CN105742505A - 一种高性能钙钛矿太阳能电池及其制备方法 - Google Patents
一种高性能钙钛矿太阳能电池及其制备方法 Download PDFInfo
- Publication number
- CN105742505A CN105742505A CN201610243807.7A CN201610243807A CN105742505A CN 105742505 A CN105742505 A CN 105742505A CN 201610243807 A CN201610243807 A CN 201610243807A CN 105742505 A CN105742505 A CN 105742505A
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- layer
- graphene oxide
- titanium ore
- calcium titanium
- ammonia
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 229920000144 PEDOT:PSS Polymers 0.000 claims abstract description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 29
- MCEWYIDBDVPMES-UHFFFAOYSA-N [60]pcbm Chemical compound C123C(C4=C5C6=C7C8=C9C%10=C%11C%12=C%13C%14=C%15C%16=C%17C%18=C(C=%19C=%20C%18=C%18C%16=C%13C%13=C%11C9=C9C7=C(C=%20C9=C%13%18)C(C7=%19)=C96)C6=C%11C%17=C%15C%13=C%15C%14=C%12C%12=C%10C%10=C85)=C9C7=C6C2=C%11C%13=C2C%15=C%12C%10=C4C23C1(CCCC(=O)OC)C1=CC=CC=C1 MCEWYIDBDVPMES-UHFFFAOYSA-N 0.000 claims abstract description 23
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052709 silver Inorganic materials 0.000 claims abstract description 10
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004332 silver Substances 0.000 claims abstract description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 71
- 229910000069 nitrogen hydride Inorganic materials 0.000 claims description 65
- 229910021529 ammonia Inorganic materials 0.000 claims description 48
- JTCFNJXQEFODHE-UHFFFAOYSA-N [Ca].[Ti] Chemical compound [Ca].[Ti] JTCFNJXQEFODHE-UHFFFAOYSA-N 0.000 claims description 47
- -1 ammonia modified graphene Chemical class 0.000 claims description 32
- 230000005540 biological transmission Effects 0.000 claims description 28
- 229910021389 graphene Inorganic materials 0.000 claims description 17
- 230000027756 respiratory electron transport chain Effects 0.000 claims description 16
- 238000004528 spin coating Methods 0.000 claims description 16
- 239000011259 mixed solution Substances 0.000 claims description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 230000005611 electricity Effects 0.000 claims 1
- 230000005525 hole transport Effects 0.000 abstract 6
- 239000002131 composite material Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000000034 method Methods 0.000 description 10
- 238000010586 diagram Methods 0.000 description 9
- 239000010409 thin film Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- XXWFDPVOXNJASB-UHFFFAOYSA-N ethanol;phenol Chemical compound CCO.OC1=CC=CC=C1 XXWFDPVOXNJASB-UHFFFAOYSA-N 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- RHZWSUVWRRXEJF-UHFFFAOYSA-N indium tin Chemical compound [In].[Sn] RHZWSUVWRRXEJF-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- GKWLILHTTGWKLQ-UHFFFAOYSA-N 2,3-dihydrothieno[3,4-b][1,4]dioxine Chemical compound O1CCOC2=CSC=C21 GKWLILHTTGWKLQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
- H10K30/80—Constructional details
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K30/00—Organic devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Photovoltaic Devices (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
Description
Claims (10)
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106159102A (zh) * | 2016-09-28 | 2016-11-23 | Tcl集团股份有限公司 | 叠层qled器件及其制备方法 |
CN106684247A (zh) * | 2017-03-15 | 2017-05-17 | 中南大学 | 一种钙钛矿太阳能电池及其制备方法 |
CN107732016A (zh) * | 2017-11-20 | 2018-02-23 | 苏州黎元新能源科技有限公司 | 一种高稳定性钙钛矿太阳能电池 |
CN108461632A (zh) * | 2017-02-21 | 2018-08-28 | 华邦电子股份有限公司 | 钙钛矿复合结构 |
CN108666429A (zh) * | 2018-05-16 | 2018-10-16 | 上海交通大学 | 一种具有高电荷传输性质的钙钛矿薄膜的制备方法 |
CN110010769A (zh) * | 2019-03-26 | 2019-07-12 | 浙江大学 | 一种取向生长有机无机杂化钙钛矿薄膜的制备方法 |
CN110828177A (zh) * | 2019-10-28 | 2020-02-21 | 宁波大学 | 一种基于卤化物钙钛矿的光敏电容器及其制备方法 |
CN113955748A (zh) * | 2020-07-21 | 2022-01-21 | 国家纳米科学中心 | 一种氨基化氧化石墨烯纳米片的制备方法和在有机太阳能电池中的应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103855307A (zh) * | 2014-03-14 | 2014-06-11 | 国家纳米科学中心 | 一种钙钛矿太阳电池及其制备方法 |
CN105098082A (zh) * | 2015-08-10 | 2015-11-25 | 北京大学深圳研究生院 | 一种钙钛矿太阳能电池的制备方法 |
-
2016
- 2016-04-19 CN CN201610243807.7A patent/CN105742505B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103855307A (zh) * | 2014-03-14 | 2014-06-11 | 国家纳米科学中心 | 一种钙钛矿太阳电池及其制备方法 |
CN105098082A (zh) * | 2015-08-10 | 2015-11-25 | 北京大学深圳研究生院 | 一种钙钛矿太阳能电池的制备方法 |
Non-Patent Citations (1)
Title |
---|
DA-YOUNG LEE ET AL.: ""Graphene oxide/PEDOT:PSS composite hole transport layer for efficient and stable planar heterojunction perovskite solar cells"", 《NANOSCALE》 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106159102A (zh) * | 2016-09-28 | 2016-11-23 | Tcl集团股份有限公司 | 叠层qled器件及其制备方法 |
CN108461632A (zh) * | 2017-02-21 | 2018-08-28 | 华邦电子股份有限公司 | 钙钛矿复合结构 |
CN106684247A (zh) * | 2017-03-15 | 2017-05-17 | 中南大学 | 一种钙钛矿太阳能电池及其制备方法 |
CN107732016A (zh) * | 2017-11-20 | 2018-02-23 | 苏州黎元新能源科技有限公司 | 一种高稳定性钙钛矿太阳能电池 |
CN108666429A (zh) * | 2018-05-16 | 2018-10-16 | 上海交通大学 | 一种具有高电荷传输性质的钙钛矿薄膜的制备方法 |
CN110010769A (zh) * | 2019-03-26 | 2019-07-12 | 浙江大学 | 一种取向生长有机无机杂化钙钛矿薄膜的制备方法 |
CN110828177A (zh) * | 2019-10-28 | 2020-02-21 | 宁波大学 | 一种基于卤化物钙钛矿的光敏电容器及其制备方法 |
CN110828177B (zh) * | 2019-10-28 | 2021-10-01 | 宁波大学 | 一种基于卤化物钙钛矿的光敏电容器及其制备方法 |
CN113955748A (zh) * | 2020-07-21 | 2022-01-21 | 国家纳米科学中心 | 一种氨基化氧化石墨烯纳米片的制备方法和在有机太阳能电池中的应用 |
CN113955748B (zh) * | 2020-07-21 | 2023-08-22 | 国家纳米科学中心 | 一种氨基化氧化石墨烯纳米片的制备方法和在有机太阳能电池中的应用 |
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CN105742505B (zh) | 2018-01-12 |
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