CN105886075B - 一种拉丝润滑剂及其制备方法 - Google Patents

一种拉丝润滑剂及其制备方法 Download PDF

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CN105886075B
CN105886075B CN201610239656.8A CN201610239656A CN105886075B CN 105886075 B CN105886075 B CN 105886075B CN 201610239656 A CN201610239656 A CN 201610239656A CN 105886075 B CN105886075 B CN 105886075B
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叶洲
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Abstract

本发明公开了一种拉丝润滑剂及制备方法，包括如下重量份数的组分：基础油40～50份、乳化剂1～10份、防锈剂0.5～1份、pH调节剂1～2份、油性剂12～15份、抗磨剂2～3份、抗氧剂3～6份、极压剂3～7份、氟碳表面活性剂10～15份、金属减活剂1～2份和摩擦改性剂1～3份。制备时，先将配方量的动物油脂、植物油脂和清洗煤油混合均匀后备用；然后将乳化剂、防锈剂、pH调节剂、油性剂、抗磨剂、抗氧剂和极压剂混合均匀备用；将所得混合体系混合后，加入氟碳表面活性剂、金属减活剂和摩擦改性剂，得拉丝润滑剂。与现有技术相比，采用新型基础油和抗氧剂，所得产品的润滑性和抗氧性远高于现有产品。

Description

一种拉丝润滑剂及其制备方法
技术领域
本发明属于化工领域，具体涉及一种拉丝润滑剂及其制备方法。
背景技术
在拉丝工艺中多采用润滑油作为拉丝介质，拉丝润滑油决定着工艺效率和产品质量。而拉丝润滑油的品质，往往由其基础油决定。在现有技术中，一般采用植物油作为基础油，所制备出来的拉丝润滑油的润滑性和抗氧化性均不尽如人意。
因此，一种新的具有高润滑性和抗氧化性的拉丝润滑油是社会所亟需的。
发明内容
本发明要解决的技术问题是提供一种拉丝润滑剂，以解决现有技术存在的润滑性和抗氧化性等性能较差的问题。
本发明还要解决的技术问题是提供上述拉丝润滑剂的制备方法。
为解决上述技术问题，本发明采用的技术方案如下：
一种拉丝润滑剂，它包括如下重量份数的组分：
其中，
所述的基础油为动物油脂、植物油脂和清洗煤油的混合物；
所述的乳化剂为月桂醇聚氧乙烯醚；
所述的防锈剂为硼酸；
所述的pH调节剂为柠檬酸；
所述的油性剂为酸式磷酸月桂酯；
所述的抗磨剂为水溶钼；
所述的抗氧剂为双十二碳醇酯、双(3，5-三级丁基-4-羟基苯基)硫醚和对苯二胺的混合物；
所述的极压剂为氯化石蜡；
所述的金属减活剂为噻重氮；
所述的摩擦改性剂为N，N'-间苯撑双马来酰亚胺。
其中，所述的动物油脂为工业羊油和工业鸭油，所述的植物油脂为椰子油；其中，工业羊油、工业鸭油、椰子油和清洗煤油的质量比为4:1:3:2。
其中，所述的抗氧剂中，双十二碳醇酯、双(3，5-三级丁基-4-羟基苯基)硫醚和对苯二胺的质量比为1:1:3。
其中，优选如下重量份数的组分：
上述拉丝润滑剂的制备方法，包括如下步骤：
(1)将配方量的动物油脂、植物油脂和清洗煤油于0～4℃下混合均匀后备用；
(2)将乳化剂、防锈剂、pH调节剂、油性剂、抗磨剂、抗氧剂和极压剂混合均匀后备用；
(3)将步骤(1)中所得混合体系和步骤(2)中所得混合体系混合后，于60～69℃下加入氟碳表面活性剂、金属减活剂和摩擦改性剂，混合均匀后降温至42～48℃，搅拌混合3～12h后，即得拉丝润滑剂。
有益效果：
与现有技术相比，本发明具有如下优势：
1、本发明采用新型基础油和抗氧剂，所得产品的润滑性和抗氧性远高出现有产品。
2、本发明方法操作简单，易于大规模工业推广。
具体实施方式
根据下述实施例，可以更好地理解本发明。然而，本领域的技术人员容易理解，实施例所描述的内容仅用于说明本发明，而不应当也不会限制权利要求书中所详细描述的本发明。
实施例1
材料及份数：
工业羊油20份、工业鸭油5份、椰子油15份、清洗煤油10份、月桂醇聚氧乙烯醚17份、硼酸1份、柠檬酸2份、酸式磷酸月桂酯13份、水溶钼2.5份、双十二碳醇酯1份、双(3，5-三级丁基-4-羟基苯基)硫醚1份、对苯二胺3份、氯化石蜡5份、氟碳表面活性剂12份、噻重氮2份和N，N'-间苯撑双马来酰亚胺2份。
制备方法：
(1)将配方量的动物油脂、植物油脂和清洗煤油于0～4℃下混合均匀后备用；
(2)将乳化剂、防锈剂、pH调节剂、油性剂、抗磨剂、抗氧剂和极压剂混合均匀后备用；
(3)将步骤(1)中所得混合体系和步骤(2)中所得混合体系混合后，于65℃下加入氟碳表面活性剂、金属减活剂和摩擦改性剂，混合均匀后降温至45℃，搅拌混合3～12h后，即得。
实施例2
材料、材料用量和制备方法同实施例1，所不同的是，将工业羊油20份替换为工业猪油20份。
实施例3
材料、材料用量和制备方法同实施例1，所不同的是，将工业羊油20份、工业鸭油5份替换为工业羊油25份。
实施例4
材料、材料用量和制备方法同实施例1，所不同的是，将椰子油15份替换为大豆油15份。
实施例5
材料、材料用量和制备方法同实施例1，所不同的是，将清洗煤油10份替换为柴油10份。
实施例6
材料、材料用量和制备方法同实施例1，所不同的是，将工业羊油20份、工业鸭油5份、椰子油15份和清洗煤油10份替换为工业羊油25份、椰子油25份。
实施例7
材料、材料用量和制备方法同实施例1，所不同的是，将工业羊油20份、工业鸭油5份、椰子油15份和清洗煤油10份替换为椰子油50份。
将实施例1～7中制备得到的拉丝润滑剂进行检测对比，结果如下：
可以看出，选择工业羊油、工业鸭油、椰子油和清洗煤油作为基础油，可明显提高产品的润滑性能。
需说明的是，所采用的氟碳表面活性剂可通过以下方法制备获得：先将氟醇溶于适量溶剂中，在50～70℃下通过氧化剂将所述氟醇氧化成含氟有机酸；然后将所述含氟有机酸在室温下用碱中和后制备出相应的盐，即得到所述氟碳表面活性剂。其中，氟碳表面活性剂的结构由以下通式表示：C6F13CH2COOX，其中X表示Na+或NH4+。溶剂为丙酮、四氢呋喃、二氧六环中的一种或数种。氧化剂为高锰酸钾。高锰酸钾在酸性或碱性水溶液中使用。酸性水溶液是硫酸水溶液，溶解所述高锰酸钾后形成饱和或接近饱和的溶液。硫酸水溶液的浓度为10～50％，优选20～30％。碱性水溶液是氢氧化钠水溶液，溶解所述高锰酸钾后形成饱和或接近饱和的溶液。氢氧化钠水溶液的浓度为3～40％，优选5～20％。碱为氢氧化钠水溶液或氨水。氢氧化钠水溶液浓度为2～52％。
本发明采用新型基础油和抗氧剂，所得产品的润滑性和抗氧性远高出现有产品。制备方法操作简单，易于大规模工业推广。

Claims (5)

1.一种拉丝润滑剂，其特征在于，它包括如下重量份数的组分：
其中，
所述的基础油为动物油脂、植物油脂和清洗煤油的混合物；
所述的乳化剂为月桂醇聚氧乙烯醚；
所述的防锈剂为硼酸；
所述的pH调节剂为柠檬酸；
所述的油性剂为酸式磷酸月桂酯；
所述的抗磨剂为水溶钼；
所述的抗氧剂为双十二碳醇酯、双(3，5-三级丁基-4-羟基苯基)硫醚和对苯二胺的混合物；
所述的极压剂为氯化石蜡；
所述的金属减活剂为噻重氮；
所述的摩擦改性剂为N，N'-间苯撑双马来酰亚胺。
2.根据权利要求1所述的拉丝润滑剂，其特征在于，所述的动物油脂为工业羊油和工业鸭油，所述的植物油脂为椰子油；其中，工业羊油、工业鸭油、椰子油和清洗煤油的质量比为4:1:3:2。
3.根据权利要求1所述的拉丝润滑剂，其特征在于，所述的抗氧剂中，双十二碳醇酯、双(3，5-三级丁基-4-羟基苯基)硫醚和对苯二胺的混合物的质量比为1:1:3。
4.根据权利要求1所述的拉丝润滑剂，其特征在于，它包括如下重量份数的组分：
5.权利要求1所述的拉丝润滑剂的制备方法，其特征在于包括如下步骤：
(1)将配方量的动物油脂、植物油脂和清洗煤油于0～4℃下混合均匀后备用；
(2)将乳化剂、防锈剂、pH调节剂、油性剂、抗磨剂、抗氧剂和极压剂混合均匀后备用；
(3)将步骤(1)中所得混合体系和步骤(2)中所得混合体系混合后，于60～69℃下加入氟碳表面活性剂、金属减活剂和摩擦改性剂，混合均匀后降温至42～48℃，搅拌混合3～12h后，即得拉丝润滑剂。
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