CN105920998B - A kind of Degradation Formaldehyde spray of medicinal herb components - Google Patents

A kind of Degradation Formaldehyde spray of medicinal herb components Download PDF

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Publication number
CN105920998B
CN105920998B CN201610530885.5A CN201610530885A CN105920998B CN 105920998 B CN105920998 B CN 105920998B CN 201610530885 A CN201610530885 A CN 201610530885A CN 105920998 B CN105920998 B CN 105920998B
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parts
medicinal herb
herb components
spray
degradation formaldehyde
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CN105920998A (en
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王欣欣
王光丽
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Boao Zongheng Network Technology Co ltd
Zhejiang Dimension Environmental Protection Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Medicines Containing Plant Substances (AREA)
  • Cosmetics (AREA)

Abstract

The invention discloses a kind of Degradation Formaldehyde sprays of medicinal herb components, it is related to technical field of air purification, the Degradation Formaldehyde spray of the medicinal herb components includes wormwood, birthwort, Fructus Corni, longan, cassia seed, madder, Radix Notoginseng, Asian puccoon, aloe, Semen Cuscutae, honeysuckle, eupatorium, dried orange peel, Fructus Forsythiae, the Chinese medicine Degradation Formaldehyde spray of the present invention can not only effectively remove the formaldehyde in air, it can also make with fresh air and faint scent, improve environment, relieving fatigue, it can also pleasant mental and body, work and study efficiency is improved, and easy to use.

Description

A kind of Degradation Formaldehyde spray of medicinal herb components
Technical field
The present invention relates to technical field of air purification, and in particular to a kind of Degradation Formaldehyde spray of medicinal herb components.
Background technology
With the continuous improvement of living standards of the people, indoor decorating has come into huge numbers of families, finishing material release Formaldehyde has become the major pollutants in room air.If Formaldehyde Concentration of Indoor Air is excessively high, life for a long time is indoors People will appear different degrees of dizziness and respiratory symptom, can also cause the damage of a variety of organs of whole body, be to cause not Good building syndrome(SBS)Arch-criminal, people in life about 80% time spend indoors, therefore indoor ring The quality of border quality directly influences health, so Treatment of Indoor Formaldehyde Pollution is extremely important.
Currently, the method for administering formaldehyde pollution mainly has following three kinds:First, using activated carbon or certain green plantss;Two It is ventilated;Third, using chemical agent.The rate of adsorption of activated carbon or certain green plantss is slow, to newly fitting up some months The removal unobvious of indoor formaldehyde.This is because air will be contacted with activated carbon or certain green plantss could play absorption work With, while the absorption of activated carbon can reach saturation, to lose suction-operated.Since the acquisition time of formaldehyde in plate is long, lead to The ventilative method of wind cannot thoroughly eliminate formaldehyde pollution.Third method is that the chemical agent reacted with formaldehyde is selected to disappear It removes, eliminates the efficient and thorough of formaldehyde, be the method for most quickly, most effectively reducing Formaldehyde Pollution of Indoor Air.Chemical formaldehyde elimination agent It is basically divided into three classes:The first kind is the oxidant of energy oxidation of formaldehyde, such as sodium perborate, hypochlorous acid, hydrogen peroxide etc.;Second class It is the derivative of ammonia, such as urea, amino urine etc., third class is the compound for having methine active hydrogen, such as dimethyl malenate, Methyl acetoacetate etc..But chemical formaldehyde elimination agent is easy to bring secondary pollution, in order to create a cleaning, nuisanceless, free of contamination Therefore living environment it is extremely urgent to research and develop the Degradation Formaldehyde agent that a kind of adsorption efficiency is high, rate is fast and safe and non-toxic.
Invention content
In view of the deficiencies of the prior art, the Degradation Formaldehyde agent containing medicinal herb components that the present invention provides a kind of, it is not only Can quickly and effectively degradation of formaldehyde concentration, thoroughly remove formaldehyde, and avoid secondary pollution, and can also give out pure and fresh Smell, pleasant mental and body.
In order to achieve the above object, the present invention is achieved by the following technical programs:
A kind of Degradation Formaldehyde spray of medicinal herb components, includes the Chinese herbal medicine of following parts by weight:10 ~ 20 parts of wormwood, horse pocket 20 ~ 50 parts of bell, 15 ~ 25 parts of Fructus Corni, 10 ~ 18 parts of longan, 5 ~ 18 parts of cassia seed, 8 ~ 16 parts of madder, 5 ~ 20 parts of Radix Notoginseng, Asian puccoon 5 ~ 20 parts, 6 ~ 18 parts of aloe, 10 ~ 18 parts of Semen Cuscutae, 6 ~ 15 parts of honeysuckle, 3 ~ 8 parts of eupatorium, 5 ~ 12 parts of dried orange peel, 6 ~ 15 parts of Fructus Forsythiae.
Preferably, the Degradation Formaldehyde spray of the medicinal herb components, includes the Chinese herbal medicine of following parts by weight:12 parts of wormwood, 25 parts of birthwort, 20 parts of Fructus Corni, 15 parts of longan, 12 parts of cassia seed, 12 parts of madder, 15 parts of Radix Notoginseng, 15 parts of Asian puccoon, aloe 10 Part, 16 parts of Semen Cuscutae, 12 parts of honeysuckle, 5 parts of eupatorium, 8 parts of dried orange peel, 10 parts of Fructus Forsythiae.
Preferably, the Degradation Formaldehyde spray of the medicinal herb components also contains borneol, sansevieria trifasciata, lemon, lavender, rose Rare, gardenia, lily, tealeaves, peppermint, hyacinth, sweet basil, chamomile, green tea, thyme, spearmint, jasmine, white orchid, purple sieve It is one or more in orchid.
A kind of preparation method of the Degradation Formaldehyde spray of medicinal herb components, includes the following steps:
(1)By wormwood, birthwort, Fructus Corni, longan, cassia seed, madder, Radix Notoginseng, Asian puccoon, aloe, Semen Cuscutae, gold and silver Flower, eupatorium, dried orange peel, Fructus Forsythiae are cleaned, and aloe is squeezed the juice, and are filtered, are obtained filtrate, spare;
(2)Add after birthwort, Fructus Corni, longan, cassia seed, madder, Semen Cuscutae, eupatorium, dried orange peel, Fructus Forsythiae are ground Enter in extractor, 10 ~ 20 times of solvent is then added in extractor, 5 ~ 12 h are impregnated at 50 ~ 80 DEG C, then 70 ~ 100 It is heated to reflux 0.5 ~ 2h at DEG C, wormwood, honeysuckle, Asian puccoon, Radix Notoginseng is added, is heated to reflux 1 ~ 2h at 70 ~ 100 DEG C, filters To filtrate and filter residue;
(3)By step(1)Filter residue and 5 ~ 15 times of solvents be added in extractors, be heated to reflux 0.5 ~ 4h, filter be obtained by filtration Liquid and filter residue, by the filtrate obtained twice and simultaneously, concentration;
(4)In step(2)Chinese medical extract in extract solution from aloe is added, then pH value is adjusted to 5 ~ 7,120 ~ 140 15 ~ 20min of pressure sterilizing at DEG C, and be packaged into spray bottle, obtain the Degradation Formaldehyde spray of medicinal herb components.
Preferably, the solvent is water or ethyl alcohol.
Preferably, in the Degradation Formaldehyde spray of the medicinal herb components Chinese herbal medicine a concentration of 5 ~ 15 mg/mL.
Beneficial effects of the present invention:The present invention provides a kind of Degradation Formaldehyde sprays of medicinal herb components, pass through each drug Mutual compatibility concentration of formaldehyde is reduced, by the way that irreversible chemical reaction occurs with formaldehyde to reach the work for eliminating formaldehyde With and it is using natural plants as raw material, or adverse reaction nontoxic to human body is smaller, not only with degradation of formaldehyde, clean air The effect of effect also has sterilizing, inhibits disease.The Chinese medicine Degradation Formaldehyde spray of the present invention can not only effectively remove air In formaldehyde, moreover it is possible to make with fresh air and faint scent, improve environment, relieving fatigue, moreover it is possible to which pleasant mental and body improves work and study effect Rate, and it is easy to use.
Specific implementation mode
In order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below in conjunction with the embodiment of the present invention, Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is the present invention one Divide embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making The every other embodiment obtained under the premise of creative work, shall fall within the protection scope of the present invention.
Embodiment 1:
A kind of preparation method of the Degradation Formaldehyde spray of medicinal herb components, includes the following steps:
(1)By 12 parts of wormwoods, 25 parts of birthworts, 20 portions of Fructus Cornis, 15 portions of longans, 12 parts of cassia seeds, 12 portions of madders, 15 parts Radix Notoginseng, 15 portions of Asian puccoons, 16 portions of Semen Cuscutaes, 12 portions of honeysuckles, 5 portions of eupatoriums, 8 parts of dried orange peels, 10 parts of Fructus Forsythiaes are cleaned, and 10 portions of aloes are squeezed Juice, filtering, obtains extract solution from aloe, passes through supercritical CO25 portions of lavenders of method pair, 8 parts of chamomile extractions, obtain lavender and carry Take liquid and chamomile extracting solution;
(2)Add after birthwort, Fructus Corni, longan, cassia seed, madder, Semen Cuscutae, eupatorium, dried orange peel, Fructus Forsythiae are ground Enter in extractor, 15 times of solvent is then added in extractor, 8 h are impregnated at 60 DEG C, are then heated to reflux at 100 DEG C 1h is added wormwood, honeysuckle, Asian puccoon, Radix Notoginseng, is heated to reflux 1h at 100 DEG C, filtrate and filter residue is obtained by filtration;
(3)By step(1)Filter residue and 10 times of solvents be added in extractors, be heated to reflux 2 h, filtrate and filter be obtained by filtration Slag, by the filtrate obtained twice and simultaneously, concentration;
(4)In step(2)Chinese medical extract in extract solution from aloe, lavender extracting solution and chamomile extracting solution is added, Then pH value is adjusted to 6.2 ~ 6.5,15 ~ 20min of pressure sterilizing at 140 DEG C, and is packaged into spray bottle, obtains a concentration of 8 The Degradation Formaldehyde spray of the medicinal herb components of mg/mL.
Embodiment 2:
A kind of preparation method of the Degradation Formaldehyde spray of medicinal herb components, includes the following steps:
(1)By 10 parts of wormwoods, 50 parts of birthworts, 18 portions of Fructus Cornis, 10 portions of longans, 18 parts of cassia seeds, 16 portions of madders, 18 parts Radix Notoginseng, 20 portions of Asian puccoons, 6 portions of aloes, 12 portions of Semen Cuscutaes, 15 portions of honeysuckles, 5 portions of eupatoriums, 6 parts of dried orange peels, 6 parts of Fructus Forsythiaes are cleaned, by reed Luxuriant growth is squeezed the juice, and filtering obtains extract solution from aloe, passes through supercritical CO2Method extracts violet, jasmine, obtains violet extracting solution With jasmine extracting solution;
(2)Add after birthwort, Fructus Corni, longan, cassia seed, madder, Semen Cuscutae, eupatorium, dried orange peel, Fructus Forsythiae are ground Enter in extractor, 15 times of solvent is then added in extractor, 10 h are impregnated at 50 DEG C, are then heated to reflux at 80 DEG C 1h is added wormwood, honeysuckle, Asian puccoon, Radix Notoginseng, is heated to reflux 1.5h at 80 DEG C, filtrate and filter residue is obtained by filtration;
(3)By step(1)Filter residue and 5 times of solvents be added in extractors, be heated to reflux 1h, filtrate and filter be obtained by filtration Slag, by the filtrate obtained twice and simultaneously, concentration;
(4)In step(2)Chinese medical extract in extract solution from aloe, violet extracting solution and jasmine extracting solution is added, so PH value is adjusted to 5.0 ~ 5.5 afterwards, 15 ~ 20min of pressure sterilizing at 140 DEG C, and is packaged into spray bottle, obtains a concentration of 5 mg/ The Degradation Formaldehyde spray of the medicinal herb components of mL.
Embodiment 3:
A kind of preparation method of the Degradation Formaldehyde spray of medicinal herb components, includes the following steps:
(1)By 15 parts of wormwoods, 20 parts of birthworts, 25 portions of Fructus Cornis, 12 portions of longans, 5 parts of cassia seeds, 10 portions of madders, 5 part three Seven, 16 portions of Asian puccoons, 18 portions of aloes, 10 portions of Semen Cuscutaes, 12 portions of honeysuckles, 3 portions of eupatoriums, 12 parts of dried orange peels, 15 parts of Fructus Forsythiaes are cleaned, by reed Luxuriant growth is squeezed the juice, and filtering obtains extract solution from aloe, passes through supercritical CO2Method extracts peppermint, hyacinth, sweet basil, green tea, obtains thin Lotus extracting solution, hyacinth extracting solution, sweet basil extracting solution and green tea extractive liquor;
(2)Add after birthwort, Fructus Corni, longan, cassia seed, madder, Semen Cuscutae, eupatorium, dried orange peel, Fructus Forsythiae are ground Enter in extractor, 20 times of solvent is then added in extractor, 12 h are impregnated at 80 DEG C, are then heated back at 100 DEG C 0.5h is flowed, wormwood, honeysuckle, Asian puccoon, Radix Notoginseng is added, is heated to reflux 2h at 100 DEG C, filtrate and filter residue is obtained by filtration;
(3)By step(1)Filter residue and 10 times of solvents be added in extractors, be heated to reflux 4h, filtrate and filter be obtained by filtration Slag, by the filtrate obtained twice and simultaneously, concentration;
(4)In step(2)Chinese medical extract in be added extract solution from aloe, peppermint extracting solution, hyacinth extracting solution, sweet basil Extracting solution and green tea extractive liquor, then pH value be adjusted to 6.5 ~ 7,15 ~ 20min of pressure sterilizing at 140 DEG C, and be packaged into spray bottle In, obtain the Degradation Formaldehyde spray of the medicinal herb components of a concentration of 15 mg/mL.
Embodiment 4:
A kind of preparation method of the Degradation Formaldehyde spray of medicinal herb components, includes the following steps:
(1)By 20 parts of wormwoods, 30 parts of birthworts, 15 portions of Fructus Cornis, 18 portions of longans, 12 parts of cassia seeds, 8 portions of madders, 20 parts Radix Notoginseng, 5 portions of Asian puccoons, 15 portions of aloes, 18 portions of Semen Cuscutaes, 6 portions of honeysuckles, 8 portions of eupatoriums, 5 parts of dried orange peels, 10 parts of Fructus Forsythiaes are cleaned, by reed Luxuriant growth is squeezed the juice, and filtering obtains extract solution from aloe, passes through supercritical CO2Method extracts lemon, rose, gardenia, obtains lemon extraction Liquid, rose and gardenia extracting solution;
(2)Add after birthwort, Fructus Corni, longan, cassia seed, madder, Semen Cuscutae, eupatorium, dried orange peel, Fructus Forsythiae are ground Enter in extractor, 10 times of solvent is then added in extractor, 5 h are impregnated at 60 DEG C, are then heated to reflux at 80 DEG C 2h is added wormwood, honeysuckle, Asian puccoon, Radix Notoginseng, is heated to reflux 1h at 80 DEG C, filtrate and filter residue is obtained by filtration;
(3)By step(1)Filter residue and 15 times of solvents be added in extractors, be heated to reflux 0.5h, be obtained by filtration filtrate and Filter residue, by the filtrate obtained twice and simultaneously, concentration;
(4)In step(2)Chinese medical extract in be added extract solution from aloe, lemon extract, rose and gardenia extraction Liquid, then pH value be adjusted to 5.8 ~ 6.2,15 ~ 20min of pressure sterilizing at 120 DEG C, and being packaged into spray bottle is obtained a concentration of The Degradation Formaldehyde spray of the medicinal herb components of 10 mg/mL.
Contrast experiment:
In the identical closed glass container of size, 37% formaldehyde liquid is sprayed into respectively, after 60min, respectively to secret room row Into formaldehyde Processing for removing(Wherein, A groups are without any processing, and B groups spray the Traditional Chinese medicinal spray of the present invention, and the suctions such as activated carbon are added in C groups Attached property substance;D groups are sodium hydroxide solution), control group is without any processing, respectively at different time sections to the air of secret room Sampling, and concentration of formaldehyde is detected, as a result such as table 1.
Table 1:Experimental group and control group formaldehyde in air content control mg cm-3
To sum up, the embodiment of the present invention has the advantages that:The Chinese medicine Degradation Formaldehyde spray of the present invention can not only be effective Remove the formaldehyde in air, moreover it is possible to make with fresh air and faint scent, improve environment, relieving fatigue, moreover it is possible to which pleasant mental and body improves work Learning efficiency, and it is easy to use.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation In any actual relationship or order or sequence.Moreover, the terms "include", "comprise" or its any other variant are intended to Non-exclusive inclusion, so that the process, method, article or equipment including a series of elements is not only wanted including those Element, but also include other elements that are not explicitly listed, or further include for this process, method, article or equipment Intrinsic element.In the absence of more restrictions, the element limited by sentence "including a ...", it is not excluded that There is also other identical elements in process, method, article or equipment including the element.
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations;Although with reference to the foregoing embodiments Invention is explained in detail, it will be understood by those of ordinary skill in the art that:It still can be to aforementioned each implementation Technical solution recorded in example is modified or equivalent replacement of some of the technical features;And these modification or It replaces, the spirit and scope for various embodiments of the present invention technical solution that it does not separate the essence of the corresponding technical solution.

Claims (6)

1. a kind of Degradation Formaldehyde spray of medicinal herb components, which is characterized in that include the Chinese herbal medicine of following parts by weight:Wormwood 10 ~ 20 parts, 20 ~ 50 parts of birthwort, 15 ~ 25 parts of Fructus Corni, 10 ~ 18 parts of longan, 5 ~ 18 parts of cassia seed, 8 ~ 16 parts of madder, Radix Notoginseng 5 ~ 20 Part, 5 ~ 20 parts of Asian puccoon, 6 ~ 18 parts of aloe, 10 ~ 18 parts of Semen Cuscutae, 6 ~ 15 parts of honeysuckle, 3 ~ 8 parts of eupatorium, 5 ~ 12 parts of dried orange peel, Fructus Forsythiae 6 ~ 15 parts.
2. the Degradation Formaldehyde spray of medicinal herb components as described in claim 1, which is characterized in that including in following parts by weight Herbal medicine:12 parts of wormwood, 25 parts of birthwort, 20 parts of Fructus Corni, 15 parts of longan, 12 parts of cassia seed, 12 parts of madder, 15 parts of Radix Notoginseng, purple 15 parts of grass, 10 parts of aloe, 16 parts of Semen Cuscutae, 12 parts of honeysuckle, 5 parts of eupatorium, 8 parts of dried orange peel, 10 parts of Fructus Forsythiae.
3. the Degradation Formaldehyde spray of medicinal herb components as described in claim 1, which is characterized in that the first of the medicinal herb components Aldehyde degrades spray also containing borneol, sansevieria trifasciata, lemon, lavender, rose, gardenia, lily, tealeaves, peppermint, hyacinth, sieve It is one or more in Le, chamomile, green tea, thyme, spearmint, jasmine, white orchid, violet.
4. a kind of preparation method of the Degradation Formaldehyde spray of medicinal herb components as described in claim 1 ~ 3 is any, feature exist In including the following steps:
(1)By wormwood, birthwort, Fructus Corni, longan, cassia seed, madder, Radix Notoginseng, Asian puccoon, aloe, Semen Cuscutae, honeysuckle, pendant Orchid, dried orange peel, Fructus Forsythiae are cleaned, and aloe is squeezed the juice, and are filtered, are obtained filtrate, spare;
(2)It is added and carries after birthwort, Fructus Corni, longan, cassia seed, madder, Semen Cuscutae, eupatorium, dried orange peel, Fructus Forsythiae are ground It takes in tank, 10 ~ 20 times of solvent is then added in extractor, 5 ~ 12 h are impregnated at 50 ~ 80 DEG C, then at 70 ~ 100 DEG C It is heated to reflux 0.5 ~ 2h, wormwood, honeysuckle, Asian puccoon, Radix Notoginseng is added, is heated to reflux 1 ~ 2h at 70 ~ 100 DEG C, filter is obtained by filtration Liquid and filter residue;
(3)By step(1)Filter residue and 5 ~ 15 times of solvents be added in extractors, be heated to reflux 0.5 ~ 4h, be obtained by filtration filtrate and Filter residue, by the filtrate obtained twice and simultaneously, concentration;
(4)In step(2)Chinese medical extract in extract solution from aloe is added, then pH value is adjusted to 5 ~ 7, at 120 ~ 140 DEG C 15 ~ 20min of pressure sterilizing, and be packaged into spray bottle, obtain the Degradation Formaldehyde spray of medicinal herb components.
5. the preparation method of the Degradation Formaldehyde spray of medicinal herb components as claimed in claim 4, which is characterized in that the solvent For water or ethyl alcohol.
6. the preparation method of the Degradation Formaldehyde spray of medicinal herb components as claimed in claim 4, which is characterized in that the medium-height grass A concentration of 5 ~ 15 mg/mL of Chinese herbal medicine in the Degradation Formaldehyde spray of medicine ingredient.
CN201610530885.5A 2016-07-07 2016-07-07 A kind of Degradation Formaldehyde spray of medicinal herb components Expired - Fee Related CN105920998B (en)

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CN106994334A (en) * 2017-04-27 2017-08-01 舒尔环保科技(合肥)有限公司 A kind of adsorbent being used in air purifier
CN107344056A (en) * 2017-08-27 2017-11-14 山东恒诺环保科技有限公司 A kind of pure plant removes the preparation method of formaldehyde formulations
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CN105056694A (en) * 2015-08-10 2015-11-18 东莞市百叶中草药环境应用研究院 CHA herbal medicine formaldehyde scavenging and purifying Chinese herbal medicine particles and composite filter screen containing same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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