CN105819842A - 一种柔光砖配方及其制备方法 - Google Patents

一种柔光砖配方及其制备方法 Download PDF

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CN105819842A
CN105819842A CN201610154086.2A CN201610154086A CN105819842A CN 105819842 A CN105819842 A CN 105819842A CN 201610154086 A CN201610154086 A CN 201610154086A CN 105819842 A CN105819842 A CN 105819842A
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formula
mesh
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granule
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吴则昌
邱军
吴柏惠
邓荣
吴志坚
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Roc Pottery Co Ltd Of Foshan Shi Wan China
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Abstract

本发明公开了一种柔光砖配方及其制备方法。所述柔光砖的主要化学组成如下：SiO265～72份，Al2O3 18～23份，Fe2O3 0.1～1.0份，TiO2 0.01～0.1份，CaO0.1～1.0份，MgO 0.5～1.5份，K2O 2～4份，Na2O 2.0～3.0份，烧失量为3～5%。本配方采用高铝‑高钾‑低钠配方体系，配方的骨架稳定，烧成范围宽；坯体的干坯强度高，不易裂砖，配方采用含量极低的碳酸盐、硫酸盐原料，烧出来的产品无气泡、针孔，所制备出的柔光砖产品釉面细腻、柔和，外观具有特别的质感与美感。

Description

一种柔光砖配方及其制备方法
技术领域
本发明属于陶瓷技术领域，具体涉及一种柔光砖配方及其制备方法。
背景技术
柔光砖是由烧成周期产生的非常细小粒度的晶体诱发生成的。由于柔光砖表面细腻、无强烈反光，给人一种柔和、安静、舒服的视觉感受，因此，柔光砖已成为装修领域的高级装饰材料，用它进行室内装潢，具有朴素、自然、高雅的艺术特色。然而，目前市面上大部分的柔光砖由于釉面析晶或釉的高温粘度偏大等原因，使得柔光砖的釉面不够细腻，不够柔光，不够光滑，影响产品的档次和品位。
发明内容
针对现有技术中所存在的不足，本发明的目的在于提供一种柔光砖配方及其制备方法。
本发明所采取的技术方案是：
一种柔光砖配方，按质量份计，其主要化学组成如下：SiO265～72份，Al2O3 18～23份，Fe2O3 0.1～1.0份，TiO2 0.01～0.1份，CaO0.1～1.0份，MgO 0.5～1.5份，K2O 2～4份，Na2O2.0～3.0份，烧失量2～6份。
作为优选的，所述柔光砖配方的主要化学组成如下：SiO265～70份，Al2O3 20～22份，Fe2O3 0.5～1.0份，TiO2 0.05～0.1份，CaO0.1～0.5份，MgO 0.5～1.0份，K2O 0.5～3份，Na2O 2.0～3.0份，烧失量2～6份。
一种柔光砖配方的烧制方法，包括如下步骤：
(1)按照权利要求1-3任一项所述的配方配料，球磨，过筛；
(2)造粒，陈腐，压坯成型，陈腐时间≥24h；
(3)干燥，施釉，在1200-1230℃下烧成，烧成周期为50-70min；
(4)磨边，抛光。
所述压坯成型步骤中，粉料的含水率为6.8～7.4％，粉料的颗粒级配，按重量百分比为：大于20目的颗粒＜1％，40目颗粒35～50％，80目颗粒45～60％，小于100目的颗粒＜5％，各粒级的颗粒含量之和为100％。
本发明的有益效果是：
1、本配方采用高铝-高钾-低钠配方体系，配方的骨架稳定，烧成范围宽；2、砖坯强度高，不易裂砖；3、坯体的膨胀系数与釉料的膨胀系数匹配，烧出来的产品表面平整、可以适用于不同的产品；4、配方采用含量极低的碳酸盐、硫酸盐原料，烧出来的产品无气泡、针孔；5、本发明配方所制备出的柔光砖产品釉面细腻、柔和，外观具有特别的质感与美感。
具体实施方式
下面结合实施例对本发明作进一步的说明，但并不局限于此。
实施例1
一种柔光砖配方，按质量份计，其化学组成如下：SiO265份，Al2O3 23份，Fe2O31.0份，TiO20.1份，CaO0.1份，MgO 0.5份，K2O 4份，Na2O 3.0份，烧失量3.7份。
实施例2
一种柔光砖配方，按质量份计，其化学组成如下：SiO272份，Al2O3 18份，Fe2O3 0.1份，TiO2 0.01份，CaO1.0份，MgO 1.5份，K2O 2份，Na2O 2.0份，烧失量3.4份。
实施例3
一种柔光砖配方，按质量份计，其化学组成如下：SiO270份，Al2O3 20份，Fe2O3 0.5份，TiO2 0.05份，CaO 0.5份，MgO 1.0份，K2O 3份，Na2O 2.5份，烧失量2.5份。
实施例4
一种柔光砖配方，按质量份计，其化学组成如下：SiO268份，Al2O3 20份，Fe2O3 0.7份，TiO2 0.08份，CaO0.1份，MgO 1.0份，K2O 2.5份，Na2O 2.0份，烧失量5.5份。
实施例5
一种柔光砖的制备方法，包括如下步骤：
(1)按照实施例1-4任一项给出的配方配制原材料；
(2)将原材料铲入球磨机，按照配方：水：球磨介质＝1：0.5：4的比例加入水和研磨球石，进行研磨，待球磨至浆料250目筛余为0.9～1.1％，浆料比重为1.69～1.74g/ml时停止球磨，出浆；
(3)研磨后的浆料过筛，除去未磨细的原料及杂质，然后搅拌均匀，喷雾造粒，得到的粉料陈腐35h，检测粉料中含水率为6.8～7.4％；
(4)按照粉料的含水率为6.8～7.4％，粉料的颗粒级配，按重量百分比为：大于20目的颗粒＜1％，40目颗粒35～50％，80目颗粒45～60％，小于100目的颗粒＜5％，各粒级的颗粒含量之和为100％；
(5)在干燥后的坯体表面施底、面釉，然后在1200-1230℃下烧成65min，抛光、磨边处理得到柔光砖。
实施例1-4得到的柔光砖表面平整，优等品率平均≥93％。具体测试结果如表1所示。
表1性能测试结果
本发明配方所制备出的柔光砖产品釉面细腻、光滑，外观具有特别的质感与美感。且砖体强度高，不易裂砖，可以适用于不同的产品。
以上实施例仅为介绍本发明的优选案例，对于本领域技术人员来说，在不背离本发明精神的范围内所进行的任何显而易见的变化和改进，都应被视为本发明的一部分。

Claims (4)

1.一种柔光砖配方，按质量份计，其主要化学组成如下：SiO265～72份，Al2O3 18～23份，Fe2O3 0.1～1.0份，TiO2 0.01～0.1份，CaO0.1～1.0份，MgO 0.5～1.5份，K2O 2～4份，Na2O 2.0～3.0份，烧失量2～6份。
2.根据权利要求1所述的柔光砖配方，其特征在于，按质量百分比计，其主要化学组成如下：SiO265～70份，Al2O3 20～22份，Fe2O3 0.5～1.0份，TiO2 0.05～0.1份，CaO0.1～0.5份，MgO 0.5～1.0份，K2O 0.5～3份，Na2O 2.0～3.0份，烧失量2～6份。
3.一种柔光砖配方的烧制方法，包括如下步骤：
（1）按照权利要求1-3任一项所述的配方配料，球磨，过筛；
（2）造粒，陈腐，压坯成型，陈腐时间≥ 24h；
（3）干燥，施釉，在1200～1230℃下烧成，烧成周期为50～70 min；
（4）磨边，抛光。
4.根据权利要求3所述的烧制方法，其特征在于，所述压坯成型步骤中，粉料的含水率为6.8～7.4%，粉料的颗粒级配，按重量百分比为：大于20目的颗粒＜ 1%，40目颗粒35～50%，80 目颗粒45～60%，小于100 目的颗粒＜5% ，各粒级的颗粒含量之和为100%。
CN201610154086.2A 2016-03-17 2016-03-17 一种柔光砖配方及其制备方法 Pending CN105819842A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473723A (zh) * 2017-09-03 2017-12-15 上海亚细亚陶瓷有限公司 一种柔光大理石的制备方法
CN107935563A (zh) * 2017-12-21 2018-04-20 福建省德化县三诺陶瓷有限公司 大理石釉陶瓷制品及其制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104743881A (zh) * 2015-02-06 2015-07-01 佛山石湾鹰牌陶瓷有限公司 一种微晶陶瓷复合板、其坯料及制备方法
CN104961502A (zh) * 2015-06-10 2015-10-07 佛山欧神诺陶瓷股份有限公司 一种生料厚釉仿微晶质感新型抛釉砖及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104743881A (zh) * 2015-02-06 2015-07-01 佛山石湾鹰牌陶瓷有限公司 一种微晶陶瓷复合板、其坯料及制备方法
CN104961502A (zh) * 2015-06-10 2015-10-07 佛山欧神诺陶瓷股份有限公司 一种生料厚釉仿微晶质感新型抛釉砖及其制备方法

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107473723A (zh) * 2017-09-03 2017-12-15 上海亚细亚陶瓷有限公司 一种柔光大理石的制备方法
CN107473723B (zh) * 2017-09-03 2020-06-02 上海亚细亚陶瓷有限公司 一种柔光大理石的制备方法
CN107935563A (zh) * 2017-12-21 2018-04-20 福建省德化县三诺陶瓷有限公司 大理石釉陶瓷制品及其制备方法
CN107935563B (zh) * 2017-12-21 2020-01-07 福建省德化县三诺陶瓷有限公司 大理石釉陶瓷制品及其制备方法

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