CN108069709A - A kind of glaze for glazed tile based on artificial marble's stone material polishing slag and preparation method thereof - Google Patents
A kind of glaze for glazed tile based on artificial marble's stone material polishing slag and preparation method thereof Download PDFInfo
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- CN108069709A CN108069709A CN201711423183.8A CN201711423183A CN108069709A CN 108069709 A CN108069709 A CN 108069709A CN 201711423183 A CN201711423183 A CN 201711423183A CN 108069709 A CN108069709 A CN 108069709A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/636—Polysaccharides or derivatives thereof
- C04B35/6365—Cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
- C04B2235/3454—Calcium silicates, e.g. wollastonite
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/44—Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
- C04B2235/447—Phosphates or phosphites, e.g. orthophosphate, hypophosphite
Abstract
The invention discloses a kind of glaze for glazed tile based on artificial marble's stone material polishing slag, are prepared by following main component in percentage by weight：Artificial marble's stone material polishing useless 1 25%；Wollastonite 1 25%；Feldspar 50 70%；Black mud 15 25%.The raw material of the glaze for glazed tile includes artificial marble's stone material polishing slag, the long-term pollution that artificial marble's stone material polishing slag can be avoided to be brought by landfill disposal mode to environment completely；CaCO in artificial marble's stone material polishing slag is utilized simultaneously3The characteristics of content is high in glaze for glazed tile body recipe can substitute traditional lime stone, advantageously reduce the cost of formula, turn waste into wealth completely.The invention also discloses a kind of preparation methods of the glaze for glazed tile based on artificial marble's stone material polishing slag, and flow is simple, easy to operate, it can be achieved that commercially producing, and have application prospect well.
Description
Technical field
The present invention relates to ceramic tile production technical field more particularly to a kind of potteries based on artificial marble's stone material polishing slag
Glazed ceramic brick and preparation method thereof.
Background technology
Glaze for glazed tile is also usually referred to as ceramic inner wall brick, is pottery brick (water absorption rate>10%) one kind.Glazed tile is one
Kind mature production technology, production history are long, a wide range of ceramic brick product of material source.Most of manufacturers use secondary burning
Into technique, i.e., a biscuiting first is carried out to green body, then after the billet surface of biscuiting carries out the techniques such as glazing, stamp, then
It is once fired by glaze, finished product.Glazed tile is classified according to formula system, is generally divided into clay-long stone-type and clay-stone
Grey two kinds of stone-type.
On the other hand, artificial marble's stone material is a kind of new decorative material for building developed in recent years, it is with Dali
The powders such as stone, lime stone are primary raw material, and by adding made of a certain amount of unsaturated-resin class jointing material, it, which has, makes
Type beauty, natural in color, the advantages that machinability is strong, intensity is high, radiationless are the ideal materials for substituting lithotome.However
With the fast development of artificial marble's stone material, a large amount of artificial marble's stone material polishing slags are but difficult to handle, almost all of at present
Artificial marble's stone material enterprise is handled by the way of landfill.
But a considerable amount of trees are also contained in polishing slag as jointing material using resin due to artificial stone
Fat ingredient, resin is in the soil compared with difficult degradation, and therefore, the mode for filling polishing slag undoubtedly causes environment harm.For this purpose,
How to handle the polishing slag of artificial stone well, be not only artificial marble's stone material industry, also decorated including whole building material
Industry is all worth thinking and solves the problems, such as.
The content of the invention
For overcome the deficiencies in the prior art, thrown one of the objects of the present invention is to provide one kind based on artificial marble's stone material
The glaze for glazed tile of light waste residue, raw material include artificial marble's stone material polishing slag, can avoid artificial marble's stone material completely
The long-term pollution that polishing slag is brought by landfill disposal mode to environment；Simultaneously using in artificial marble's stone material polishing slag
CaCO3The characteristics of content is high in glaze for glazed tile body recipe can substitute traditional lime stone, advantageously reduce and match somebody with somebody completely
The cost of side, turns waste into wealth.
The second object of the present invention is to provide a kind of system of the glaze for glazed tile based on artificial marble's stone material polishing slag
Preparation Method, flow is simple, easy to operate, it can be achieved that commercially producing, and has application prospect well.
An object of the present invention adopts the following technical scheme that realization：
A kind of glaze for glazed tile based on artificial marble's stone material polishing slag, it is following main by percentage by weight
Ingredient is prepared：
Further, prepare raw material and further include auxiliary material, the auxiliary material includes methylcellulose, sodium tripolyphosphate and water；First
The dosage of base cellulose and sodium tripolyphosphate is the 0.05-0.5% of the sum of the main component weight；The dosage of water is described
The 30-35% of the sum of main component weight.
Further, artificial marble's stone material polishing slag includes following components in percentage by weight：CaCO3
85-92%, unsaturated-resin 4-6%, SiO20.8-3%, Al2O30.5-2%, MgO 0.5-2%, Fe2O30.5-1%,
TiO20.5-1%.
Further, the moisture of artificial marble's stone material polishing slag is 25-35%.
Further, it is prepared by following main component in percentage by weight：
The second object of the present invention adopts the following technical scheme that realization：
A kind of preparation method of the glaze for glazed tile based on artificial marble's stone material polishing slag, including：
Marble polishing slag preparation process：The waste water generated during artificial marble's stone material processing polished is collected
Afterwards, flocculant is added in, successively after precipitation, press filtration and uniform treatment, obtains marble polishing slag；
Green body powder preparation process：Artificial marble's stone material polishing slag, wollastonite, feldspar and the black mud of formula ratio are mixed
It closes, sieves successively after ball milling, except iron and granulation, obtain green body powder；
Biscuit preparation process：The green body powder pressing is molded, molding blank is obtained, pottery is obtained after molding blank drying
Ceramic tile base, ceramic adobe burn till for the first time, obtain biscuit；
Glazing and burn till step：The biscuit after purging, spray water, applying ground-coat enamel, apply overglaze, ink-jet printed process, into
Row burn till for the second time to get.
Further, in the green body powder preparation process, the raw material for preparing of mixing further includes methylcellulose, trimerization
Sodium phosphate and water, all raw materials carry out ball milling in the ball mill, obtain mud, the fineness of the mud is more than 325 mesh standard sieves
3.0-3.5%, moisture 30-35%；Then, the mud sieves by 80 mesh vibrating screens, and carries out except iron, Ran Houjin
Row mist projection granulating powder obtains powder, and the moisture of the powder is 6-8%；Then, the aging 20-28h of the powder, is obtained
Take green body powder.
Further, in the biscuit preparation process, the briquetting pressure of the green body powder is 350-380kg/cm2,
The corner of molding blank is thick poor<0.3mm, the flexural strength before molding blank drying>8kg/cm2。
Further, in the biscuit preparation process, the drying temperature of the molding blank is 145-155 DEG C, dry
Time is 90-120min, the moisture of the ceramic adobe obtained after dry<0.3%, intensity >=100N of ceramic adobe；Institute
It is 1180-1200 DEG C, firing time 40-70min to state ceramic adobe and carry out the firing temperature burnt till for the first time, the biscuit of acquisition
Water absorption rate be 15-25%.
Further, in the glazing and burning till step, the temperature burnt till for the second time is 1140-1160 DEG C, when burning till
Between be 60-80min.
Compared with prior art, the beneficial effects of the present invention are：
(1) glaze for glazed tile provided by the present invention based on artificial marble's stone material polishing slag, raw material include someone
Marble polishing slag is made, artificial marble's stone material polishing slag can be completely avoided handles by land-fill method to give environment band
The long-term pollution come, the utilization for artificial marble polishing slag provide new approach；Meanwhile utilize artificial marble
CaCO in material polishing slag3The characteristics of content is high can substitute traditional lime stone in the glaze for glazed tile body recipe completely,
The cost of formula is advantageously reduced, is turned waste into wealth, is a kind of green, environmentally friendly, sustainable mode of production, there is good economy
Benefit and ecological benefits.Also, the quality of the glaze for glazed tile meets national standard, is commercially valuable glaze for glazed tile
Product.
(2) preparation method of the glaze for glazed tile provided by the present invention based on artificial marble's stone material polishing slag, flow
Simply, it is easy to operate, it can be achieved that commercially produce, there is application prospect well.
Description of the drawings
The production stream for the glaze for glazed tile based on artificial marble's stone material polishing slag that Fig. 1 is provided by the embodiment of the present invention
Cheng Tu.
Specific embodiment
In the following, with reference to attached drawing and specific embodiment, the present invention is described further, it is necessary to which explanation is, not
Under the premise of conflicting, new implementation can be formed between various embodiments described below or between each technical characteristic in any combination
Example.
A kind of glaze for glazed tile based on artificial marble's stone material polishing slag, it is following main by percentage by weight
Ingredient is prepared：Artificial marble's stone material polishing slag 1-25%；Wollastonite 1-25%；Feldspar 50-70%；Black mud 15-25%.
Artificial marble's stone material polishing slag refer mainly to artificial marble in polishing process with after polish abrasive mutual grinding
The particle of generation is after the waste water generated during the polishing treatment of artificial marble's stone material is collected, by flocculation sediment, press filtration and
It is obtained after homogenizing processing.Since the wearability of artificial marble's stone material is poor, the main component in polishing slag is
CaCO3, resin and a small amount of polish abrasive.After homogenizing is handled, the ingredient of artificial marble's stone material polishing slag compares
Relatively stablize, be suitble to use in glaze for glazed tile, then be equipped with traditional ceramic raw material, according to the production technology of glaze for glazed tile,
It can be prepared by quality and meet national standard, commercially valuable Ceramic glaze brick product.
The raw material for preparing of traditional glaze for glazed tile includes this four classes raw material of feldspar, black mud, wollastonite and lime stone, and originally
Invention, completely instead of lime stone, is advantageously reduced the cost of formula, turned waste into wealth with artificial marble polishing waste residue.
As further embodiment, prepare raw material and further include auxiliary material, auxiliary material includes methylcellulose, sodium tripolyphosphate
And water；The dosage of methylcellulose and sodium tripolyphosphate is the 0.05-0.5% of the sum of main component weight；The dosage of water is
The 30-35% of the sum of main component weight.Methylcellulose plays the role of increasing blank strength, is conducive to the suspension of slurry；
And sodium tripolyphosphate is water-reducing agent, there is grinding aid.
As further embodiment, artificial marble's stone material polishing slag is including in percentage by weight with the following group
Point：CaCO385-92%, unsaturated-resin 4-6%, SiO20.8-3%, Al2O30.5-2%, MgO 0.5-2%, Fe2O3
0.5-1%, TiO20.5-1%.Unsaturated-resin is common industrial chemicals in artificial marble industry, it, which is played, bonds, is solid
To change the effect of other inorganic raw materials, such as can be multifarious chemistry, product type is the adjacent benzene-type unsaturated-resin of TC-680B,
It is a kind of using phthalic anhydride and standard dyadic alcohol as the unsaturated polyester resin of main Material synthesis, has been dissolved in styrene
In, it is suitable for making artificial stone, quartzy stone manufacture.
As further embodiment, the moisture of artificial marble's stone material polishing slag is 25-35%.
As further embodiment, it is prepared by following main component in percentage by weight：It is artificial big
Reason stone material polishing slag 4-12%；Wollastonite 5-15%；Feldspar 50-70%；Black mud 15-25%.
The glaze for glazed tile based on artificial marble's stone material polishing slag that the embodiment of the present invention is provided, for artificial at present
Marble industry handles polishing slag by the way of landfill, and environment can be caused to pollute this shortcoming for a long time, uses
The mode of thinking transboundary carries out harmless metaplasia using the polishing slag of current artificial marble as the raw materials for production of glaze for glazed tile
Production is handled, and is a kind of environmentally protective, economy recyclable production model, can be the section student of Ornamental Stone Industry and ceramic tile industry
Production provides reference；Meanwhile utilize CaCO in artificial marble's stone material polishing slag3The characteristics of content is high, the Ceramic glaze adobe
Traditional lime stone can be substituted in body formula completely, the cost of formula is advantageously reduced, turns waste into wealth, is a kind of green, ring
It protects, the sustainable mode of production, with good economic efficiency and ecological benefits.Also, the quality of the glaze for glazed tile meets
National standard is commercially valuable Ceramic glaze brick product.
In addition, the glaze for glazed tile based on artificial marble's stone material polishing slag that the embodiment of the present invention is provided, belongs to viscous
Soil-lime stone-type.This is because carrying out chemical analysis by the polishing slag to artificial marble's stone material, main ingredient is carbon
Sour calcium, this can just provide body recipe required CaO ingredients, and unsaturated-resin in marble polishing slag,
The harmful components such as abrasive material are burned completely in the sintering process of high temperature biscuiting and the glaze firing of ceramic body, and here it is utilize stone material
Polishing slag prepares glaze for glazed tile, eliminates the basis of the technology of environmental pollution.
A kind of preparation method of the glaze for glazed tile based on artificial marble's stone material polishing slag, as shown in Figure 1, including：
Marble polishing slag preparation process：The waste water generated during artificial marble's stone material processing polished is collected
Afterwards, flocculant is added in, successively after precipitation, press filtration and uniform treatment, obtains marble polishing slag；
Green body powder preparation process：Artificial marble's stone material polishing slag, wollastonite, feldspar and the black mud of formula ratio are mixed
It closes, sieves successively after ball milling, except iron and granulation, obtain green body powder；
Biscuit preparation process：Green body powder pressing is molded, molding blank is obtained, Ceramic Tiles is obtained after molding blank drying
Base, ceramic adobe burn till for the first time, obtain biscuit；
Glazing and burn till step：Biscuit carries out the after purging, spray water, applying ground-coat enamel, apply overglaze, ink-jet printed process
Twice firing to get.
As further embodiment, in green body powder preparation process, the raw material for preparing of mixing further includes methyl fibre
Dimension element, sodium tripolyphosphate and water, all raw materials carry out ball milling in the ball mill, obtain mud, and the fineness of mud is accurate for 325 targets
Tail over 3.0-3.5%, moisture 30-35%；Then, mud sieves by 80 mesh vibrating screens, and carries out except iron, Ran Houli
Mist projection granulating powder is carried out with spray drying tower, obtains powder, the moisture of powder is 6-8%；Then, powder carry is arrived
Aging 20-28h in filler bin obtains green body powder.
As further embodiment, in biscuit preparation process, carry out dry method using full-automatic brick machine and be pressed into
Type, briquetting pressure 350-380kg/cm2, the corner of molding blank is thick poor<0.3mm, the flexural strength before molding blank drying>
8kg/cm2；Green body after shaping enters dry kiln drying, and the temperature of dry kiln is 145-155 DEG C, drying time 90-
120min, the moisture of the ceramic adobe obtained after dry<0.3%, intensity >=100N of ceramic adobe；Dried ceramics
Adobe enters roller kilns and burn till for the first time, and firing temperature is 1180-1200 DEG C, firing time 40-70min, acquisition
The water absorption rate of biscuit is 15-25%, belongs to the ceramic brick product in Ceramic Tiles.
As further embodiment, in glazing and burning till step, burnt till for the second time into roller way kiln,
The temperature burnt till is 1140-1160 DEG C, firing time 60-80min.It burns till and is commonly referred to as fired by glaze for the second time, the production after glaze firing
Product are using the processes such as trimming, detection, classification, packaging, last finished product.
The preparation method for the glaze for glazed tile based on artificial marble's stone material polishing slag that the embodiment of the present invention is provided, stream
Journey is simple, easy to operate, it can be achieved that commercially producing, and has application prospect well.
It is specific embodiment of the present invention below, used raw material, equipment etc. remove special limit in the following embodiments
It can be obtained outside fixed by buying pattern.
Embodiment 1-5
A kind of glaze for glazed tile based on artificial marble's stone material polishing slag, by main component, (artificial marble's stone material polishes
Waste residue 1-25%；Wollastonite 1-25%；Feldspar 50-70%；Black mud 15-25%) and auxiliary material () be prepared, it is specific to be formulated
Table see the table below 1.
The formula table of the glaze for glazed tile of 1 embodiment 1-5 of table
Note：The dosage of auxiliary material respectively refers to the percentage for accounting for the sum of main component weight
The glaze for glazed tile based on artificial marble's stone material polishing slag of embodiment 1-5 is prepared in accordance with the following methods：
Marble polishing slag preparation process：The waste water generated during artificial marble's stone material processing polished is collected
Afterwards, flocculant is added in, successively after precipitation, press filtration and uniform treatment, obtains marble polishing slag, water content is water
It is 25-35% to divide content；
Green body powder preparation process：By artificial marble's stone material polishing slag, wollastonite, feldspar, black mud, the methyl of formula ratio
Cellulose, sodium tripolyphosphate and water, which are added in ball mill, carries out ball milling, obtains mud, the fineness of mud is 325 mesh standard sieves
Remaining 3.0-3.5%, moisture 30-35%；Then, mud sieves by 80 mesh vibrating screens, and except iron, then carry out
Mist projection granulating powder obtains powder, and the moisture of powder is 6-8%；Then, the aging 20-28h of powder obtains green body powder；
Biscuit preparation process：Green body powder carries out dry method compression moulding using full-automatic brick machine, and briquetting pressure is
370kg/cm2, the corner of molding blank is thick poor<0.3mm, the flexural strength before molding blank drying>10kg/cm2；After shaping
Green body enters dry kiln drying, and the temperature of dry kiln is 150 DEG C, drying time 105min, the ceramic adobe obtained after dry
Moisture<0.3%, intensity >=100N of ceramic adobe；Dried ceramic adobe enters roller kilns and carries out first time burning
Into firing temperature is 1190 DEG C, firing time 55min, and the water absorption rate of the biscuit of acquisition is 15-25%；
Glazing and burn till step：Biscuit enters in roller way kiln to be burnt till for the second time, and the temperature burnt till is 1150 DEG C, is burnt
It is 70min into the time, the product after glaze firing is using the processes such as trimming, detection, classification, packaging, last finished product.
Effect assessment and performance detection
The glaze for glazed tile based on artificial marble's stone material polishing slag that Example 1-5 is obtained send to national quality and supervises
It superintends and directs inspection and quarantine general bureau to be detected, test basis GB/T 4100-2015《Ceramic Tiles》With GB 6566-2010《Construction material
Radionuclide is limited the quantity》It carries out, judgment basis is CCGF 410-2015《Ceramic Tiles product quality supervision spot-check implementation specification》.
The testing result record sheet of the glaze for glazed tile of 2 embodiment 1-5 of table
It can be obtained from the record of table 2, the glaze for glazed tile of embodiment 1-5, the project detected meets GB/T 4100-2015
Annex L standards, radionuclide meet A classes decorating and renovating material technical requirement, foundation specified in GB 6566-2010
CCGF 410-2015《Ceramic Tiles product quality supervision spot-check implementation specification》It is determined as qualification.
The above embodiment is only the preferred embodiment of the present invention, it is impossible to the scope of protection of the invention is limited with this,
The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention
Claimed scope.
Claims (10)
1. a kind of glaze for glazed tile based on artificial marble's stone material polishing slag, which is characterized in that by percentage by weight
Following main component be prepared：
2. the glaze for glazed tile as described in claim 1 based on artificial marble's stone material polishing slag, which is characterized in that prepare former
Material further includes auxiliary material, and the auxiliary material includes methylcellulose, sodium tripolyphosphate and water；The use of methylcellulose and sodium tripolyphosphate
Amount is the 0.05-0.5% of the sum of the main component weight；The dosage of water is the 30- of the sum of the main component weight
35%.
3. the glaze for glazed tile as described in claim 1 based on artificial marble's stone material polishing slag, which is characterized in that the people
Making marble polishing slag includes following components in percentage by weight：CaCO385-92%, unsaturated-resin 4-
6%th, SiO20.8-3%, Al2O30.5-2%, MgO 0.5-2%, Fe2O30.5-1%, TiO20.5-1%.
4. the glaze for glazed tile as described in claim 1 based on artificial marble's stone material polishing slag, which is characterized in that the people
The moisture for making marble polishing slag is 25-35%.
5. the glaze for glazed tile as described in claim 1 based on artificial marble's stone material polishing slag, which is characterized in that by according to
The following main component of weight percent meter is prepared：
6. a kind of preparation method of the glaze for glazed tile based on artificial marble's stone material polishing slag, which is characterized in that including：
Marble polishing slag preparation process：After the waste water generated during artificial marble's stone material processing polished is collected, add
Enter flocculant, successively after precipitation, press filtration and uniform treatment, obtain marble polishing slag；
Green body powder preparation process：Artificial marble's stone material polishing slag of formula ratio, wollastonite, feldspar and black mud are mixed, ball
It sieves successively after mill, except iron and granulation, obtains green body powder；
Biscuit preparation process：The green body powder pressing is molded, molding blank is obtained, Ceramic Tiles is obtained after molding blank drying
Base, ceramic adobe burn till for the first time, obtain biscuit；
Glazing and burn till step：The biscuit carries out the after purging, spray water, applying ground-coat enamel, apply overglaze, ink-jet printed process
Twice firing to get.
7. the preparation method of the glaze for glazed tile as claimed in claim 6 based on artificial marble's stone material polishing slag, feature
It is, in the green body powder preparation process, the raw material for preparing of mixing further includes methylcellulose, sodium tripolyphosphate and water,
All raw materials carry out ball milling in the ball mill, obtain mud, and the fineness of the mud is 3.0-3.5% more than 325 mesh standard sieves, water
It is 30-35% to divide content；Then, the mud sieves by 80 mesh vibrating screens, and carries out, except iron, then carrying out mist projection granulating system
Powder obtains powder, and the moisture of the powder is 6-8%；Then, the aging 20-28h of the powder obtains green body powder.
8. the preparation method of the glaze for glazed tile as claimed in claim 6 based on artificial marble's stone material polishing slag, feature
It is, in the biscuit preparation process, the briquetting pressure of the green body powder is 350-380kg/cm2, the four of molding blank
Angle is thick poor<0.3mm, the flexural strength before molding blank drying>8kg/cm2。
9. the preparation method of the glaze for glazed tile as claimed in claim 6 based on artificial marble's stone material polishing slag, feature
It is, in the biscuit preparation process, the drying temperature of the molding blank is 145-155 DEG C, drying time 90-
120min, the moisture of the ceramic adobe obtained after dry<0.3%, intensity >=100N of ceramic adobe；The ceramic adobe
It is 1180-1200 DEG C, firing time 40-70min to carry out the firing temperature burnt till for the first time, and the water absorption rate of the biscuit of acquisition is
15-25%.
10. the preparation method of the glaze for glazed tile as claimed in claim 6 based on artificial marble's stone material polishing slag, feature
It is, in the glazing and burning till step, the temperature burnt till for the second time is 1140-1160 DEG C, firing time 60-80min.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109095909A (en) * | 2018-08-02 | 2018-12-28 | 阳西博德精工建材有限公司 | A kind of glaze for glazed tile and production method using blast furnace slag production |
| CN109483716A (en) * | 2018-11-12 | 2019-03-19 | 湖北鑫来利陶瓷发展有限公司 | Utilize the Antique Imitation Tiles and its production technology of marble wastes production |
| CN113788668A (en) * | 2021-11-16 | 2021-12-14 | 广东简一(集团)陶瓷有限公司 | Ceramic tile manufactured by using waste materials and preparation method thereof |
| CN114195448A (en) * | 2021-12-07 | 2022-03-18 | 华南理工大学 | Self-leveling mortar and preparation method thereof |
| CN115677324A (en) * | 2022-11-24 | 2023-02-03 | 科达制造股份有限公司 | Light brick prepared from waste residues of artificial quartz stone and preparation method thereof |
| CN115677383A (en) * | 2022-11-08 | 2023-02-03 | 广西欧神诺陶瓷有限公司 | Glazed tile prepared from polishing waste residues and preparation method thereof |
| CN116884536A (en) * | 2023-08-29 | 2023-10-13 | 济南明泉数字商务有限公司 | Automatic optimization method and system for production formula of industrial waste residue bricks |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1579988A (en) * | 2003-08-07 | 2005-02-16 | 刘爱林 | Ceramic wall-floor brick |
| CN105924134A (en) * | 2016-04-25 | 2016-09-07 | 广东宏宇新型材料有限公司 | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof |
| CN106699146A (en) * | 2016-12-28 | 2017-05-24 | 佛山市三水新明珠建陶工业有限公司 | Semi-polished ceramic glazed tile having fluorescent effect and manufacturing method thereof |
| CN106810206A (en) * | 2017-02-13 | 2017-06-09 | 景德镇陶瓷大学 | A kind of utilization gangue prepares the super flat method for throwing glaze Ceramic Tiles |
| CN107117941A (en) * | 2017-06-08 | 2017-09-01 | 合肥华盖光伏科技有限公司 | A kind of flooring material and preparation method thereof |
-
2017
- 2017-12-25 CN CN201711423183.8A patent/CN108069709A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1579988A (en) * | 2003-08-07 | 2005-02-16 | 刘爱林 | Ceramic wall-floor brick |
| CN105924134A (en) * | 2016-04-25 | 2016-09-07 | 广东宏宇新型材料有限公司 | Resource-saving glazed tile with pearlescent and color-variable effect and preparation method thereof |
| CN106699146A (en) * | 2016-12-28 | 2017-05-24 | 佛山市三水新明珠建陶工业有限公司 | Semi-polished ceramic glazed tile having fluorescent effect and manufacturing method thereof |
| CN106810206A (en) * | 2017-02-13 | 2017-06-09 | 景德镇陶瓷大学 | A kind of utilization gangue prepares the super flat method for throwing glaze Ceramic Tiles |
| CN107117941A (en) * | 2017-06-08 | 2017-09-01 | 合肥华盖光伏科技有限公司 | A kind of flooring material and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 严捍东: "《土木工程材料 第2版》", 31 August 2014, 同济大学出版社 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109095909A (en) * | 2018-08-02 | 2018-12-28 | 阳西博德精工建材有限公司 | A kind of glaze for glazed tile and production method using blast furnace slag production |
| CN109483716A (en) * | 2018-11-12 | 2019-03-19 | 湖北鑫来利陶瓷发展有限公司 | Utilize the Antique Imitation Tiles and its production technology of marble wastes production |
| CN113788668A (en) * | 2021-11-16 | 2021-12-14 | 广东简一(集团)陶瓷有限公司 | Ceramic tile manufactured by using waste materials and preparation method thereof |
| CN114195448A (en) * | 2021-12-07 | 2022-03-18 | 华南理工大学 | Self-leveling mortar and preparation method thereof |
| CN115677383A (en) * | 2022-11-08 | 2023-02-03 | 广西欧神诺陶瓷有限公司 | Glazed tile prepared from polishing waste residues and preparation method thereof |
| CN115677383B (en) * | 2022-11-08 | 2023-10-20 | 广西欧神诺陶瓷有限公司 | Glazed tile prepared from polished waste residues and preparation method thereof |
| CN115677324A (en) * | 2022-11-24 | 2023-02-03 | 科达制造股份有限公司 | Light brick prepared from waste residues of artificial quartz stone and preparation method thereof |
| CN115677324B (en) * | 2022-11-24 | 2023-12-29 | 科达制造股份有限公司 | Light brick made of artificial quartz stone waste residues and preparation method thereof |
| CN116884536A (en) * | 2023-08-29 | 2023-10-13 | 济南明泉数字商务有限公司 | Automatic optimization method and system for production formula of industrial waste residue bricks |
| CN116884536B (en) * | 2023-08-29 | 2024-03-12 | 济南明泉数字商务有限公司 | Automatic optimization method and system for production formula of industrial waste residue bricks |
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