CN105729923B - 装修用抗菌低气味轻质复合板 - Google Patents
装修用抗菌低气味轻质复合板 Download PDFInfo
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Abstract
本发明公开了一种装修用抗菌低气味轻质复合板,由复合板和面饰两个部分组成,所述复合板由25‑35wt%玻璃纤维和65‑75wt%抗菌低气味丙纶纤维制备而成。本发明装修用抗菌低气味轻质复合板,丙纶纤维进行抗菌除味处理赋予轻质复合板材优异的抗菌性能,延长板材的使用时间,长时间保持美观,不变形变色,并且气味低,保证使用者的健康;本发明还具有优良的综合力学性能;产品易于成型,加工工艺简单,能够提高生产效率,降低生产成本,不会产生甲醛等化学性污染。
Description
技术领域
本发明涉及高分子复合材料技术领域,具体涉及一种装修用抗菌低气味轻质复合板。
背景技术
随着建筑业的飞速发展,模板工程的地位日益突出,模板技术直接影响工程建设的质量、造价和效益,同时绿色、低碳、可持续等理念也在各类工程应用中逐渐成为热点。传统的建筑模板如木模板、竹胶合板、木胶合板等需要大量使用木材,不仅造成森林资源的破坏,而且废弃物无法实现再次利用,大部分被弃置或焚烧,极易造成环境污染。现代钢模板的生产耗能、材料费用、安装费用都较高,比较适用于大模板、工具式模板的使用。加之塑料行业的不断发展,因此,木塑复合模板应运而生,它结合了木材与塑料的优点,如耐候、可靠、环保、便利、可回收等。
装饰材料分为两大部分:一部分为室外材料,一部分为室内材料。室内材料再分为实材,板材、片材、型材、线材五个类型。实材也就是原材,主要是指原木及原木制成。常用的原木有杉木、红松、榆木、水曲柳,香樟、椴木,比较贵重的有花梨木、榉木、橡木等。在装修中所用木方主要由杉木制成,其他木材主要用于配套家具和雕花配件。
内墙装饰传统的作法是刷石灰水或墙粉,但容易污染,不能用湿法擦洗,多用于一般建筑。较高级的建筑多用平光调和漆,色泽丰富,不易污染,但掺入的有机溶剂挥发量大,污染大气,影响施工人员的健康,随着科学的发展,有机合成树脂原料广泛地用于油漆,使油漆产品面貌发生根本变化而被称为涂料,成为一类重要的内外墙装饰材料。用纸裱糊室内墙面和顶棚有悠久的历史,但已被塑料壁纸和玻璃纤维贴墙布所替代。石膏板有防火、隔声、隔热、轻质高强、施工方便等特点,主要用于墙面和平顶;作平顶时,可打成各种花纹的孔,以提高吸声和装饰效果。钙塑板有良好的装饰效果,能保温隔声,是多功能板材。装修用抗菌低气味轻质复合板用于装饰高级宾馆、公寓的也日益增多。
本发明提供了一种装修用抗菌低气味轻质复合板,具有优异的抗菌性能,并且气味低。
发明内容
针对现有技术存在的不足,本发明要解决的技术问题是提供一种装修用抗菌低气味轻质复合板。
为解决上述问题,本发明采用如下技术方案:
一种装修用抗菌低气味轻质复合板(又称玻璃纤维/丙纶纤维抗菌低气味轻质复合板),由复合板和面饰两个部分组成,所述复合板由25-35wt%玻璃纤维和65-75wt%抗菌低气味丙纶纤维制备而成;
所述抗菌低气味丙纶纤维由下述重量份的原料制备而成:丙纶切片50-70份、硬脂酸锌1-5份、硅藻土1-5份、氧化镁1-5份、抗菌剂0.5-1.5份、除味剂0.5-1.5份。
所述抗菌剂由1,3-二氯-5,5-二甲基海因、1,3-二氯-5-甲基-5-乙基海因、5-(4-氯丁基)海因混合而成,所述1,3-二氯-5,5-二甲基海因、1,3-二氯-5-甲基-5-乙基海因、5-(4-氯丁基)海因的质量比为(1-3):(1-3):(1-3)。
所述除味剂由40-60wt%二乙基二丙烯酸铝盐和40-60wt%2-羟基丁二酸锌组成。
优选地,其特征在于,所述面饰为棉布、麻布或化纤面料。
优选地,所述的玻璃纤维,长度为6-8cm;所述的丙纶纤维,长度为6-11cm。
具体的,在本发明中:
1,3-二氯-5,5-二甲基海因,CAS号:118-52-5。
1,3-二氯-5-甲基-5-乙基海因,CAS号:89415-87-2。
5-(4-氯丁基)海因,CAS号:40126-55-4。
二乙基二丙烯酸铝盐,CAS号:1068-22-0
2-羟基丁二酸锌,CAS号:2847-05-4。
硬脂酸锌,CAS号:557-05-1。
本发明装修用抗菌低气味轻质复合板,丙纶纤维进行抗菌除味处理赋予轻质复合板材优异的抗菌性能,延长板材的使用时间,长时间保持美观,不变形变色,并且气味低,保证使用者的健康;本发明还具有优良的综合力学性能;产品易于成型,加工工艺简单,能够提高生产效率,降低生产成本,不会产生甲醛等化学性污染。
具体实施方式
下面是对本发明的优选实施例进行详细阐述,以使本发明的优点和特征能更易于被本领域技术人员理解,从而对本发明的保护范围做出更为清楚明确的界定。
实施例原料介绍:
硅藻土,CAS号:91053-39-3,采用上海亮江钛白化工制品有限公司提供的型号为3000的超白硅藻土粉1250目。
氧化镁,CAS号:1309-48-4,粒径10-20nm。
玻璃纤维,CAS号:65997-17-3,采用广州市昊兆化工有限公司生产的A级无碱玻璃纤维。
丙纶切片,CAS号:9003-07-0,采用甘肃兰港石化有限公司生产的牌号为BH的聚丙烯切片。
面饰,采用纯棉水刺布,克重100g/m2。
实施例1
复合板原料:3kg玻璃纤维、7kg抗菌低气味丙纶纤维。
抗菌低气味丙纶纤维原料:丙纶切片6.2kg、硬脂酸锌0.3kg、硅藻土0.3kg、氧化镁0.3kg、抗菌剂0.09kg、除味剂0.08kg。
所述抗菌剂由0.03kg1,3-二氯-5,5-二甲基海因、0.03kg1,3-二氯-5-甲基-5-乙基海因、0.03kg5-(4-氯丁基)海因混合而成。
所述除味剂由0.04kg二乙基二丙烯酸铝盐和0.04kg 2-羟基丁二酸锌组成。
装修用抗菌低气味轻质复合板(又称玻璃纤维/丙纶纤维抗菌低气味轻质复合板)的制备方法,包括以下步骤:
(1)将丙纶切片、硬脂酸锌、硅藻土、氧化镁、抗菌剂、除味剂放入高速混合机,混合均匀后加入双螺杆挤出机,再经双螺杆挤出机在温度为210℃下进行溶融混合造粒,得到母粒;经BCF纺丝机组纺丝,采用常规丙纶纺丝工艺,得到抗菌低气味丙纶纤维,线密度:1300dtex/144f。
(2)将长度为7cm的玻璃纤维和长度为9cm的抗菌低气味丙纶纤维混合均匀,投入开松机内进行开松处理,每次处理7min,重复3次;然后送入大仓;将开松混合过的纤维输送至梳理机进行梳理成形;将梳理后的纤维送入铺网机中交叉铺网;将铺好的网折叠后送入预针刺机中进行预针刺成毡。
将预针刺好的毡继续送入主针刺机中进行主针刺,加热预压成卷材,加热温度150℃,时间120s;
开启热压辊,上、下辊的温度分别恒定在110℃和130℃,将热风干燥后的卷材送入放卷机放卷引毡,放卷引毡的放卷速度与生产线速度同步,放卷速度为2.5mm/min左右;采用红外烘箱进行加热至温度为160℃,时间70s,采用预压辊进行预压成型,脱模后即可制得纤维复合板,克重为1100g/m2;
(3)将纤维复合板经过平板加热软化处理,采用电热丝烘箱进行加热至温度为190℃,加热时间为90秒,升起热复合辊,将纤维复合板送入热复合辊中,待纤维复合板拉平整后降下热复合辊,同时将胶膜和面饰分别粘在纤维复合板上下表面上,将其一同送入热复合辊中;经水冷辊压冷却成板材,按照工艺单要求,剪裁成要求规格的成品,即得所述装修用抗菌低气味轻质复合板,克重为1200g/m2。
实施例2
按实施例1的原料配比和方法制备装修用抗菌低气味轻质复合板,区别仅仅在于:所述抗菌剂由0.045kg1,3-二氯-5,5-二甲基海因、0.045kg1,3-二氯-5-甲基-5-乙基海因混合而成。得到实施例2的装修用抗菌低气味轻质复合板,克重为1200g/m2。
实施例3
按实施例1的原料配比和方法制备装修用抗菌低气味轻质复合板,区别仅仅在于:所述抗菌剂由0.045kg1,3-二氯-5,5-二甲基海因、0.045kg5-(4-氯丁基)海因混合而成。得到实施例3的装修用抗菌低气味轻质复合板,克重为1200g/m2。
实施例4
按实施例1的原料配比和方法制备装修用抗菌低气味轻质复合板,区别仅仅在于:所述抗菌剂由0.045kg1,3-二氯-5-甲基-5-乙基海因、0.045kg5-(4-氯丁基)海因混合而成。得到实施例4的装修用抗菌低气味轻质复合板,克重为1200g/m2。
实施例5
按实施例1的原料配比和方法制备装修用抗菌低气味轻质复合板,区别仅仅在于:所述除味剂为0.08kg二乙基二丙烯酸铝盐。得到实施例5的装修用抗菌低气味轻质复合板,克重为1200g/m2。
实施例6
按实施例1的原料配比和方法制备装修用抗菌低气味轻质复合板,区别仅仅在于:所述除味剂为0.08kg 2-羟基丁二酸锌。得到实施例6的装修用抗菌低气味轻质复合板,克重为1200g/m2。
测试例1
对实施例1-6制备得到的装修用抗菌低气味轻质复合板抗菌性能进行测试,采用常规微生物杀菌力检测,大肠杆菌ATYCC 25922、金黄色葡萄球菌ATCC 6538。具体测试结果见表1:
表1:装修用抗菌低气味轻质复合板抗菌性能测试数据表
比较实施例1与实施例2-4,在抗菌剂加入总量相同的情况下,实施例1(抗菌剂采用1,3-二氯-5,5-二甲基海因、1,3-二氯-5-甲基-5-乙基海因、5-(4-氯丁基)海因复配)装修用抗菌低气味轻质复合板抗菌性能明显优于实施例2-4(抗菌剂采用1,3-二氯-5,5-二甲基海因、1,3-二氯-5-甲基-5-乙基海因、5-(4-氯丁基)海因中任意二者复配)。
测试例2
对实施例1-6制备得到的装修用抗菌低气味轻质复合板按SMC 30156-2007标准方法检测,试样按C类,取50cm3,容器取1L;时效处理条件为温度80℃,时间120min。气味公判标准分为1-6级,气味评判标准如下:1不易感觉到;2可感觉到,但不刺鼻;3可明显感觉到,但不刺鼻;4刺鼻;5非常刺鼻;6不可忍受。具体测试结果见表2:
表2:抗菌低气味ABS塑料气味测试数据表
样品 | 气味等级 |
实施例1 | 1.5 |
实施例2 | 2.5 |
实施例3 | 3 |
实施例4 | 2.5 |
实施例5 | 3.5 |
实施例6 | 3.5 |
比较实施例1与实施例2-3,在除味剂加入总量相同的情况下,实施例1(二乙基二丙烯酸铝盐和2-羟基丁二酸锌复配)装修用抗菌低气味轻质复合板的气味等级明显优于实施例2-3(二乙基二丙烯酸铝盐和2-羟基丁二酸锌中单一原料)。
Claims (2)
1.一种装修用抗菌低气味轻质复合板,其特征在于,由复合板和面饰两个部分组成,所述复合板由25-35wt%玻璃纤维和65-75wt%抗菌低气味丙纶纤维制备而成;
所述抗菌低气味丙纶纤维由下述重量份的原料制备而成:丙纶切片50-70份、硬脂酸锌1-5份、硅藻土1-5份、氧化镁1-5份、抗菌剂0.5-1.5份、除味剂0.5-1.5份;
所述抗菌剂由1,3-二氯-5,5-二甲基海因、1,3-二氯-5-甲基-5-乙基海因、5-(4-氯丁基)海因混合而成,所述1,3-二氯-5,5-二甲基海因、1,3-二氯-5-甲基-5-乙基海因、5-(4-氯丁基)海因的质量比为(1-3):(1-3):(1-3);
所述除味剂由40-60wt%二乙基二丙烯酸铝盐和40-60wt%2-羟基丁二酸锌组成。
2.根据权利要求1所述的装修用抗菌低气味轻质复合板,其特征在于,所述面饰为棉布、麻布或化纤面料。
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