CN105924134B - There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface - Google Patents
There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface Download PDFInfo
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- CN105924134B CN105924134B CN201610261367.8A CN201610261367A CN105924134B CN 105924134 B CN105924134 B CN 105924134B CN 201610261367 A CN201610261367 A CN 201610261367A CN 105924134 B CN105924134 B CN 105924134B
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- C04B33/00—Clay-wares
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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Abstract
There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface of the present invention, on the basis of great change is not made to the production technology of existing glazed tile, emphasis is to the formula composition of biscuit body, bottom, the formula composition of overglaze frit, bottom, the formula composition of overglaze, the frit composition of pearly-lustre screen printing glaze, the formula composition of pearly-lustre screen printing glaze, the formula composition of refractive body grain slurry, the adjustment and optimization of glazing parameter and printing technology, so that nick convex is presented in glazed tile product surface obtained, sidelight or under light-illuminating, glaze paint is sent as inlayed a grain tourmaline jewel flickers tempting radiance, and the pattern color at print pearly-lustre screen printing glaze can be with the difference of light angle, show different colors, such as seven color rainbows, seem bedecked with jewels, it is splendid, with unique dicoration and artistry；The technology possesses stronger universality simultaneously, is easy in industry promote.
Description
Technical field：
The present invention relates to the preparing technical fields of glazed tile, and referring in particular to a kind of surface has the resource of pearly-lustre and color changeable effect
Economizing type glazed tile and preparation method thereof.
Background technology：
Tourmaline stone is also tourmaline, this jewel for ensconcing rainbow temporary lodging, is transcribed as " rainbow for falling into the human world ", always
As happiness and the symbol of wealth, chased by people, and for making precious jewellery, ornament, art work etc., it is expensive,
Therefore as can developing this decoration art that will inlay tourmaline jewel in the Wall or floor tile technology of mass automatic production
Product effect is replicated on ceramic wall and floor bricks product, is made this art treasures to something can only be found by accident, and not through seeking, is passed through the paving of common Wall or floor tile
Patch, is implemented in the interior decoration of average family, so that take on an entirely new look at home, it is splendid, it will necessarily be in ceramic decoration skill
Apparent technological innovation is generated in art, leads the new development of ceramic decoration technology, there is considerable economic benefit.
The content of the invention：
It is an object of the invention to overcome disadvantages mentioned above, providing a kind of surface has the resource-conserving of pearly-lustre and color changeable effect
Glazed tile and preparation method thereof, on the basis of great change is not made to existing glazed tile production technology, by biscuit body
Formula composition, bottom, the formula composition of overglaze frit, bottom, the formula composition of overglaze, pearly-lustre screen printing glaze frit composition, pearly-lustre
The adjustment and optimization of formula composition, printing technology and glazing parameter that the formula composition of screen printing glaze, refractive body grain are starched, so that system
The glazed tile product surface obtained has finger at the print pearly-lustre screen printing glaze of the resource-conserving glazed tile surface of pearly-lustre and color changeable effect to touch
It touches in dimpling shape, is sent under sidelight or light-illuminating as having inlayed a grain tourmaline jewel and flicker tempting radiance, and
Different colors, such as seven color rainbows can be occurred with the variation of light angle by printing the pattern color at pearly-lustre screen printing glaze, be had only
The defects of special dicoration and artistry, and product glaze quality is good, resistant is strong, pin-free, glaze bubble；Simultaneously the technology possess compared with
Strong universality is easy in industry promote.
To solve the above problems, the invention is realized by the following technical scheme：
There is the resource-conserving glazed tile of pearly-lustre and color changeable effect on the surface of the present invention, including：
Biscuit body：It is prepared by following parts by weight component：
28~38 parts of the mixed sand of potassium feldspar and albite and quartz, 15~25 parts of clay, 5~13 parts of limestone particle, silicon
Grey 2~6 parts of stone grain, ceramic polished 15~25 parts of waste residue, 10~20 parts of glazed tile waste residue, additional 1~2 part of waterglass, trimerization phosphorus
Sour 0.1~0.3 part of sodium, 0.4~0.6 part of metasilicate pentahydrate sodium, 50~55 parts of water；
Ceramic polished waste residue therein is the press filtration of the various waste water generated in ceramic polished brick production process after processing
Body refuse；
Glazed tile waste residue therein is the press filtration body refuse of the various waste water generated in glazed tile production process after processing；
Ground-coat enamel：It is prepared by following parts by weight component：
25~35 parts of frit a, 3~9 parts of zirconium silicate, 3~9 parts of feldspar powder, 15~25 parts of kaolin burn talcum 20~30
Part, 3~9 parts of alumina powder, 3~9 parts of silica flour, additional 0.06~0.12 part of carboxymethyl cellulose, sodium tripolyphosphate 0.4~
0.8 part, 37~45 parts of water, the glaze volume of ground-coat enamel is 0.6~0.9 ㎏/㎡, and the glaze volume is aqueous glaze slip weight；
Overglaze：It is prepared by following parts by weight component：
45~65 parts of frit a, 2~10 parts of zirconium silicate, 20~34 parts of kaolin, 2~10 parts of feldspar powder, calcined alumina
2~8 parts of powder, 2~6 parts of talcum of burning, additional 0.06~0.1 part of carboxymethyl cellulose, 0.4~0.8 part of sodium tripolyphosphate, water 37~
45 parts, the glaze volume of overglaze is 0.65~0.95 ㎏/㎡, and the glaze volume is aqueous glaze slip weight；
Frit a wherein in ground-coat enamel and overglaze is prepared by following parts by weight component：
24~34 parts of feldspar powder, 8~18 parts of calcium carbonate, 4~12 parts of glass dust, 3~11 parts of zirconium English powder, lithium porcelain stone powder 8~
18 parts, 2~6 parts of talcum powder, 1~5 part of potassium carbonate, 1~5 part of borax, 17~27 parts of silica flour；
Pearly-lustre screen printing glaze：It is prepared by following parts by weight component：
94~98 parts of frit b, 1~3 part of zinc oxide, 1~3 part of titanium dioxide, ceramic 80~180 parts of glue roller squeegee oil, pearly-lustre print
The thickness of brushing glazing printed patterns is 0.6~0.9 ㎜；
Wherein frit b is prepared by following parts by weight component：
25~35 parts of feldspar powder, 17~23 parts of calcium carbonate, 2~6 parts of boric acid, 10~16 parts of zinc oxide, alumina powder 1~3
Part, 1~3 part of zirconium silicate, 1~3 part of strontium carbonate, 1~4 part of potassium carbonate, 0.5~1.5 part of lanthana, 29~39 parts of silica flour；
Refractive body grain is starched：It is prepared by following parts by weight component：
35~45 parts of frit c grains, ceramic 100 parts of glue roller squeegee oil, refractive body grain slurry sizing amount is 0.18~0.24 ㎏/㎡,
The sizing amount is wet pulp weight；
Wherein frit c are prepared by following parts by weight component：
16~22 parts of feldspar powder, 10~16 parts of calcium carbonate, 4~8 parts of boric acid, 3~7 parts of talcum powder, 8~14 parts of zirconium English powder,
2~6 parts of spodumene powder, 4~8 parts of zinc oxide, 0.5~3.5 part of strontium carbonate, 0.5~3.5 part of cerium oxide, potassium carbonate 0.5~2.5
Part, 0.5~2.5 part of sodium carbonate, 30~40 parts of silica flour.
There is the preparation method of the resource-conserving glazed tile of pearly-lustre and color changeable effect the invention further relates to a kind of surface, wrap
Include following steps：
A, the preparation of biscuit body, prepares by weight：
By 28~38 parts of the mixed sand of potassium feldspar and albite and quartz, 15~25 parts of clay, 5~13 parts of limestone particle,
2~6 parts of silicon ash stone grain, ceramic polished 15~25 parts of waste residue, 10~20 parts of glazed tile waste residue, additional 1~2 part of waterglass, trimerization
0.1~0.3 part of sodium phosphate, 0.4~0.6 part of metasilicate pentahydrate sodium, 50~55 parts of water are mixed together and wear into fineness as 250 mesh sieves
Tail over as the slurry of mass percent 2%~5%, be made through removing iron sieving spray drying containing mass percent 6.5%~
The powder of 7.5% moisture, in 300~400 kilograms per centimeters2With automatic hydraulic press compression moulding, dry kiln drying under pressure limit
Dry, roller kiln burning is 1075 DEG C~1140 DEG C into, maximum sintering temperature scope, and firing time 40~70 minutes is to get biscuit body；
Ceramic polished waste residue therein is the press filtration of the various waste water generated in ceramic polished brick production process after processing
Body refuse；
Glazed tile waste residue therein is the press filtration body refuse of the various waste water generated in glazed tile production process after processing；
B, the preparation of ground-coat enamel, prepares by weight：
By 25~35 parts of frit a, 3~9 parts of zirconium silicate, 3~9 parts of feldspar powder, 15~25 parts of kaolin, burn talcum 20~
30 parts, 3~9 parts of alumina powder, 3~9 parts of silica flour, additional 0.06~0.12 part of carboxymethyl cellulose, sodium tripolyphosphate 0.4~
0.8 part, 37~45 parts of water, it is that 325 mesh sieves tail over as the glaze of mass percent 0.2%~0.4% to be mixed together and wear into fineness
Slurry is stored by screening out iron up to ground-coat enamel；
C, the preparation of overglaze, prepares by weight：
By 45~65 parts of frit a, 2~10 parts of zirconium silicate, 20~34 parts of kaolin, 2~10 parts of feldspar powder, calcined oxide
2~8 parts of aluminium powder burns 2~6 parts of talcum, additional 0.06~0.1 part of carboxymethyl cellulose, 0.4~0.8 part of sodium tripolyphosphate, water 37
~45 parts, it is that 325 mesh sieves tail over as the glaze slip of mass percent 0.2%~0.4% to be mixed together and wear into fineness, by screening out
Iron is stored up to overglaze；
Frit a wherein in ground-coat enamel and overglaze is prepared by following parts by weight component：
24~34 parts of feldspar powder, 8~18 parts of calcium carbonate, 4~12 parts of glass dust, 3~11 parts of zirconium English powder, lithium porcelain stone powder 8~
18 parts, 2~6 parts of talcum powder, 1~5 part of potassium carbonate, 1~5 part of borax, 17~27 parts of silica flour, the granularity of all components is respectively less than
180 mesh；All components are put into togerther mixer to mix, frit tank furnace is melted, 1500 DEG C~1540 DEG C of glass melting temperature scope, so
Water quenching is into frit granules, drying frit a afterwards；
D, the preparation of pearly-lustre screen printing glaze, prepares by weight：
By 94~98 parts of frit b, 1~3 part of zinc oxide, 1~3 part of titanium dioxide, ceramic 80~180 parts of mixing of glue roller squeegee oil
It is that 325 mesh sieves are tailed over as the glaze slip of mass percent 0.02%~0.06% to wear into fineness, is stored up to pearl by screening out iron
Light screen printing glaze；
Wherein frit b is prepared by following parts by weight component：
25~35 parts of feldspar powder, 17~23 parts of calcium carbonate, 2~6 parts of boric acid, 10~16 parts of zinc oxide, alumina powder 1~3
Part, 1~3 part of zirconium silicate, 1~3 part of strontium carbonate, 1~4 part of potassium carbonate, 0.5~1.5 part of lanthana, 29~39 parts of silica flour, institute
The granularity for having component is respectively less than 180 mesh；All components are put into togerther mixer to mix, frit tank furnace is melted, glass melting temperature model
1500 DEG C~1540 DEG C are enclosed, then water quenching is into frit granules, drying frit b；
E, the preparation of refractive body grain slurry, prepares by weight：
By 35~45 parts of frit c grains, ceramic 100 parts of glue roller squeegee oil is mixed evenly to be starched up to refractive body grain；
Wherein frit c are prepared by following parts by weight component：
16~22 parts of feldspar powder, 10~16 parts of calcium carbonate, 4~8 parts of boric acid, 3~7 parts of talcum powder, 8~14 parts of zirconium English powder,
2~6 parts of spodumene powder, 4~8 parts of zinc oxide, 0.5~3.5 part of strontium carbonate, 0.5~3.5 part of cerium oxide, potassium carbonate 0.5~2.5
Part, 0.5~2.5 part of sodium carbonate, 30~40 parts of silica flour, the granularity of all components are respectively less than 180 mesh；All components are put together
Enter mixer mixing, frit tank furnace is melted, 1500 DEG C~1540 DEG C of glass melting temperature scope, and then water quenching is dried into frit granules
It is the thin frit grain of purpose of 70 mesh~180 up to frit c to be broken into granularity again；
F, the preparation of product and burn till：
The biscuit body that step A is obtained first applies the ground-coat enamel that step B is obtained, and the glaze volume of ground-coat enamel is 0.6~0.9 ㎏/㎡,
The glaze volume is aqueous glaze slip weight；Then the overglaze that step C is obtained is applied, the glaze volume of overglaze is 0.65~0.95 ㎏/㎡,
The glaze volume is aqueous glaze slip weight；Further according to the pearl for needing to be obtained with silk-screen plate or offset printing roll marks step D of design
Light screen printing glaze, the thickness of printing pearly-lustre screen printing glaze pattern is 0.6~0.9 ㎜；It is carried out again with ink-jet decorating machine ink-jet printed；It applies again
The refractive body grain slurry that step E is obtained, the sizing amount of refractive body grain slurry is 0.18~0.24 ㎏/㎡, and the sizing amount is wet pulp
Weight, drying device are dried or after water mark is can't see on surface just into roller kiln burning into maximum sintering temperature scope is 1090 DEG C
~1130 DEG C, firing time is 45~65 minutes, by edging, classification process, is eventually fabricated finished product.
There are resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof, the glaze paint of manufacture in the surface of the present invention
For brick product under sidelight or light-illuminating, surface is sent as having inlayed a grain tourmaline jewel flickers tempting radiance, and
These different color such as seven color rainbows can occur as having inlayed the pattern color at tourmaline jewel with the variation of light angle,
Seem bedecked with jewels, splendid, there is unique dicoration and artistry, while the technology possesses stronger universality, easily
It is promoted in industry.
There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on the surface of the present invention：
By the optimization to biscuit body formula composition, substantial amounts of ceramic polished waste residue and glaze are mixed in plain body recipe
Face brick waste residue, these waste residues of one side not only greatly reduce production cost, have also achieved the purpose that energy-saving and emission-reduction；The opposing party
Face adds the biscuit body of these waste residues manufacture, is largely studied through applicant and show it in high-temperature burning process due to these
The discharge of a large amount of gases, substantial amounts of open pore is formed in plain billet surface in waste residue (especially ceramic polished waste residue), these
Open pore is the uniform excellent guarantee of biscuit body water absorption rate, surface gas permeability and hydrophobicity, is ensured that in printed patterns
When thickness is up to the pearly-lustre screen printing glaze of 0.6~0.9 ㎜ and applies refractive body grain slurry, the liquid in pearly-lustre screen printing glaze and refractive body grain slurry
Medium rapid osmotic into overglaze, can be such that the pattern of printing quickly solidifies in a short time, and ensure original state in a short time
It is not destroyed, refractive body grain is adhere strongly on overglaze, without being blown off or the smoking wind of kiln by kiln hood drifting dust wind turbine
Machine is taken away；Simultaneously when burning till, these stomatas are the optimal channel of gas discharge again, will not be because of medium oil Jie of ceramic glue roller squeegee oil
Quality excessively makes product gas discharge in high temperature difficult, so that product pin hole, glaze bubble, orange peel glaze occurs and quick-fried glaze etc. even occurs
Defect.The optimization of the formula composition of ground-coat enamel and overglaze frit, ground-coat enamel knead dough glaze formula composition, on the one hand ensures that ground-coat enamel and overglaze exist
Good air permeability in high temperature enables the gas that the ceramic waste residue in biscuit body discharges in high temperature to discharge in time, will not be because of gas
Body excessively discharges difficult and causes the destruction to biscuit body；On the other hand a firm entity can be formed with biscuit body again,
The flatness of product and thermal shock resistance will not be influenced because of the difference of the coefficient of expansion between three；Overglaze formula composition it is excellent
Change can also ensure that overglaze has suitable high temperature viscosity and melting behaviour in high temperature, so that it is guaranteed that being printed on the pearly-lustre on its face
Screen printing glaze and the refractive body grain applied on its face maintain the original state, the jewel such as inlayed and the effect for providing reflection source；Simultaneously also
It may insure that overglaze will not melt pearly-lustre screen printing glaze and refractive body grain in high temperature because high temperature viscosity is too low, melt capacity is too strong
Enter wherein, so as to lose the effect that tourmaline jewel flickers tempting radiance and refractive body loses reflection light；Such as high temperature viscosity mistake
Height, melt capacity is too low, then the combination of pearly-lustre screen printing glaze and refractive body grain and overglaze is bad, is also easy to produce soil pick-up, rough surface etc.
Defect；On the one hand the optimization of pearly-lustre screen printing glaze frit formula composition and the formula composition of pearly-lustre screen printing glaze ensures that pearly-lustre prints
Glaze has suitable surface tension in high temperature, will not penetrate into overglaze, so as to ensure the convex jewel that for example a grain is inlayed；
On the other hand, the high grade of transparency, high gloss and the high index of refraction of pearly-lustre screen printing glaze are in turn ensured, so that ink jet printing is in its face
On pattern color with light to inject angle different and generate the effect of discoloration, therefore be with the addition of in right amount to table in formula composition
Zinc oxide that face tension, transparency and glossiness play regulatory role, titanium dioxide, boric acid, zirconium silicate, strontium carbonate raw material, so that
After pearly-lustre printing glaze firing into microprotrusion highly transparent glaze, due to being with the addition of in right amount containing La2O3And TiO2The material of high refractive index
Material, along with refractive body forms the reflection collective effect to light, therefore when light is irradiated to different angle on product surface
When, the highly transparent glaze drop of these microprotrusions forms the double action of reflection and refraction to light, forms a kind of approximate rainbow
The phenomenon that, along with pattern color is to the interference effect of human eye, a kind of pattern color of self-assembling formation so that human eye viewing is got up
The discoloration special-effect generated as the angle of light is different.The optimization of refractive body grain frit and refractive body grain slurry formula composition,
It is ensure that with suitable melting behaviour and certain stability, otherwise can be not suitable for incorporating because of its melting behaviour in overglaze from
And lose the reflex to light；Or because it is Nian Jie with overglaze bad, cracking and rough surface are also easy to produce, generates soil pick-up；Apply bottom
Glaze, overglaze, refractive body grain slurry and the glazing process parameter of pearly-lustre screen printing glaze and technique adjustment and the optimization of stamp, it is ensured that print
The globality of floral pattern, and will not be unfavorable to the reflection of light and refraction effect generation to refractive body grain slurry, pearly-lustre screen printing glaze
It influences；Biscuit body, bottom, overglaze, the suitable coefficient of expansion of refractive body grain slurry are in turn ensured simultaneously, ensure that the flatness of product.
The surface of the present invention has resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof to have the following advantages：
1st, due to optimize the formula composition of biscuit body, bottom, the formula composition of overglaze frit, bottom, overglaze formula composition,
Pearly-lustre screen printing glaze frit composition, the formula composition of pearly-lustre screen printing glaze, refractive body grain frit composition, the formula composition of refractive body grain slurry
And apply the adjustment and optimization of bottom, overglaze, refractive body grain slurry, the glazing process parameter of print pearly-lustre screen printing glaze and printing technology etc., from
And make the product of manufacture under light-illuminating or sidelight, flicker tempting light just as having inlayed a grain such as tourmaline jewel and having sent
Awns.And the seven color colors such as rainbow can occur with the variation of light angle in the pattern color at print pearly-lustre screen printing glaze, have
Unique dicoration and artistry.
2nd, the product surface flatness, the modulus of rupture, flexural strength, resistance to acid and alkali, thermal shock resistance, radioactivity, lead cadmium are molten
Output reaches the requirement of GB/T4100-2015, GB6566-2011 and HJ/T297-2006 standard.
3rd, larger amount of ceramic polished waste residue and glazed tile waste residue have been used in plain body recipe so that be produced into reduction
This while, has saved resource again, has achieved the purpose that energy-saving and emission-reduction, and has used existing glazed tile production technology, it is easy to accomplish
Industrialized scale.
Description of the drawings：
Fig. 1 is the process flow chart for preparing the resource-conserving glazed tile that there are pearly-lustre and color changeable effect in surface of the invention.
Specific embodiment：
The present invention is described in further detail with reference to embodiment.
Example 1
There is the preparation method of the resource-conserving glazed tile of pearly-lustre and color changeable effect on a kind of surface, comprises the following steps：
A, biscuit body is prepared：
The formula constituent of biscuit body see the table below 1：
The composition table (parts by weight) of table 1, biscuit body
The mixed sand of potassium feldspar and albite and quartz, clay, lime stone are weighed respectively by 1 biscuit body composition of table
Grain, silicon ash stone grain, ceramic polished waste residue, glazed tile waste residue, additional 1~2 part of waterglass, 0.1~0.3 part of tripolyphosphate
Sodium, 0.4~0.6 part of metasilicate pentahydrate sodium, 50~55 parts of water enter ball mill tailing over as quality hundred to 250 mesh sieves fine crushing
Divide the slurry than 2%~5%, the powder of 6.5%~7.5% moisture of mass percent is made through removing iron sieving spray drying,
300~400 kilograms per centimeters2It is dried under pressure limit with automatic hydraulic press compression moulding, dry kiln, roller kiln burning is into most high fever
It it is 1075 DEG C~1140 DEG C into temperature range, firing time 40~70 minutes is to get biscuit body；The ceramic polished waste residue is
The press filtration body refuse of the various waste water generated in ceramic polished brick production process after processing；Glazed tile waste residue produced for glazed tile
The various waste water generated in journey press filtration body refuse after processing.
B, ground-coat enamel is prepared：
Frit a is prepared, the formula composition composition of frit a is shown in Table 2：
The composition table (parts by weight) of table 2, frit a
The above-mentioned raw materials that granularity is less than to 180 mesh carry out dispensing by 2 parts by weight of table, are uniformly mixed, and are melted in Cinker clew furnace,
1500 DEG C~1540 DEG C of glass melting temperature scope, water quenching is into frit granules, drying frit a；
Ground-coat enamel is prepared, the formula composition composition of ground-coat enamel is shown in Table 3：
Table 3, ground-coat enamel formula composition table (parts by weight)
| Component | Frit a | Zirconium silicate | Feldspar powder | Kaolin | Burn talcum | Alumina powder | Silica flour |
| 1# | 25 | 9 | 9 | 20 | 28 | 3 | 6 |
| 2# | 30 | 6 | 6 | 25 | 21 | 9 | 3 |
| 3# | 35 | 3 | 3 | 15 | 29 | 6 | 9 |
| 4# | 29 | 5 | 7 | 18 | 30 | 4 | 7 |
| 5# | 33 | 8 | 5 | 23 | 20 | 7 | 4 |
| 6# | 31 | 7 | 4 | 22 | 25 | 5 | 6 |
Frit a, zirconium silicate, feldspar powder, kaolin, burning according to made from the ground-coat enamel formula composition of table 3 weighs above-mentioned steps B
Talcum, alumina powder, silica flour, additional 0.06~0.12 part of carboxymethyl cellulose, 0.4~0.8 part of sodium tripolyphosphate, 37
~45 parts of water enters ball mill ball milling together, and it is that 325 mesh sieves tail over as mass percent 0.2%~0.4% to wear into fineness
Glaze slip is stored by screening out iron up to ground-coat enamel.
C, overglaze is prepared：
The formula composition of overglaze such as the following table 4：
Table 4, overglaze formula composition table (parts by weight)
The frit a identical with ground-coat enamel according to made of the formula composition of the overglaze of table 4 weighs above-mentioned steps B, zirconium silicate, height
Ridge soil, feldspar powder, calcined oxide aluminium powder, burning talcum, additional 0.06~0.1 part of carboxymethyl cellulose, the three of 0.4~0.8 part
Polyphosphate sodium, 37~45 parts of water enters ball mill ball milling together, and it is that 325 mesh sieves are tailed over as mass percent to wear into fineness
0.2%~0.4% glaze slip is stored by screening out iron up to overglaze.
D, pearly-lustre screen printing glaze is prepared：
Prepare frit b, formula composition composition such as the following table 5 of frit b：
The formula composition table (parts by weight) of table 5, frit b
The above-mentioned raw materials that granularity is less than to 180 mesh carry out dispensing by 5 parts by weight of table, are uniformly mixed and are melted in Cinker clew furnace,
1500 DEG C~1540 DEG C of melted temperature range, water quenching is into frit granules, drying frit b；
Pearly-lustre screen printing glaze is prepared, the formula composition composition of pearly-lustre screen printing glaze see the table below 6：
The formula composition table (parts by weight) of table 6, pearly-lustre screen printing glaze
| Component | Frit b | Zinc oxide | Titanium dioxide | Ceramic glue roller squeegee oil |
| 1# | 94 | 3 | 3 | 80 |
| 2# | 98 | 1 | 1 | 180 |
| 3# | 96 | 2 | 2 | 130 |
Frit b, zinc oxide, titanium dioxide, ceramic glue roller squeegee oil are weighed according to the formula composition of 6 pearly-lustre screen printing glaze of table to mix together
It is that 325 mesh sieves tail over as the glaze slip of mass percent 0.02%~0.06% to close and wear into fineness, by screening out iron up to pearly-lustre
Screen printing glaze.
E, refractive body grain slurry is prepared：
Frit c is prepared, the formula composition composition of frit c see the table below 7：
C table 7, frit formula composition tables (parts by weight)
The above-mentioned raw materials that granularity is less than to 180 mesh carry out dispensing by 7 parts by weight of table, are uniformly mixed and are melted in Cinker clew furnace,
1500 DEG C~1540 DEG C of melted temperature range, then water quenching is into frit granules, and drying is broken into granularity as the mesh of 70 mesh~180 again
Thin frit grain up to frit c；
Prepare refractive body grain slurry, formula composition such as the following table 8 of refractive body grain slurry：
The formula composition table (parts by weight) of table 8, refractive body grain slurry
| Component | Frit c | Ceramic glue roller squeegee oil |
| 1# | 35 | 100 |
| 2# | 40 | 100 |
| 3# | 45 | 100 |
Frit c is weighed according to the formula composition that 8 refractive body grain of table is starched, ceramic glue roller squeegee oil, which is mixed together, to stir evenly i.e.
Obtain refractive body grain slurry.
F, the preparation of product and burn till：
The biscuit body that step A is obtained first applies the ground-coat enamel that step B is obtained, and the glaze volume of ground-coat enamel is 0.6~0.9 ㎏/㎡,
The glaze volume is aqueous glaze slip weight；Then the overglaze that step C is obtained is applied, the glaze volume of overglaze is 0.65~0.95 ㎏/㎡,
The glaze volume is aqueous glaze slip weight；Further according to the pearly-lustre for needing to be obtained with silk screen or offset printing roll marks step D of design
Screen printing glaze, the thickness of printing pearly-lustre screen printing glaze pattern is 0.6~0.9 ㎜；It is carried out again with ink-jet decorating machine ink-jet printed；Step is applied again
The refractive body grain slurry that rapid E is obtained, the sizing amount of refractive body grain slurry is 0.18~0.24 ㎏/㎡, and the sizing amount is wet pulp weight,
Drying device is dried or after water mark is can't see on surface just into roller kiln burning into maximum sintering temperature is 1090 DEG C~1130
DEG C, firing time is 45~65 minutes, by edging, classification process, is eventually fabricated finished product.
There are the resource-conserving glaze paint brick product of pearly-lustre and color changeable effect, surface in the surface being prepared using the above method
With pico- concave-convex sense, under sidelight or light-illuminating, it is tempting that surface sends flicker as having inlayed a grain tourmaline jewel
Radiance, and these different colors can occur as having inlayed pattern color at tourmaline jewel with the variation of light angle,
Such as seven color rainbows, it appears it is bedecked with jewels, splendid, there is unique dicoration and artistry, and glaze quality is good, resistance to soiling
By force, the defects of surface is pin-free, glaze steeps breaches the deficiency of the single glaze decorating of existing glazed tile.
Product leading indicator such as the following table 9 after testing：
Table 9：Product quality inspection result
In conclusion only presently preferred embodiments of the present invention, not makees the present invention limitation in any form；It is all
The those of ordinary skill of the industry can swimmingly implement the present invention by described above；But all it is familiar with this professional technology people
Member without departing from the scope of the present invention, repair by a little change for being made using disclosed above technology contents
Decorations and the equivalent variations developed are the equivalent embodiment of the present invention；Meanwhile all substantial technologicals according to the invention are to above real
Apply change, modification and the differentiation for any equivalent variations that example is made, still fall within technical scheme protection domain it
It is interior.
Claims (2)
1. there is the resource-conserving glazed tile of pearly-lustre and color changeable effect on surface, it is characterised in that：
Biscuit body：It is prepared by following parts by weight component：
28~38 parts of the mixed sand of potassium feldspar and albite and quartz, 15~25 parts of clay, 5~13 parts of limestone particle, wollastonite
2~6 parts of grain, ceramic polished 15~25 parts of waste residue, 10~20 parts of glazed tile waste residue, additional 1~2 part of waterglass, sodium tripolyphosphate
0.1~0.3 part, 0.4~0.6 part of metasilicate pentahydrate sodium, 50~55 parts of water；
Ceramic polished waste residue therein is the press filtration body refuse of the various waste water generated in ceramic polished brick production process after processing；
Glazed tile waste residue therein is the press filtration body refuse of the various waste water generated in glazed tile production process after processing；
Ground-coat enamel：It is prepared by following parts by weight component：
25~35 parts of frit a, 3~9 parts of zirconium silicate, 3~9 parts of feldspar powder, 15~25 parts of kaolin burn 20~30 parts of talcum, oxygen
3~9 parts of aluminium powder of change, 3~9 parts of silica flour, additional 0.06~0.12 part of carboxymethyl cellulose, 0.4~0.8 part of sodium tripolyphosphate,
37~45 parts of water, the glaze volume of ground-coat enamel is 0.6~0.9 ㎏/㎡, and the glaze volume is aqueous glaze slip weight；
Overglaze：It is prepared by following parts by weight component：
45~65 parts of frit a, 2~10 parts of zirconium silicate, 20~34 parts of kaolin, 2~10 parts of feldspar powder, calcined oxide aluminium powder 2~
8 parts, 2~6 parts of talcum of burning, additional 0.06~0.1 part of carboxymethyl cellulose, 0.4~0.8 part of sodium tripolyphosphate, 37~45 parts of water,
The glaze volume of overglaze is 0.65~0.95 ㎏/㎡, and the glaze volume is aqueous glaze slip weight；
Frit a wherein in ground-coat enamel and overglaze is prepared by following parts by weight component：
24~34 parts of feldspar powder, 8~18 parts of calcium carbonate, 4~12 parts of glass dust, 3~11 parts of zirconium English powder, 8~18 parts of lithium porcelain stone powder,
2~6 parts of talcum powder, 1~5 part of potassium carbonate, 1~5 part of borax, 17~27 parts of silica flour；
Pearly-lustre screen printing glaze：It is prepared by following parts by weight component：
94~98 parts of frit b, 1~3 part of zinc oxide, 1~3 part of titanium dioxide, ceramic 80~180 parts of glue roller squeegee oil, pearly-lustre screen printing glaze
The thickness of printed patterns is 0.6~0.9 ㎜；
Wherein frit b is prepared by following parts by weight component：
25~35 parts of feldspar powder, 17~23 parts of calcium carbonate, 2~6 parts of boric acid, 10~16 parts of zinc oxide, 1~3 part of alumina powder, silicon
Sour 1~3 part of zirconium, 1~3 part of strontium carbonate, 1~4 part of potassium carbonate, 0.5~1.5 part of lanthana, 29~39 parts of silica flour；
Refractive body grain is starched：It is prepared by following parts by weight component：
35~45 parts of frit c grains, ceramic 100 parts of glue roller squeegee oil, refractive body grain slurry sizing amount is 0.18~0.24 ㎏/㎡, described
Sizing amount be wet pulp weight；
Wherein frit c are prepared by following parts by weight component：
16~22 parts of feldspar powder, 10~16 parts of calcium carbonate, 4~8 parts of boric acid, 3~7 parts of talcum powder, 8~14 parts of zirconium English powder, lithium brightness
2~6 parts of mountain flour, 4~8 parts of zinc oxide, 0.5~3.5 part of strontium carbonate, 0.5~3.5 part of cerium oxide, 0.5~2.5 part of potassium carbonate, carbon
Sour 0.5~2.5 part of sodium, 30~40 parts of silica flour；
The biscuit body that will be obtained, the ground-coat enamel first applied, the overglaze then applied, further according to design need use silk screen
The pearly-lustre screen printing glaze that version or offset printing roll marks obtain carries out refractive body grain slurry that is ink-jet printed, then applying, warp with ink-jet decorating machine
Baker is dried or after water mark is can't see on surface just into roller kiln burning into maximum sintering temperature scope is 1090 DEG C~1130
DEG C, firing time is 45~65 minutes, by edging, classification process, is eventually fabricated finished product.
2. there is the preparation method of the resource-conserving glazed tile of pearly-lustre and color changeable effect on surface, it is characterised in that：
It comprises the following steps：
A, the preparation of biscuit body, prepares by weight：
By 28~38 parts of the mixed sand of potassium feldspar and albite and quartz, 15~25 parts of clay, 5~13 parts of limestone particle, silicon ash
2~6 parts of stone grain, ceramic polished 15~25 parts of waste residue, 10~20 parts of glazed tile waste residue, additional 1~2 part of waterglass, tripolyphosphate
0.1~0.3 part of sodium, 0.4~0.6 part of metasilicate pentahydrate sodium, 50~55 parts of water are mixed together the sieve for wearing into that fineness is 250 mesh sieves
The remaining slurry for mass percent 2%~5% is made through removing iron sieving spray drying containing 6.5%~7.5% water of mass percent
The powder divided, in 300~400 kilograms per centimeters2It is dried under pressure limit with automatic hydraulic press compression moulding, dry kiln, roller kilns
It burns till, maximum sintering temperature scope is 1075 DEG C~1140 DEG C, and firing time 40~70 minutes is to get biscuit body；
Ceramic polished waste residue therein is the press filtration body refuse of the various waste water generated in ceramic polished brick production process after processing；
Glazed tile waste residue therein is the press filtration body refuse of the various waste water generated in glazed tile production process after processing；
B, the preparation of ground-coat enamel, prepares by weight：
By 25~35 parts of frit a, 3~9 parts of zirconium silicate, 3~9 parts of feldspar powder, 15~25 parts of kaolin burns 20~30 parts of talcum,
3~9 parts of alumina powder, 3~9 parts of silica flour, additional 0.06~0.12 part of carboxymethyl cellulose, sodium tripolyphosphate 0.4~0.8
Part, 37~45 parts of water, it is that 325 mesh sieves tail over as the glaze slip of mass percent 0.2%~0.4% to be mixed together and wear into fineness,
It is stored by screening out iron up to ground-coat enamel；
C, the preparation of overglaze, prepares by weight：
By 45~65 parts of frit a, 2~10 parts of zirconium silicate, 20~34 parts of kaolin, 2~10 parts of feldspar powder, calcined oxide aluminium powder 2
~8 parts, burn 2~6 parts of talcum, additional 0.06~0.1 part of carboxymethyl cellulose, 0.4~0.8 part of sodium tripolyphosphate, water 37~45
Part, it is that 325 mesh sieves are tailed over as the glaze slip of mass percent 0.2%~0.4% to be mixed together and wear into fineness, by screening out iron storage
It deposits up to overglaze；
Frit a wherein in ground-coat enamel and overglaze is prepared by following parts by weight component：
24~34 parts of feldspar powder, 8~18 parts of calcium carbonate, 4~12 parts of glass dust, 3~11 parts of zirconium English powder, 8~18 parts of lithium porcelain stone powder,
2~6 parts of talcum powder, 1~5 part of potassium carbonate, 1~5 part of borax, 17~27 parts of silica flour, the granularity of all components is respectively less than 180
Mesh；All components are put into togerther mixer to mix, frit tank furnace is melted, 1500 DEG C~1540 DEG C of glass melting temperature scope, then
Water quenching is into frit granules, drying frit a；
D, the preparation of pearly-lustre screen printing glaze, prepares by weight：
By 94~98 parts of frit b, 1~3 part of zinc oxide, 1~3 part of titanium dioxide, ceramic 80~180 parts of mixing of glue roller squeegee oil wear into
Fineness is that 325 mesh sieves are tailed over as the glaze slip of mass percent 0.02%~0.06%, is printed up to pearly-lustre by screening out iron and storing
Brushing glazing；
Wherein frit b is prepared by following parts by weight component：
25~35 parts of feldspar powder, 17~23 parts of calcium carbonate, 2~6 parts of boric acid, 10~16 parts of zinc oxide, 1~3 part of alumina powder, silicon
Sour 1~3 part of zirconium, 1~3 part of strontium carbonate, 1~4 part of potassium carbonate, 0.5~1.5 part of lanthana, 29~39 parts of silica flour, all components
Granularity be respectively less than 180 mesh；All components are put into togerther mixer to mix, frit tank furnace is melted, glass melting temperature scope 1500
DEG C~1540 DEG C, then water quenching is into frit granules, drying frit b；
E, the preparation of refractive body grain slurry, prepares by weight：
By 35~45 parts of frit c grains, ceramic 100 parts of glue roller squeegee oil is mixed evenly to be starched up to refractive body grain；
Wherein frit c are prepared by following parts by weight component：
16~22 parts of feldspar powder, 10~16 parts of calcium carbonate, 4~8 parts of boric acid, 3~7 parts of talcum powder, 8~14 parts of zirconium English powder, lithium brightness
2~6 parts of mountain flour, 4~8 parts of zinc oxide, 0.5~3.5 part of strontium carbonate, 0.5~3.5 part of cerium oxide, 0.5~2.5 part of potassium carbonate, carbon
Sour 0.5~2.5 part of sodium, 30~40 parts of silica flour, the granularity of all components are respectively less than 180 mesh；All components are put into togerther mixed
Conjunction machine mixes, and frit tank furnace is melted, 1500 DEG C~1540 DEG C of glass melting temperature scope, and then water quenching is broken again into frit granules, drying
It is the thin frit grain of purpose of 70 mesh~180 up to frit c to be broken into granularity；
F, the preparation of product and burn till：
The biscuit body that step A is obtained, first applies the ground-coat enamel that step B is obtained, and the glaze volume of ground-coat enamel is 0.6~0.9 ㎏/㎡, described
Glaze volume be aqueous glaze slip weight；Then the overglaze that step C is obtained is applied, the glaze volume of overglaze is 0.65~0.95 ㎏/㎡, described
Glaze volume be aqueous glaze slip weight；It is printed further according to the pearly-lustre for needing to be obtained with silk-screen plate or offset printing roll marks step D of design
Brushing glazing, the thickness of printing pearly-lustre screen printing glaze pattern is 0.6~0.9 ㎜；It is carried out again with ink-jet decorating machine ink-jet printed；Step is applied again
The refractive body grain slurry that E is obtained, the sizing amount of refractive body grain slurry is 0.18~0.24 ㎏/㎡, and the sizing amount is wet pulp weight, is passed through
Baker is dried or after water mark is can't see on surface just into roller kiln burning into maximum sintering temperature scope is 1090 DEG C~1130
DEG C, firing time is 45~65 minutes, by edging, classification process, is eventually fabricated finished product.
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| CN201610261367.8A CN105924134B (en) | 2016-04-25 | 2016-04-25 | There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface |
| PCT/CN2016/000460 WO2017185195A1 (en) | 2016-04-25 | 2016-08-17 | Resource-saving glazed tile with pearlescent and colour-variable effect on surface and preparation method therefor |
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| CN201610261367.8A CN105924134B (en) | 2016-04-25 | 2016-04-25 | There is resource-conserving glazed tile of pearly-lustre and color changeable effect and preparation method thereof on surface |
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| CN106477885B (en) * | 2016-11-07 | 2019-05-31 | 广东易成陶瓷实业有限公司 | A kind of high hardness wear-resisting medium temperature semi-faience and preparation method thereof |
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| WO2017185195A1 (en) | 2017-11-02 |
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