plastic alloy composition, vehicle structure reinforcing member and vehicle
CN108299733A (en) * 2018-02-09 2018-07-20 苏州虹吸塑胶制品有限公司 Plastic alloy composition, automotive interior part and vehicle
CN108329591A (en) * 2018-02-09 2018-07-27 苏州虹吸塑胶制品有限公司 Plastic alloy composition, vehicle structural members and vehicle
CN108329592A (en) * 2018-02-09 2018-07-27 苏州虹吸塑胶制品有限公司 Plastic alloy composition, body panels component and vehicle
CN114456488A (en) * 2022-01-19 2022-05-10 中北大学 Tear-resistant PBSeT/PP/HDPE composite material and preparation method thereof
CN114456488B (en) * 2022-01-19 2024-01-26 中北大学 Tear-resistant PBSeT/PP/HDPE composite material and preparation method thereof

Also Published As

Publication number Publication date
WO2018006758A1 (en) 2018-01-11
AU2017294210B2 (en) 2022-04-14
AU2017294210A1 (en) 2019-01-24
CN108485039B (en) 2021-02-05
JP2020500236A (en) 2020-01-09
CN108485039A (en) 2018-09-04
JP6871371B2 (en) 2021-05-12

Similar Documents

Publication Publication Date Title
CN105924753A (en) Plastic alloy composition
Ruksakulpiwat et al. Improvement of impact property of natural fiber–polypropylene composite by using natural rubber and EPDM rubber
WO2016065614A1 (en) Thermoplastic composite, method for preparing thermoplastic composite, and injection-molded product
AU2003283960A1 (en) Polyethylene compositions for injection molding
JP4818662B2 (en) Thermoplastic resin composition
CN107531964A (en) PP composite material
CN102352080A (en) Formula of high-impact-resistance PVC (polyvinyl chloride) pipe
CN103183958B (en) A kind of milled fiber reinforced nylon 6 plastics and preparation method thereof
CN104761794A (en) Gutta percha shape memory polymer composite material and preparation method thereof
CN109337192A (en) A kind of PP composite material and preparation method thereof
CN101225228A (en) Fiber glass, elastomer and inorganic nano-particle synergistic modified nylon and preparation thereof
CN104479194A (en) Wear-resistant PE (polyethylene) composition as well as preparation method and application thereof
CN105037922A (en) High-impact-resistant anti-aging automobile bumper
KR101476037B1 (en) Polypropylene resine composition
CN103937094B (en) A kind of resisting plays screw explosion Reinforced Polypropylene material, its preparation method and application thereof
CN107567374A (en) Method for preparing fiber-reinforced polymer composition
Awanis et al. Effect of coupling agent on mechanical properties of composite from microcrystalline cellulose and recycled polypropylene
Jonbi et al. Mechanical properties of polypropylene plastic waste usage and high-density polyethylene in concrete
CN105985567B (en) Continuous fiber enhancing prepreg tape polyolefin blends and preparation method thereof
CN105670126B (en) High-strength light-weight thin-walled injection moulding polypropene composition
CN105037921A (en) Anti-impact-resistant modified polypropylene bumper material
CN104817770A (en) Polypropylene modified composite material automobile bumper
CN104559112A (en) Production material of high insulating safety helmet and preparation method of production material
CN108192213B (en) Polypropylene composite material and preparation method thereof
CN109608761A (en) High elongation rate, low temperature resistant PP building template PP Pipe Compound and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160907

WD01 Invention patent application deemed withdrawn after publication