CN105886142A - 一种洗衣片及其制备方法 - Google Patents

一种洗衣片及其制备方法 Download PDF

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CN105886142A
CN105886142A CN201610400826.6A CN201610400826A CN105886142A CN 105886142 A CN105886142 A CN 105886142A CN 201610400826 A CN201610400826 A CN 201610400826A CN 105886142 A CN105886142 A CN 105886142A
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魏伯贤
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
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    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3753Polyvinylalcohol; Ethers or esters thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds

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Abstract

本发明涉及一种洗衣片及其制备方法,首先,包括成膜剂4~7%;乙氧基化烷基硫酸钠3~5%;椰油基二乙醇酰胺3~5%;十二烷基硫酸钠10~15%;填充剂8~13%;甘油0.1~0.4%;色素0.1~0.2%;去离子水50~65%;然后,⑴将成膜剂与去离子水充分搅拌混合,加温至85~95℃;⑵将乙氧基化烷基硫酸钠、椰油基二乙醇酰胺、十二烷基硫酸钠、填充剂混合搅拌;⑶将步骤⑴得到的混合料、步骤⑵得到的混合料与甘油、色素一起倒入乳化锅搅拌;⑷完成后,将得到的搅拌料上滚筒烘干机烘干;⑸成品切片、包装。本发明有益效果为:方便携带且不会增加洗涤后清洁工作;有利于减少用水,节能环保;能更深层清洁衣物。

Description

一种洗衣片及其制备方法
技术领域
本发明涉及洗涤用品类,尤其涉及一种方便携带且不会增加洗涤后清洁工作的洗衣片及其制备方法。
背景技术
随着生活水平的不断提高,人们对家具生活品质以及卫生环境的要求也越来越高。现有的用于清洗衣物的洗涤用品一般有洗衣皂、洗衣粉和洗衣液这三种,洗衣皂是一种传统的洗衣用品,是用动物油脂或植物油脂与烧碱进行一系列反应后生成的脂肪酸钠盐,属于一种典型的阴离子表面活性剂,洗衣皂中含有各种添加剂对皮肤会有一定的伤害,整体呈块状,在清洗时需将整个皂体拿起才能使用,不方便,洗完衣物后残留的水分会使皂体整个软化,既不卫生也会造成浪费,最大缺点是不耐硬水,在硬水中洗涤会产生皂垢,皂垢粘附在衣物上,使被洗涤衣物板结,并在洗涤用具上形成污垢。
洗衣粉是一种碱性的合成洗涤剂,呈粉末状,粉剂不溶解水的微粒残留在衣物上,导致衣物***及颜色变暗,机洗时长期在洗衣槽和内筒之间无法排尽,而粘附在内槽壁上的污垢、残留物滋生大量细菌,造成衣物“二次污染”,易引发皮肤病;手洗时溶解在水里的洗衣粉,可通过皮肤吸收进入人体内,长期积累易损害肝脏,甚至致癌,对人体的伤害极大,不建议长期使用;在使用后,一般会放置于阳台或洗手间,在潮湿或光照的情况下,容易导致洗衣粉中的酶失去活性,从而影响洗涤效果。
洗衣液的有效成分主要是非离子型表面活性剂,去污能力强,比洗衣皂和洗衣粉技术含量高,呈中性,温和不伤手,洗衣液使用后产生的废液能快速降解,对环境污染小;但一般洗衣液为瓶装,在使用时需要从瓶中倒出,用量很难控制且使用不方便。
从肥皂、洗衣粉到洗衣液,洗涤产品从未停止过创新的步伐。近年来,市场上出现了一种新型洗涤产品洗衣片,全称纳米超浓缩洗衣片,是一种全新的洗涤产品,改变了以往洗涤产品的形态,轻便是它最大的特点,因其不含有荧光增白剂,磷等有害成分,成为新一代洗涤产品,是一种中性的合成洗涤剂;洗衣片实现的定量洗涤克服了传统洗衣粉、洗衣液使用中计量的繁琐,即节约了洗涤用品,其低泡超浓缩的环保特性又节约了用水。
由上可知,洗衣片正是洗涤行业实现健康转型的一个突破口。在未来的洗涤市场上,洗衣粉、洗衣液等传统洗涤产品将逐渐失去竞争力,失去生存空间,一种健康绿色的全新洗涤模式,必将掀起一场新的洗涤浪潮;采用洗衣片,不仅大大提高产品去污能力,且具有抗菌、防霉、不伤织品和皮肤的特点;与传统方式相比,这种洗衣片洗衣物,至少可节约一半的用水量,而且大大减少对环境的污染。
但是,市场上已普遍存在的洗衣片还未能实现上述分析中所期待的较佳清洁效果,在洗涤后还需要做一些清洁工作,其原因在于,洗衣片的配方生产方法急需提高。
发明内容
针对以上缺陷,本发明提供一种方便携带且不会增加洗涤后清洁工作的洗衣片及其制备方法。
为实现上述目的,本发明采用以下技术方案:
一种洗衣片的制备方法,首先,按照重量份数进行配比,
成膜剂 4~7%;
乙氧基化烷基硫酸钠 3~5%;
椰油基二乙醇酰胺 3~5%;
十二烷基硫酸钠 10~15%;
填充剂 8~13%;
甘油 0.1~0.4%;
色素 0.1~0.2%;
去离子水 50~65%;
然后,依次进行以下步骤:
⑴将成膜剂与去离子水充分搅拌混合,加温至85~95℃;
⑵将乙氧基化烷基硫酸钠、椰油基二乙醇酰胺、十二烷基硫酸钠、填充剂混合搅拌;
⑶将步骤⑴得到的混合料、步骤⑵得到的混合料与甘油、色素一起倒入乳化锅搅拌;
⑷完成后,将得到的搅拌料上滚筒烘干机烘干;
⑸将烘干后的成品切片、包装。
所述成膜剂为聚乙烯醇,填充剂为高岭土。
本发明所述的洗衣片及其制备方法的有益效果为:
⑴方便携带且不会增加洗涤后清洁工作;
⑵体积小,有利于降低成本,不占空间,携带方便,也适用于出差旅行;
⑶存放方便,温和不伤手;
⑷有利于减少用水,节能更环保;
⑸采用乙氧基化烷基硫酸钠、椰油基二乙醇酰胺、十二烷基硫酸钠的原料配比,能更深层清洁衣物,能保护衣物不褪色,增加衣物的光亮度和穿着次数。
具体实施方式
本发明实施例所述的洗衣片,其配方包括按照重量分数,由以下原料组成:
成膜剂 4~7%;
乙氧基化烷基硫酸钠 3~5%;
椰油基二乙醇酰胺 3~5%;
十二烷基硫酸钠 10~15%;
填充剂 8~13%;
甘油 0.1~0.4%;
色素 0.1~0.2%;
去离子水 50~65%;
其中,成膜剂为聚乙烯醇,填充剂为高岭土。
本发明实施例所述的洗衣片,其制备方法由以下步骤组成:
⑴首先,将成膜剂与去离子水充分搅拌混合,加温至85~95℃;
⑵将乙氧基化烷基硫酸钠、椰油基二乙醇酰胺、十二烷基硫酸钠、填充剂混合搅拌;
⑶将步骤⑴得到的混合料、步骤⑵得到的混合料与甘油、色素一起倒入乳化锅搅拌;
⑷完成后,将得到的搅拌料上滚筒烘干机烘干;
⑸将烘干后的成品切片、包装。
以上实施例是本发明较优选具体实施方式的一种,本领域技术人员在本技术方案范围内进行的通常变化和替换应包含在本发明的保护范围内。

Claims (3)

1.一种洗衣片的制备方法,其特征在于,由以下步骤组成,首先,按照重量份数进行配比,
成膜剂 4~7%;
乙氧基化烷基硫酸钠 3~5%;
椰油基二乙醇酰胺 3~5%;
十二烷基硫酸钠 10~15%;
填充剂 8~13%;
甘油 0.1~0.4%;
色素 0.1~0.2%;
去离子水 50~65%;
然后,依次进行以下步骤:
⑴将成膜剂与去离子水充分搅拌混合,加温至85~95℃;
⑵将乙氧基化烷基硫酸钠、椰油基二乙醇酰胺、十二烷基硫酸钠、填充剂混合搅拌;
⑶将步骤⑴得到的混合料、步骤⑵得到的混合料与甘油、色素一起倒入乳化锅搅拌;
⑷完成后,将得到的搅拌料上滚筒烘干机烘干;
⑸将烘干后的成品切片、包装。
2.根据权利要求1所述的洗衣片的制备方法,其特征在于:所述成膜剂为聚乙烯醇。
3.根据权利要求1所述的洗衣片的制备方法,其特征在于:所述填充剂为高岭土。
CN201610400826.6A 2016-06-08 2016-06-08 一种洗衣片及其制备方法 Pending CN105886142A (zh)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106434019A (zh) * 2016-09-07 2017-02-22 郝云华 一种可用于内衣灭菌的洗衣片
CN106434024A (zh) * 2016-09-12 2017-02-22 广州洁明洗涤制品有限公司 一种纳米超浓缩清水洗衣片及其制备方法
CN106566709A (zh) * 2016-11-03 2017-04-19 饶士江 一种无磷无香精的洗衣片
CN106590986A (zh) * 2016-12-26 2017-04-26 佛山市芊茹化妆品有限公司 一种具有衣物柔顺效果的温和洗衣片
CN106635487A (zh) * 2016-12-26 2017-05-10 佛山市芊茹化妆品有限公司 一种具有衣物杀菌效果的温和洗衣片
CN106867710A (zh) * 2016-10-07 2017-06-20 广州市博贤化妆品有限公司 一种清水浓缩洗衣片及其制备方法
WO2018076512A1 (zh) * 2016-10-31 2018-05-03 彭月媚 速溶低刺激性洗衣片
WO2018141104A1 (en) * 2017-02-06 2018-08-09 The Procter & Gamble Company Laundry detergent sheet comprising lines of frangibility
CN109112020A (zh) * 2018-10-17 2019-01-01 广州立白企业集团有限公司 一种速溶皂片及其制备方法
US11118146B2 (en) 2017-09-25 2021-09-14 The Procter & Gamble Company Unitary laundry detergent article
US11912962B2 (en) 2020-02-20 2024-02-27 The Procter & Gamble Company Flexible, porous, dissolvable solid sheet articles containing cationic surfactant
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421519A (zh) * 2001-11-23 2003-06-04 吕秀娟 薄片状卫生洗涤用品、制造方法及其用途
US20050003991A1 (en) * 2003-04-03 2005-01-06 Reg Macquarrie Film-form compositions for delivery of soaps and detergents
CN102492573A (zh) * 2011-12-06 2012-06-13 大连晟骊商贸有限公司 一种洗衣片
CN104403849A (zh) * 2014-10-28 2015-03-11 江南大学 一种水溶膜包装的固体洗涤剂组合物
CN105238584A (zh) * 2015-11-04 2016-01-13 广州兰洁宝生物科技有限公司 一种超浓缩洗衣片
CN105586165A (zh) * 2016-01-29 2016-05-18 广州康钰生物科技有限公司 一种具有护色功能的洗衣片及其制备方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421519A (zh) * 2001-11-23 2003-06-04 吕秀娟 薄片状卫生洗涤用品、制造方法及其用途
US20050003991A1 (en) * 2003-04-03 2005-01-06 Reg Macquarrie Film-form compositions for delivery of soaps and detergents
CN102492573A (zh) * 2011-12-06 2012-06-13 大连晟骊商贸有限公司 一种洗衣片
CN104403849A (zh) * 2014-10-28 2015-03-11 江南大学 一种水溶膜包装的固体洗涤剂组合物
CN105238584A (zh) * 2015-11-04 2016-01-13 广州兰洁宝生物科技有限公司 一种超浓缩洗衣片
CN105586165A (zh) * 2016-01-29 2016-05-18 广州康钰生物科技有限公司 一种具有护色功能的洗衣片及其制备方法

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106434019A (zh) * 2016-09-07 2017-02-22 郝云华 一种可用于内衣灭菌的洗衣片
CN106434024A (zh) * 2016-09-12 2017-02-22 广州洁明洗涤制品有限公司 一种纳米超浓缩清水洗衣片及其制备方法
CN106867710A (zh) * 2016-10-07 2017-06-20 广州市博贤化妆品有限公司 一种清水浓缩洗衣片及其制备方法
WO2018076512A1 (zh) * 2016-10-31 2018-05-03 彭月媚 速溶低刺激性洗衣片
CN106566709A (zh) * 2016-11-03 2017-04-19 饶士江 一种无磷无香精的洗衣片
CN106590986A (zh) * 2016-12-26 2017-04-26 佛山市芊茹化妆品有限公司 一种具有衣物柔顺效果的温和洗衣片
CN106635487A (zh) * 2016-12-26 2017-05-10 佛山市芊茹化妆品有限公司 一种具有衣物杀菌效果的温和洗衣片
WO2018141104A1 (en) * 2017-02-06 2018-08-09 The Procter & Gamble Company Laundry detergent sheet comprising lines of frangibility
CN110214174A (zh) * 2017-02-06 2019-09-06 宝洁公司 包括易碎线的衣物洗涤剂片
US11118146B2 (en) 2017-09-25 2021-09-14 The Procter & Gamble Company Unitary laundry detergent article
CN109112020A (zh) * 2018-10-17 2019-01-01 广州立白企业集团有限公司 一种速溶皂片及其制备方法
CN109112020B (zh) * 2018-10-17 2020-12-22 广州立白企业集团有限公司 一种速溶皂片及其制备方法
US12006410B2 (en) 2019-11-29 2024-06-11 The Procter & Gamble Company Flexible, porous, dissolvable solid sheet articles having large pores and method of making same
US11912962B2 (en) 2020-02-20 2024-02-27 The Procter & Gamble Company Flexible, porous, dissolvable solid sheet articles containing cationic surfactant
US12018232B2 (en) 2020-10-09 2024-06-25 The Procter & Gamble Company Multilayer dissolvable solid article containing solid particles for making the same

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Application publication date: 20160824