CN105851025A - Insecticide for controlling Ampelophaga rubiginosa - Google Patents
Insecticide for controlling Ampelophaga rubiginosa Download PDFInfo
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- CN105851025A CN105851025A CN201610300321.2A CN201610300321A CN105851025A CN 105851025 A CN105851025 A CN 105851025A CN 201610300321 A CN201610300321 A CN 201610300321A CN 105851025 A CN105851025 A CN 105851025A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N45/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds having three or more carbocyclic rings condensed among themselves, at least one ring not being a six-membered ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
- A01N35/04—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing aldehyde or keto groups, or thio analogues thereof, directly attached to an aromatic ring system, e.g. acetophenone; Derivatives thereof, e.g. acetals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an insecticide, in particular to an insecticide for controlling Ampelophaga rubiginosa. The insecticide is prepared from 2-allyloxyethanol, N,N-dimethylaminoethanol acrylate, 17a-methyl-17b-hydroxy-androst-4-en-3-one, cis-2-butene-1,4-diol, (2alpha, 3beta)-2,3-bis(acetyloxy)-urs-12-en-28-oic acid and the like. The insecticide for controlling Ampelophaga rubiginosa is simple in preparation method, good in Ampelophaga rubiginosa eliminating effect, capable of reducing harm of the Ampelophaga rubiginosa to vineyards to increase yield of the vineyards, free of poison to people and grapevines and little in envinronment pollution and is suitable for popularization and application.
Description
Technical field
The present invention relates to a kind of insecticide, be specifically related to a kind of preventing and treating vine hawk moth insecticide.
Background technology
Vine hawk moth, for Lepidoptera, Sphingidae.Host's Fructus Vitis viniferae, larva food leaf becomes to incise and hole, and advanced age only remains petiole.Portugal
Grape hawkmoth, becomes polypide length 45 millimeter, wing expanse 90 millimeter, and body is loose in spindle, body wing dark brown, and back side color is dark,
Outside of belly color is light, nearly khaki.Body back of the body central authorities have 1 canescence ordinate from shirtfront to abdomen end, have 1 ash to fore wing base portion after compound eye
The ordinate that white is wider.Compound eye is spherical relatively big, crineous.The short veteranellinae shape of feeler, dorsal part canescence.The each horizontal line of fore wing is dark tea
Brown, middle horizontal line is wider, and interior horizontal line takes second place, and outer horizontal line is the most corrugated, has 1 dark-coloured triangle speckle, speckle at the nearly drift angle of leading edge
Under connect sub-border line, sub-border line is wavy, outer horizontal line width.Opistholoma sepia, part broad in the middle is pitchy, echinid
Color is the reddest.In the middle part of wing and outside is respectively arranged with 1 dark dark brown horizontal line, and during wing expanse, forward and backward wing two line connects, and outside is the most corrugated.
In raw 1~2 generations in vine hawk moth year, surviving the winter in soil with pupa, mid-May in next year sprouts wings;Early and middle ten days entered to sprout wings and contained June
Phase.Nocturnalism, has phototaxis.Many copulation between the lights, post-coitum 24~lay eggs for 36 hours, dissipate originates in the tender tip or blade back, often more
Female lay eggs 155~180, ovum phase 6~8 days.Larva daytime is static, and night takes food blade, secrets out of when being touched from mouthpart
Clear water, larval phase 30~45 days.Starting people's soil under grape trellis mid-July to pupate, summer pupa has thin reticular membrane, often sticks with fallen leaves
Together, pupa time 15~18 days.Visible generation adult at the beginning of 8 months by the end of July, 2 generation larvas seen from early August cause harm, the many and first generation
Larva rod together, when causing harm more serious, often eats light blade;Entering late September to early October, larva buries and pupates more
Winter.
Vine hawk moth is very big to the harm of Fructus Vitis viniferae, if being not added with, to take precautions against, to cause Portugal in vine hawk moth harm early stage
Grape garden drops in production over a large area, and serious may be by grape leaf eat everything up.On the market for vine hawk moth insecticide kind relatively
Few, and it is poor to eliminate vine hawk moth effect, it is impossible to effectively eliminate vine hawk moth.
Summary of the invention
It is an object of the invention to solve the deficiency poor to vine hawk moth eradicating efficacy that above-mentioned prior art exists, carry
The preventing and treating vine hawk moth insecticide that vine hawk moth is effective is eliminated for a kind of.
A kind of preventing and treating vine hawk moth insecticide, is characterized in that and is prepared from by the raw material of following weight:
Ethylene glycol monoallyl ether 30-36 part, N, N dimethylamine base ethanol acrylate 23-29 part, 17a-methyl-17 b-hydroxyl is male
Gona-4-en-3-one 5-9 part, cis-1,2-dihydroxymethyl ethylene 28-34 part, (2alpha, 3beta)-2,3-diacetoxy
Usu-12-alkene-28-acid 11-17 part, 4-methoxyl group-n-butyl alcohol 38-46 part, ethoxyethoxyethyl acrylate 41-47
Part, 2,6-dimethoxy-acetophenone 3-5 parts, 7-aminocephalosporanic acid 8-12 part.
Preferably, the preventing and treating vine hawk moth using the raw material of following weight to prepare has with insecticide and preferably kills
Worm effect: ethylene glycol monoallyl ether 33 parts, N, N dimethylamine base ethanol acrylate 23 parts, 17a-methyl-17 b-hydroxyl is male
Gona-4-en-3-one 9 parts, cis-1,2-dihydroxymethyl ethylene 31 parts, (2alpha, 3beta)-2,3-diacetoxy Usu-
12-alkene-28-acid 11 parts, 4-methoxyl group-n-butyl alcohol 46 parts, ethoxyethoxyethyl acrylate 44 parts, 2,6-dimethoxys
1-Phenylethanone. 3 parts, 7-aminocephalosporanic acid 12 parts.
Further, preferably preventing and treating vine hawk moth insecticide to obtain insecticidal effect, described preventing and treating vine hawk moth is used
Insecticide also includes the raw material of following weight: 2-oxo cyclopentanecarboxylic acid ethyl ester 36-40 part, (R)-N-(2,4-dihydroxy-
3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt 27-33 part, 2-(2-diethylamino ethoxy) ethanol 18-24
Part.
Preferably, preventing and treating vine hawk moth insecticide, its parts by weight of raw materials proportioning is: 2-oxo cyclopentanecarboxylic acid ethyl ester 38
Part, (R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt 27 parts, 2-(2-diethylamino
Base oxethyl) ethanol 24 parts.
The preparation method of the present invention: be proportionally added into deionized water in reaction pot, add ethylene glycol monoene while stirring
Propyl ether, N, N dimethylamine base ethanol acrylate, 17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone, cis-1,2-dihydroxy
Ethylene methacrylic, continues to stir to being uniformly dispersed, is then heated to 50-60 DEG C;Add (2alpha, 3beta)-2,3-diacetyl
Epoxide Usu-12-alkene-28-acid, 4-methoxyl group-n-butyl alcohol, ethoxyethoxyethyl acrylate, after stirring is allowed to dissolve,
It is cooled to less than 30 DEG C;Add 2,6-dimethoxy-acetophenone, 7-aminocephalosporanic acid, stir, it is thus achieved that finished product.
This preventing and treating vine hawk moth insecticide, preparation method is simple, eliminates vine hawk moth effective, effectively reduces Portugal
The harm to vineyard of the grape hawkmoth, improves the yield in vineyard, and not poisons people and vine, low in the pollution of the environment,
Be suitable to popularization and application in preventing and treating vine hawk moth field of pesticides.
Detailed description of the invention
The detailed description of the invention of the present invention given below, is used for being further described the present invention.In the present invention, such as nothing
Special instruction, each raw material all by working substance content be in terms of 100%.
In following example, raw material introduction:
Ethylene glycol monoallyl ether, CAS accession number is: 111-45-5;
N, N dimethylamine base ethanol acrylate, CAS accession number is: 2439-35-2;
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone, CAS accession number is: 58-18-4;
Cis-1,2-dihydroxymethyl ethylene, CAS accession number is: 6117-80-2;
(2alpha, 3beta)-2,3-diacetoxy Usu-12-alkene-28-acid, CAS accession number is: 57498-76-7;
4-methoxyl group-n-butyl alcohol, CAS accession number is: 111-32-0;
Ethoxyethoxyethyl acrylate, CAS accession number is: 7328-17-8;
2,6-dimethoxy-acetophenones, CAS accession number is: 2040-04-2;
7-aminocephalosporanic acid, CAS accession number is: 957-68-6;
2-oxo cyclopentanecarboxylic acid ethyl ester, CAS accession number is: 611-10-9;
(R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt, CAS accession number is:
867-81-2;
2-(2-diethylamino ethoxy) ethanol, CAS accession number is: 140-82-9.
Embodiment 1
Weigh the raw material of following weight: ethylene glycol monoallyl ether 30g, N, N dimethylamine base ethanol acrylate 29g,
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 7g, cis-1,2-dihydroxymethyl ethylene 28g, (2alpha, 3beta)-2,
3-diacetoxy Usu-12-alkene-28-acid 17g, 4-methoxyl group-n-butyl alcohol 42g, ethoxyethoxyethyl acrylate
41g, 2,6-dimethoxy-acetophenone 5g, 7-aminocephalosporanic acid 10g.
The present embodiment preventing and treating vine hawk moth method for producing insecticide: be proportionally added into deionized water in reaction pot,
Add ethylene glycol monoallyl ether, N while stirring, N dimethylamine base ethanol acrylate, 17a-methyl-17 b-hydroxy-androstane-
4-alkene-3-ketone, cis-1,2-dihydroxymethyl ethylene, continue stirring to being uniformly dispersed, be then heated to 50-60 DEG C;Add
(2alpha, 3beta)-2,3-diacetoxy Usu-12-alkene-28-acid, 4-methoxyl group-n-butyl alcohol, ethoxy ethoxy second
Base acrylate, after stirring is allowed to dissolve, is cooled to less than 30 DEG C;Add 2,6-dimethoxy-acetophenone, 7-amino cephalo
Mould alkanoic acid, stirs, it is thus achieved that finished product.
Embodiment 2
Weigh the raw material of following weight: ethylene glycol monoallyl ether 33g, N, N dimethylamine base ethanol acrylate 23g,
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 9g, cis-1,2-dihydroxymethyl ethylene 31g, (2alpha, 3beta)-2,
3-diacetoxy Usu-12-alkene-28-acid 11g, 4-methoxyl group-n-butyl alcohol 46g, ethoxyethoxyethyl acrylate
44g, 2,6-dimethoxy-acetophenone 3g, 7-aminocephalosporanic acid 12g.
The present embodiment prevents and treats vine hawk moth with method for producing insecticide with embodiment 1.
Embodiment 3
Weigh the raw material of following weight: ethylene glycol monoallyl ether 36g, N, N dimethylamine base ethanol acrylate 26g,
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 5g, cis-1,2-dihydroxymethyl ethylene 34g, (2alpha, 3beta)-2,
3-diacetoxy Usu-12-alkene-28-acid 14g, 4-methoxyl group-n-butyl alcohol 38g, ethoxyethoxyethyl acrylate
47g, 2,6-dimethoxy-acetophenone 4g, 7-aminocephalosporanic acid 8g.
The present embodiment prevents and treats vine hawk moth with method for producing insecticide with embodiment 1.
Embodiment 4
Weigh the raw material of following weight: ethylene glycol monoallyl ether 33g, N, N dimethylamine base ethanol acrylate 23g,
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 9g, cis-1,2-dihydroxymethyl ethylene 31g, (2alpha, 3beta)-2,
3-diacetoxy Usu-12-alkene-28-acid 11g, 4-methoxyl group-n-butyl alcohol 46g, ethoxyethoxyethyl acrylate
44g, 2,6-dimethoxy-acetophenone 3g, 7-aminocephalosporanic acid 12g, 2-oxo cyclopentanecarboxylic acid ethyl ester 36g, (R)-N-(2,
4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt 33g, 2-(2-diethylamino ethoxy) ethanol
21g。
The present embodiment preventing and treating vine hawk moth method for producing insecticide: be proportionally added into deionized water in reaction pot,
Add ethylene glycol monoallyl ether, N while stirring, N dimethylamine base ethanol acrylate, 17a-methyl-17 b-hydroxy-androstane-
4-alkene-3-ketone, cis-1,2-dihydroxymethyl ethylene, continue stirring to being uniformly dispersed, be then heated to 50-60 DEG C;Add
(2alpha, 3beta)-2,3-diacetoxy Usu-12-alkene-28-acid, 4-methoxyl group-n-butyl alcohol, ethoxy ethoxy second
Base acrylate, after stirring is allowed to dissolve, is cooled to less than 30 DEG C;Add 2,6-dimethoxy-acetophenone, 7-amino cephalo
Mould alkanoic acid, 2-oxo cyclopentanecarboxylic acid ethyl ester, (R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-the third ammonia
Acid single sodium salt, 2-(2-diethylamino ethoxy) ethanol, stir, it is thus achieved that finished product.
Embodiment 5
Weigh the raw material of following weight: ethylene glycol monoallyl ether 33g, N, N dimethylamine base ethanol acrylate 23g,
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 9g, cis-1,2-dihydroxymethyl ethylene 31g, (2alpha, 3beta)-2,
3-diacetoxy Usu-12-alkene-28-acid 11g, 4-methoxyl group-n-butyl alcohol 46g, ethoxyethoxyethyl acrylate
44g, 2,6-dimethoxy-acetophenone 3g, 7-aminocephalosporanic acid 12g, 2-oxo cyclopentanecarboxylic acid ethyl ester 38g, (R)-N-(2,
4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt 27g, 2-(2-diethylamino ethoxy) ethanol
24g。
The present embodiment prevents and treats vine hawk moth with method for producing insecticide with embodiment 4.
Embodiment 6
Weigh the raw material of following weight: ethylene glycol monoallyl ether 33g, N, N dimethylamine base ethanol acrylate 23g,
17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 9g, cis-1,2-dihydroxymethyl ethylene 31g, (2alpha, 3beta)-2,
3-diacetoxy Usu-12-alkene-28-acid 11g, 4-methoxyl group-n-butyl alcohol 46g, ethoxyethoxyethyl acrylate
44g, 2,6-dimethoxy-acetophenone 3g, 7-aminocephalosporanic acid 12g, 2-oxo cyclopentanecarboxylic acid ethyl ester 40g, (R)-N-(2,
4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt 30g, 2-(2-diethylamino ethoxy) ethanol
18g。
The present embodiment prevents and treats vine hawk moth with method for producing insecticide with embodiment 4.
The toxic effect test of vine hawk moth indoor is carried out with embodiment 1-6 gained finished product.
1. for examination worm source: pick up from the vineyard caused harm by vine hawk moth for examination vine hawk moth, gather population be 5 ages children
Worm, raises to pupating at indoor grape leave, and rearing conditions is temperature (28 ± 1) DEG C, relative humidity 75%-85%, illumination bar
Part is L:D=12:12h.Adult is put into after pupa is sprouted wings foster worm bottle, and adult feeds with 10% hydromel, puts into grape leave and supplies
It is laid eggs.Larva raising after hatching, to 3 ages, is selected in the same size, and 3 healthy instar larvaes carry out toxicity test.
2. reagent agent: embodiment 1-6 preventing and treating vine hawk moth insecticide.
3. test method:
Leaf dipping method is used to measure each embodiment indoor virulence to vine hawk moth.Take the grape leave of fresh and healthy, kill to be measured
Worm agent is soaked and takes out nature after 10s and dry, after blade put in culture dish and access examination worm 60, with preservative film parcel training
Support ware in case larva escapes.Finally culture dish is put into temperature: (28 ± 1) DEG C, relative humidity: 75%-85%, photoperiod: L:D=
In the constant temperature climate box of 12:12h condition, respectively at 24,48, the dead borer population of statistics after 72h.
4. dead criterion: touch larva with brush pen and no longer wriggle and be considered as death.
5. statistical method: according to test gained initial data, calculating the mortality rate of each process, formula is as follows:
Mortality rate=(dead borer population/total borer population) × 100%
Table 1: the embodiment 1-6 insecticide mortality rate to vine hawk moth
Being contrasted from upper table, the present invention prevents and treats vine hawk moth insecticide, vine hawk moth is respectively provided with lethal effect.Wherein real
Execute the example 1-6 mortality rate to vine hawk moth after 72h and all reach more than 95%, especially embodiment 5 after 48h to vine hawk moth
Mortality rate i.e. can reach 100%, and not only mortality rate is high and kills the shortest, obvious to the fragmentation effect of vine hawk moth.
The present invention prevents and treats the medicament that vine hawk moth insecticide is low toxicity, low-residual, not poisons the mankind and plant, ring
Environment pollution is few.
Claims (4)
1. a preventing and treating vine hawk moth insecticide, it is characterised in that be prepared from by the raw material of following weight: second two
Alcohol mono allyl ether 30-36 part, N, N dimethylamine base ethanol acrylate 23-29 part, 17a-methyl-17 b-hydroxy-androstane-4-
Alkene-3-ketone 5-9 part, cis-1,2-dihydroxymethyl ethylene 28-34 part, (2alpha, 3beta)-2,3-diacetoxy Usu-
12-alkene-28-acid 11-17 part, 4-methoxyl group-n-butyl alcohol 38-46 part, ethoxyethoxyethyl acrylate 41-47 part, 2,
6-dimethoxy-acetophenone 3-5 part, 7-aminocephalosporanic acid 8-12 part.
2. prevent and treat vine hawk moth insecticide as claimed in claim 1, it is characterised in that parts by weight of raw materials proportioning is: ethylene glycol list
Allyl ether 33 parts, N, N dimethylamine base ethanol acrylate 23 parts, 17a-methyl-17 b-prasterone androstane-4-alkene-3-ketone 9 parts,
Cis-1,2-dihydroxymethyl ethylene 31 parts, (2alpha, 3beta)-2,3-diacetoxy Usu-12-alkene-28-acid 11 parts,
4-methoxyl group-n-butyl alcohol 46 parts, ethoxyethoxyethyl acrylate 44 parts, 2,6-dimethoxy-acetophenones 3 parts, 7-amino
Cephalosporinic acid 12 parts.
3. prevent and treat vine hawk moth insecticide as claimed in claim 1 or 2, it is characterised in that also include following weight
Raw material: 2-oxo cyclopentanecarboxylic acid ethyl ester 36-40 part, (R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-
Alanine list sodium salt 27-33 part, 2-(2-diethylamino ethoxy) ethanol 18-24 part.
4. prevent and treat vine hawk moth insecticide as claimed in claim 3, it is characterised in that parts by weight of raw materials proportioning is: 2-oxo ring
Penta Ethyl formate 38 parts, (R)-N-(2,4-dihydroxy-3,3-dimethyl-1-oxo butyl)-beta-alanine list sodium salt 27
Part, 2-(2-diethylamino ethoxy) ethanol 24 parts.
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CN201610300321.2A CN105851025A (en) | 2016-05-06 | 2016-05-06 | Insecticide for controlling Ampelophaga rubiginosa |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1646472A (en) * | 2002-04-17 | 2005-07-27 | 伊萨罗里斯卡公司 | Analogous compounds of strobilurines and their use as acaricides and insecticides |
CN103355343A (en) * | 2013-07-26 | 2013-10-23 | 海南正业中农高科股份有限公司 | Agricultural composition containing sulphur |
CN104996209A (en) * | 2015-06-30 | 2015-10-28 | 云南天质网络科技有限公司 | Prevention and control method for grape sphinx moth |
-
2016
- 2016-05-06 CN CN201610300321.2A patent/CN105851025A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1646472A (en) * | 2002-04-17 | 2005-07-27 | 伊萨罗里斯卡公司 | Analogous compounds of strobilurines and their use as acaricides and insecticides |
CN103355343A (en) * | 2013-07-26 | 2013-10-23 | 海南正业中农高科股份有限公司 | Agricultural composition containing sulphur |
CN104996209A (en) * | 2015-06-30 | 2015-10-28 | 云南天质网络科技有限公司 | Prevention and control method for grape sphinx moth |
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