CN105885494B - Radiation curing fluosilicic coating and its preparation method and application - Google Patents
Radiation curing fluosilicic coating and its preparation method and application Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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Abstract
The invention belongs to paint fields, it is related to radiation curing fluosilicic coating and its preparation method and application, specifically disclose a kind of radiation curing fluosilicic coating, the composition and content of the coating are as follows: 30~70wt% of reactive acrylate's prepolymer, 15~50wt% of reactive acrylate monomer, 3~8wt% of photoinitiator, 0~35wt% of pigment, 0~10wt% of filler, 0~5wt% of auxiliary agent.Compared with the existing technology; not only color, the expressive force of pattern are more preferable when the present invention is surface-treated ornament materials; and have both good antibacterial, anti-pollution automatically cleaning, waterproof, fungicidal properties; weather resistance, heat resistance, mechanical performance more preferably, using the also more extensive, processing, beautification, the protection that can be widely applied to indoor and outdoor decorative material surface.
Description
Technical field
The invention belongs to paint fields, in particular to radiation curing fluosilicic coating and its preparation method and application.
Background technique
Radiation curing technology starts from early 1960s Bayer A.G and successfully develops light in the application of coating industry
Solidified carpentry coating.The development that present UV technology is advanced by leaps and bounds, especially with its excellent surface property and high solidification
The features such as speed, low pollution, energy conservation, becomes environmentally-friendly technique, and application range is from original floor paint, woodwork coating to now
Ink and plastic paint, antistatic coatings, car paint and more advanced optical fiber/optical cable, CD, solar film, plate
The production etc. of mummy in display function film, archaeology.
In China, radiation curable coating can calculate or a new industry, and industrialization is less than 10 years, but every year with close
20% development speed development.As the improvement of people's living standards, to various building decorations, decoration demand increase, to environmental protection,
Energy conservation and the requirements such as sustainable development are also higher and higher, therefore, to each production link of product, the construction link of engineering
It is required that also higher and higher, the functional requirement for needing to show to product is higher and higher, and existing radiation curable coating is difficult to meet
Consumer demand.
Summary of the invention
The purpose of the present invention is to overcome the deficiency in the prior art, provides a kind of radiation curing fluosilicic coating and preparation method thereof
And application, not only color, the expressive force of pattern are more preferable when being surface-treated to ornament materials, but also have both good anti-
Bacterium, anti-pollution automatically cleaning, waterproof, fungicidal properties, weather resistance, heat resistance, mechanical performance more preferably, using also it is more extensive, can be wide
General processing, beautification, protection applied to indoor and outdoor decorative material surface.
For this purpose, being prepared the present invention provides a kind of radiation curing fluosilicic coating by the raw material of following weight percent:
30~70wt% of reactive acrylate's prepolymer, 15~50wt% of reactive acrylate monomer, 3~8wt% of photoinitiator,
0~35wt% of pigment, 0~10wt% of filler, 0~5wt% of auxiliary agent.
Preferably, the composition and content of the coating are as follows: 30~70wt% of reactive acrylate's prepolymer, reaction
20~50wt% of property acrylate monomer, 3~8wt% of photoinitiator, 0~35wt% of pigment, 0~10wt% of filler, auxiliary agent 0~
5wt%.
Preferably, reactive acrylate's prepolymer is selected from epoxy acrylate, urethane acrylate, gathers
Ester acrylate, acrylate copolymer, fluorine-containing epoxy acrylate, fluorochemical urethane acrylate, contains amino acrylates
Fluorine polyester acrylate, fluorine-containing amino acrylates, fluoro-acrylate copolymer, siliceous epoxy acrylate, siliceous poly- ammonia
Ester acrylate, Silicon-containing Polyester acrylate, siliceous amino acrylates, silyl acrylate ester copolymer, fluosilicic propylene oxide
Acid esters, fluosilicic urethane acrylate, fluosilicic polyester acrylate, fluosilicic amino acrylates, silicon-fluorin acrylic acid ester copolymer
At least one of composed group.
Preferably, the reactive acrylate monomer, which is selected from the reactive acrylate monomer, is selected from propylene
Acid butyl ester, cyclohexyl acrylate, Isooctyl acrylate monomer EHA, hydroxy-ethyl acrylate HEA, hydroxyethyl methacrylate MHEA, two contractings
Tripropylene glycol diacrylate TPGDA, dipropylene glycol diacrylate DPGDA, neopentylglycol diacrylate NPGDA, the third oxygen
Change neopentylglycol diacrylate PO-NPGDA, bis- (diethylene glycol) the diacrylate PDDA of phthalic acid, 1,6 hexylene glycols two
Acrylate HDDA, trimethylolpropane trimethacrylate TMPTA, ethoxyquin trimethylolpropane trimethacrylate EO-
TMODA, the third oxidation trimethylolpropane trimethacrylate PO-TMPDA, pentaerythritol triacrylate PETA, dipentaerythritol
At least one of group composed by six acrylate DPHA.
Preferably, the reactive acrylate monomer be selected from ethoxyethoxyethyl acrylate EOEOEA,
2- phenoxyethyl acrylate PHEA, isobornyl acrylate IBOA, dodecyl acrylate LA, lauryl methacrylate
LMA, octadecyl acrylate SA, octadecyl methacrylate SMA, tetrahydrofuran acrylate THFA, tetrahydrofuran methyl propylene
Acid esters THFMA, Isosorbide-5-Nitrae butanediol diacrylate BDDA, phthalic acid triethylene glycol dimethacrylate PTDMA, three contractings
Triethylene glycol dimethacrylate TEGDMA, (4) ethoxylated bisphenol a diacrylate EO4-BPADA, (9) ethoxyquin three
Hydroxymethyl-propane triacrylate EO9-TMTA, (9) ethoxyquin trimethylol-propane trimethacrylate EO9-TMPMA, third
Aoxidize glycerol tri-acrylate PO3-GTA, ring trimethylolpropane dimethoxym ethane acrylate CTFA, methoxy poly (ethylene glycol)
(340) acrylate MPEG (340) A, polyethylene glycol (200) diacrylate PEG (200) DA, (400) two propylene of polyethylene glycol
At least one of group composed by acid esters PEG (400) DA, polyethylene glycol (600) diacrylate PEG (600) DA.
Preferably, the photoinitiator is selected from from benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl
Ether, benzil dimethyl ketal, from acetophenone, 2,2- dimethoxy -2- phenyl acetophenone, 2,2- diethoxy -2- phenyl benzene
Ethyl ketone, 1,1- dichloroacetophenone, 1- hydroxy acetophenone, 1- hydroxy-cyclohexyl phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1-
Acetone, 1- (4- isopropyl phenyl) -2- hydroxy-2-methyl -1- acetone, 1- [4- (2- hydroxyl-oxethyl) phenyl] -2- hydroxyl -2-
Methyl-1-acetone, 2- methyl-1-[4- (methyl mercapto) phenyl]-2- morpholinyl-1- acetone, 2- benzyl-2- dimethylamino-
1- (4- morpholino phenyl) -1- butanone, 2- tert-butyl anthraquinone, 1- chloroanthraquinone, 2- amyl anthraquinone, 2,4- dimethyl thioxanthone,
2,4- diethyl thioxanthone, 2- isopropyl thioxanthone, 4- isopropyl thioxanthone, 2- chloro thioxanthone, 2,4- bis- are different
Propyl thioxanthone, benzophenone, 4- chlorobenzophenone, to methyl benzophenone, 4- benzoyl -4 '-methyldiphenyl base sulphur
Ether, 2,4,6- trimethyl benzoyl diphenyl base phosphine oxide, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxides, two (2,
6- dimethylbenzoyl) -2,4,4- trimethylpentylphosphine oxide, the oxidation of 2,4,6- trimethylbenzoyl phenyl ethyoxyl
Phosphine, methyl benzoylbenzoate, at least one of group composed by methyl o-benzoylbenzoate.
Preferably, the pigment is: titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue, ultramarine green, phthalein
The inorganic, organic pigments such as the mountain valley with clumps of trees and bamboo is blue, the phthalein mountain valley with clumps of trees and bamboo is green, brown chrome yellow, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl powder.
Preferably, the filler is selected from kaolin, flatting silica, delustring slurry, abrasion-resistant powder or their mixture；It is described
Auxiliary agent include levelling agent, defoaming agent, in wetting dispersing agent, adhesion promoter, ultraviolet absorbing agent, screening uv-ray agent etc.
One or more kinds of mixtures.
A kind of preparation method of radiation curing fluosilicic coating, by reactive acrylate's prepolymer, reactive acrylate
Monomer, auxiliary agent, pigment, filler mixing, stir evenly, disperse, grind, add photoinitiator, be stirred for, disperse, filter, obtain
To the radiation curing fluosilicic coating.
Radiation curing fluosilicic coating of the invention can be applicable to category of glass: float glass, tempered glass, semi-tempered glass,
Laminated glass, bulletproof glass, builds imitative curtain wall plexiglas, wire glass, pattern glass, glass scape brick, glass at typhoon protection glass
Glass mosaic, solar photovoltaic assembly anti reflection glass；Functional glass: heat-protecting glass, antibiotic glass, self-cleaning glass, peace
The glass substrates such as full glass, uvioresistant glass；Inorganic board class: cement fibrolite plate, calcium silicate board, magnesium oxide plate, glass magnesium board, magnesite
Plate, plasterboard etc.；The wood base such as solid wood board, medium density fiberboard, glued board, particieboard, density board, bamboo substrate, bamboo and wood board, stalk board
Plate；Roll up the metal substrates such as aluminium, aluminium sheet, steel plate, iron plate, galvanized sheet；The substrates such as ceramic wafer, class ceramic wafer, pottery clay plates；Wood-plastic board,
The composite boards such as stone-plastic plate, artificial stone plate；The plastic sheets such as PVC, ABS, PC, PMMA, engineering plastic offset plate；Flexible parent metal:
The substrate surfaces such as the flexibility plastic cement such as textile, PVC, PU, PET membrane material, paper.
Compared with prior art, acrylic resin modified fluosilicic, fluorine-silicon modified acrylic resin and fluorine is mainly added in the present invention
Acrylic resin modified and its mutually effective collocation can the more efficient weather resistance for improving paint film, mechanical performance, high resistance to
Hot property, high-chemical-resistance, high-low temperature resistant be poor, oxidation resistent susceptibility, and low surface energy, has hydrophobic, oleophobic at low surface tension
Performance and self-cleaning function have and are more widely applied field and space；As large arch dam, the environmental protection of extremely low VOC emission, section
Energy, efficient new coating will replace existing traditional coating.Fluosilicic therein is acrylic resin modified, fluorine-silicon modified acrylic tree
Rouge and fluorin modified crylic acid resin and other acrylic polymers, acrylic monomers are in radiation curing (ultraviolet light solidification or electronics
Beam solidifies) mechanism under the conditions of react to form silicon, fluorine be arranged in surface fine and close macromolecular network structure paint film,
It has effectively gathered the advantage of traditional fluorocarbon coating and organosilicon coating respectively in performance, carries out at surface to ornament materials
Not only color, the expressive force of pattern are more preferable when reason, but also have both good antibacterial, anti-pollution automatically cleaning, waterproof, fungicidal properties, resistance to
Wait performance, heat resistance, mechanical performance more preferably, using also it is more extensive, can be widely applied to indoor and outdoor decorative material surface
Processing, beautification, protection.
Specific embodiment
Embodiment 1: the raw material of following weight percent: reactive acrylate's prepolymer 70KG, reactive propylene is weighed
Acid ester monomer 15KG, photoinitiator 3KG, pigment 7KG, auxiliary agent 5KG.It is prepared as follows: (1) according to the quality in total system
Ratio is by the acrylate monomer and fluorine-silicon modified acrylic ester or/and fluorin modified crylic acid ester or/and fluosilicic modified third in system
Olefin(e) acid ester, acrylic ester prepolymer mixing, are warming up to 50~60 DEG C, stir evenly；(2) then in step (1) according to totality
The part of auxiliary of system is added in ratio in system, and stirring is sufficiently until be completely dissolved；(3) filler of total system, pigment etc. are pressed again
It is added in the system of step (2), stirs according to ratio, disperse, wetting；(4) it is ground again with three-roller or ball mill or sand mill etc.
Mill equipment is fully ground (3) gained, until reaching standard；(5) according still further to ratio in system by initiator etc. other
Auxiliary agent is added obtained by (4), and fully dispersed until being completely dissolved, mixing gained.
Wherein: reactive acrylate's prepolymer is by fluorine-silicon modified acrylic ester, fluorin modified crylic acid ester, fluosilicic modified propylene
Acid esters composition, reactive acrylate monomer is by 1,6 hexanediyl ester HDDA, trimethylolpropane trimethacrylate
TMPTA composition, the photoinitiator is by 2,2- dimethoxy -2- phenyl acetophenone, 2,2- diethoxy -2- phenyl acetophenone group
At pigment is carbon black, and auxiliary agent is wetting dispersing agent, adhesion promoter, ultraviolet absorbing agent.
Embodiment 2: reactive acrylate's prepolymer 30KG, reactive acrylate monomer 50KG, photoinitiator are weighed
8KG, filler 7KG, auxiliary agent 5KG.It is prepared by the following method: (1) according to the mass ratio in total system by third in system
Olefin(e) acid ester monomer and fluorine-silicon modified acrylic ester or fluorin modified crylic acid ester or fluosilicic modification acrylate, acrylic ester prepolymer mix
It closes, is warming up to 50~60 DEG C, stirs evenly；(2) it is then helped in step (1) according to the part that system is added in ratio in total system
Agent, stirring is sufficiently until be completely dissolved；(3) filler of total system etc. is proportionally added in the system of step (2), is stirred
It mixes, disperses, wetting, dispersion or grinding are until reach standard；(4) other auxiliary agents such as initiator are added according still further to ratio in system
(3) gained, and it is fully dispersed until being completely dissolved, mixing gained.
Embodiment 3: reactive acrylate's prepolymer 50KG, reactive acrylate monomer 46KG, photoinitiator are weighed
4KG.Prepared by the following method: (1) according to the mass ratio in total system by system acrylate monomer and silicon change
Property acrylate or fluorin modified crylic acid ester or fluosilicic modification acrylate, acrylic ester prepolymer mixing, be warming up to 50~60
DEG C, it stirs evenly；(2) initiator is added obtained by (1) according still further to ratio in system, and fully dispersed up to being completely dissolved, is mixed
Close gained.
Embodiment 4: reactive acrylate's prepolymer 60KG, reactive acrylate monomer 20KG, photoinitiator are weighed
7KG, filler 10KG, auxiliary agent 3KG, are prepared by the following method: (1) according to the mass ratio in total system by third in system
Olefin(e) acid ester monomer and fluorine-silicon modified acrylic ester or fluorin modified crylic acid ester or fluosilicic modification acrylate, acrylic ester prepolymer mix
It closes, is warming up to 50~60 DEG C, stirs evenly；(2) it is then helped in step (1) according to the part that system is added in ratio in total system
Agent, stirring is sufficiently until be completely dissolved；(3) filler of total system etc. is proportionally added in the system of step (2), is stirred
It mixes, disperses, wetting, dispersion or grinding are until reach standard；(4) other auxiliary agents such as initiator are added according still further to ratio in system
(3) gained, and it is fully dispersed until being completely dissolved, mixing gained.
Embodiment 5: reactive acrylate's prepolymer 30KG, reactive acrylate monomer 25KG, photoinitiator are weighed
5KG, pigment 35KG, auxiliary agent 5KG.It is prepared as described in Example 1.
The acrylic ester prepolymer is selected from epoxy acrylate, urethane acrylate, polyester acrylate, amino
Acrylate, acrylate copolymer, fluorine-containing epoxy acrylate, fluorochemical urethane acrylate, fluorine-containing polyester acrylate,
It is fluorine-containing amino acrylates, fluoro-acrylate copolymer, siliceous epoxy acrylate, silicon-based polyurethane acrylate, siliceous
Polyester acrylate, siliceous amino acrylates, silyl acrylate ester copolymer, fluosilicic epoxy acrylate, fluosilicic polyurethane
Acrylate, fluosilicic polyester acrylate, fluosilicic amino acrylates, in group composed by silicon-fluorin acrylic acid ester copolymer extremely
Few one kind.
The reactive acrylate monomer be selected from butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer EHA,
Hydroxy-ethyl acrylate HEA, hydroxyethyl methacrylate MHEA, tri (propylene glycol) diacrylate TPGDA, dipropylene glycol dipropyl
Olefin(e) acid ester DPGDA, neopentylglycol diacrylate NPGDA, the third oxidation neopentylglycol diacrylate PO-NPGDA, O-phthalic
Bis- (diethylene glycol) the diacrylate PDDA of acid, 1,6 hexanediyl ester HDDA, trimethylolpropane trimethacrylate
TMPTA, ethoxyquin trimethylolpropane trimethacrylate EO-TMODA, the third oxidation trimethylolpropane trimethacrylate PO-
At least one of group composed by TMPDA, pentaerythritol triacrylate PETA, dipentaerythritol hexaacrylate DPHA.
The reactive acrylate monomer is selected from ethoxyethoxyethyl acrylate EOEOEA, 2- phenoxy group second
Base acrylate PHEA, isobornyl acrylate IBOA, dodecyl acrylate LA, lauryl methacrylate LMA, acrylic acid ten
Octaester SA, octadecyl methacrylate SMA, tetrahydrofuran acrylate THFA, tetrahydrofuran methyl acrylate THFMA, Isosorbide-5-Nitrae
Butanediol diacrylate BDDA, phthalic acid triethylene glycol dimethacrylate PTDMA, three contracting triethylene glycol dimethyl
Acrylate TEGDMA, (4) ethoxylated bisphenol a diacrylate EO4-BPADA, (9) ethoxyquin trimethylolpropane tris third
Olefin(e) acid ester EO9-TMTA, (9) ethoxyquin trimethylol-propane trimethacrylate EO9-TMPMA, three propylene of glycerol propoxylate
Acid esters PO3-GTA, ring trimethylolpropane dimethoxym ethane acrylate CTFA, methoxy poly (ethylene glycol) (340) acrylate MPEG
(340) A, polyethylene glycol (200) diacrylate PEG (200) DA, polyethylene glycol (400) diacrylate PEG (400) DA, poly-
At least one of group composed by ethylene glycol (600) diacrylate PEG (600) DA.
The photoinitiator is selected from from benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzil two
Methyl ketal, from acetophenone, 2,2- dimethoxy -2- phenyl acetophenone, 2,2- diethoxy -2- phenyl acetophenone, 1,1- bis-
Chloro-acetophenone, 1- hydroxy acetophenone, 1- hydroxy-cyclohexyl phenyl ketone, 2- hydroxy-2-methyl -1- phenyl -1- acetone, 1- (4-
Isopropyl phenyl) -2- hydroxy-2-methyl -1- acetone, 1- [4- (2- hydroxyl-oxethyl) phenyl] -2- hydroxy-2-methyl -1- third
Ketone, 2- methyl-1-[4- (methyl mercapto) phenyl]-2- morpholinyl-1- acetone, 2- benzyl-2- dimethylamino-1- (4- morpholine
Base phenyl) -1- butanone, 2- tert-butyl anthraquinone, 1- chloroanthraquinone, 2- amyl anthraquinone, 2,4- dimethyl thioxanthone, 2,4- diethyl
Thioxanthone, 2- isopropyl thioxanthone, 4- isopropyl thioxanthone, 2- chloro thioxanthone, 2,4- diisopropyl thioxanthene
Ketone, benzophenone, 4- chlorobenzophenone, to methyl benzophenone, 4- benzoyl -4 '-dimethyl diphenyl sulfide, 2,4,6- tri-
Methyl benzoyl diphenyl phosphine oxide, bis- (2,4,6- trimethylbenzoyl)-phenyl phosphine oxides, two (2,6- dimethyl benzenes
Formoxyl) -2,4,4- trimethylpentylphosphine oxide, 2,4,6- trimethylbenzoyl phenyl ethyoxyls phosphine oxide, benzophenone
At least one of group composed by methyl formate, methyl o-benzoylbenzoate.
The pigment is: titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue, ultramarine green, phthalocyanine blue, the phthalein mountain valley with clumps of trees and bamboo
The inorganic, organic pigments such as green, brown chrome yellow, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl powder.
The filler is selected from kaolin, flatting silica, delustring slurry, abrasion-resistant powder or their mixture；
The auxiliary agent include levelling agent (such as: Efka 3033,3383, SL432 etc.), defoaming agent (such as: DEC 2700,
Efka 2018N etc.), wetting dispersing agent (such as: EFKA4010, WD264) and adhesion promoter, ultraviolet absorbing agent
The mixture of one or more of (5050,5151,951,3310 etc.), screening uv-ray agent.
Claims (2)
1. a kind of radiation curing fluosilicic coating, characterized in that the composition and content of the coating are as follows: reactive acrylate is pre-
70 wt% of polymers, reactive acrylate monomer 15wt%, photoinitiator 3wt%, pigment 7wt%, auxiliary agent 5wt%；
The radiation curing fluosilicic coating is prepared as follows: (1) will be anti-in system according to the mass ratio in total system
Answering property acrylate monomer and the mixing of reactive acrylate's prepolymer, are warming up to 50~60 DEG C, stir evenly；(2) then to
The auxiliary agent of system is added in step (1) according to ratio in total system, stirring is sufficiently until be completely dissolved；(3) again by total system
Pigment is proportionally added in the system of step (2), is stirred, and is dispersed, wetting;(4) again with three-roller or ball mill or sand milling
Machine is fully ground (3) gained, until reaching standard；(5) (4) institute is added in photoinitiator according still further to ratio in system
, and it is fully dispersed until being completely dissolved, mixing gained；
Wherein, reactive acrylate's prepolymer is by fluorine-silicon modified acrylic ester, fluorin modified crylic acid ester, fluosilicic modified propylene
Acid esters composition, the reactive acrylate monomer is by 1,6- hexanediyl ester HDDA, trimethylolpropane tris propylene
Acid esters TMPTA composition, the photoinitiator is by 2,2- dimethoxy -2- phenyl acetophenone, 2,2- diethoxy -2- phenyl benzene second
Ketone composition, the pigment are carbon black, and the auxiliary agent is wetting dispersing agent, adhesion promoter, ultraviolet absorbing agent.
2. a kind of application of radiation curing fluosilicic coating according to claim 1, it is characterized in that: can be applied to:
Inorganic board: glass industry, by primary coat processing cement fibrolite plate, calcium silicate board, magnesium oxide plate, glass magnesium board, magnesite board,
Plasterboard；
Wood base board: solid wood board, medium density fiberboard, density board, glued board, particieboard, bamboo substrate, bamboo and wood board, stalk board；
Metal substrate: volume aluminium, aluminium sheet, steel plate, iron plate, galvanized sheet；
Ceramic wafer, class ceramic wafer, pottery clay plates substrate；
Composite board: wood-plastic board, stone-plastic plate, artificial stone plate；
Plastic sheet: PVC, ABS, PC, PMMA, engineering plastic offset plate；
Flexible parent metal: textile, PVC, PU, PET flexibility plastic cement membrane material, paper substrate external coating；One kind is obtained with plate, piece
Material, the radiation curing fluosilicic colored decorating plate that membrane material is substrate.
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| WO2014097825A1 (en) * | 2012-12-18 | 2014-06-26 | 横浜ゴム株式会社 | Ultraviolet-ray-curable resin composition and laminate |
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| CN103642382A (en) * | 2013-11-25 | 2014-03-19 | 中国科学院长春应用化学研究所 | Ultraviolet light curing anti-fouling paint and preparation method thereof |
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