CN105754471B - It is a kind of applied to the strippable anti-fouling paint of pop can and its preparation and application method - Google Patents

It is a kind of applied to the strippable anti-fouling paint of pop can and its preparation and application method Download PDF

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Publication number
CN105754471B
CN105754471B CN201610177648.5A CN201610177648A CN105754471B CN 105754471 B CN105754471 B CN 105754471B CN 201610177648 A CN201610177648 A CN 201610177648A CN 105754471 B CN105754471 B CN 105754471B
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Prior art keywords
pop
fouling paint
remover
strippable anti
strippable
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CN201610177648.5A
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CN105754471A (en
Inventor
彭超
涂思敏
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Fuzhou Fusu Science And Technology Research Institute Co Ltd
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Fuzhou Fusu Science And Technology Research Institute Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D177/00—Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/10—Transparent films; Clear coatings; Transparent materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of strippable anti-fouling paint applied to pop can and its preparation and application method, the strippable anti-fouling paint is by film forming matter, wetting agent, remover, defoamer, antiseptic and alcohol solvent are prepared from, when using, strippable anti-fouling paint is coated on easy-to-draw tank surface, after natural drying or low temperature drying, in easy-to-draw tank surface one layer of uniform protection film layer of compact and firm of formation, the protection film layer can cover the surface of easy-to-draw tank body any irregular curved surface or best bright finish, play a part of isolation dust and prevent germ contamination.

Description

It is a kind of applied to the strippable anti-fouling paint of pop can and its preparation and application method
Technical field
The present invention relates to Stripable paint, and in particular to a kind of strippable anti-fouling paint and its preparation applied to pop can Method is with using.
Background technology
The birth of pop can, to environmental protection highly significant, especially plastic products bring a series of environment after being in fashion and asked Topic, and slack tank tramples down after finishing off just can be very convenient with recycling for pop can, along with its is light, portative Characteristic, young man pulls open draw ring, and to lift the sensation drunk happily of tank also very frank and straightforward.Therefore, this cruel but also packaged form decades of fashion not only Come the fashionable whole world always, be widely used in the packagings for foodstuff such as beer, drink, can.It is reported that, the aluminium that the whole world is produced every year Pop can processed about alreadys exceed 200,000,000,000, and pop can has turned into people's everyday exposure and used most, most frequent packaging One of container.Whether pop can, bottled drink, open with regard to that can drink.According to investigations, most people is all to open ready-to-drink, even if having Be particular about point, that is, it is adept rub tank mouth, at most with napkin paper wipe it is several under, but napkin paper is difficult by the bacterium of tank mouth groove All clean, and whether napkin paper is clean in itself, and if Carried bacteria also is difficult to guarantee, and somebody's suction pipe is in fact further worsened, Because suction pipe be all mostly for a long time be exposed to outside, and suction pipe it is safe and healthy also be difficult to it is secure.It is every according to result of the test Individual can mouthful, as soon as careless wipe, there is ten thousand bacterium more than 40, after testing, and these bacteriums have Escherichia coli, staphylococcus, thin spiral disease Poison, acinetobacter calcoaceticus, streptococcus etc., this concentration likely result in the diseases such as diarrhoea, tight for some vulnerable crowds Heavy is likely to result in lethal effect.
Most pop cans are all overall expose outside, easily by dust and microorganism etc. during transport and storage Pollution, is even more especially easily to conceal foul at cover and draw ring, is not easily cleaned, this may be because being infected with pathogenic bacteria and virus And infect human body.In addition, during exposure, thering are the insects such as fly to fall above unavoidably, it is also difficult to avoid mouse etc. and tank body Contact, and mouse can inherently propagate a variety of diseases such as the plague, Hemorrhagic fever, Leptospira, also be deposited in its excreta In pathogenic bacteria, if really polluting tank mouth, people are not added with cleaning and had a drink with regard to mouth-to-mouth, will trigger disease.Except draw ring It may bring outside problem, the font printed on pop-top can tank with colored ink, pattern may also bring safety and sanitation hidden danger.Oil Containing sizing material, pigment and solvent etc. in ink, these are all inedible materials, but easily pollution tank mouth, hence into people Mouth in, it is permanent in the past, healthhazard should not be underestimated.
Each food all be unable to do without the key element such as " safe, hygienic, environmentally friendly, attractive in appearance ", but make number one should be peace Entirely, next to that the key element such as health, environmental protection.Because there is above-mentioned deficiency in pop can drink of the prior art, consumer is referenced There is potential safety hazard in journey.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of safe, hygienic, environmental protection applied to easy-to-draw Strippable anti-fouling paint of tank and preparation method thereof and application method.
To achieve the above object, the present invention uses following technical scheme：
A kind of strippable anti-fouling paint applied to pop can, its raw material is made up of the component of following parts by weight：
20~35 parts of film forming matter；0.1~0.5 part of wetting agent；0.05~0.3 part of remover；
0.1~0.3 part of defoamer；0.3~0.8 part of antiseptic；60~80 parts of solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:3~5 compositions；
The wetting agent is organic silicon wetting agent or fluorine class wetting agent；
The remover is organic silicon remover, such as dimethyl silicone polymer class remover；
The defoamer is organosiloxane class defoamer or polyethers defoamer；
The antiseptic is glass-base nanometer silver ion；
The solvent is alcohol solvent.
Further, the organic silicon wetting agent is Bi Ke companies of Germany BYK-346.
The fluorine class wetting agent is the FY-F502 of the Guangzhou Fu Yuangui companies or FS-310 of Guangzhou company of Fu Yuangui companies.
The organic silicon remover is the silok-8000 of the Guangzhou Si Luoke chemical companies or PE- of Kening Co., Ltd of Germany 100。
The dimethyl silicone polymer class remover is the BT-1143B or Guangzhou Ba Tai chemical industry of Guangzhou Ba Tai chemical companies The BT-3193 of company.
The organosiloxane class defoamer is the B-296 or the high auxiliary agent of German enlightening of federal fine chemistry industry company in Guangdong TEGO Airex902W。
The polyethers defoamer is the BEK-760 of the Guangzhou Guan Zhi new materials company or DF- of Rhodia of France 4226。
The modified vinyl acetate resin and modified polyamide resin are commercially available prod.
The raw material is food grade materials.
A kind of preparation method of strippable anti-fouling paint of the present invention is as follows：In the environment of aeration-drying, first By alcohol solvent by being added in heating stirring bucket, temperature is set in 60~70 DEG C, starts after agitator is slowly stirred and adds Film forming matter is simultaneously stirred, after thing to be filmed is completely dissolved, and is sequentially added wetting agent, defoamer, remover and antiseptic, is then stirred Uniformly, stand, discharging obtains strippable anti-fouling paint.
Strippable anti-fouling paint of the present invention is applied to pop can, and its application method is as follows：Will be described peelable antifouling Coating is coated（Dip-coating/spraying/brushing）In after easy-to-draw tank surface, natural drying or low temperature drying, in pop can body surface Face forms one layer of uniform protection film layer of compact and firm, and the protection film layer of formation can cover any irregular curved surface of easy-to-draw tank body Or the surface of best bright finish.
The present invention uses above technical scheme, and the strippable anti-fouling paint prepared is a liquid filmogen, It is prepared from by food grade materials.The strippable anti-fouling paint is coated on easy-to-draw tank surface, and one layer can be formed after drying The uniform protection film layer of compact and firm, is covered in the surface of pop can any irregular curved surface or best bright finish, plays isolation Dust and the effect of germ contamination.Consumer easily can take up protection film layer monoblock while draw ring is pulled open and take off, behaviour Facilitate ,/being rushed with water/can be wiped with hand instead of original consumer and the mode such as wipe with paper, without worrying sanitary condition, also consumer The happy dripping sensation of " tossing off the cup ".The present invention has further the advantage that：
1st, material system of the present invention is chloride, heavy metal, toxic element etc., and, fast drying corrosion-free to pop can base material is applied It is short between man-hour.2nd, protection film layer can cover the surface of pop can any irregular curved surface or best bright finish, not stay dead angle.3rd, it is solid Change the diaphragm film formed water insoluble, it is transparent, with insulation, dust-proof, isolation germ contamination, oil resistant, sea water resistance, resistance to ultraviolet Line, the anti-aging, diluted alkaline of resistance to diluted acid, rub resistance, antirust, anti-oxidation discoloration, the function of resistance to solar exposure.4th, protection film layer it is transparent, It is easy to check, seals up for safekeeping conveniently, enables rapid.5th, strippable anti-fouling paint of the invention passes through FDA Food and Drug Administration （FDA）Food hygienic standard and U.S. ASTM F963-11 safety and sanitation standard detection, can be safe to use.
Embodiment
A kind of strippable anti-fouling paint applied to pop can, its raw material is made up of the component of following parts by weight：
20~35 parts of film forming matter；0.1~0.5 part of wetting agent；0.05~0.3 part of remover；
0.1~0.3 part of defoamer；0.3~0.8 part of antiseptic；60~80 parts of solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:3~5 compositions；
The wetting agent is organic silicon wetting agent or fluorine class wetting agent；
The remover is organic silicon remover or dimethyl silicone polymer class remover；
The defoamer is organosiloxane class defoamer or polyethers defoamer；
The antiseptic is glass-base nanometer silver ion；
The solvent is alcohol solvent.
The organic silicon wetting agent is BYK-346 or wet-500；The fluorine class wetting agent is FY-F502 or FS-310； The organic silicon remover is silok-8000 or PE-100；The dimethyl silicone polymer class remover be BT-1143B or BT-3193；The organosiloxane class defoamer is B-296 or TEGO Airex902W；The polyethers defoamer is BEK- 760 or DF-4226.
Embodiment 1
A kind of strippable anti-fouling paint applied to pop can, its raw material is made up of the component of following parts by weight：
20 parts of film forming matter；
0.1 part of organic silicon wetting agent BYK-346；
0.05 part of organic silicon remover silok-8000；
0.1 part of organosiloxane class defoamer B-296；
0.3 part of glass-base nanometer silver ion；
60 parts of alcohol solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:3 compositions.
Embodiment 2
A kind of strippable anti-fouling paint applied to pop can, its raw material is made up of the component of following parts by weight：
25 parts of film forming matter；
0.2 part of organic silicon wetting agent wet-500；
0.1 part of organic silicon remover PE-100；
0.2 part of organosiloxane class defoamer TEGO Airex902W；
0.5 part of glass-base nanometer silver ion；
70 parts of alcohol solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:4 compositions.
Embodiment 3
A kind of strippable anti-fouling paint applied to pop can, its raw material is made up of the component of following parts by weight：
30 parts of film forming matter；
0.35 part of fluorine class wetting agent FY-F502；
0.2 part of dimethyl silicone polymer class remover BT-1143B；
0.15 part of polyethers defoamer BEK-760；
0.6 part of glass-base nanometer silver ion；
75 parts of alcohol solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:5 compositions.
Embodiment 4
A kind of strippable anti-fouling paint applied to pop can, its raw material is made up of the component of following parts by weight：
35 parts of film forming matter；
0.5 part of fluorine class wetting agent FS-310；
0. 3 parts of dimethyl silica alkanes remover BT-3193；
0. 3 parts of polyethers defoamer DF-4226；
0.8 part of glass-base nanometer silver ion；
80 parts of alcohol solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:3.5 composition.
Embodiment 5
A kind of preparation method of strippable anti-fouling paint applied to pop can is as follows：By weight, each raw material is weighed, In the environment of aeration-drying, alcohol solvent is added in heating stirring bucket first, temperature 60~70 DEG C are set in, startup is stirred Mix and film forming matter is added after device is slowly stirred and is stirred, after thing to be filmed is completely dissolved, sequentially add wetting agent, defoamer, stripping Agent and antiseptic, then stir, and stand, and discharging obtains strippable anti-fouling paint.
Embodiment 6
A kind of application method of strippable anti-fouling paint applied to pop can is as follows：Strippable anti-fouling paint is coated （Dip-coating/spraying/brushing）In after easy-to-draw tank surface, natural drying or low temperature drying, in easy-to-draw tank surface formation one The layer uniform protection film layer of compact and firm, the protection film layer of formation can cover any irregular curved surface of easy-to-draw tank body or high bright and clean The surface of degree, plays a part of isolation dust and prevents germ contamination.

Claims (11)

1. a kind of strippable anti-fouling paint applied to pop can, it is characterised in that：Its raw material by following parts by weight component group Into：
20~35 parts of film forming matter；0.1~0.5 part of wetting agent；0.05~0.3 part of remover；
0.1~0.3 part of defoamer；0.3~0.8 part of antiseptic；60~80 parts of solvent；
The film forming matter is by being modified vinyl acetate resin and modified polyamide resin by weight 1:3~5 compositions；
The wetting agent is organic silicon wetting agent or fluorine class wetting agent；
The remover is organic silicon remover；
The defoamer is organosiloxane class defoamer or polyethers defoamer；
The antiseptic is glass-base nanometer silver ion；
The solvent is alcohol solvent.
2. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：It is described organic Silicon class wetting agent is BYK-346.
3. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：The fluorine class Wetting agent is FY-F502.
4. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：It is described organic Silicon class remover is silok-8000.
5. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：It is described organic Silicon class remover is dimethyl silicone polymer class remover.
6. a kind of strippable anti-fouling paint applied to pop can according to claim 5, it is characterised in that：Described poly- two Methylsiloxane class remover is BT-1143B or BT-3193.
7. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：It is described organic Type siloxane defoamer is B-296 or TEGO Airex902W.
8. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：The polyethers Class defoamer is BEK-760 or DF-4226.
9. a kind of strippable anti-fouling paint applied to pop can according to claim 1, it is characterised in that：The raw material It is food grade materials.
10. a kind of preparation method of strippable anti-fouling paint applied to pop can as claimed in claim 1, its feature exists In：Alcohol solvent is added in heating stirring bucket first, temperature is set in 60~70 DEG C, is added after starting agitator stirring Film forming matter is simultaneously stirred, after thing to be filmed is completely dissolved, and is sequentially added wetting agent, defoamer, remover and antiseptic, is then stirred Uniformly, stand, discharging obtains strippable anti-fouling paint.
11. a kind of application method of strippable anti-fouling paint applied to pop can as claimed in claim 1, its feature exists In：The strippable anti-fouling paint is coated on easy-to-draw tank surface, after spontaneously drying or drying, formed in easy-to-draw tank surface Layer protecting film layer.
CN201610177648.5A 2016-03-25 2016-03-25 It is a kind of applied to the strippable anti-fouling paint of pop can and its preparation and application method Active CN105754471B (en)

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CN106497265A (en) * 2016-10-23 2017-03-15 郑荣荣 A kind of method for protective glass light fixture
CN107588653A (en) * 2017-07-31 2018-01-16 浦江县晶富农业科技有限公司 Multifunctional equipment for seed drying screening

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US20110177146A1 (en) * 2009-07-27 2011-07-21 E. I. Du Pont De Nemours And Company Removable antimicrobial coating compositions containing cationic rheology agent and methods of use
US20110182959A1 (en) * 2009-07-27 2011-07-28 E.I. Du Pont De Nemours And Company. Removable antimicrobial coating compositions containing acid-activated rheology agent and methods of use
CN104031498B (en) * 2014-05-28 2015-03-25 江苏巨珩新材料科技有限公司 Water-based paint for surface of pop-top can and preparation method of water-based paint

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