CN105901015A - 一种抗菌金属氧化物复合材料及其制备方法 - Google Patents
一种抗菌金属氧化物复合材料及其制备方法 Download PDFInfo
- Publication number
- CN105901015A CN105901015A CN201610295252.0A CN201610295252A CN105901015A CN 105901015 A CN105901015 A CN 105901015A CN 201610295252 A CN201610295252 A CN 201610295252A CN 105901015 A CN105901015 A CN 105901015A
- Authority
- CN
- China
- Prior art keywords
- metal oxide
- antibacterial metal
- oxide composite
- preparation
- silane coupling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 32
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 29
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 28
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000003756 stirring Methods 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 19
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 15
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920001661 Chitosan Polymers 0.000 claims abstract description 12
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 claims abstract description 12
- 229940075579 propyl gallate Drugs 0.000 claims abstract description 12
- 235000010388 propyl gallate Nutrition 0.000 claims abstract description 12
- 239000000473 propyl gallate Substances 0.000 claims abstract description 12
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- 238000007789 sealing Methods 0.000 claims abstract description 10
- 238000005406 washing Methods 0.000 claims abstract description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 13
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 12
- 230000008878 coupling Effects 0.000 claims description 12
- 238000010168 coupling process Methods 0.000 claims description 12
- 238000005859 coupling reaction Methods 0.000 claims description 12
- 229910000077 silane Inorganic materials 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 claims description 11
- 229960002216 methylparaben Drugs 0.000 claims description 11
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims description 10
- 238000002604 ultrasonography Methods 0.000 claims description 9
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000002023 wood Substances 0.000 claims 1
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 5
- 241000588724 Escherichia coli Species 0.000 abstract description 4
- NLMKTBGFQGKQEV-UHFFFAOYSA-N 2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO NLMKTBGFQGKQEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004287 Dehydroacetic acid Substances 0.000 abstract 1
- 229940045110 chitosan Drugs 0.000 abstract 1
- 229940061632 dehydroacetic acid Drugs 0.000 abstract 1
- 235000019258 dehydroacetic acid Nutrition 0.000 abstract 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 abstract 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 abstract 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 abstract 1
- 238000001132 ultrasonic dispersion Methods 0.000 abstract 1
- 230000001629 suppression Effects 0.000 description 8
- 229960000935 dehydrated alcohol Drugs 0.000 description 7
- 239000003242 anti bacterial agent Substances 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 5
- 229940088710 antibiotic agent Drugs 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 230000003115 biocidal effect Effects 0.000 description 4
- 244000063299 Bacillus subtilis Species 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229960004756 ethanol Drugs 0.000 description 3
- HKBTYXGDKCDBMD-UHFFFAOYSA-N ethenoxyethene octadecanoic acid Chemical compound C=COC=C.CCCCCCCCCCCCCCCCCC(O)=O HKBTYXGDKCDBMD-UHFFFAOYSA-N 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- IRHTZOCLLONTOC-UHFFFAOYSA-N hexacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCO IRHTZOCLLONTOC-UHFFFAOYSA-N 0.000 description 2
- 241000283153 Cetacea Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/16—Heavy metals; Compounds thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
Description
热失重5%的温度(℃) | 大肠杆菌的抑制率(%) | 对枯草杆菌的抑制率(%) | 对金黄色葡萄球菌的抑制率(%) | |
实施例1 | 331 | 100 | 97 | 100 |
实施例2 | 332 | 100 | 97 | 100 |
实施例3 | 333 | 100 | 97 | 100 |
实施例4 | 334 | 100 | 97 | 100 |
实施例5 | 332 | 100 | 97 | 100 |
对比例1 | 327 | 100 | 97 | 100 |
对比例2 | 324 | 100 | 92 | 93 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610295252.0A CN105901015B (zh) | 2016-05-06 | 2016-05-06 | 一种抗菌金属氧化物复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610295252.0A CN105901015B (zh) | 2016-05-06 | 2016-05-06 | 一种抗菌金属氧化物复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN105901015A true CN105901015A (zh) | 2016-08-31 |
CN105901015B CN105901015B (zh) | 2018-05-11 |
Family
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Family Applications (1)
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CN201610295252.0A Expired - Fee Related CN105901015B (zh) | 2016-05-06 | 2016-05-06 | 一种抗菌金属氧化物复合材料及其制备方法 |
Country Status (1)
Country | Link |
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CN (1) | CN105901015B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107313290A (zh) * | 2017-07-25 | 2017-11-03 | 滁州卷烟材料厂 | 一种防腐抗菌瓦楞纸箱 |
US11357718B2 (en) | 2016-07-28 | 2022-06-14 | eXion labs Inc. | Polymer-based antimicrobial compositions and methods of use thereof |
CN118183706A (zh) * | 2024-05-17 | 2024-06-14 | 湖南大学 | 一种复合改性抗菌材料及其制备方法和应用 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002212510A (ja) * | 2001-01-19 | 2002-07-31 | Haruo Kunii | 三元素硬化剤 |
CN101189971A (zh) * | 2006-11-20 | 2008-06-04 | 北京崇高纳米科技有限公司 | 一种无机/有机纳米复合抗菌剂及其纤维制品应用 |
CN104341947A (zh) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | 一种具有杀菌防腐型的玻璃移门用涂料及其制备方法 |
CN104449024A (zh) * | 2014-12-30 | 2015-03-25 | 马艳荣 | 一种疏水性纳米二氧化钛的制备方法 |
CN104479155A (zh) * | 2014-12-26 | 2015-04-01 | 北京林业大学 | 一种壳聚糖/二氧化钛溶胶抗菌包装膜制备方法 |
-
2016
- 2016-05-06 CN CN201610295252.0A patent/CN105901015B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002212510A (ja) * | 2001-01-19 | 2002-07-31 | Haruo Kunii | 三元素硬化剤 |
CN101189971A (zh) * | 2006-11-20 | 2008-06-04 | 北京崇高纳米科技有限公司 | 一种无机/有机纳米复合抗菌剂及其纤维制品应用 |
CN104341947A (zh) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | 一种具有杀菌防腐型的玻璃移门用涂料及其制备方法 |
CN104479155A (zh) * | 2014-12-26 | 2015-04-01 | 北京林业大学 | 一种壳聚糖/二氧化钛溶胶抗菌包装膜制备方法 |
CN104449024A (zh) * | 2014-12-30 | 2015-03-25 | 马艳荣 | 一种疏水性纳米二氧化钛的制备方法 |
Non-Patent Citations (2)
Title |
---|
杨平 等: "偶联剂改性对纳米二氧化钛光催化活性的影响", 《硅酸盐学报》 * |
王杏等: "《纳米二氧化钛的生产与应用》", 31 July 2014 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11357718B2 (en) | 2016-07-28 | 2022-06-14 | eXion labs Inc. | Polymer-based antimicrobial compositions and methods of use thereof |
US11426343B2 (en) | 2016-07-28 | 2022-08-30 | eXion labs Inc. | Polymer-based antimicrobial compositions and methods of use thereof |
CN107313290A (zh) * | 2017-07-25 | 2017-11-03 | 滁州卷烟材料厂 | 一种防腐抗菌瓦楞纸箱 |
CN118183706A (zh) * | 2024-05-17 | 2024-06-14 | 湖南大学 | 一种复合改性抗菌材料及其制备方法和应用 |
Also Published As
Publication number | Publication date |
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CN105901015B (zh) | 2018-05-11 |
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