CN105860685A - Styrene-acrylic waterproof paint capable of emitting noctilucence and preparation method thereof - Google Patents

Styrene-acrylic waterproof paint capable of emitting noctilucence and preparation method thereof Download PDF

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Publication number
CN105860685A
CN105860685A CN201610409363.XA CN201610409363A CN105860685A CN 105860685 A CN105860685 A CN 105860685A CN 201610409363 A CN201610409363 A CN 201610409363A CN 105860685 A CN105860685 A CN 105860685A
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China
Prior art keywords
parts
styrene
waterproof paint
rotating speed
noctilucence
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Pending
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CN201610409363.XA
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Chinese (zh)
Inventor
蒋能
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Anhui Kuailai Waterproofing & Anti-Corrosion Co Ltd
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Anhui Kuailai Waterproofing & Anti-Corrosion Co Ltd
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Priority to CN201610409363.XA priority Critical patent/CN105860685A/en
Publication of CN105860685A publication Critical patent/CN105860685A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses styrene-acrylic waterproof paint capable of emitting noctilucence and a preparation method thereof. The styrene-acrylic waterproof paint is prepared from, by weight, 95-115 parts of styrene-acrylic emulsion with the solid content of 45%, 12-16 parts of rosin-modified phenolic resin, 1-2 parts of rhamnolipid, 8-12 parts of periclase, 5-10 parts of gold ore tailings, 30-40 parts of turpentine, 4-7 parts of aluminium hydroxy distearate, 1.5-2.5 parts of ammonium polyacryloyldimethyl taurate, 2-3 parts of sodium polystyrene sulfonate, 3-5 parts of zinc sulfide, 4-6 parts of strontium sulfide, 2-4 parts of calcium tungstate, 5-7 parts of magnesium gallate, 4-8 parts of pitchstone and 5-9 parts of coal gangue. According to the waterproof paint, the added raw materials such as zinc sulfide, strontium sulfide, calcium tungstate and magnesium gallate can improve the luminescence property of the waterproof paint, and therefore the waterproof paint can achieve the good noctilucence effects, in addition, brightness is high, the duration time is long at night, and the styrene-acrylic waterproof paint can be widely applied to the fields of architectural decoration, transportation facilities, military facilities, fire emergency systems and the like.

Description

A kind of phenylpropyl alcohol water-repellent paint sending out noctilucence and preparation method thereof
Technical field
The present invention relates to a kind of phenylpropyl alcohol water-repellent paint sending out noctilucence and preparation method thereof, belong to water-repellent paint field.
Background technology
The water-repellent paint used in architectural engineering becomes building water-proof paint, referred to as water-repellent paint, is by coating Construction and form one layer of general name with the repellent membrane mate-rials of water resistance, be with waterproof, moistureproof, antiseepage, leakproof be main The functional type building coating of purpose.Building water-proof paint is with synthesis macromolecule, Colophonium, polymer modified asphalt, inorganic material etc. For main body, mix appropriate auxiliary agent, material modified, packing material etc. and be processed into.Compared with waterproof roll, water-repellent paint is constructed Simple and convenient, it is adaptable to the basal plane of any shape, and fine and close seamless film can be formed, therefore, water-repellent paint has been widely used In various waterproofing works.Along with the fast development of Architectural Paint in China, the harshest to the performance requirement of water-repellent paint.At present The water-repellent paint that can send out noctilucence on market also has certain deficiency, the shortcoming that there is also illumination effect difference.
Summary of the invention
In order to overcome above-mentioned deficiency, the invention provides a kind of phenylpropyl alcohol water-repellent paint sending out noctilucence and preparation side thereof Method.The water-repellent paint illumination effect that the present invention prepares is good, and brightness is high, and the persistent period is long.
For achieving the above object, the present invention adopts the following technical scheme that:
A kind of phenylpropyl alcohol water-repellent paint sending out noctilucence, is made up of the raw material of following weight portion: solid content is the phenylpropyl alcohol of 45% Emulsion 95-115, rosin modified phenolic resin 12-16, rhamnolipid 1-2, periclase 8-12, gold ore tailing 5-10, Oleum Terebinthinae 30-40, aluminium hydroxy distearate 4-7, polypropylene acyl group dimethyltaurine ammonium 1.5-2.5, polyethers epoxy co-modified silicone oil 5- 10, sierozem power 3-6, kayexalate 2-3, zinc sulfide 3-5, strontium sulfide 4-6, artificial schellite 2-4, gallium acid magnesium 5-7, cocos nucifera oil acyl Monoethanolamine polyethenoxy ether 1-2, pitchstone 4-8, gangue 5-9.
The preparation method of a kind of phenylpropyl alcohol water-repellent paint sending out noctilucence, comprises the following steps:
(1) by periclase, gold ore tailing, pitchstone, gangue mix homogeneously, pulverizing, sieve, then heating is fused into molten Melt liquid, put into after stirring and clear water carries out shrend, de-dry；The glass particle material obtained is pulverized, sieves, Under the rotating speed of 8000-10000r/min, ball milling 1-2h, sieves, then with nitrogen for current-carrying gas by dried powder body according to giving Powder amount is that 220-260g/min sends in balling furnace oxygen-acetylene flame stream, and current-carrying gas nitrogen flow rate is 40-50L/min；Oxygen In gas-natural bluster stream, oxygen flow is 55-65L/min, and gas discharge is 70-80L/min；Drop after nodularization leaves height Warm fire flame cools down behind field, then through cyclone collection, obtains spherical glass powder；
(2) the spherical glass powder obtained is mixed homogeneously with sierozem power, zinc sulfide, strontium sulfide, artificial schellite, gallium acid magnesium, so After add water stirring make the suspension that concentration is 50-55%, be subsequently adding kayexalate and polypropylene acyl group dimethyl Taurine ammonium, stirs 15-20min under the rotating speed of 2000-3000r/min, filters, dry；
(3) Oleum Terebinthinae is added in blender, add rhamnolipid and coconut palm oleoyl monoethanolamine polyethenoxy ether, fully Stir, be subsequently adding the epoxy co-modified silicone oil of rosin modified phenolic resin, aluminium hydroxy distearate and polyethers, at 500- Stir 2-3min under the rotating speed of 600r/min, add styrene-acrylic emulsion, under the rotating speed of 400-500r/min, stir 2-3min, Raw material after the drying of rear addition step (2), stirs 3-6min under the rotating speed of 700-800r/min, gets product.
Beneficial effects of the present invention:
The zinc sulfide that adds in water-repellent paint of the present invention, strontium sulfide, artificial schellite, the raw material such as gallium acid magnesium, can increase waterproof The luminescent properties of coating so that water-repellent paint can send good luminous effect at night, and brightness is high, and the persistent period is long, Can be widely applied to the fields such as building decoration, means of transport, military installations, fire-fighting emergent system.
Detailed description of the invention
A kind of phenylpropyl alcohol water-repellent paint sending out noctilucence, is made up of the raw material of following weight (kg): solid content is the benzene of 45% The acid of acrylic emulsion 110, rosin modified phenolic resin 14, rhamnolipid 1.5, periclase 10, gold ore tailing 8, Oleum Terebinthinae 35, distearyl Hydroxy Al 5, polypropylene acyl group dimethyltaurine ammonium 2, the epoxy co-modified silicone oil of polyethers 8, sierozem power 4.5, polystyrolsulfon acid Sodium 2.5, zinc sulfide 4, strontium sulfide 5, artificial schellite 3, gallium acid magnesium 6, coconut palm oleoyl monoethanolamine polyethenoxy ether 1.5, pitchstone 6, coal Spoil 7.
The preparation method of a kind of phenylpropyl alcohol water-repellent paint sending out noctilucence, comprises the following steps:
(1) by periclase, gold ore tailing, pitchstone, gangue mix homogeneously, pulverizing, sieve, then heating is fused into molten Melt liquid, put into after stirring and clear water carries out shrend, de-dry；The glass particle material obtained is pulverized, sieves, Under the rotating speed of 9000r/min, ball milling 1.5h, sieves, and then with nitrogen for current-carrying gas by dried powder body according to powder sending quantity is 240g/min sends in balling furnace oxygen-acetylene flame stream, and current-carrying gas nitrogen flow rate is 45L/min；In oxygen-natural bluster stream Oxygen flow is 60L/min, and gas discharge is 75L/min；Drop after nodularization cools down after leaving thermal-flame field, then Through cyclone collection, obtain spherical glass powder；
(2) the spherical glass powder obtained is mixed homogeneously with sierozem power, zinc sulfide, strontium sulfide, artificial schellite, gallium acid magnesium, so After add water stirring make the suspension that concentration is 52%, be subsequently adding kayexalate and polypropylene acyl group dimethyl cattle sulphur Acid ammonium, stirs 18min under the rotating speed of 2500r/min, filters, dry；
(3) Oleum Terebinthinae is added in blender, add rhamnolipid and coconut palm oleoyl monoethanolamine polyethenoxy ether, fully Stir, be subsequently adding the epoxy co-modified silicone oil of rosin modified phenolic resin, aluminium hydroxy distearate and polyethers, at 600r/ Stir 2min under the rotating speed of min, add styrene-acrylic emulsion, under the rotating speed of 400r/min, stir 3min, be eventually adding step (2) Raw material after drying, stirs 4min under the rotating speed of 750r/min, gets product.
The performance test results of the water-repellent paint that above-described embodiment is produced is as shown in the table:

Claims (2)

1. the phenylpropyl alcohol water-repellent paint that can send out noctilucence, it is characterised in that be made up of the raw material of following weight portion: solid content is The styrene-acrylic emulsion 95-115 of 45%, rosin modified phenolic resin 12-16, rhamnolipid 1-2, periclase 8-12, gold ore tailing 5- 10, Oleum Terebinthinae 30-40, aluminium hydroxy distearate 4-7, polypropylene acyl group dimethyltaurine ammonium 1.5-2.5, polyethers epoxy change altogether Property silicone oil 5-10, sierozem power 3-6, kayexalate 2-3, zinc sulfide 3-5, strontium sulfide 4-6, artificial schellite 2-4, gallium acid magnesium 5- 7, coconut palm oleoyl monoethanolamine polyethenoxy ether 1-2, pitchstone 4-8, gangue 5-9.
2. the preparation method of the phenylpropyl alcohol water-repellent paint that can send out noctilucence as claimed in claim 1, it is characterised in that include with Lower step:
(1) by periclase, gold ore tailing, pitchstone, gangue mix homogeneously, pulverizing, sieve, then heating is fused into melted Liquid, puts into after stirring and carries out shrend in clear water, de-dry；The glass particle material obtained is pulverized, sieves, Under the rotating speed of 8000-10000r/min, ball milling 1-2h, sieves, then with nitrogen for current-carrying gas by dried powder body according to giving Powder amount is that 220-260g/min sends in balling furnace oxygen-acetylene flame stream, and current-carrying gas nitrogen flow rate is 40-50L/min；Oxygen In gas-natural bluster stream, oxygen flow is 55-65L/min, and gas discharge is 70-80L/min；Drop after nodularization leaves height Warm fire flame cools down behind field, then through cyclone collection, obtains spherical glass powder；
(2) the spherical glass powder obtained is mixed homogeneously with sierozem power, zinc sulfide, strontium sulfide, artificial schellite, gallium acid magnesium, then add The suspension that concentration is 50-55% is made in water stirring, is subsequently adding kayexalate and polypropylene acyl group dimethyltaurine Ammonium, stirs 15-20min under the rotating speed of 2000-3000r/min, filters, dry；
(3) Oleum Terebinthinae is added in blender, add rhamnolipid and coconut palm oleoyl monoethanolamine polyethenoxy ether, be sufficiently stirred for Uniformly, it is subsequently adding the epoxy co-modified silicone oil of rosin modified phenolic resin, aluminium hydroxy distearate and polyethers, at 500-600r/ Stir 2-3min under the rotating speed of min, add styrene-acrylic emulsion, under the rotating speed of 400-500r/min, stir 2-3min, finally add Enter the raw material after step (2) is dried, under the rotating speed of 700-800r/min, stir 3-6min, get product.
CN201610409363.XA 2016-06-12 2016-06-12 Styrene-acrylic waterproof paint capable of emitting noctilucence and preparation method thereof Pending CN105860685A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116463045A (en) * 2023-04-24 2023-07-21 广州碧家索建材有限公司 Ash rubber waterproof coating and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN104987791A (en) * 2015-06-30 2015-10-21 芜湖县双宝建材有限公司 Environment-friendly waterproof coating and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386719A (en) * 2008-08-28 2009-03-18 冯守中 Multifunctional coatings and preparation method thereof
CN104987791A (en) * 2015-06-30 2015-10-21 芜湖县双宝建材有限公司 Environment-friendly waterproof coating and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《中国化学教师手册》编写组编: "《中学化学教师手册》", 31 December 1985, 上海教育出版社 *
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陈树川等: "《材料物理性能》", 30 September 1999, 上海交通大学出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116463045A (en) * 2023-04-24 2023-07-21 广州碧家索建材有限公司 Ash rubber waterproof coating and preparation method thereof
CN116463045B (en) * 2023-04-24 2024-02-02 广州碧家索建材有限公司 Ash rubber waterproof coating and preparation method thereof

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Application publication date: 20160817