CN105886075B - A kind of wire drawing lubricant and preparation method thereof - Google Patents

A kind of wire drawing lubricant and preparation method thereof Download PDF

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Publication number
CN105886075B
CN105886075B CN201610239656.8A CN201610239656A CN105886075B CN 105886075 B CN105886075 B CN 105886075B CN 201610239656 A CN201610239656 A CN 201610239656A CN 105886075 B CN105886075 B CN 105886075B
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parts
wire drawing
oil
antioxidant
drawing lubricant
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CN105886075A (en
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叶洲
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Jiangsu SanRui Biotechnology Co.,Ltd.
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Jiangsu Jiuzhou Environmental Protection Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/048Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/124Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms containing hydroxy groups; Ethers thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • C10M2207/401Fatty vegetable or animal oils used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/066Arylene diamines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086Imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/08Thiols; Sulfides; Polysulfides; Mercaptals
    • C10M2219/082Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
    • C10M2219/087Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Derivatives thereof, e.g. sulfurised phenols
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106Thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06Organic compounds derived from inorganic acids or metal salts
    • C10M2227/066Organic compounds derived from inorganic acids or metal salts derived from Mo or W
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10Inhibition of oxidation, e.g. anti-oxidants

Abstract

The invention discloses a kind of wire drawing lubricant and preparation methods, include the component of following parts by weight:1~3 part of 40~50 parts of base oil, 1~10 part of emulsifier, 0.5~1 part of antirust agent, 1~2 part of pH adjusting agent, 12~15 parts of oiliness improver, 2~3 parts of antiwear additive, 3~6 parts of antioxidant, 3~7 parts of extreme pressure agent, 10~15 parts of fluorocarbon surfactant, 1~2 part of metal deactivator and friction modifiers.It is first that the animal fat of formula ratio, vegetable fat and cleaning kerosene is spare after mixing during preparation;Then emulsifier, antirust agent, pH adjusting agent, oiliness improver, antiwear additive, antioxidant and extreme pressure agent are uniformly mixed spare;After gained mixed system is mixed, fluorocarbon surfactant, metal deactivator and friction modifiers are added in, obtain wire drawing lubricant.Compared with prior art, using novel foundation oil and antioxidant, the lubricity and antioxidant of products obtained therefrom are far above existing product.

Description

A kind of wire drawing lubricant and preparation method thereof
Technical field
The invention belongs to chemical fields, and in particular to a kind of wire drawing lubricant and preparation method thereof.
Background technology
Mostly using lubricating oil as wire drawing medium in drawing process, drawing lubricating oil decides process efficiency and product matter Amount.And the quality of drawing lubricating oil, often determined by its base oil.In the prior art, generally using based on vegetable oil Oil, the lubricity and inoxidizability of prepared drawing lubricating oil out are not fully up to expectations.
Therefore, it is a kind of it is new there is high-lubricity and antioxidative drawing lubricating oil be social institute there is an urgent need for.
Invention content
The technical problem to be solved in the present invention is to provide a kind of wire drawing lubricant, to solve lubricity of the existing technology The problem of with the poor-performings such as inoxidizability.
The present invention also technical problems to be solved are to provide the preparation method of above-mentioned wire drawing lubricant.
In order to solve the above technical problems, the technical solution adopted by the present invention is as follows:
A kind of wire drawing lubricant, it includes the component of following parts by weight:
Wherein,
The base oil is animal fat, vegetable fat and the mixture for cleaning kerosene;
The emulsifier is ethoxylated dodecyl alcohol;
The antirust agent is boric acid;
The pH adjusting agent is citric acid;
The oiliness improver is acid phosphate lauryl;
The antiwear additive is water-soluble molybdenum;
The antioxidant is double Lauryl Alcohol esters, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers and p-phenylenediamine Mixture;
The extreme pressure agent is chlorinated paraffin;
The metal deactivator is thiadiazole;
The friction modifiers are N, penylene bismaleimide between N'-.
Wherein, the animal fat is industrial sheep oil and industrial duck oil, and the vegetable fat is coconut oil;Wherein, Industrial sheep oil, industrial duck oil, coconut oil and to clean the mass ratio of kerosene be 4:1:3:2.
Wherein, in the antioxidant, double Lauryl Alcohol esters, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers and right The mass ratio of phenylenediamine is 1:1:3.
Wherein, the component of preferably following parts by weight:
The preparation method of above-mentioned wire drawing lubricant, includes the following steps:
(1) it is the animal fat of formula ratio, vegetable fat and cleaning kerosene is spare after mixing at 0~4 DEG C;
(2) emulsifier, antirust agent, pH adjusting agent, oiliness improver, antiwear additive, antioxidant and extreme pressure agent are uniformly mixed standby With;
(3) after mixing gained mixed system in step (1) and the middle gained mixed system of step (2), at 60~69 DEG C Fluorocarbon surfactant, metal deactivator and friction modifiers are added in, 42~48 DEG C is cooled to after mixing, is stirred 3 To get wire drawing lubricant after~12h.
Advantageous effect:
Compared with prior art, the present invention has following advantage:
1st, the present invention has production using novel foundation oil and antioxidant, the remote height of lubricity and antioxidant of products obtained therefrom Product.
2nd, the method for the present invention is easy to operate, is easy to large-scale industry popularization.
Specific embodiment
According to following embodiments, the present invention may be better understood.It is however, as it will be easily appreciated by one skilled in the art that real It applies the described content of example and is merely to illustrate the present invention, without sheet described in detail in claims should will not be limited Invention.
Embodiment 1
Material and number:
Industrial 20 parts of sheep oil, industrial 5 parts of duck oil, 15 parts of coconut oil, 10 parts of kerosene of cleaning, ethoxylated dodecyl alcohol 17 Part, 1 part of boric acid, 2 parts of citric acid, 13 parts of acid phosphate lauryl, 2.5 parts of water-soluble molybdenum, 1 part of double Lauryl Alcohol esters, bis- (3,5- tri- Grade butyl -4- hydroxy phenyls) 1 part of thioether, 3 parts of p-phenylenediamine, 5 parts of chlorinated paraffin, 12 parts of fluorocarbon surfactant, thiadiazole 2 Part and 2 parts of penylene bismaleimide between N, N'-.
Preparation method:
(1) it is the animal fat of formula ratio, vegetable fat and cleaning kerosene is spare after mixing at 0~4 DEG C;
(2) emulsifier, antirust agent, pH adjusting agent, oiliness improver, antiwear additive, antioxidant and extreme pressure agent are uniformly mixed standby With;
(3) it by after gained mixed system mixing in gained mixed system in step (1) and step (2), is added at 65 DEG C Fluorocarbon surfactant, metal deactivator and friction modifiers are cooled to 45 DEG C, after being stirred 3~12h after mixing, To obtain the final product.
Embodiment 2
Material, material utilization amount and the preparation method is the same as that of Example 1, the difference is that industrial 20 parts of sheep oil is replaced with industry 20 parts of lard.
Embodiment 3
Material, material utilization amount and the preparation method is the same as that of Example 1, the difference is that by industrial 20 parts of sheep oil, industrial duck oil 5 Part replaces with industrial 25 parts of sheep oil.
Embodiment 4
Material, material utilization amount and the preparation method is the same as that of Example 1, the difference is that by coconut oil 15 parts replace with soybean oil 15 parts.
Embodiment 5
Material, material utilization amount and the preparation method is the same as that of Example 1, the difference is that 10 parts of kerosene of cleaning is replaced with diesel oil 10 parts.
Embodiment 6
Material, material utilization amount and the preparation method is the same as that of Example 1, the difference is that by industrial 20 parts of sheep oil, industrial duck oil 5 Part, 15 parts of coconut oil and 10 parts of kerosene of cleaning replace with industrial 25 parts of sheep oil, 25 parts of coconut oil.
Embodiment 7
Material, material utilization amount and the preparation method is the same as that of Example 1, the difference is that by industrial 20 parts of sheep oil, industrial duck oil 5 Part, 15 parts of coconut oil and 10 parts of kerosene of cleaning replace with 50 parts of coconut oil.
The wire drawing lubricant being prepared in Examples 1 to 7 is detected comparison, it is as a result as follows:
As can be seen that oil based on the industrial sheep oil of selection, industrial duck oil, coconut oil and cleaning kerosene, can significantly improve The greasy property of product.
It should be noted that used fluorocarbon surfactant can be prepared by the following method acquisition:First fluorine alcohol is dissolved in In appropriate solvent, the fluorine alcohol is oxidized to by fluorine-containing organic acid by oxidant at 50~70 DEG C;Then fluorine-containing have described Machine acid is at room temperature with preparing corresponding salt to get to the fluorocarbon surfactant after alkali neutralization.Wherein, fluorocarbon surface is lived The structure of property agent is expressed by the following formula:C6F13CH2COOX, wherein X represent Na+ or NH4+.Solvent for acetone, tetrahydrofuran, One or several kinds in dioxane.Oxidant is potassium permanganate.Potassium permanganate uses in acid or alkaline aqueous solution.It is acid Aqueous solution is aqueous sulfuric acid, and saturation or the solution close to saturation are formed after dissolving the potassium permanganate.Aqueous sulfuric acid it is dense Spend is 10~50%, preferably 20~30%.Alkaline aqueous solution is sodium hydrate aqueous solution, and formation is full after dissolving the potassium permanganate And/or the solution close to saturation.A concentration of the 3~40% of sodium hydrate aqueous solution, preferably 5~20%.Alkali is water-soluble for sodium hydroxide Liquid or ammonium hydroxide.Sodium hydrate aqueous solution a concentration of 2~52%.
The present invention is far higher by existing product using novel foundation oil and antioxidant, the lubricity and antioxidant of products obtained therefrom. Preparation method is easy to operate, is easy to large-scale industry popularization.

Claims (5)

1. a kind of wire drawing lubricant, which is characterized in that it includes the component of following parts by weight:
Wherein,
The base oil is animal fat, vegetable fat and the mixture for cleaning kerosene;
The emulsifier is ethoxylated dodecyl alcohol;
The antirust agent is boric acid;
The pH adjusting agent is citric acid;
The oiliness improver is acid phosphate lauryl;
The antiwear additive is water-soluble molybdenum;
The antioxidant is the mixed of double Lauryl Alcohol esters, bis- (3,5- three-level butyl -4- hydroxy phenyls) thioethers and p-phenylenediamine Close object;
The extreme pressure agent is chlorinated paraffin;
The metal deactivator is thiadiazole;
The friction modifiers are N, penylene bismaleimide between N'-.
2. wire drawing lubricant according to claim 1, which is characterized in that the animal fat is industrial sheep oil and industry Duck oil, the vegetable fat are coconut oil;Wherein, the mass ratio of industrial sheep oil, industrial duck oil, coconut oil and cleaning kerosene is 4:1:3:2。
3. wire drawing lubricant according to claim 1, which is characterized in that double Lauryl Alcohol esters, double in the antioxidant The mass ratio of the mixture of (3,5- three-level butyl -4- hydroxy phenyls) thioether and p-phenylenediamine is 1:1:3.
4. wire drawing lubricant according to claim 1, which is characterized in that it includes the component of following parts by weight:
5. the preparation method of wire drawing lubricant described in claim 1, it is characterised in that include the following steps:
(1) it is the animal fat of formula ratio, vegetable fat and cleaning kerosene is spare after mixing at 0~4 DEG C;
(2) it is emulsifier, antirust agent, pH adjusting agent, oiliness improver, antiwear additive, antioxidant and extreme pressure agent is spare after mixing;
(3) it by after gained mixed system mixing in gained mixed system in step (1) and step (2), is added at 60~69 DEG C Fluorocarbon surfactant, metal deactivator and friction modifiers are cooled to 42~48 DEG C, are stirred 3~12h after mixing Afterwards to get wire drawing lubricant.
CN201610239656.8A 2016-04-18 2016-04-18 A kind of wire drawing lubricant and preparation method thereof Active CN105886075B (en)

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CN112852529A (en) * 2021-01-25 2021-05-28 广西平果博导铝镁线缆有限公司 Formula of wire drawing oil

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1197109A (en) * 1997-04-18 1998-10-28 郭紫鸣 Copper wiredrawing lubricating oil reactivation agent
US20040097628A1 (en) * 2001-03-09 2004-05-20 Kazuhiro Sekiba Greasy silicone composition
CN101029269A (en) * 2007-04-09 2007-09-05 大连三达奥克化学有限公司 Lubricating and cooling emulsified oil of iron-nickel alloy wire fine drawing and its production
CN101935576A (en) * 2010-10-09 2011-01-05 辽宁奥克化学股份有限公司 Cutting fluid with anti-oxidation performance, preparation method and application thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1197109A (en) * 1997-04-18 1998-10-28 郭紫鸣 Copper wiredrawing lubricating oil reactivation agent
US20040097628A1 (en) * 2001-03-09 2004-05-20 Kazuhiro Sekiba Greasy silicone composition
CN101029269A (en) * 2007-04-09 2007-09-05 大连三达奥克化学有限公司 Lubricating and cooling emulsified oil of iron-nickel alloy wire fine drawing and its production
CN101935576A (en) * 2010-10-09 2011-01-05 辽宁奥克化学股份有限公司 Cutting fluid with anti-oxidation performance, preparation method and application thereof

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Patentee after: Jiangsu SanRui Biotechnology Co.,Ltd.

Address before: 6 Gangcheng West Road, Binjiang Industrial Park, Taizhou Economic Development Zone, Taizhou City, Jiangsu Province 225300

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Denomination of invention: A drawing lubricant and its preparation method

Effective date of registration: 20230215

Granted publication date: 20180622

Pledgee: Bank of Nanjing Co.,Ltd. Taizhou Branch

Pledgor: Jiangsu SanRui Biotechnology Co.,Ltd.

Registration number: Y2023320000070

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