CN105731700B - One kind administers lake eutrophication ozone and ultraviolet irradiation equipment integrating and method - Google Patents
One kind administers lake eutrophication ozone and ultraviolet irradiation equipment integrating and method Download PDFInfo
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- CN105731700B CN105731700B CN201610129674.0A CN201610129674A CN105731700B CN 105731700 B CN105731700 B CN 105731700B CN 201610129674 A CN201610129674 A CN 201610129674A CN 105731700 B CN105731700 B CN 105731700B
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- water
- aeration
- control system
- aeration tank
- lake
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Links
- 238000012851 eutrophication Methods 0.000 title claims abstract description 35
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 169
- 238000005273 aeration Methods 0.000 claims abstract description 158
- 230000005284 excitation Effects 0.000 claims abstract description 33
- 238000005276 aerator Methods 0.000 claims abstract description 29
- 239000010802 sludge Substances 0.000 claims abstract description 17
- 238000012545 processing Methods 0.000 claims abstract description 14
- 238000007667 floating Methods 0.000 claims abstract description 13
- 238000001914 filtration Methods 0.000 claims description 16
- 238000003466 welding Methods 0.000 claims description 15
- IVDFJHOHABJVEH-UHFFFAOYSA-N pinacol Chemical compound CC(C)(O)C(C)(C)O IVDFJHOHABJVEH-UHFFFAOYSA-N 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- 238000009413 insulation Methods 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- QSKPIOLLBIHNAC-UHFFFAOYSA-N 2-chloro-acetaldehyde Chemical compound ClCC=O QSKPIOLLBIHNAC-UHFFFAOYSA-N 0.000 claims description 7
- PATYHUUYADUHQS-UHFFFAOYSA-N 4-methylpropiophenone Chemical compound CCC(=O)C1=CC=C(C)C=C1 PATYHUUYADUHQS-UHFFFAOYSA-N 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 7
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052785 arsenic Inorganic materials 0.000 claims description 7
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 229940037626 isobutyl stearate Drugs 0.000 claims description 7
- CPXCDEMFNPKOEF-UHFFFAOYSA-N methyl 3-methylbenzoate Chemical compound COC(=O)C1=CC=CC(C)=C1 CPXCDEMFNPKOEF-UHFFFAOYSA-N 0.000 claims description 7
- VNBLTKHUCJLFSB-UHFFFAOYSA-N n-(trimethoxysilylmethyl)aniline Chemical compound CO[Si](OC)(OC)CNC1=CC=CC=C1 VNBLTKHUCJLFSB-UHFFFAOYSA-N 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- ZDYUUBIMAGBMPY-UHFFFAOYSA-N oxalic acid;hydrate Chemical class O.OC(=O)C(O)=O ZDYUUBIMAGBMPY-UHFFFAOYSA-N 0.000 claims description 7
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 125000005456 glyceride group Chemical group 0.000 claims description 6
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 5
- 230000005260 alpha ray Effects 0.000 claims description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 5
- 230000032050 esterification Effects 0.000 claims description 5
- 238000005886 esterification reaction Methods 0.000 claims description 5
- 239000011812 mixed powder Substances 0.000 claims description 5
- 239000002861 polymer material Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 229910021642 ultra pure water Inorganic materials 0.000 claims description 5
- 239000012498 ultrapure water Substances 0.000 claims description 5
- 238000009827 uniform distribution Methods 0.000 claims description 5
- 241001553178 Arachis glabrata Species 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 4
- 235000020232 peanut Nutrition 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- KNDQHSIWLOJIGP-UMRXKNAASA-N (3ar,4s,7r,7as)-rel-3a,4,7,7a-tetrahydro-4,7-methanoisobenzofuran-1,3-dione Chemical compound O=C1OC(=O)[C@@H]2[C@H]1[C@]1([H])C=C[C@@]2([H])C1 KNDQHSIWLOJIGP-UMRXKNAASA-N 0.000 claims description 3
- 235000017060 Arachis glabrata Nutrition 0.000 claims description 3
- 235000010777 Arachis hypogaea Nutrition 0.000 claims description 3
- 235000018262 Arachis monticola Nutrition 0.000 claims description 3
- WGINUBKWLUSQGI-UHFFFAOYSA-N C1(=CC=CC=C1)C1=CC=CC=C1.[I] Chemical group C1(=CC=CC=C1)C1=CC=CC=C1.[I] WGINUBKWLUSQGI-UHFFFAOYSA-N 0.000 claims description 3
- 238000003491 array Methods 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 230000006872 improvement Effects 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- 230000004044 response Effects 0.000 claims description 3
- 230000001954 sterilising effect Effects 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 claims description 3
- VGGRCVDNFAQIKO-UHFFFAOYSA-N formic anhydride Chemical compound O=COC=O VGGRCVDNFAQIKO-UHFFFAOYSA-N 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 239000004519 grease Substances 0.000 claims 1
- VKOBVWXKNCXXDE-UHFFFAOYSA-N icosanoic acid Chemical class CCCCCCCCCCCCCCCCCCCC(O)=O VKOBVWXKNCXXDE-UHFFFAOYSA-N 0.000 claims 1
- 238000012544 monitoring process Methods 0.000 claims 1
- 239000012535 impurity Substances 0.000 abstract description 3
- 238000010586 diagram Methods 0.000 description 9
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- -1 methoxyl group Acetate ethanol ester Chemical class 0.000 description 5
- 239000005416 organic matter Substances 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 230000015556 catabolic process Effects 0.000 description 4
- 238000006731 degradation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 241000192700 Cyanobacteria Species 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/42—Nitriles
- C08F220/44—Acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Engineering & Computer Science (AREA)
- Hydrology & Water Resources (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention discloses one kind to administer lake eutrophication ozone and ultraviolet irradiation equipment integrating and method, is made up of the first water delivery device, aeration tank, support, discharge pipeline, sludge sump, aerator, ozone supply room, the second water delivery device, ultraviolet excitation chamber, water pipe, floating platform and control system；Lake Water enters in aeration tank through the first water delivery device, and the lake water after aerator is handled inputs ultraviolet excitation chamber through the second water delivery device, is discharged into by the lake water after the processing of ultraviolet excitation chamber through water pipe in lake.A kind of lake eutrophication ozone of administering of the present invention irradiates equipment integrating and method novel and reasonable structure with ultraviolet, and removal of impurity is high, and the scope of application is wide.
Description
Technical field
The invention belongs to lake ecological environment administer field, and in particular to one kind administer lake eutrophication ozone with it is ultraviolet
Line irradiates equipment integrating and method.
Background technology
Lake is one of a national economy and the important freshwater resources of social development, and it, which not only has, regulates the climate, stores
Water, water supply, the functions such as aquatic products, tourism are provided, and in protection bio-diversity and maintain regional environment ecosystem balance
In also play vital effect.In recent years, with the rapid development of excessive exploitation and industrial or agricultural of the mankind to natural resources,
The eutrophication problem of lake pollution problem, especially lake, oneself turn into the current study hotspot about ecological environment problem it
One.At present, the lake in the whole world about 30%~40% by different degrees of eutrophication the eutrophy in China lake
Change problem is then more acute, is more than 1km in area2More than 2300 individual lakes in more than 6% in eutrophic state or just
Threatened by eutrophication.Great water special " China's nutrient benchmark and the eutrophication control research on standard in country
Problem, in more than 200 individual lakes of selection, the lake more than 7s% is in eutrophication or supereutrophic state, wherein too
The blue-green alga blooms such as lake, Chaohu, Dian Chi frequently break out.It can be rated as within 2007 " year of blue-green algae ", oneself occurs and possessed eutrophication
The area of lake of condition amounts to 14000km2As many as, from the quantity of lake, nearly 3/4 lake reaches rich nutrition level, institute
The area accounted for also close to the gross area 2/3.It can be seen that lake eutrophication problem has popularity and seriousness, oneself is through reaching
The degree that can not be ignored.
The eutrophication in China lake has obvious area differentiation feature, and more south is disturbed including mankind's activity
Side most of lakes, for example, Taihu Lake, Chaohu and Dian Chi " three lakes " " water quality type " eutrophication and triggered by climate warm-dry tendency
" water type " eutrophication, such as Hulun nur of lake of north China.And substantially both because the nutrient concentrations such as nitrogen, phosphorus are superfluous
Trigger.The statistics of OECD (DECD) shows that the eutrophic lake more than 80% belongs to phosphorus limit in the world
Type processed, the eutrophication process in the most of lakes of China are also controlled by phosphorus recycling.Therefore, the biology of phosphorus in lake is carried out
The research of the benchmark of geochemical cycle and phosphorus and control standard seems very necessary.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of improvement lake eutrophication ozone and ultraviolet irradiation one
Body equipment, including：First water delivery device 1, aeration tank 2, support 3, discharge pipeline 4, sludge sump 5, aerator 6, ozone supply room
7, the second water delivery device 8, ultraviolet excitation chamber 9, water pipe 10, floating platform 11, control system 12；The aeration tank 2 passes through
First water delivery device 1 is connected with lake, and the first water delivery device 1 is provided with water pump, and water pump is connected with the wire of control system 12；The exposure
Discharge pipeline 4 is provided between the bottom of gas pond 2 and sludge sump 5, the tail end of discharge pipeline 4 is provided with magnetic valve, and magnetic valve is led with control system 12
Line connects；The lower section of aeration tank 2 is provided with support 3, and the lower section of support 3 is provided with floating platform 11, the table of floating platform 11
Face is provided with the aerator 6 being connected with the interior bottom portion of aeration tank 2, and the aerator 6 passes through pipeline and the phase of ozone supply room 7
Even, the second water delivery device 8 is provided between the aeration tank 2 and ultraviolet excitation chamber 9, the side wall of ultraviolet excitation chamber 9 is provided with
Water pipe 10, the control system 12 are located at the surface of floating platform 11.
Further, the aeration tank 2 includes：Aeration tank housing 2-1, horizontal filtering baffle plate 2-2, drainage plate 2-3 is tilted,
Vertical division board 2-4, level sensor 2-5；The inclination drainage plate 2-3 is located at position to the left inside the housing 2-1 of aeration tank, inclines
Oblique drainage plate 2-3 upper ends are arc, and bottom is incline structure, tilt drainage plate 2-3 side walls and wall seamless in the housing 2-1 of aeration tank
Welding, it is 10 °~45 ° to tilt drainage plate 2-3 with horizontal plane angle；The horizontal filtering baffle plate 2-2 is arranged horizontally in inclination and drawn
Flowing plate 2-3 bottom positions, horizontal filtering baffle plate 2-2 right walls are with tilting drainage plate 2-3 bottoms seamless welding, remaining side wall and aeration
Pond housing 2-1 inwall seamless weldings, horizontal filtering baffle plate 2-2 surfaces are uniform-distribution with substantial amounts of through hole, and quantity is 30~100
Individual, through hole spacing is 1mm~20mm, and pore diameter range value is 1mm~3mm；The vertical division board 2-4 is arranged vertically on inclination and drawn
Flowing plate 2-3 bottom positions, vertical division board 2-4 top surfaces are with tilting drainage plate 2-3 bottoms seamless welding, remaining side wall and aeration tank
Housing 2-1 inwall seamless weldings；The inside of aeration tank 2 is provided with level sensor 2-5, and level sensor 2-5 is away from aeration tank 2
Cornice 5mm~20mm, level sensor 2-5 is held to be connected with the wire of control system 12.
Further, the aerator 6 includes：Air pump 6-1, it is aerated main 6-2, aeration branch pipe 6-3, aeration head 6-4；
Described air pump 6-1 one end connects ozone supply room 7 by pipeline, and other end connection aeration main 6-2, air pump 6-1 is with control
12 wires of uniting connect；The aeration main 6-2 stretches into the bottom of aeration tank 2 above aeration tank 2；The aeration branch pipe 6-3 is put down
The baseplane of aeration tank 2, aeration branch pipe 6-3 and aeration main 6-2 through connections are laid on, aeration main 6-2 quantity is 2~6,
Aeration main 6-2 mutual distances arranged in parallel and arranged in parallel multiple aeration main 6-2 are equal, adjacent two aeration mains
The distance between 6-2 is 10mm~50mm, and the multiple ends of aeration main 6-2 bis- being arranged parallel to each other and middle part pass through connecting tube phase
Connect insertion；The aeration branch pipe 6-3 is provided with aeration head 6-4, aeration head 6-4 and aeration branch pipe 6-3 through connections, aeration
Head 6-4 quantity is 50~100, and multiple aeration head 6-4 arrange along the word uniform rectilinears of aeration branch pipe 6-3 mono-, adjacent aeration head
6-4 spacing 20mm~50mm, aeration head 6-4 jets direction are arranged to upward, and the aeration head 6-4 surfaces are uniform-distribution with largely
Aperture is 0.5mm~1.2mm micropore.
Further, second water delivery device 8 includes：Enter water conduit tube 8-1, water inlet pipe 8-2, distributive pipe 8-3；It is described
Enter water conduit tube 8-1 one end and be connected to the side wall top position of aeration tank 2, other end connection water inlet pipe 8-2；It is described enter water conduit tube 8-
1 with water inlet pipe 8-2 through connections；The water inlet pipe 8-2 is provided with distributive pipe 8-3, and distributive pipe 8-3 quantity is 2~4
Individual, symmetric arrays, distributive pipe 8-3 are connected distributive pipe 8-3 with water inlet pipe 8-2 internal run-throughs two-by-two.
Further, the ultraviolet excitation chamber 9 includes：Shell 9-1, fluorescent tube 9-2, short-circuit alarming device 9-3；The fluorescent tube
9-2 is evenly arranged in inside shell 9-1 so that layer structure is parallel, and quantity is 15~30, adjacent two layers distance 50mm~80mm,
Adjacent fluorescent tube 9-2 level intervals are spacing 30mm~50mm, and fluorescent tube 9-2 is connected with the wire of control system 12, fluorescent tube 9-2 and shell
It is electrically insulated structures between 9-1, fluorescent tube 9-2 is connected with short-circuit alarming device 9-3 wires, short-circuit alarming device 9-3 and control system 12
Wire connects.
Further, the inclination drainage plate 2-3 is molded by high polymer material pressing mold, tilt drainage plate 2-3 composition into
Divide and manufacturing process is as follows：
First, drainage plate 2-3 constituents are tilted：
Count in parts by weight, 7~15 parts of dicyclohexyl amine, 1~12 part of arsenic triethyl, anilinomethyl trimethoxy silane 3~
17 parts, 4~20 parts of p-methylphenyl ethyl ketone, 5~26 parts of isobutyl stearate, three 10~30 parts of peanut acid glycerides, concentration is
600~800 parts of 20ppm~120ppm pinacol, 2~14 parts of phthalic anhydride, 7~16 parts of SA dibutyl ester, crosslinking
3~20 parts of agent, 5~25 parts of chloroacetaldehyde, two 1~10 part of oxalic acid hydrates, 8~20 parts of methyl cellosolve acetate, acrylonitrile 6~25
Part；
The crosslinking agent is any one in carbic anhydride, adjacent iodine biphenyl, ortho-nitraniline；
2nd, drainage plate 2-3 manufacturing process is tilted, is comprised the steps of：
1st step, 500~950 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 0.008 μ S/cm~0.04 is added in a kettle,
Start reactor in agitator, rotating speed be 130rpm~200rpm, startup heat pump, make reactor temperature rise to 42 DEG C~
60℃；Dicyclohexyl amine, arsenic triethyl, anilinomethyl trimethoxy silane are sequentially added, to being completely dissolved, adjusting pH value is for stirring
3.5~7.5, agitator speed is adjusted to 75rpm~120rpm, temperature is 50 DEG C~90 DEG C, esterification 3~7 hours；
2nd step, p-methylphenyl ethyl ketone, isobutyl stearate is taken to crush, powder diameter is 430~520 mesh；Add three peanuts
Acid glyceride is well mixed, and is laid in pallet, and tiling thickness is 15mm~40mm, use dosage for 1.0kGy~3.5kGy,
The alpha ray that energy is 3.0MeV~7.0MeV irradiates 20~35 minutes, and the β x ray irradiation xs 10~60 minutes of Isodose；
3rd step, the mixed-powder handled through the 2nd step are dissolved in pinacol, add reactor, agitator speed 40rpm
~60rpm, temperature are 75 DEG C~85 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.05MPa~-0.03MPa, protects
Hold this state response 3~9 hours；Pressure release is simultaneously passed through nitrogen, and it is 0.005MPa~0.020MPa to make reacting kettle inner pressure, and insulation is quiet
Put 4~10 hours；Agitator speed is promoted to 80rpm~160rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add adjacent benzene two
After formic anhydride, SA dibutyl ester are completely dissolved, add crosslinking agent and be stirred so that the hydrophile-lipophile balance of reactor solution
It is worth for 4.0~10, insulation stands 3~6 hours；
4th step, when agitator speed is 80rpm~110rpm, sequentially add chloroacetaldehyde, two oxalic acid hydrates, methoxyl group
Acetate ethanol ester and acrylonitrile, reactor pressure is lifted, reach 0.08MPa~0.30MPa, temperature is 135 DEG C~155
DEG C, polymerisation 3~10 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, is cooled to 35 DEG C~50 DEG C, is discharged,
Enter molding press to can be prepared by tilting drainage plate 2-3.
The invention also discloses a kind of method that ozone and ultraviolet irradiation are integrated processing lake eutrophication, including
Following steps：
1st step, control system 12 start the first water delivery device 1 and input Lake Water in aeration tank 2, inflow control is existed
10m3/ h~50m3/ h, Lake Water in aeration tank 2 by tilting drainage plate 2-3 guiding, and horizontal filtering baffle plate 2-2
Peptizaiton, while by vertical division board 2-4 laminar flow shunting, be uniformly distributed to the bottom of aeration tank 2 and be gradually increasing,
Until reach setting water level；
2nd step, for the first time run 5min~15min after, control system 12 start aerator 6 in air pump 6-1, will be fresh
Air sprays eventually through aeration head 6-4 by being aerated main 6-2, aeration branch pipe 6-3 input, the Lake Water of aeration tank 2 is carried out
Air Exposure, it is 1m to control gas flow3/ h~5m3/h；
3rd step, the second water delivery device 8 input the Lake Water after being handled in aeration tank 2 in ultraviolet excitation chamber 9, control
System 12 starts fluorescent tube 9-2, carries out ultraviolet sterilization to processing water, while use water rate control in 10m3/ h~50m3/h；Short circuit
Alarm 9-3 starts, and when short-circuit alarming device 9-3 monitors there is short-circuit generation in circuit, short-circuit alarming device 9-3 is to control system 12
Signal is sent, control system 12 sends audio alarm, while water pump, the aeration that control system 12 is closed in the first water delivery device 1
Fluorescent tube 9-2, the magnetic valve of the tail end of discharge pipeline 4 in device 6, ultraviolet excitation chamber 9 so that whole system is stopped；When being
After system recovers normal, short-circuit alarming device 9-3 sends signal to control system 12, while control system 12 opens the first water delivery device
Water pump, aerator 6 in 1, the fluorescent tube 9-2 in ultraviolet excitation chamber 9, the magnetic valve of the tail end of discharge pipeline 4 so that whole system
Recover normal work；
4th step, the level sensor 2-5 positioned at the top of aeration tank 2, it is safe for operation to the water level of aeration tank 2 to be supervised in real time
Survey, when level sensor 2-5 monitors that water level exceeds water level early warning higher limit, i.e. water level eaves 5cm~10cm on aeration tank 2
When, level sensor sends signal to control system 12, and control system 12 sends audio alarm, while control system 12 closes the
Water pump, aerator 6 in one water delivery device 1, the fluorescent tube 9-2 in ultraviolet excitation chamber 9, the magnetic valve of the tail end of discharge pipeline 4, make
Whole system is obtained to be stopped；When level sensor 2-5 monitors that water level is less than water level early warning lower limit, i.e. water level is down to aeration
On pond 2 during below eaves 20cm, level sensor sends signal to control system 12, and control system 12 opens the first water delivery device 1
In water pump, aerator 6, the fluorescent tube 9-2 in ultraviolet excitation chamber 9, the magnetic valve of the tail end of discharge pipeline 4 so that whole system
Recover normal work；
After 5th step, operation 10min~50min, control system 12 is opened through the electric control valve of water pipe 10, after processing
Clear water is discharged into lake；
6th step, operation 5~10 days after, control system 12 monitors that sludge reaches certain value, then promotes the tail of discharge pipeline 4
The magnetic valve at end is opened, and sludge is discharged into sludge sump 5 by discharge pipeline 4.
It is a kind of disclosed in patent of the present invention to administer lake eutrophication ozone and ultraviolet irradiation equipment integrating and method, its
Advantage is：
(1) device is good using aeration processing lake water, microorganism removal effect；
(2) device uses ultraviolet irradiation after-treatment lake water, bright to N, P in lake water etc. nutrient removal effect
It is aobvious；
(3) device is tilted drainage plate and prepared using high polymer material, and purifying rate lifting is notable.
A kind of improvement lake eutrophication ozone and ultraviolet irradiation equipment integrating of the present invention and method structure are new
Clever rationally removal of impurity is high, and the scope of application is wide.
Brief description of the drawings
Fig. 1 is that a kind of heretofore described lake eutrophication ozone of administering is illustrated with ultraviolet irradiation equipment integrating
Figure.
Fig. 2 is heretofore described aeration tank internal structure schematic diagram.
Fig. 3 is heretofore described aerator schematic diagram.
Fig. 4 is the second heretofore described water delivery device schematic diagram.
Fig. 5 is heretofore described ultraviolet excitation chamber internal structure schematic diagram.
Fig. 6 is inclination drainage plate 2-3 of the present invention to lake water organic matter total degradation rate figure.
In figure 1 above~Fig. 5, the first water delivery device 1, aeration tank 2, aeration tank housing 2-1, horizontal filtering baffle plate 2-2, incline
Oblique drainage plate 2-3, vertical division board 2-4, level sensor 2-5, support 3, discharge pipeline 4, sludge sump 5, aerator 6, air pump
6-1, main 6-2 is aerated, aeration branch pipe 6-3, aeration head 6-4, ozone supply room 7, the second water delivery device 8, enters water conduit tube 8-1,
Water inlet pipe 8-2, distributive pipe 8-3, ultraviolet excitation chamber 9, shell 9-1, fluorescent tube 9-2, short-circuit alarming device 9-3, water pipe 10, float
Moving platform 11, control system 12.
Embodiment
A kind of lake eutrophication ozone of administering provided by the invention is integrally set with ultraviolet irradiation below in conjunction with the accompanying drawings
It is standby to be further described.
As shown in figure 1, it is that a kind of lake eutrophication ozone of administering provided by the invention irradiates equipment integrating with ultraviolet
Schematic diagram.Find out in figure, including：First water delivery device 1, aeration tank 2, support 3, discharge pipeline 4, sludge sump 5, aerator 6,
Ozone supply room 7, the second water delivery device 8, ultraviolet excitation chamber 9, water pipe 10, floating platform 11, control system 12；The exposure
Gas pond 2 is connected by the first water delivery device 1 with lake, and the first water delivery device 1 is provided with water pump, and water pump connects with the wire of control system 12
Connect；Discharge pipeline 4 is provided between the bottom of aeration tank 2 and sludge sump 5, the tail end of discharge pipeline 4 is provided with magnetic valve, magnetic valve and control
The wire of system 12 connects；The lower section of aeration tank 2 is provided with support 3, and the lower section of support 3 is provided with floating platform 11, the floating
The surface of platform 11 is provided with the aerator 6 being connected with the interior bottom portion of aeration tank 2, and the aerator 6 passes through pipeline and ozone
Supply chamber 7 is connected, and the second water delivery device 8, the ultraviolet excitation chamber 9 are provided between the aeration tank 2 and ultraviolet excitation chamber 9
Side wall is provided with water pipe 10, and the control system 12 is located at the surface of floating platform 11.
As shown in Fig. 2 it is heretofore described aeration tank internal structure schematic diagram.Find out from Fig. 2 or Fig. 1, it is described
Aeration tank 2 includes：Aeration tank housing 2-1, horizontal filtering baffle plate 2-2, tilt drainage plate 2-3, vertical division board 2-4, and water level passes
Sensor 2-5；The inclination drainage plate 2-3 is located at position to the left inside the housing 2-1 of aeration tank, and it is arc to tilt drainage plate 2-3 upper ends
Shape, bottom are incline structure, tilt drainage plate 2-3 side walls and aeration tank housing 2-1 inwall seamless weldings, tilt drainage plate 2-3
It it is 10 °~45 ° with horizontal plane angle；The horizontal filtering baffle plate 2-2, which is arranged horizontally in, tilts drainage plate 2-3 bottom positions, water
Flat filtering baffle 2-2 right walls are with tilting drainage plate 2-3 bottoms seamless welding, remaining side wall and wall seamless in the housing 2-1 of aeration tank
Welding, horizontal filtering baffle plate 2-2 surfaces are uniform-distribution with substantial amounts of through hole, and quantity is 30~100, and through hole spacing is 1mm
~20mm, pore diameter range value are 1mm~3mm；The vertical division board 2-4, which is arranged vertically on, tilts drainage plate 2-3 bottom positions,
Vertical division board 2-4 top surfaces are with tilting drainage plate 2-3 bottoms seamless welding, remaining side wall and wall seamless in the housing 2-1 of aeration tank
Welding；The inside of the aeration tank 2 is provided with level sensor 2-5, level sensor 2-5 away from the upper end cornice 5mm of aeration tank 2~
20mm, level sensor 2-5 are connected with the wire of control system 12.
As shown in figure 3, it is heretofore described aerator schematic diagram.Find out from Fig. 3 or Fig. 1, the aeration dress
Putting 6 includes：Air pump 6-1, it is aerated main 6-2, aeration branch pipe 6-3, aeration head 6-4；Described air pump 6-1 one end is connected by pipeline
Ozone supply room 7, other end connection are aerated main 6-2, and air pump 6-1 is connected with the wire of control system 12；The aeration main 6-2
The bottom of aeration tank 2 is stretched into above aeration tank 2；The aeration branch pipe 6-3 is laid in the baseplane of aeration tank 2, aeration branch pipe 6-3
With being aerated main 6-2 through connections, aeration main 6-2 quantity is 2~6, and multiple aeration main 6-2 are arranged in parallel and flat
The aeration main 6-2 mutual distances of row arrangement are equal, and the distance between adjacent two aeration mains 6-2 is 10mm~50mm, more
The individual ends of aeration main 6-2 bis- being arranged parallel to each other and middle part are connected with each other by connecting tube and penetrated；On the aeration branch pipe 6-3
Provided with aeration head 6-4, aeration head 6-4 and aeration branch pipe 6-3 through connections, aeration head 6-4 quantity are 50~100, multiple exposures
Gas head 6-4 arranges along the word uniform rectilinears of aeration branch pipe 6-3 mono-, adjacent aeration head 6-4 spacing 20mm~50mm, aeration head 6-4
Jet direction is arranged to upward, and the aeration head 6-4 surfaces are uniform-distribution with the micropore that a large amount of apertures are 0.5mm~1.2mm.
As shown in figure 4, it is the second heretofore described water delivery device schematic diagram.Find out from Fig. 4 or Fig. 1, described
Two water delivery devices 8 include：Enter water conduit tube 8-1, water inlet pipe 8-2, distributive pipe 8-3；It is described enter water conduit tube 8-1 one end be connected to exposure
The side wall top position of gas pond 2, other end connection water inlet pipe 8-2；It is described enter water conduit tube 8-1 and water inlet pipe 8-2 through connections；
The water inlet pipe 8-2 is provided with distributive pipe 8-3, and distributive pipe 8-3 quantity is 2~4, distributive pipe 8-3 symmetric arrays two-by-two,
Distributive pipe 8-3 is connected with water inlet pipe 8-2 internal run-throughs.
As shown in figure 5, it is heretofore described ultraviolet excitation chamber internal structure schematic diagram.From Fig. 5 or Fig. 1
Go out, the ultraviolet excitation chamber 9 includes：Shell 9-1, fluorescent tube 9-2, short-circuit alarming device 9-3；The fluorescent tube 9-2 is with layer structure
Parallel to be evenly arranged in inside shell 9-1, quantity is 15~30, adjacent two layers distance 50mm~80mm, adjacent fluorescent tube 9-2 water
Flat spacing is spacing 30mm~50mm, and fluorescent tube 9-2 is connected with the wire of control system 12, is electric exhausted between fluorescent tube 9-2 and shell 9-1
Edge structure, fluorescent tube 9-2 are connected with short-circuit alarming device 9-3 wires, and short-circuit alarming device 9-3 is connected with the wire of control system 12.
It is of the present invention it is a kind of administer lake eutrophication ozone and ultraviolet and irradiate the course of work of equipment integrating be.
1st step, control system 12 start the first water delivery device 1 and input Lake Water in aeration tank 2, inflow control is existed
10m3/ h~50m3/ h, Lake Water in aeration tank 2 by tilting drainage plate 2-3 guiding, and horizontal filtering baffle plate 2-2
Peptizaiton, while by vertical division board 2-4 laminar flow shunting, be uniformly distributed to the bottom of aeration tank 2 and be gradually increasing,
Until reach setting water level；
2nd step, for the first time run 5min~15min after, control system 12 start aerator 6 in air pump 6-1, will be fresh
Air sprays eventually through aeration head 6-4 by being aerated main 6-2, aeration branch pipe 6-3 input, the Lake Water of aeration tank 2 is carried out
Air Exposure, it is 1m to control gas flow3/ h~5m3/h；
3rd step, the second water delivery device 8 input the Lake Water after being handled in aeration tank 2 in ultraviolet excitation chamber 9, control
System 12 starts fluorescent tube 9-2, carries out ultraviolet sterilization to processing water, while use water rate control in 10m3/ h~50m3/h；Short circuit
Alarm 9-3 starts, and when short-circuit alarming device 9-3 monitors there is short-circuit generation in circuit, short-circuit alarming device 9-3 is to control system 12
Signal is sent, control system 12 sends audio alarm, while water pump, the aeration that control system 12 is closed in the first water delivery device 1
Fluorescent tube 9-2, the magnetic valve of the tail end of discharge pipeline 4 in device 6, ultraviolet excitation chamber 9 so that whole system is stopped；When being
After system recovers normal, short-circuit alarming device 9-3 sends signal to control system 12, while control system 12 opens the first water delivery device
Water pump, aerator 6 in 1, the fluorescent tube 9-2 in ultraviolet excitation chamber 9, the magnetic valve of the tail end of discharge pipeline 4 so that whole system
Recover normal work；
4th step, the level sensor 2-5 positioned at the top of aeration tank 2, it is safe for operation to the water level of aeration tank 2 to be supervised in real time
Survey, when level sensor 2-5 monitors that water level exceeds water level early warning higher limit, i.e. water level eaves 5cm~10cm on aeration tank 2
When, level sensor sends signal to control system 12, and control system 12 sends audio alarm, while control system 12 closes the
Water pump, aerator 6 in one water delivery device 1, the fluorescent tube 9-2 in ultraviolet excitation chamber 9, the magnetic valve of the tail end of discharge pipeline 4, make
Whole system is obtained to be stopped；When level sensor 2-5 monitors that water level is less than water level early warning lower limit, i.e. water level is down to aeration
On pond 2 during below eaves 20cm, level sensor sends signal to control system 12, and control system 12 opens the first water delivery device 1
In water pump, aerator 6, the fluorescent tube 9-2 in ultraviolet excitation chamber 9, the magnetic valve of the tail end of discharge pipeline 4 so that whole system
Recover normal work；
After 5th step, operation 10min~50min, control system 12 is opened through the electric control valve of water pipe 10, after processing
Clear water is discharged into lake；
6th step, operation 5~10 days after, control system 12 monitors that sludge reaches certain value, then promotes the tail of discharge pipeline 4
The magnetic valve at end is opened, and sludge is discharged into sludge sump 5 by discharge pipeline 4.
A kind of lake eutrophication ozone of administering of the present invention irradiates equipment integrating novel and reasonable structure with ultraviolet,
Removal of impurity is high, and the scope of application is wide.
It is the embodiment of inclination drainage plate 2-3 of the present invention manufacturing process below, embodiment is in order to furtherly
Bright present disclosure, but should not be construed as limiting the invention.Without departing from the spirit and substance of the case in the present invention, it is right
The modification and replacement that the inventive method, step or condition are made, belong to the scope of the present invention.
Unless otherwise specified, the conventional meanses that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
Count in parts by weight, and according to following steps manufacture inclination drainage plate 2-3 of the present invention：
1st step, 500 parts of the ultra-pure water that electrical conductivity is 0.008 μ S/cm is added in a kettle, start in reactor and stir
Device, rotating speed 130rpm, start heat pump, reactor temperature is risen to 42 DEG C；Sequentially add 7 parts of dicyclohexyl amine, three second
1 part of base arsenic, 3 parts of anilinomethyl trimethoxy silane, to being completely dissolved, regulation pH value is 3.5, and agitator speed is adjusted to for stirring
75rpm, temperature are 50 DEG C, esterification 3 hours；
2nd step, 4 parts of p-methylphenyl ethyl ketone is taken, 5 parts of crushing of isobutyl stearate, powder diameter is 430 mesh；Add three flowers
Raw 10 parts of acid glyceride is well mixed, is laid in pallet, and tiling thickness is 15mm, uses the dosage to be for 1.0kGy, energy
3.0MeV alpha ray irradiates 20 minutes, and the β x ray irradiation xs 10 minutes of Isodose；
3rd step, the mixed-powder handled through the 2nd step are dissolved in 600 parts of the pinacol that concentration is 20ppm, add reactor,
Agitator speed is 40rpm, and temperature is 75 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.05MPa, keeps this shape
State is reacted 3 hours；Pressure release is simultaneously passed through nitrogen, and it is 0.005MPa to make reacting kettle inner pressure, and insulation stands 4 hours；Agitator speed
It is promoted to 80rpm, simultaneous reactions kettle pressure release to 0MPa；2 parts of phthalic anhydride is sequentially added, 7 parts of SA dibutyl ester is completely
After dissolving, add 3 parts of crosslinking agent and be stirred so that the hydrophilic lipophilic balance of reactor solution is 4.0, and it is small that insulation stands 3
When；The crosslinking agent is carbic anhydride；
4th step, when agitator speed is 80rpm, sequentially add 5 parts of chloroacetaldehyde, two 1 part of oxalic acid hydrates, methoxyl group second
8 parts of alcohol acetate, 6 parts of acrylonitrile, reactor pressure is lifted, reach 0.08MPa, temperature is 135 DEG C, and polymerisation 3 is small
When；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 35 DEG C is cooled to, discharging, enters molding press and can be prepared by tilting drainage
Plate 2-3.
Embodiment 2
Count in parts by weight, and according to following steps manufacture inclination drainage plate 2-3 of the present invention：
1st step, 950 parts of the ultra-pure water that electrical conductivity is 0.04 μ S/cm is added in a kettle, start in reactor and stir
Device, rotating speed 200rpm, start heat pump, reactor temperature is risen to 60 DEG C；Sequentially add 15 parts of dicyclohexyl amine, three second
12 parts of base arsenic, 17 parts of anilinomethyl trimethoxy silane, to being completely dissolved, regulation pH value is 7.5, and agitator speed is adjusted for stirring
To 120rpm, temperature is 90 DEG C, esterification 7 hours；
2nd step, 20 parts of p-methylphenyl ethyl ketone is taken, 26 parts of crushing of isobutyl stearate, powder diameter is 520 mesh；Add three
30 parts of peanut acid glyceride is well mixed, is laid in pallet, and tiling thickness is 40mm, uses the dosage to be for 3.5kGy, energy
7.0MeV alpha ray irradiates 35 minutes, and the β x ray irradiation xs 60 minutes of Isodose；
3rd step, the mixed-powder handled through the 2nd step are dissolved in 800 parts of the pinacol that concentration is 120ppm, add reaction
Kettle, agitator speed 60rpm, temperature are 85 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.03MPa, keeps this
State response 9 hours；Pressure release is simultaneously passed through nitrogen, and it is 0.020MPa to make reacting kettle inner pressure, and insulation stands 10 hours；Agitator turns
Speed is promoted to 160rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add 14 parts of phthalic anhydride, 16 parts of SA dibutyl ester
After being completely dissolved, add 20 parts of crosslinking agent and be stirred so that the hydrophilic lipophilic balance of reactor solution is 10, and insulation is stood
6 hours；The crosslinking agent is ortho-nitraniline；
4th step, when agitator speed is 110rpm, sequentially add 25 parts of chloroacetaldehyde, two 10 parts of oxalic acid hydrates, methoxyl group
20 parts of acetate ethanol ester, 25 parts of acrylonitrile, reactor pressure is lifted, reach 0.30MPa, temperature is 155 DEG C, polymerisation
10 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 50 DEG C is cooled to, discharging, enters molding press and can be prepared by tilting
Drainage plate 2-3.
Embodiment 3
Count in parts by weight, and according to following steps manufacture inclination drainage plate 2-3 of the present invention：
1st step, 550 parts of the ultra-pure water that electrical conductivity is 0.028 μ S/cm is added in a kettle, start in reactor and stir
Device, rotating speed 180rpm, start heat pump, reactor temperature is risen to 46 DEG C；Sequentially add 9 parts of dicyclohexyl amine, three second
11 parts of base arsenic, 9 parts of anilinomethyl trimethoxy silane, to being completely dissolved, regulation pH value is 3.7, and agitator speed is adjusted for stirring
To 100rpm, temperature is 59 DEG C, esterification 5 hours；
2nd step, 42 parts of p-methylphenyl ethyl ketone is taken, 8 parts of crushing of isobutyl stearate, powder diameter is 452 mesh；Add three flowers
Raw 13 parts of acid glyceride is well mixed, is laid in pallet, and tiling thickness is 16mm, uses the dosage to be for 1.35kGy, energy
3.7MeV alpha ray irradiates 25 minutes, and the β x ray irradiation xs 20 minutes of Isodose；
3rd step, the mixed-powder handled through the 2nd step are dissolved in 700 parts of the pinacol that concentration is 60ppm, add reactor,
Agitator speed is 46rpm, and temperature is 78 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.04MPa, keeps this shape
State is reacted 6 hours；Pressure release is simultaneously passed through nitrogen, and it is 0.009MPa to make reacting kettle inner pressure, and insulation stands 5 hours；Agitator speed
It is promoted to 90rpm, simultaneous reactions kettle pressure release to 0MPa；4 parts of phthalic anhydride is sequentially added, 9 parts of SA dibutyl ester is completely
After dissolving, add 7 parts of crosslinking agent and be stirred so that the hydrophilic lipophilic balance of reactor solution is 8, and insulation stands 5 hours；
The crosslinking agent is adjacent iodine biphenyl；
4th step, when agitator speed is 90rpm, sequentially add 9 parts of chloroacetaldehyde, two 8 parts of oxalic acid hydrates, methoxyl group second
12 parts of alcohol acetate, 9 parts of acrylonitrile, reactor pressure is lifted, reach 0.09MPa, temperature is 145 DEG C, and polymerisation 6 is small
When；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 45 DEG C is cooled to, discharging, enters molding press and can be prepared by tilting drainage
Plate 2-3.
Reference examples
Reference examples tilt processing procedure of the drainage plate for Eutrophication Lake Water for certain commercially available brand.
Embodiment 4
The inclination drainage plate described in inclination drainage plate 2-3 and reference examples that embodiment 1~3 is prepared is used for eutrophy
Change the processing procedure of lake water.Processing terminate after respectively to the property of Eutrophication Lake Water, and its join to Eutrophication Lake Water is every
Several influences detect.Table 1 is the inclination drainage plate performance measurement contrast described in embodiment 1~3 and reference examples.
As seen from Table 1, inclination drainage plate 2-3 of the present invention, its degree of polymerization of degrading, degraded strength enhancing rate, degraded
Yield enhancing rate, water purification rate, the product for being above prior art production.
In addition, as shown in fig. 6, it is inclination drainage plate 2-3 of the present invention to lake water organic matter total degradation rate.Seen in figure
Go out, the inclination drainage plate 2-3 materials manufactured by high polymer material are evenly distributed, and material surface product is bigger with volume, surface point
The concentration relative comparison example for dissipating the dispersible carrier that property is good, dissociates in continuous phase is high.Using the inclination drainage plate 2-3 of the present invention, make
The aggregation of lake water organic matter is agglomerating small, forms the precipitation body of dispersed structure, by the inclination drainage plate 2-3 of high polymer material manufacture to lake
Water organic matter has good degradation property；Using inclination drainage plate 2-3 of the present invention, it is excellent to lake water organic matter total degradation rate
In existing product.
Claims (6)
1. one kind administers lake eutrophication ozone and ultraviolet irradiation equipment integrating, including：First water delivery device（1）, aeration
Pond（2）, support（3）, discharge pipeline（4）, sludge sump（5）, aerator（6）, ozone supply room（7）, the second water delivery device（8）,
Ultraviolet excitation chamber（9）, water pipe（10）, floating platform（11）, control system（12）；Characterized in that, the aeration tank（2）
Pass through the first water delivery device（1）It is connected with lake, the first water delivery device（1）Provided with water pump, water pump and control system（12）Wire
Connection；The aeration tank（2）Bottom and sludge sump（5）Between be provided with discharge pipeline（4）, discharge pipeline（4）Tail end is provided with magnetic valve, electricity
Magnet valve and control system（12）Wire connects；The aeration tank（2）Lower section is provided with support（3）, the support（3）Lower section is provided with floating
Moving platform（11）, the floating platform（11）Surface is provided with and aeration tank（2）The aerator that interior bottom portion is connected（6）, institute
State aerator（6）Pass through pipeline and ozone supply room（7）It is connected, the aeration tank（2）With ultraviolet excitation chamber（9）Between set
There is the second water delivery device（8）, the ultraviolet excitation chamber（9）Side wall is provided with water pipe（10）, the control system（12）It is located at
Floating platform（11）Surface；
The aeration tank（2）Including：Aeration tank housing（2-1）, horizontal filtering baffle plate（2-2）, tilt drainage plate（2-3）, vertically
Division board（2-4）, level sensor（2-5）；The inclination drainage plate（2-3）Positioned at aeration tank housing（2-1）Internal position to the left
Put, tilt drainage plate（2-3）Upper end is arc, and bottom is incline structure, tilts drainage plate（2-3）Side wall and aeration tank housing
（2-1）Inwall seamless welding, tilt drainage plate（2-3）It it is 10 °~45 ° with horizontal plane angle；The horizontal filtering baffle plate（2-2）
It is arranged horizontally in inclination drainage plate（2-3）Bottom position, horizontal filtering baffle plate（2-2）Right wall is with tilting drainage plate（2-3）Bottom
Seamless welding, remaining side wall and aeration tank housing（2-1）Inwall seamless welding, horizontal filtering baffle plate（2-2）Surface is uniformly distributed
Substantial amounts of through hole, quantity is 30~100, and through hole spacing is 1mm~20mm, and pore diameter range value is 1mm~3mm；It is described
Vertical division board（2-4）It is arranged vertically on inclination drainage plate（2-3）Bottom position, vertical division board（2-4）Top surface draws with inclination
Flowing plate（2-3）Bottom seamless welding, remaining side wall and aeration tank housing（2-1）Inwall seamless welding；The aeration tank（2）It is internal
Provided with level sensor（2-5）, level sensor（2-5）Away from aeration tank（2）Upper end cornice 5mm~20mm, level sensor（2-
5）With control system（12）Wire connects.
2. a kind of lake eutrophication ozone of administering according to claim 1 irradiates equipment integrating, its feature with ultraviolet
It is, the aerator（6）Including：Air pump（6-1）, it is aerated main（6-2）, aeration branch pipe（6-3）, aeration head（6-4）；Institute
State air pump（6-1）One end connects ozone supply room by pipeline（7）, other end connection aeration main（6-2）, air pump（6-1）With
Control system（12）Wire connects；The aeration main（6-2）From aeration tank（2）Aeration tank is stretched into top（2）Bottom；It is described
Aeration branch pipe（6-3）It is laid in aeration tank（2）Baseplane, aeration branch pipe（6-3）With being aerated main（6-2）Through connection, aeration
Main（6-2）Quantity be 2~6, multiple aeration mains（6-2）Aeration main arranged in parallel and arranged in parallel（6-2）Phase
Mutual edge distance is equal, adjacent two aeration mains（6-2）The distance between be 10mm~50mm, multiple aerations being arranged parallel to each other
Main（6-2）Two ends and middle part are connected with each other by connecting tube to be penetrated；The aeration branch pipe（6-3）It is provided with aeration head（6-4）,
Aeration head（6-4）With aeration branch pipe（6-3）Through connection, aeration head（6-4）Quantity is 50~100, multiple aeration heads（6-4）
Along aeration branch pipe（6-3）One word uniform rectilinear arranges, adjacent aeration head（6-4）Spacing 20mm~50mm, aeration head（6-4）Spray
Gas direction is arranged to upward, the aeration head（6-4）Surface is uniform-distribution with the micropore that a large amount of apertures are 0.5mm~1.2mm.
3. a kind of lake eutrophication ozone of administering according to claim 1 irradiates equipment integrating, its feature with ultraviolet
It is, second water delivery device（8）Including：Enter water conduit tube（8-1）, water inlet pipe（8-2）, distributive pipe（8-3）；The water inlet
Main（8-1）One end is connected to aeration tank（2）Side wall top position, other end connection water inlet pipe（8-2）；It is described enter water conduit tube
（8-1）With water inlet pipe（8-2）Through connection；The water inlet pipe（8-2）It is provided with distributive pipe（8-3）, distributive pipe（8-3）'s
Quantity is 2~4, distributive pipe（8-3）Symmetric arrays two-by-two, distributive pipe（8-3）With water inlet pipe（8-2）Internal run-through connects.
4. a kind of lake eutrophication ozone of administering according to claim 2 irradiates equipment integrating, its feature with ultraviolet
It is, the ultraviolet excitation chamber（9）Including：Shell（9-1）, fluorescent tube（9-2）, short-circuit alarming device（9-3）；The fluorescent tube（9-
2）Shell is evenly arranged in so that layer structure is parallel（9-1）Inside, quantity are 15~30, the mm of adjacent two layers distance 50~
80mm, adjacent fluorescent tube（9-2）Level interval is 30 mm of spacing~50mm, fluorescent tube（9-2）With control system（12）Wire connects,
Fluorescent tube（9-2）With shell（9-1）Between be electrically insulated structures, fluorescent tube（9-2）With short-circuit alarming device（9-3）Wire connects, short circuit
Alarm（9-3）With control system（12）Wire connects.
5. a kind of lake eutrophication ozone of administering according to claim 2 irradiates equipment integrating, its feature with ultraviolet
It is, the inclination drainage plate（2-3）It is molded by high polymer material pressing mold, tilts drainage plate（2-3）Constituent and manufacture
Process is as follows：
First, drainage plate is tilted（2-3）Constituent：
Count in parts by weight, 7~15 parts of dicyclohexyl amine, 1~12 part of arsenic triethyl, 3~17 parts of anilinomethyl trimethoxy silane,
4~20 parts of p-methylphenyl ethyl ketone, 5~26 parts of isobutyl stearate, three 10~30 parts of peanut acid glycerides, concentration be 20ppm~
600~800 parts of 120ppm pinacol, 2~14 parts of phthalic anhydride, 7~16 parts of SA dibutyl ester, crosslinking agent 3~20
Part, 5~25 parts of chloroacetaldehyde, two 1~10 part of oxalic acid hydrates, 8~20 parts of methyl cellosolve acetate, 6~25 parts of acrylonitrile；
The crosslinking agent is any one in carbic anhydride, adjacent iodine biphenyl, ortho-nitraniline；
2nd, drainage plate is tilted（2-3）Manufacturing process, comprise the steps of：
1st step, 500~950 parts of the ultra-pure water that electrical conductivity is the μ S/cm of 0.008 μ S/cm~0.04 is added in a kettle, start
Agitator in reactor, rotating speed are 130rpm~200rpm, start heat pump, reactor temperature is risen to 42 DEG C~60
℃；Dicyclohexyl amine, arsenic triethyl, anilinomethyl trimethoxy silane are sequentially added, to being completely dissolved, adjusting pH value is for stirring
3.5~7.5, agitator speed is adjusted to 75rpm~120rpm, temperature is 50 DEG C~90 DEG C, esterification 3~7 hours；
2nd step, p-methylphenyl ethyl ketone, isobutyl stearate is taken to crush, powder diameter is 430~520 mesh；It is sweet to add three arachidic acids
Grease is well mixed, and is laid in pallet, and tiling thickness is 15 mm~40mm, uses dosage as 1.0kGy~3.5kGy, energy
Irradiated 20~35 minutes for 3.0MeV~7.0MeV alpha ray, and the β x ray irradiation xs 10~60 minutes of Isodose；
3rd step, through the 2nd step handle mixed-powder be dissolved in pinacol, add reactor, agitator speed be 40rpm~
60rpm, temperature are 75 DEG C~85 DEG C, and starting vavuum pump makes the vacuum of reactor reach -0.05MPa~-0.03MPa, keeps
This state response 3~9 hours；Pressure release is simultaneously passed through nitrogen, and it is 0.005 MPa~0.020MPa to make reacting kettle inner pressure, and insulation is quiet
Put 4~10 hours；Agitator speed is promoted to 80rpm~160rpm, simultaneous reactions kettle pressure release to 0MPa；Sequentially add adjacent benzene two
After formic anhydride, SA dibutyl ester are completely dissolved, add crosslinking agent and be stirred so that the hydrophile-lipophile balance of reactor solution
It is worth for 4.0~10, insulation stands 3~6 hours；
4th step, when agitator speed is 80rpm~110rpm, sequentially add chloroacetaldehyde, two oxalic acid hydrates, methyl cellosolve
Acetate and acrylonitrile, reactor pressure is lifted, reach 0.08MPa~0.30MPa, temperature is 135 DEG C~155 DEG C, is gathered
Close reaction 3~10 hours；Reacting kettle inner pressure is down to 0MPa after the completion of reaction, 35 DEG C~50 DEG C is cooled to, discharging, enters pressing mold
Machine can be prepared by tilting drainage plate（2-3）.
6. one kind is using improvement lake eutrophication ozone as described in claim 4 and ultraviolet irradiation equipment integrating processing
The method of lake eutrophication, it is characterised in that including following steps：
1st step, control system（12）Start the first water delivery device（1）Lake Water is inputted into aeration tank（2）It is interior, make inflow control
In 10m3/ h~50m3/ h, Lake Water is in aeration tank（2）In by tilting drainage plate（2-3）Guiding, and horizontal filtering baffle plate
（2-2）Peptizaiton, while pass through vertical division board（2-4）Laminar flow shunting, be uniformly distributed to aeration tank（2）Bottom
And be gradually increasing, until reaching setting water level；
2nd step, for the first time run 5min~15min after, control system（12）Start aerator（6）In air pump（6-1）, will be new
Fresh air is by being aerated main（6-2）, aeration branch pipe（6-3）Input, eventually through aeration head（6-4）Spray, to aeration tank（2）
Lake Water carries out Air Exposure, and it is 1m to control gas flow3/ h~5m3/h；
3rd step, the second water delivery device（8）By aeration tank（2）Lake Water input ultraviolet excitation chamber after interior processing（9）It is interior, control
System processed（12）Start fluorescent tube（9-2）, ultraviolet sterilization is carried out to processing water, while use water rate control in 10m3/ h~50m3/
h；Short-circuit alarming device（9-3）Start, when short-circuit alarming device（9-3）Monitor there is short-circuit generation in circuit, short-circuit alarming device（9-3）
To control system（12）Send signal, control system（12）Send audio alarm, while control system（12）Close the first water delivery
Device（1）In water pump, aerator（6）, ultraviolet excitation chamber（9）In fluorescent tube（9-2）, discharge pipeline（4）The electromagnetism of tail end
Valve so that whole equipment is stopped；After equipment recovers normal, short-circuit alarming device（9-3）To control system（12）Send letter
Number, while control system（12）Open the first water delivery device（1）In water pump, aerator（6）, ultraviolet excitation chamber（9）In
Fluorescent tube（9-2）, discharge pipeline（4）The magnetic valve of tail end so that whole equipment recovers normal work；
4th step, positioned at aeration tank（2）The level sensor at top（2-5）, to aeration tank（2）Water level is safe for operation to be carried out in real time
Monitoring, works as level sensor（2-5）Monitor that water level exceeds water level early warning higher limit, i.e., water level is in aeration tank（2）Upper eaves 5cm~
During 10cm, level sensor is to control system（12）Send signal, control system（12）Send audio alarm, while control system
（12）Close the first water delivery device（1）In water pump, aerator（6）, ultraviolet excitation chamber（9）In fluorescent tube（9-2）, spoil disposal
Pipe（4）The magnetic valve of tail end so that whole equipment is stopped；Work as level sensor（2-5）Monitor that water level is pre- less than water level
Alert lower limit, i.e. water level are down to aeration tank（2）During upper below eaves 20cm, level sensor is to control system（12）Send signal,
Control system（12）Open the first water delivery device（1）In water pump, aerator（6）, ultraviolet excitation chamber（9）In fluorescent tube
（9-2）, discharge pipeline（4）The magnetic valve of tail end so that whole equipment recovers normal work；
After 5th step, operation 10min~50min, control system（12）Open through water pipe（10）Electric control valve, after processing
Clear water is discharged into lake；
6th step, operation 5~10 days after, control system（12）Monitor that sludge reaches certain value, then promote discharge pipeline（4）Tail
The magnetic valve at end is opened, and sludge passes through discharge pipeline（4）It is discharged into sludge sump（5）In.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876578A (en) * | 2006-06-13 | 2006-12-13 | 张强 | Eutrophication water body self-cleaning restoration method and restoring device |
| CN102092865A (en) * | 2010-12-10 | 2011-06-15 | 同济大学 | Integrated buoy type solar driven stream-making aerator and water body in-situ remediation method |
| CN104261578A (en) * | 2014-10-24 | 2015-01-07 | 上海冬翼光电有限公司 | Water body purification system |
| CN204298200U (en) * | 2014-11-20 | 2015-04-29 | 北京明信德诚环境设备有限公司 | Biochemical treatment equipment and organically-polluted water continous processing system |
| CN105314736A (en) * | 2015-10-15 | 2016-02-10 | 何锦柱 | Eutrophic purification system |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR100843313B1 (en) * | 2007-11-13 | 2008-07-03 | 주식회사 동양일렉트로닉스 | Circulation type water purifier |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876578A (en) * | 2006-06-13 | 2006-12-13 | 张强 | Eutrophication water body self-cleaning restoration method and restoring device |
| CN102092865A (en) * | 2010-12-10 | 2011-06-15 | 同济大学 | Integrated buoy type solar driven stream-making aerator and water body in-situ remediation method |
| CN104261578A (en) * | 2014-10-24 | 2015-01-07 | 上海冬翼光电有限公司 | Water body purification system |
| CN204298200U (en) * | 2014-11-20 | 2015-04-29 | 北京明信德诚环境设备有限公司 | Biochemical treatment equipment and organically-polluted water continous processing system |
| CN105314736A (en) * | 2015-10-15 | 2016-02-10 | 何锦柱 | Eutrophic purification system |
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