CN105885494A - Radiation curing silicon fluoride coating and preparation method and application thereof - Google Patents
Radiation curing silicon fluoride coating and preparation method and application thereof Download PDFInfo
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- CN105885494A CN105885494A CN201610392720.6A CN201610392720A CN105885494A CN 105885494 A CN105885494 A CN 105885494A CN 201610392720 A CN201610392720 A CN 201610392720A CN 105885494 A CN105885494 A CN 105885494A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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Abstract
The invention belongs to the field of coatings, relates to a radiation curing silicon fluoride coating and a preparation method and application thereof, and particularly discloses a radiation curing silicon fluoride coating. The coating is prepared from 30-70wt% of reactive acrylate prepolymer, 15-50wt% of reactive acrylate monomer, 3-8wt% of photoinitiator, 0-35wt% of pigment, 0-10wt% of filler and 0-5wt% of additive. Compared with the prior art, the radiation curing silicon fluoride coating has better color and pattern expressive force when carrying out surface treatment on decorative materials, has good antibacterial, anti-pollution, self-cleaning, waterproof and anti-mold properties and better weather resistance, heat resistance and mechanical performance, is wider is application range and can be widely applied to surface treatment, beautifying and protection of indoor and outdoor decoration materials.
Description
Technical field
The invention belongs to paint field, particularly to radiation curing fluosilicic coating and preparation method thereof and should
With.
Background technology
Radiation curing technology, in the application of coating industry, starts from early 1960s Bayer A.G
Curable wood coating is developed in success.Now UV technology has obtained the development advanced by leaps and bounds, especially with
The surface property of its excellence and high curing rate, low stain, the feature such as energy-conservation, become environmentally-friendly technique,
Range of application is coated with from original floor paint, woodwork coating ink till now and plastic paint, motorcycle
Material, car paint and more advanced optical fiber/optical cable, CD, solar film, flat faced display are functional
The making etc. of mummy in film, archaeology.
In China, radiation curable coating can be calculated or a new industry, and industrialization is less than 10 years,
But develop with the development speed of nearly 20% every year.Along with the raising of people's living standard, to various building dresses
Pool, decoration demand strengthen, and require more and more higher to environmental protection, energy-conservation and sustainable development etc., therefore,
Each production link to product, the requirement of the construction link of engineering is more and more higher, to product needed table
The functional requirement revealed is more and more higher, and existing radiation curable coating is difficult to meet consumer demand.
Summary of the invention
Present invention aim to overcome that the deficiencies in the prior art, it is provided that a kind of radiation curing fluosilicic coating and
Preparation method and application, its ornament materials is carried out surface process time not only color, pattern representability more
Good, and have good antibacterial, anti-soil automatically cleaning, waterproof, fungicidal properties concurrently, weather resistance, heat-resisting
Property, mechanical performance more preferably, apply the most extensive, can be widely applied to indoor, exterior decorative materials table
The process in face, beautify, protect.
To this end, the invention provides a kind of radiation curing fluosilicic coating, by the raw material of following percentage by weight
Be prepared from: reactive acrylate's prepolymer 30～70wt%, reactive acrylate monomer 15～
50wt%, light trigger 3～8wt%, pigment 0～35wt%, filler 0～10wt%, auxiliary agent 0～
5wt%.
As preferably, the composition of described coating and content is: reactive acrylate's prepolymer 30～70
Wt%, reactive acrylate monomer 20～50wt%, light trigger 3～8wt%, pigment 0～
35wt%, filler 0～10wt%, auxiliary agent 0～5wt%.
As preferably, described reactive acrylate's prepolymer is selected from epoxy acrylate, polyurethane third
Olefin(e) acid ester, polyester acrylate, amino acrylates, acrylate copolymer, fluorine-containing epoxy acrylic
Ester, fluorochemical urethane acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates, fluorine-containing third
Olefin(e) acid ester copolymer, siliceous epoxy acrylate, silicon-based polyurethane acrylate, Silicon-containing Polyester acrylic acid
Ester, siliceous amino acrylates, silyl acrylate ester copolymer, fluosilicic epoxy acrylate, fluosilicic are poly-
Urethane acrylate, fluosilicic polyester acrylate, fluosilicic amino acrylates, silicon-fluorin acrylic acid ester copolymerization
At least one in the group that thing is formed.
As preferably, described reactive acrylate monomer is selected from described reactive acrylate monomer
Selected from butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer EHA, 2-(Acryloyloxy)ethanol HEA,
Hydroxyethyl methylacrylate MHEA, tri (propylene glycol) diacrylate TPGDA, dipropylene glycol two
Acrylate DPGDA, neopentylglycol diacrylate NPGDA, the third oxidation neopentyl glycol diacrylate
Double (diethylene glycol) the diacrylate PDDA of ester PO-NPGDA, phthalic acid, 1,6 two
Alcohol diacrylate HDDA, trimethylolpropane trimethacrylate TMPTA, ethoxyquin trihydroxy methyl
Propane triacrylate EO-TMODA, third oxidation trimethylolpropane trimethacrylate PO-TMPDA,
In the group that pentaerythritol triacrylate PETA, dipentaerythritol acrylate DPHA are formed
At least one.
As preferably, described reactive acrylate monomer is selected from ethoxyethoxyethyl acrylate
EOEOEA, 2-phenoxyethyl acrylate PHEA, isobornyl acrylate IBOA, acrylic acid ten
Diester LA, lauryl methacrylate LMA, octadecyl acrylate SA, octadecyl methacrylate
SMA, oxolane acrylate THFA, tetrahydrofuran methyl acrylate THFMA, Isosorbide-5-Nitrae fourth
Omega-diol diacrylate BDDA, phthalic acid TEGDMA PTDMA, three
Contracting TEGDMA TEGDMA, (4) ethoxylated bisphenol a diacrylate
EO4-BPADA, (9) ethoxyquin trimethylolpropane trimethacrylate EO9-TMTA, (9) ethoxy
Change trimethylol-propane trimethacrylate EO9-TMPMA, glycerol propoxylate triacrylate
PO3-GTA, ring trimethylolpropane dimethoxym ethane acrylate CTFA, methoxy poly (ethylene glycol) (340)
Acrylate MPEG (340) A, Polyethylene Glycol (200) diacrylate PEG (200) DA, poly-second two
Alcohol (400) diacrylate PEG (400) DA, Polyethylene Glycol (600) diacrylate PEG (600) DA
At least one in the group formed.
As preferably, described light trigger is selected from from benzoin methyl ether, benzoin ethyl ether, benzene occasionally
Relation by marriage isopropyl ether, benzil dimethyl ketal, from 1-Phenylethanone., 2,2-dimethoxy-2-phenyl acetophenone,
2,2-diethoxy-2-phenyl acetophenone, 1,1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxyl ring
Base phenyl ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxyl
Base-2-methyl isophthalic acid-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone,
2-methyl isophthalic acid-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, 2-benzyl-2-dimethylamino
-1-(4-morpholino phenyl)-1-butanone, 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone, 2,4-
Dimethyl thioxanthone, 2,4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone
Anthrone, 2-chloro thioxanthone, 2,4-diisopropyl thioxanthone, benzophenone, 4-chlorodiphenyl first
Ketone, to methyl benzophenone, 4-benzoyl-4 '-dimethyl diphenyl sulfide, 2,4,6-trimethylbenzene
Formoxyl diphenyl phosphine oxide, double (2,4,6-trimethylbenzoyl)-phenyl phosphine oxide, two (2,6-
Dimethylbenzoyl)-2,4,4-trimethylpentylphosphine oxide, 2,4,6-trimethylbenzoyl phenyl
In the group that ethyoxyl phosphine oxide, methyl benzoylbenzoate, methyl o-benzoylbenzoate are formed extremely
Few one.
As preferably, described pigment is: titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine
Indigo plant, ultramarine green, phthalocyanine blue, phthalein mountain valley with clumps of trees and bamboo chrome yellow green, brown, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence
Etc. inorganic, organic pigment.
As preferably, described filler selected from Kaolin, flatting silica, delustring slurry, abrasion-resistant powder or they
Mixture；Described auxiliary agent includes levelling agent, defoamer, wetting dispersing agent, adhesion promoter, purple
One or more mixture in ultraviolet absorbers, screening uv-ray agent etc..
The preparation method of a kind of radiation curing fluosilicic coating, by reactive acrylate's prepolymer, reactivity
Acrylate monomer, auxiliary agent, pigment, filler mix, and stir, disperse, and grind, add light
Initiator, it is stirred for, disperses, filter, obtain described radiation curing fluosilicic coating.
The radiation curing fluosilicic coating of the present invention can be applicable to category of glass: float glass, safety glass, half
Safety glass, laminated glass, typhoon protection glass, bulletproof glass, building imitate curtain wall plexiglas, wired
Glass, pattern glass, glass scape brick, glass Mosaic, solar photovoltaic assembly anti reflection glass；Merit
Energy property glass: the glass such as heat-protecting glass, antibiotic glass, self-cleaning glass, safety glass, uvioresistant glass
Glass substrate；Inorganic board class: cement fibrolite plate, calcium silicate board, magnesium oxide plate, glass magnesium board, magnesite board,
Plasterboard etc.；Solid wood board, MDF, plywood, particieboard, density board, bamboo substrate, bamboo wood combine
The wood base board such as plate, stalk board；The metal basal boards such as volume aluminum, aluminium sheet, steel plate, iron plate, galvanized sheet；Pottery
The substrates such as plate, class ceramic wafer, pottery clay plates；The composite boards such as wood-plastic board, stone-plastic plate, artificial stone plate；
The plastic sheets such as PVC, ABS, PC, PMMA, engineering plastic offset plate；Flexible parent metal: textile, PVC,
The substrate surfaces such as flexible plastic film material, the paper such as PU, PET.
Compared with prior art, the present invention mainly adds that fluosilicic is acrylic resin modified, fluorine-silicon modified acrylic
Resin and fluorin modified crylic acid resin and the most effective collocation thereof can more efficient raising paint film resistance to
Time performance, mechanical performance, high-fire resistance energy, high-chemical-resistance, high-low temperature resistant are poor, oxidation resistent susceptibility,
Low surface energy, low surface tension, there is hydrophobic, oleophobic performance, and self-cleaning function, have the widest
General application and space；As large arch dam, the environmental protection of extremely low VOC emission, energy-conservation, efficient
New coating will replace existing traditional coating.Fluosilicic therein is acrylic resin modified, Si modification propylene
Acid resin and fluorin modified crylic acid resin and other acrylic polymers, acrylic monomers are at radiation curing
React under the conditions of the mechanism of (ultraviolet light polymerization or electronic beam curing) and form silicon, fluorine is arranged in surface
Fine and close macromolecular network structure paint film, in performance its effectively gathered traditional fluorocarbon coating and
The respective advantage of organosilicon coating, it carries out the table of not only color, pattern when surface processes to ornament materials
Existing power is more preferable, and has good antibacterial, anti-soil automatically cleaning, waterproof, fungicidal properties concurrently, weather resistance,
Thermostability, mechanical performance more preferably, apply the most extensive, can be widely applied to indoor, exterior decoration material
The process on material surface, beautify, protect.
Detailed description of the invention
Embodiment 1: weigh the raw material of following percentage by weight: reactive acrylate prepolymer 70KG,
Reactive acrylate monomer 15KG, light trigger 3KG, pigment 7KG, auxiliary agent 5KG.By following
Prepared by method: the acrylate monomer in system and silicon are changed by (1) according to the mass ratio in total system
Property acrylate is or/and fluorin modified crylic acid ester is or/and fluosilicic modification acrylate, acrylic ester prepolymer
Mixing, is warming up to 50～60 DEG C, stirs；(2) then in step (1) according in total system
Ratio adds the part of auxiliary of system, and stirring is fully until being completely dissolved；(3) filling out total system again
Material, pigment etc. proportionally join in the system of step (2), stirring, dispersion, moistening；(4) again
With three-roller or the milling apparatus such as ball mill or sand mill, (3rd) gained is fully ground until
Reach standard；(5) according still further to ratio in system, other auxiliary agents such as initiator are added (4) gained, and
Fully dispersed until being completely dissolved, mix gained.
Wherein: reactive acrylate's prepolymer is by fluorine-silicon modified acrylic ester, fluorin modified crylic acid ester, silicon
Fluorin modified crylic acid ester form, reactive acrylate monomer by 1,6 hexanediyl ester HDDA,
Trimethylolpropane trimethacrylate TMPTA form, described light trigger by 2,2-dimethoxy-2-
Phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone form, pigment is carbon black, and auxiliary agent is moistening
Dispersant, adhesion promoter, UV absorbent.
Embodiment 2: weigh reactive acrylate prepolymer 30KG, reactive acrylate monomer
50KG, light trigger 8KG, filler 7KG, auxiliary agent 5KG.It is prepared by the following method: (1)
According to the mass ratio in total system by the acrylate monomer in system and fluorine-silicon modified acrylic ester or fluorine
Modification acrylate or fluosilicic modification acrylate, acrylic ester prepolymer mixing, be warming up to 50～60
DEG C, stir；(2) in step (1), the part of system is then added according to ratio in total system
Auxiliary agent, stirring is fully until being completely dissolved；(3) filler etc. of total system is proportionally joined step
Suddenly in the system of (2), stirring, dispersion, moistening, disperses or grinds until reaching standard；(4) again
According to ratio in system other auxiliary agents such as initiator are added (3) gained, and fully dispersed until completely
Dissolve, mix gained.
Embodiment 3: weigh reactive acrylate prepolymer 50KG, reactive acrylate monomer
46KG, light trigger 4KG.It is prepared by the following method: (1) is according to the mass ratio in total system
Acrylate monomer in system and fluorine-silicon modified acrylic ester or fluorin modified crylic acid ester or fluosilicic are changed by example
Property acrylate, acrylic ester prepolymer mixing, be warming up to 50～60 DEG C, stir；(2) again
According to ratio in system, initiator is added (1) gained, and fully dispersed until being completely dissolved, mix institute
?.
Embodiment 4: weigh reactive acrylate prepolymer 60KG, reactive acrylate monomer
20KG, light trigger 7KG, filler 10KG, auxiliary agent 3KG, be prepared by the following method: (1)
According to the mass ratio in total system by the acrylate monomer in system and fluorine-silicon modified acrylic ester or fluorine
Modification acrylate or fluosilicic modification acrylate, acrylic ester prepolymer mixing, be warming up to 50～60
DEG C, stir；(2) in step (1), the part of system is then added according to ratio in total system
Auxiliary agent, stirring is fully until being completely dissolved；(3) filler etc. of total system is proportionally joined step
Suddenly in the system of (2), stirring, dispersion, moistening, disperses or grinds until reaching standard；(4) again
According to ratio in system other auxiliary agents such as initiator are added (3) gained, and fully dispersed until completely
Dissolve, mix gained.
Embodiment 5: weigh reactive acrylate prepolymer 30KG, reactive acrylate monomer
25KG, light trigger 5KG, pigment 35KG, auxiliary agent 5KG.Make as described in Example 1
Standby.
Described acrylic ester prepolymer is selected from epoxy acrylate, urethane acrylate, polyester third
Olefin(e) acid ester, amino acrylates, acrylate copolymer, fluorine-containing epoxy acrylate, fluorochemical urethane
Acrylate, fluorine-containing polyester acrylate, fluorine-containing amino acrylates, fluoro-acrylate copolymer,
Siliceous epoxy acrylate, silicon-based polyurethane acrylate, Silicon-containing Polyester acrylate, siliceous aminopropan
Olefin(e) acid ester, silyl acrylate ester copolymer, fluosilicic epoxy acrylate, fluosilicic urethane acrylate,
In the group that fluosilicic polyester acrylate, fluosilicic amino acrylates, silicon-fluorin acrylic acid ester copolymer are formed
At least one.
Described reactive acrylate monomer is different selected from butyl acrylate, cyclohexyl acrylate, acrylic acid
Monooctyl ester EHA, 2-(Acryloyloxy)ethanol HEA, hydroxyethyl methylacrylate MHEA, tripropylene glycol
Diacrylate TPGDA, propylene glycol diacrylate DPGDA, neopentylglycol diacrylate
NPGDA, the third oxidation neopentylglycol diacrylate PO-NPGDA, the double (diethyl two of phthalic acid
Alcohol) diacrylate PDDA, 1,6 hexanediyl ester HDDA, trimethylolpropane tris third
Olefin(e) acid ester TMPTA, ethoxyquin trimethylolpropane trimethacrylate EO-TMODA, the third oxidation three hydroxyls
Propane tri PO-TMPDA, pentaerythritol triacrylate PETA, dipentaerythritol
At least one in the group that six acrylate DPHA are formed.
Described reactive acrylate monomer selected from ethoxyethoxyethyl acrylate EOEOEA,
2-phenoxyethyl acrylate PHEA, isobornyl acrylate IBOA, dodecyl acrylate LA,
Lauryl methacrylate LMA, octadecyl acrylate SA, octadecyl methacrylate SMA, tetrahydrochysene
Furanacrylate THFA, tetrahydrofuran methyl acrylate THFMA, Isosorbide-5-Nitrae butanediol two propylene
Acid esters BDDA, phthalic acid TEGDMA PTDMA, three contracting triethylene glycols
Dimethylacrylate TEGDMA, (4) ethoxylated bisphenol a diacrylate EO4-BPADA,
(9) ethoxyquin trimethylolpropane trimethacrylate EO9-TMTA, (9) ethoxyquin trihydroxy methyl third
Alkane trimethyl acrylic ester EO9-TMPMA, glycerol propoxylate triacrylate PO3-GTA, ring three
Hydroxymethyl-propane dimethoxym ethane acrylate CTFA, methoxy poly (ethylene glycol) (340) acrylate
MPEG (340) A, Polyethylene Glycol (200) diacrylate PEG (200) DA, Polyethylene Glycol (400)
Diacrylate PEG (400) DA, Polyethylene Glycol (600) diacrylate PEG (600) DA are formed
Group at least one.
Described light trigger is selected from from benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl
Ether, benzil dimethyl ketal, from 1-Phenylethanone., 2,2-dimethoxy-2-phenyl acetophenone, 2,2-bis-
Ethyoxyl-2-phenyl acetophenone, 1,1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl benzene
Base ketone, 2-hydroxy-2-methyl-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxyl-2-
Methyl isophthalic acid-acetone, 1-[4-(2-hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-first
Base-1-[4-(methyl mercapto) phenyl]-2-morpholinyl-1-acetone, 2-benzyl-2-dimethylamino-1-
(4-morpholino phenyl)-1-butanone, 2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone, 2,4-
Dimethyl thioxanthone, 2,4-diethyl thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone
Anthrone, 2-chloro thioxanthone, 2,4-diisopropyl thioxanthone, benzophenone, 4-chlorodiphenyl first
Ketone, to methyl benzophenone, 4-benzoyl-4 '-dimethyl diphenyl sulfide, 2,4,6-trimethylbenzene
Formoxyl diphenyl phosphine oxide, double (2,4,6-trimethylbenzoyl)-phenyl phosphine oxide, two (2,6-
Dimethylbenzoyl)-2,4,4-trimethylpentylphosphine oxide, 2,4,6-trimethylbenzoyl phenyl
In the group that ethyoxyl phosphine oxide, methyl benzoylbenzoate, methyl o-benzoylbenzoate are formed extremely
Few one.
Described pigment is: titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue, ultramarine green,
Phthalocyanine blue, phthalein mountain valley with clumps of trees and bamboo chrome yellow green, brown, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence etc. are inorganic, organic
Pigment.
Described filler is selected from Kaolin, flatting silica, delustring slurry, abrasion-resistant powder or their mixture；
Described auxiliary agent includes levelling agent (such as: EFKA 3033,3383, SL432 etc.), defoamer
(such as: DEC 2700, EFKA 2018N etc.), wetting dispersing agent are (such as: EFKA4010, WD264
Deng) and adhesion promoter, UV absorbent (5050,5151,951,3310 etc.), ultraviolet
One or more mixture in line screening agent.
Claims (10)
1. a radiation curing fluosilicic coating, is characterized in that, the composition of described coating and content is: anti-
Answering property acrylic ester prepolymer 30～70wt%, reactive acrylate monomer 15～50wt%, light-initiated
Agent 3～8wt%, pigment 0～35wt%, filler 0～10wt%, auxiliary agent 0～5wt%.
Radiation curing fluosilicic coating the most according to claim 1, is characterized in that, described coating
Form and content is: reactive acrylate's prepolymer 30～70wt%, reactive acrylate monomer
20～50wt%, light trigger 3～8wt%, pigment 0～35wt%, filler 0～10wt%, help
Agent 0～5wt%.
Radiation curing fluosilicic coating the most according to claim 2, is characterized in that: described reactivity
Acrylic ester prepolymer is selected from epoxy acrylate, urethane acrylate, polyester acrylate, amino
Acrylate, acrylate copolymer, fluorine-containing epoxy acrylate, fluorochemical urethane acrylate, contain
Fluorine polyester acrylate, fluorine-containing amino acrylates, fluoro-acrylate copolymer, siliceous propylene oxide
Acid esters, silicon-based polyurethane acrylate, Silicon-containing Polyester acrylate, siliceous amino acrylates, siliceous
Acrylate copolymer, fluosilicic epoxy acrylate, fluosilicic urethane acrylate, fluosilicic polyester
At least one in the group that acid esters, fluosilicic amino acrylates, silicon-fluorin acrylic acid ester copolymer are formed.
Radiation curing fluosilicic coating the most according to claim 2, is characterized in that: described reactivity
Acrylate monomer is selected from butyl acrylate, cyclohexyl acrylate, Isooctyl acrylate monomer EHA, acrylic acid
Hydroxyl ethyl ester HEA, hydroxyethyl methylacrylate MHEA, tri (propylene glycol) diacrylate TPGDA,
Propylene glycol diacrylate DPGDA, neopentylglycol diacrylate NPGDA, the third oxidation new penta 2
Double (diethylene glycol) the diacrylate PDDA of alcohol diacrylate PO-NPGDA, phthalic acid,
1,6 hexanediyl ester HDDA, trimethylolpropane trimethacrylate TMPTA, ethoxyquin
Trimethylolpropane trimethacrylate EO-TMODA, the third oxidation trimethylolpropane trimethacrylate
PO-TMPDA, pentaerythritol triacrylate PETA, dipentaerythritol acrylate DPHA institute
At least one in the group of composition.
Radiation curing fluosilicic coating the most according to claim 2, is characterized in that: described reactivity
Acrylate monomer is selected from ethoxyethoxyethyl acrylate EOEOEA, 2-Phenoxyethyl propylene
Acid esters PHEA, isobornyl acrylate IBOA, dodecyl acrylate LA, lauryl methacrylate
LMA, octadecyl acrylate SA, octadecyl methacrylate SMA, oxolane acrylate THFA,
Tetrahydrofuran methyl acrylate THFMA, Isosorbide-5-Nitrae butanediol diacrylate BDDA, O-phthalic
Triethylenetetraminehexaacetic acid diol dimethacrylate PTDMA, three contracting TEGDMAs
TEGDMA, (4) ethoxylated bisphenol a diacrylate EO4-BPADA, (9) ethoxyquin three
Hydroxymethyl-propane triacrylate EO9-TMTA, (9) ethoxyquin trimethylol propane trimethyl acrylic acid
Ester EO9-TMPMA, glycerol propoxylate triacrylate PO3-GTA, ring trimethylolpropane first contract
Aldehyde acrylate CTFA, methoxy poly (ethylene glycol) (340) acrylate MPEG (340) A, poly-second two
Alcohol (200) diacrylate PEG (200) DA, Polyethylene Glycol (400) diacrylate PEG (400) DA,
At least one in the group that Polyethylene Glycol (600) diacrylate PEG (600) DA is formed.
Radiation curing fluosilicic coating the most according to claim 2, is characterized in that: described is light-initiated
Agent is selected from from benzoin methyl ether, benzoin ethyl ether, benzoin isopropyl ether, benzil dimethyl contracting
Ketone, from 1-Phenylethanone., 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone,
1,1-dichloroacetophenone, 1-hydroxy acetophenone, 1-hydroxy-cyclohexyl phenyl ketone, 2-hydroxy-2-methyl
-1-phenyl-1-acetone, 1-(4-isopropyl phenyl)-2-hydroxy-2-methyl-1-acetone, 1-[4-(2-
Hydroxyl-oxethyl) phenyl]-2-hydroxy-2-methyl-1-acetone, 2-methyl isophthalic acid-[4-(methyl mercapto) benzene
Base]-2-morpholinyl-1-acetone, 2-benzyl-2-dimethylamino-1-(4-morpholino phenyl)-1-butanone,
2-tert-butyl group anthraquinone, 1-chloroanthraquinone, 2-amyl anthraquinone, 2,4-dimethyl thioxanthone, 2,4-diethyl
Thioxanthone, 2-isopropyl thioxanthone, 4-isopropyl thioxanthone, 2-chloro thioxanthone, 2,4-
Diisopropyl thioxanthone, benzophenone, 4-chlorobenzophenone, to methyl benzophenone, 4-benzoyl
Base-4 '-dimethyl diphenyl sulfide, 2,4,6-trimethyl benzoyl diphenyl base phosphine oxide, double (2,4,6-
Trimethylbenzoyl)-phenyl phosphine oxide, two (2,6-dimethylbenzoyl)-2,4,4-trimethyl
Amyl group phosphine oxide, 2,4,6-trimethylbenzoyl phenyl ethyoxyl phosphine oxide, methyl benzoylbenzoate,
At least one in the group that methyl o-benzoylbenzoate is formed.
Radiation curing fluosilicic coating the most according to claim 2, is characterized in that: described pigment is:
Titanium dioxide, carbon black, iron oxide red, iron oxide yellow, ultramarine blue, ultramarine green, phthalocyanine blue, the phthalein mountain valley with clumps of trees and bamboo be green,
Palm fibre inorganic, the organic pigment such as chrome yellow, bright red, Cu-Zn alloy powder, aluminum paste powder, pearl essence.
Radiation curing fluosilicic coating the most according to claim 2, is characterized in that: described filler choosing
From Kaolin, flatting silica, delustring slurry, abrasion-resistant powder or their mixture；Described auxiliary agent includes levelling
Agent, defoamer, wetting dispersing agent, adhesion promoter, UV absorbent, screening uv-ray agent etc.
In one or more mixture.
9. the preparation side according to the radiation curing fluosilicic coating described in claim 1～7 any one
Method, is characterized in that: by reactive acrylate's prepolymer, reactive acrylate monomer, auxiliary agent, face
The mixing of material, filler, stirs, disperses, and grinds, and adds light trigger, is stirred for, disperses,
Filter, obtain described radiation curing fluosilicic coating.
10. an application for radiation curing fluosilicic coating according to claim 2, is characterized in that: can
It is applied to: glass industry, the cement fibrolite plate through primary coat process, calcium silicate board, magnesium oxide plate, glass
The inorganic board such as magnesium plate, magnesite board, plasterboard；Solid wood board, MDF, density board, plywood, wood shavings
The wood base boards such as plate, bamboo substrate, bamboo wood board, stalk board；Volume aluminum, aluminium sheet, steel plate, iron plate, plating
The metal basal boards such as zine plate；The substrates such as ceramic wafer, class ceramic wafer, pottery clay plates；Wood-plastic board, stone-plastic plate, people
Make the composite boards such as slabstone；The plastic sheets such as PVC, ABS, PC, PMMA, engineering plastic offset plate；
Flexible parent metal: the substrate surface applications such as flexible plastic film material, the paper such as textile, PVC, PU, PET；
Obtain a kind of radiation curing fluosilicic colored decorating plate etc. with sheet material, sheet material, film material as base material.
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