CN105724425A - Non-cultivated land weed killer composition and application thereof - Google Patents
Non-cultivated land weed killer composition and application thereof Download PDFInfo
- Publication number
- CN105724425A CN105724425A CN201610071595.9A CN201610071595A CN105724425A CN 105724425 A CN105724425 A CN 105724425A CN 201610071595 A CN201610071595 A CN 201610071595A CN 105724425 A CN105724425 A CN 105724425A
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- ammonium
- flumioxazin
- glufosinate
- fenoxaprop
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- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- TUTWLYPCGCUWQI-UHFFFAOYSA-N decanamide Chemical compound CCCCCCCCCC(N)=O TUTWLYPCGCUWQI-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- MEFQWPUMEMWTJP-UHFFFAOYSA-N fluroxypyr Chemical compound NC1=C(Cl)C(F)=NC(OCC(O)=O)=C1Cl MEFQWPUMEMWTJP-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 150000002333 glycines Chemical class 0.000 description 1
- 229940097068 glyphosate Drugs 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- VORRFUUQXVSQOQ-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 VORRFUUQXVSQOQ-UHFFFAOYSA-N 0.000 description 1
- 238000002663 nebulization Methods 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- NQQVFXUMIDALNH-UHFFFAOYSA-N picloram Chemical compound NC1=C(Cl)C(Cl)=NC(C(O)=O)=C1Cl NQQVFXUMIDALNH-UHFFFAOYSA-N 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- OORLZFUTLGXMEF-UHFFFAOYSA-N sulfentrazone Chemical compound O=C1N(C(F)F)C(C)=NN1C1=CC(NS(C)(=O)=O)=C(Cl)C=C1Cl OORLZFUTLGXMEF-UHFFFAOYSA-N 0.000 description 1
- ZDXMLEQEMNLCQG-UHFFFAOYSA-N sulfometuron methyl Chemical group COC(=O)C1=CC=CC=C1S(=O)(=O)NC(=O)NC1=NC(C)=CC(C)=N1 ZDXMLEQEMNLCQG-UHFFFAOYSA-N 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a non-cultivated land weed killer composition.The composition is prepared from fenoxaprop-p-ethyl, flumioxazin and glufosinate-ammonium by the weight ratio of 1:(0.01-90):(0.01-90).The invention further relates to application of the non-cultivated land weed killer composition in preventing and killing non-cultivated land weeds.The weed killer composition is used for preventing and killing the non-cultivated land weeds and has an obvious synergistic effect compared with single-component fenoxaprop-p-ethyl, flumioxazin and glufosinate-ammonium, the dosage of farm chemical and pharmacy cost are reduced, weed killer resistance of the weeds is delayed, and the adverse effect on the ecological environment is delayed.
Description
Technical field
The present invention relates to agriculture field, in particular it relates to a kind of bare place herbicidal composition, and should
The purposes of herbicidal composition.
Background technology
Bare place weeds mainly include forest land, lawn, highway, railway, warehouse, ridge, ditch, gloomy
The weeds on the ground such as woods firebreak is other.Bare place weeds affect urban, are corps diseases, insect pest
Vector and hibernacle, affect farm irrigation facility, highway and rail facility etc., be to cause crop
The one of the main reasons that the underproduction, living facilities are destroyed.The main weeds producing harm have wild oat, see wheat
Ma, Herba Setariae Viridis, barnyard grass, Semen Euphorbiae, Herba Eleusines Indicae, Herba Digitariae, Amaranthus retroflexus, Herba Portulacae, Herba seu Flos Convolvuli arvensis, thorn
Youngster's dish, Herba Commelinae, Herba Abutili etc..
The major herbicides kind being currently used for preventing and kill off bare place weeds has: 2 first 4 chlorine, N,N'-dimethyl-.gamma..gamma.'-dipyridylium, grass
Sweet phosphine, glufosinate-ammonium, imazethapyr, sulfometuronmethyl, picloram, fluroxypyr, benzene are phonetic
Sulphur grass amine, sulfentrazone etc., corresponding product has nearly 300, accounts for herbicide and all registers product
4.2%.When above-mentioned various herbicide kind is used alone, all can show defect in a certain respect and limitation
Property.Meanwhile, produced anti-along with more above-mentioned herbicide kind ground large area are used alone a lot of weeds
The property of medicine, causes the effect of herbicide to decline, and a large amount of uses also can cause the pollution of environment.
Therefore, in the urgent need to developing a kind of efficient, new herbicides of low toxicity, low-residual.
Summary of the invention
It is an object of the invention to provide a kind of bare place herbicidal composition and application thereof, current to overcome
Herbicide is difficult to efficiently, the defect of environmental protection, synthetically preventing and treating bare place weeds.
To achieve these goals, first aspect present invention: a kind of bare place herbicidal composition is provided,
Described compositions contains fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium, described fenoxaprop-P-ethyl,
The weight ratio of flumioxazin and glufosinate-ammonium is 1:(0.01-90): (0.01-90).
Second aspect present invention, it is provided that bare place herbicidal composition as above is miscellaneous at preventing and treating bare place
Purposes in grass.
By technique scheme, fenoxaprop-P-ethyl in the bare place herbicidal composition of the present invention,
Flumioxazin and glufosinate-ammonium are applied in combination according to special ratios, broad weed-killing spectrum, and can be to multiple bare place
Weeds prevent and treat simultaneously, relative to oligomict fenoxaprop-P-ethyl, flumioxazin or glufosinate-ammonium energy
Enough obtain the effect of notable synergistic, and dosage is low, not only delayed the generation of herbicide resistance but also saved into
This.The herbicidal composition of the present invention is applicable to the preventing and treating of bare place weeds, and safety is good, to ecological ring
The protection in border serves positive effect.
Other features and advantages of the present invention will be described in detail in detailed description of the invention part subsequently.
Detailed description of the invention
Hereinafter the detailed description of the invention of the present invention is described in detail.It should be appreciated that this place is retouched
The detailed description of the invention stated is merely to illustrate and explains the present invention, is not limited to the present invention.
In the present invention, the content sum of each component in herbicidal composition is 100 weight %.
First aspect present invention: providing a kind of bare place herbicidal composition, described compositions contains essence
Azoles diclofop-methyl, flumioxazin and glufosinate-ammonium, described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium
Weight ratio be 1:(0.01-90): (0.01-90).
In the present invention, fenoxaprop-P-ethyl is compound (R)-2-[4-(6-chloro-1,3-benzothiazole-2-base oxygen)
Phenoxy group] trade name of ethyl propionate, English name is Fenoxaprop-P-ethyl, and molecular formula is
C18H16ClNO5, relative molecular weight is 361.8, and No. CAS is 71283-80-2, structural formula such as formula (1)
Shown in:
In the present invention, flumioxazin is compound N-(7-fluoro-3,4-dihydro-3-oxo-4-propine-2-base
-2H-1,4-benzimidazole dihydrochloride-6-base) cyclohexene-1-base-1, the trade name of 2-diformamide, English name is
Flumioxazin, molecular formula is C19H15FN2O4, relative molecular weight is 354.3, and No. CAS is
103361-09-7, shown in structural formula such as formula (2):
In the present invention, glufosinate-ammonium is the commodity of compound 2-amino-4-(hydroxy-methyl-phosphinyl) butanoic acid ammonium
Name, English name is Glufosinate-ammonium, and molecular formula is C5H15N2O4P, relative molecular weight
Being 198.2, No. CAS is 77182-82-2, shown in structural formula such as formula (3):
According to the first aspect of the invention, the weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium
Amount ratio has potentiation, in order to further enhance their potentiation, preferably in wider scope
In the case of, the weight ratio of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium is 1:(0.05-10):
(0.05-10).In the case of Jin Yibuyouxuan, described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium
Weight ratio be 1:(0.1-1): (1-5).Under this preferable case, they threes have prominent potentiation
Effect, it is possible to the herbicidal effect measuring more excellent with less herbicide application.
According to the first aspect of the invention, the herbicidal composition of the present invention can make removing of various routine
Grass agent dosage form, such as aqueous suspension agent, oil-suspending agent, wettable powder, water dispersible granules or microemulsion.
Difference according to formulation of herbicide, it is possible to use different auxiliary agents.Herbicide accordingly, as the present invention
A kind of preferred implementation of compositions, the herbicidal composition of the present invention is possibly together with various auxiliary agents.Preferably
The weight ratio of ground, the gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and described auxiliary agent
For 1:(0.2-10).
Such as, the bare place herbicidal composition of the present invention can make aqueous suspension agent.Wherein, described essence
The gross weight of azoles diclofop-methyl, flumioxazin and glufosinate-ammonium and the weight ratio of auxiliary agent can be 1:
(0.8-5.0).Described auxiliary agent can be in dispersion moisture agent, thickening agent, defoamer and water extremely
Few one.Wherein, the gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and dispersion profit
The weight ratio of humectant, thickening agent, defoamer and water can be 1:(0.05-0.4): (0.01-0.1):
(0.005-0.04): (0.8-4).Wherein, described dispersion moisture agent can be selected from sodium lignin sulfonate,
Calcium lignosulfonate, sodium methylene bis-naphthalene sulfonate, calcium dodecyl benzene sulfonate, succinate sodium sulfonate,
At least one in diisobutyl sodium naphthalene sulfonate (pulling open powder) and sodium laurylsulfate.Wherein, described increasing
Thick dose can be selected from xanthan gum, aluminium-magnesium silicate, polyvinyl alcohol, polyvinylpyrrolidone and poly-acetic acid second
At least one in alkene ester.Wherein, described defoamer can be polyether antifoam agent and/or organic silicon defoamer.
Such as, the bare place herbicidal composition of the present invention can make wettable powder.Wherein, described
The gross weight of fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and the weight ratio of auxiliary agent can be 1:
(0.2-0.8).Described auxiliary agent can be dispersion moisture agent and/or inert solid carrier.Wherein, described essence
The gross weight of azoles diclofop-methyl, flumioxazin and glufosinate-ammonium and dispersion moisture agent and inert solid carrier
Weight ratio can be 1:(0.05-0.2): (0.15-0.6).Wherein, described dispersion moisture agent can be choosing
From sodium lignin sulfonate, calcium lignosulfonate, sodium methylene bis-naphthalene sulfonate, calcium dodecyl benzene sulfonate,
In succinate sodium sulfonate, diisobutyl sodium naphthalene sulfonate (pulling open powder) and sodium laurylsulfate at least one
Kind.Wherein, described inert solid carrier can be selected from kieselguhr, Kaolin, clay, silicon dioxide,
In attapulgite, montmorillonite, bentonite, Pulvis Talci, White Carbon black, calcium carbonate and corn starch at least
A kind of.
Such as, the bare place herbicidal composition of the present invention can make water dispersible granules.Wherein, described
The gross weight of fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and the weight ratio of auxiliary agent can be 1:
(0.3-1.5).Described auxiliary agent can be in dispersion moisture agent, inert solid carrier and binding agent
At least one.Wherein, the gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and dispersion
The weight ratio of wetting agent, inert solid carrier and binding agent can be 1:(0.06-0.22): (0.18-0.65):
(0.15-0.6).Wherein, described dispersion moisture agent can be selected from sodium lignin sulfonate, lignin sulfonic acid
Calcium, sodium methylene bis-naphthalene sulfonate, calcium dodecyl benzene sulfonate, succinate sodium sulfonate, diisobutyl naphthalene
At least one in sodium sulfonate (pulling open powder) and sodium laurylsulfate.Wherein, described inert solid carrier
Can be selected from kieselguhr, Kaolin, clay, silicon dioxide, attapulgite, montmorillonite, bentonite,
At least one in Pulvis Talci, White Carbon black and calcium carbonate.Wherein, described binding agent can be selected from sucrose,
At least one in glucose, maltose, dextrin and starch.
Such as, the bare place herbicidal composition of the present invention can make microemulsion.Wherein, described essence
The gross weight of azoles diclofop-methyl, flumioxazin and glufosinate-ammonium and the weight ratio of auxiliary agent can be 1:
(0.9-5.0).Described auxiliary agent can be at least one in organic solvent, emulsifying agent and water.Its
In, the gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and organic solvent, emulsifying agent
Can be 1:(0.1-0.5 with the weight ratio of water): (0.05-0.5): (0.8-4).Wherein, described solvent
For selected from benzene,toluene,xylene, solvent naphtha, methanol, ethanol, isopropanol, acetone, acetonitrile, N-
At least one in methyl pyrrolidone, N,N-dimethylformamide, decyl amide, dichloromethane.Wherein,
Described emulsifying agent can be selected from Sorbitan polyoxyethylenated alcohol, fatty alcohol-polyoxyethylene ether, polyoxy second
Alkene Sorbitan alcohol ether monoleate, styrylphenol polyoxyethylene ether, dibenzyl phenol polyethenoxy ether,
At least one in aliphatic amine polyoxyethylene ether and calcium dodecyl benzene sulfonate.
According to the first aspect of the invention, under preferable case, the bare place herbicidal composition of the present invention is special
Shi He not prepare with the dosage form of oil-suspending agent, preserve, transport and use.In this preferable case, enter
One step preferably, the gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and the weight of auxiliary agent
Amount ratio is 1:(1-10), more preferably 1:(1-6).Wherein, described auxiliary agent can be selected from dispersant,
At least one in thickening agent and organic suspension medium.Wherein, described fenoxaprop-P-ethyl, propine fluorine grass
The gross weight of amine and glufosinate-ammonium can be 1 with the weight ratio of dispersant, thickening agent and organic suspension medium:
(0.2-2): (0.05-0.8): (0.9-7).Wherein, described dispersant can be various to reduce dispersion
The material that in system, solid or liquid particle are assembled；Preferably, described dispersant is to gather selected from anhydrous sorbitol
Oxygen vinyl Ether, fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan ether monoleate, Sorbitan
Alcohol monolaurate, sodium laurylsulfate, styrylphenol polyoxyethylene ether, dibenzyl phenol polyoxy second
At least one in alkene ether and aliphatic amine polyoxyethylene ether；It is more preferably fatty alcohol-polyoxyethylene ether and/or gathers
Oxygen ethylene Sorbitan alcohol ether monoleate.Wherein, described thickening agent can be various can to improve material
The material of viscosity, it is preferable that described thickening agent is selected from Polyethylene Glycol, polyvinylpyrrolidone, poly-
At least one in vinyl alcohol, polyvinyl acetate, organobentonite and aluminium-magnesium silicate；The most poly-
Ethylene glycol.Wherein, described organic suspension medium can be various conventional inert fluid organic material matter, excellent
Selection of land, described organic suspension medium is selected from soybean oil, rapeseed oil, Semen Maydis oil, sunflower oil, Semen Gossypii
Oil, Semen Lini oil, Oleum Cocois, Petiolus Trachycarpi oil, Oleum Arachidis hypogaeae semen, olive oil, Oleum Ricini and their ester exchange
At least one in product；More preferably soybean oil.
According to the first aspect of the invention, as a kind of embodiment specifically preferred according to the invention, described non-
Arable land herbicidal composition contains fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium, described essence azoles standing grain
The weight ratio of grass spirit, flumioxazin and glufosinate-ammonium is 1:(0.1-1): (1-5)；Described combinations of herbicides
Thing possibly together with fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan ether monoleate, Polyethylene Glycol and
Soybean oil；The gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and fatty alcohol polyoxy second
The weight ratio of alkene ether, polyoxyethylene sorbitan ether monoleate, Polyethylene Glycol and soybean oil is permissible
1:(0.2-0.8): (0.1-0.5): (0.05-0.35): (1.5-5).Situation in this preferred implementation
Under, described herbicidal composition is particularly suitable for the preventing and treating of bare place weeds, has wider weeds and kills
Spectrum of going out and higher kill preventive effect.Wherein, described fatty alcohol-polyoxyethylene ether such as R-O-(CH2CH2O)n-H
Shown in, R is the alkyl of saturated or unsaturated C12-C18, and n is the integer of 10-20；Preferably
Ground, R is the alkyl of saturated or unsaturated C12-C15, and n is the integer of 15-20.Wherein,
The mean molecule quantity (measuring according to the method in Chinese Pharmacopoeia version two in 2010) of described Polyethylene Glycol
Can be 200-6000, preferably 1000-2000.
According to the first aspect of the invention, described bare place herbicidal composition can carry with final product form
In confession, i.e. compositions, each composition is the most blended；Can also provide with the form of independent preparation by every kind of composition,
At mix homogeneously before use.
Second aspect present invention, it is provided that bare place herbicidal composition as above is miscellaneous at preventing and treating bare place
Purposes in grass.
According to the second aspect of the invention, described bare place weeds can be selected from Amaranthus retroflexus, Herba Portulacae,
Herba seu Flos Convolvuli arvensis, field thistle, Herba Commelinae, Herba Abutili, wild oat, amur foxtail, Herba Setariae Viridis, barnyard grass, Semen Euphorbiae,
At least one in Herba Eleusines Indicae and Herba Digitariae.
Further describe the present invention by the following examples, but not thereby limiting the invention.
In following example, fenoxaprop-P-ethyl is purchased from Chambroad Agrochemical Technology Co., Ltd.；Propine fluorine
Grass amine is purchased from Shangyu Nutrichem Co., Ltd；Glufosinate-ammonium is purchased from Zhejiang Yongnong Chemical Industry Co. Ltd.；
Fatty alcohol-polyoxyethylene ether is purchased from blue star auxiliary reagent factory, Xingtai, and hydrocarbon carbon atomic number is C12-C15, oxygen ethylene
Radix is 15-20；Polyoxyethylene sorbitan ether monoleate is purchased from blue star auxiliary reagent factory, Xingtai；Poly-second
Glycol is purchased from blue star auxiliary reagent factory, Xingtai, and mean molecule quantity is 1000-2000；Sodium lignin sulfonate is purchased from sky
Tianjin Skien thinks biochemical technology company limited；Calcium dodecyl benzene sulfonate is purchased from Jinan greatization industry Limited Liability
Company；Sodium methylene bis-naphthalene sulfonate is purchased from circling in the air chemical industry (Zhangjiagang) company limited；Lauryl sulphate acid
Sodium is purchased from novelty river, Hubei Chemical Co., Ltd.；Xanthan gum is purchased from Zhengzhou feudal dynasty chemical products company limited；
Organic silicon defoamer is purchased from Jinan Rui Yuan Chemical Co., Ltd.；Sucrose is purchased from the north, Yingkou limited public affairs of sugar industry
Department；Solvent naphtha S-200 is purchased from Hualun Chemical Co., Ltd., Jiangsu；N-Methyl pyrrolidone is auspicious purchased from Suzhou
Ring Chemical Co., Ltd..
Embodiment 1
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 4 weight portions, the flumioxazin of 2 weight portions, the careless ammonium of 12 weight portions
Phosphine, the fatty alcohol-polyoxyethylene ether of 10 weight portions, the polyoxyethylene sorbitan ether list oil of 6 weight portions
Acid esters, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 61 weight portions, obtain this after sand milling
The herbicidal composition of embodiment.
Embodiment 2
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 8.5 weight portions, the flumioxazin of 0.9 weight portion, 8.6 weight portions
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 4 weight portions, the polyoxyethylene sorbitan ether of 2 weight portions
Monoleate, the Polyethylene Glycol of 2 weight portions and the soybean oil mix homogeneously of 74 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 3
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 3.2 weight portions, the flumioxazin of 0.4 weight portion, 14.4 weight portions
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 4 weight portions, the polyoxyethylene sorbitan ether of 2 weight portions
Monoleate, the Polyethylene Glycol of 2 weight portions and the soybean oil mix homogeneously of 74 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 4
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 5.9 weight portions, the flumioxazin of 5.7 weight portions, 6.4 weight portions
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 14 weight portions, the polyoxyethylene sorbitan ether of 9 weight portions
Monoleate, the Polyethylene Glycol of 4 weight portions and the soybean oil mix homogeneously of 55 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 5
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 2.6 weight portions, the flumioxazin of 2.6 weight portions, 12.8 weight portions
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 14 weight portions, the polyoxyethylene sorbitan ether of 9 weight portions
Monoleate, the Polyethylene Glycol of 4 weight portions and the soybean oil mix homogeneously of 55 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 6
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 16.2 weight portions, the flumioxazin of 0.9 weight portion, 0.9 weight portion
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 14 weight portions, the polyoxyethylene sorbitan ether of 9 weight portions
Monoleate, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 54 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 7
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 1.9 weight portions, the flumioxazin of 0.1 weight portion, 16 weight portions
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 14 weight portions, the polyoxyethylene sorbitan ether of 9 weight portions
Monoleate, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 54 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 8
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 1.6 weight portions, the flumioxazin of 15.4 weight portions, 1 weight portion
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 10 weight portions, the polyoxyethylene sorbitan ether of 6 weight portions
Monoleate, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 61 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 9
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 0.9 weight portion, the flumioxazin of 9 weight portions, the grass of 8.1 weight portions
Ammonium phosphine, the fatty alcohol-polyoxyethylene ether of 10 weight portions, the polyoxyethylene sorbitan ether list of 6 weight portions
Oleate, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 61 weight portions, obtain after sand milling
The herbicidal composition of the present embodiment.
Embodiment 10
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 17.1 weight portions, the flumioxazin of 0.6 weight portion, 0.3 weight portion
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 10 weight portions, the polyoxyethylene sorbitan ether of 6 weight portions
Monoleate, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 61 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 11
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 0.2 weight portion, the flumioxazin of 7.8 weight portions, 10 weight portions
Glufosinate-ammonium, the fatty alcohol-polyoxyethylene ether of 10 weight portions, the polyoxyethylene sorbitan ether of 6 weight portions
Monoleate, the Polyethylene Glycol of 5 weight portions and the soybean oil mix homogeneously of 61 weight portions, after sand milling
Herbicidal composition to the present embodiment.
Embodiment 12
18% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 0.1 weight portion, the flumioxazin of 9 weight portions, the grass of 8.9 weight portions
Ammonium phosphine, the styrylphenol polyoxyethylene ether of 10 weight portions, the anhydrous sorbitol list Laurel of 6 weight portions
Acid esters, the aluminium-magnesium silicate of 5 weight portions and the Semen Maydis oil mix homogeneously of 61 weight portions, obtain this after sand milling
The herbicidal composition of embodiment.
Embodiment 13
36% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium aqueous suspension agent
Take the fenoxaprop-P-ethyl of 8 weight portions, the flumioxazin of 4 weight portions, the careless ammonium of 24 weight portions
Phosphine, the sodium lignin sulfonate of 4 weight portions, the sodium lauryl sulphate of 3 weight portions, the Huang of 0.5 weight portion
Virgin rubber, the organic silicon defoamer of 0.5 weight portion and the water mix homogeneously of 56 weight portions, obtain after sand milling
The herbicidal composition of the present embodiment.
Embodiment 14
72% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium wettable powder
Take the fenoxaprop-P-ethyl of 16 weight portions, the flumioxazin of 8 weight portions, the grass of 48 weight portions
Ammonium phosphine, the sodium lignin sulfonate of 6 weight portions, the sodium methylene bis-naphthalene sulfonate of 4 weight portions and 18 weight portions
Kieselguhr mix homogeneously, obtain the herbicidal composition of the present embodiment after crushed.
Embodiment 15
63% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium water dispersible granules
Take the fenoxaprop-P-ethyl of 14 weight portions, the flumioxazin of 7 weight portions, the grass of 42 weight portions
Ammonium phosphine, the sodium methylene bis-naphthalene sulfonate of 6 weight portions, the sodium lauryl sulphate of 3 weight portions, 10 weight
The sucrose of part and the Kaolin mix homogeneously of 18 weight portions, mediate pelletize after crushed and obtain the present embodiment
Herbicidal composition.
Embodiment 16
22.5% fenoxaprop-P-ethyl flumioxazin glufosinate-ammonium microemulsion
Take the fenoxaprop-P-ethyl of 5 weight portions, the flumioxazin of 2.5 weight portions, the grass of 15 weight portions
Ammonium phosphine, the solvent naphtha S-200 of 4.5 weight portions, the N-Methyl pyrrolidone of 2 weight portions, 4 weight portions
Fatty alcohol-polyoxyethylene ether, the calcium dodecyl benzene sulfonate of 4 weight portions and the water mixing of 63 weight portions are all
Even, obtain the herbicidal composition of the present embodiment.
Comparative example 1
18% fenoxaprop-P-ethyl flumioxazin oil-suspending agent
Take the fenoxaprop-P-ethyl of 10 weight portions, the flumioxazin of 8 weight portions, the fat of 10 weight portions
Fat polyoxyethylenated alcohol, the polyoxyethylene sorbitan ether monoleate of 6 weight portions, 5 weight portions
The soybean oil mix homogeneously of Polyethylene Glycol and 61 weight portions, obtains the herbicide of the present embodiment after sand milling
Compositions.
Comparative example 2
18% fenoxaprop-P-ethyl glufosinate-ammonium oil-suspending agent
Take the fenoxaprop-P-ethyl of 5 weight portions, the glufosinate-ammonium of 13 weight portions, the fatty alcohol of 10 weight portions
Polyoxyethylene ether, the polyoxyethylene sorbitan ether monoleate of 6 weight portions, the poly-second of 5 weight portions
The soybean oil mix homogeneously of glycol and 61 weight portions, obtains the combinations of herbicides of the present embodiment after sand milling
Thing.
Comparative example 3
18% flumioxazin glufosinate-ammonium oil-suspending agent
Take the flumioxazin of 5 weight portions, the glufosinate-ammonium of 13 weight portions, the poly alkyl alcohol of 10 weight portions
Oxygen vinyl Ether, the polyoxyethylene sorbitan ether monoleate of 6 weight portions, the poly-second two of 5 weight portions
The soybean oil mix homogeneously of alcohol and 61 weight portions, obtains the herbicidal composition of the present embodiment after sand milling.
Comparative example 4
18% fenoxaprop-P-ethyl oil-suspending agent
Take the fenoxaprop-P-ethyl of 18 weight portions, the fatty alcohol-polyoxyethylene ether of 10 weight portions, 6 weight
Part polyoxyethylene sorbitan ether monoleate, the Polyethylene Glycol of 5 weight portions and 61 weight portions big
Oleum Glycines mix homogeneously, obtains the herbicidal composition of the present embodiment after sand milling.
Comparative example 5
18% flumioxazin oil-suspending agent
Take the flumioxazin of 18 weight portions, the fatty alcohol-polyoxyethylene ether of 10 weight portions, 6 weight portions
Polyoxyethylene sorbitan ether monoleate, the Polyethylene Glycol of 5 weight portions and the Semen sojae atricolor of 61 weight portions
Oil mix homogeneously, obtains the herbicidal composition of the present embodiment after sand milling.
Comparative example 6
18% glufosinate-ammonium oil-suspending agent
Take the glufosinate-ammonium of 18 weight portions, the fatty alcohol-polyoxyethylene ether of 10 weight portions, gathering of 6 weight portions
Oxygen ethylene Sorbitan alcohol ether monoleate, the Polyethylene Glycol of 5 weight portions and the soybean oil of 61 weight portions are mixed
Close uniformly, after sand milling, obtain the herbicidal composition of the present embodiment.
Comparative example 7
18% clodinafop-propargyl flumioxazin glufosinate-ammonium oil-suspending agent
Take 4 weight portions clodinafop-propargyl (No. CAS be 105512-06-9, purchased from agriculture bioscience forever limited
Company), the flumioxazin of 2 weight portions, the glufosinate-ammonium of 12 weight portions, the poly alkyl alcohol of 10 weight portions
Oxygen vinyl Ether, the polyoxyethylene sorbitan ether monoleate of 6 weight portions, the poly-second two of 5 weight portions
The soybean oil mix homogeneously of alcohol and 61 weight portions, obtains the herbicidal composition of the present embodiment after sand milling.
Comparative example 8
18% fenoxaprop-P-ethyl Oxyfluorfen glufosinate-ammonium oil-suspending agent
Taking the fenoxaprop-P-ethyl of 4 weight portions, (No. CAS is the Oxyfluorfen of 2 weight portions
42874-03-3, purchased from Shangyu Nutrichem Co., Ltd), the glufosinate-ammonium of 12 weight portions, 10 weights
The fatty alcohol-polyoxyethylene ether of amount part, the polyoxyethylene sorbitan ether monoleate of 6 weight portions, 5
The Polyethylene Glycol of weight portion and the soybean oil mix homogeneously of 61 weight portions, obtain the present embodiment after sand milling
Herbicidal composition.
Comparative example 9
18% fenoxaprop-P-ethyl flumioxazin glyphosate oil-suspending agent
Taking the fenoxaprop-P-ethyl of 4 weight portions, the flumioxazin of 2 weight portions, the grass of 12 weight portions is sweet
Phosphine (CAS 1071-83-6, purchased from Huifeng Agricultural Chemistry Co., Ltd., Jiangsu), the fat of 10 weight portions
Fat polyoxyethylenated alcohol, the polyoxyethylene sorbitan ether monoleate of 6 weight portions, 5 weight portions
The soybean oil mix homogeneously of Polyethylene Glycol and 61 weight portions, obtains the herbicide of the present embodiment after sand milling
Compositions.
Testing example 1
Test is carried out in Dong Liu little Ying village, market town, hilllock, Changfeng County, Anhui Province, is experimental field yellow soil, and physical features is put down
Whole, soil fertility is uniform, the content of organic matter 1.1%, pH6.6.Other herbicides were not used before and after test,
Weed population is stablized, is evenly distributed.In this block bare place build-in test embodiment 1-16 and comparative example 1-9
The herbicidal composition prevention effect to weeds.Wherein, embodiment 1-12 and the herbicide of comparative example 1-9
The amount of application of compositions is 200g/ mu, and the usage amount of the herbicidal composition of embodiment 13 is 100g/
Mu, the usage amount of the herbicidal composition of embodiment 14 is 50g/ mu, the combinations of herbicides of embodiment 15
The usage amount of thing is 57.5g/ mu, and the usage amount of the herbicidal composition of embodiment 16 is 160g/ mu.
Each process is repeated 4 times, each community sampling 30m2, being diluted with water to every mu of spray amount when using is
30L, and substitute herbicidal composition as space management using water.The group arrangement of random district.Medicinal sprayer tool is
Red sun 3WBD-16 power sprayer, uses stem and leaf nebulization.Except using herbicide by such scheme
Outward, other conditions of each processing region are identical.After spraying herbicide 35 days, miscellaneous to treatment region
Grass is identified counting, 4, each community randomization, sample area 0.25m during investigation2.By formula
(1) calculating strain preventive effect, result is as shown in table 1.
Table 1
By embodiment 1-16 in table 1 compared with the data of comparative example 1-9 it can be seen that in the present invention
Fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium ternary recompounded composite relative to oligomict essence
Azoles diclofop-methyl, flumioxazin or glufosinate-ammonium, or fenoxaprop-P-ethyl and flumioxazin, essence azoles
Diclofop-methyl and the binary built of glufosinate-ammonium, flumioxazin and glufosinate-ammonium, or the herbicide of other compositions
Compositions, prevention effect is good, has potentiation, and three is compounding can prevent and treat multiple bare place weeds, subtracts
Few spraying times, cost-effective, alleviate the pollution to environment.Embodiment 1-12 is compared permissible
Finding out, the weight ratio of fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium is 1:(0.05-10):
(0.05-10), particularly weight ratio in fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium is 1:
(0.1-1): can further improve prevention effect time (1-5), and dosage can be reduced, save into
This, alleviate the pollution to environment.It addition, from embodiment 1-16 it can also be seen that the weeding of the present invention
Agent compositions, when preferred dosage form is oil-suspending agent, can obtain relative to other dosage forms and preferably prevent and treat effect
Really.
The preferred embodiment of the present invention described in detail above, but, the present invention is not limited to above-mentioned reality
Execute the detail in mode, in the technology concept of the present invention, can be to the technical side of the present invention
Case carries out multiple simple deformation, and these simple deformation belong to protection scope of the present invention.
It is further to note that each the concrete technology described in above-mentioned detailed description of the invention is special
Levy, in the case of reconcilable, can be combined by any suitable means, in order to avoid need not
The repetition wanted, various possible compound modes are illustrated by the present invention the most separately.
Additionally, combination in any can also be carried out between the various different embodiment of the present invention, as long as its
Without prejudice to the thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (9)
1. a bare place herbicidal composition, it is characterised in that described compositions contains essence azoles standing grain
Grass spirit, flumioxazin and glufosinate-ammonium, the weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium
Amount ratio is 1:(0.01-90): (0.01-90).
Compositions the most according to claim 1, it is characterised in that described fenoxaprop-P-ethyl,
The weight ratio of flumioxazin and glufosinate-ammonium is 1:(0.05-10): (0.05-10).
Compositions the most according to claim 2, it is characterised in that described fenoxaprop-P-ethyl,
The weight ratio of flumioxazin and glufosinate-ammonium is 1:(0.1-1): (1-5).
4. according to the compositions described in any one in claim 1-3, it is characterised in that described group
Compound is possibly together with auxiliary agent, the gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and auxiliary agent
Weight ratio be 1:(0.2-10).
Compositions the most according to claim 4, wherein, described auxiliary agent is selected from dispersant, increasing
At least one in thick dose and organic suspension medium.
Compositions the most according to claim 5, it is characterised in that described dispersant is for selected from losing
Water sorbitol polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan ether monoleate,
Sorbitan mono-laurate, sodium laurylsulfate, styrylphenol polyoxyethylene ether, dibenzyl
At least one in phenol polyethenoxy ether and aliphatic amine polyoxyethylene ether；Described thickening agent is selected from poly-second two
Alcohol, polyvinylpyrrolidone, polyvinyl alcohol, polyvinyl acetate, organobentonite, aluminium-magnesium silicate and
At least one in white carbon；Described organic suspension medium be selected from soybean oil, rapeseed oil, Semen Maydis oil,
Sunflower oil, Oleum Gossypii semen, Semen Lini oil, Oleum Cocois, Petiolus Trachycarpi oil, Oleum Arachidis hypogaeae semen, olive oil, Oleum Ricini and
At least one in their ester exchange offspring.
7. according to the compositions described in any one in claim 1-3, it is characterised in that described group
Compound is possibly together with fatty alcohol-polyoxyethylene ether, polyoxyethylene sorbitan ether monoleate, Polyethylene Glycol
And soybean oil；The gross weight of described fenoxaprop-P-ethyl, flumioxazin and glufosinate-ammonium and described fatty alcohol
Polyoxyethylene ether, polyoxyethylene sorbitan ether monoleate, Polyethylene Glycol and the weight ratio of soybean oil
For 1:(0.2-0.8): (0.1-0.5): (0.08-0.32): (1.5-5).
8. compositions described in any one purposes in preventing and treating bare place weeds in claim 1-7.
9. want the purposes described in 8 according to right, it is characterised in that described bare place weeds are for selected from open country
Herba bromi japonici, amur foxtail, Herba Setariae Viridis, barnyard grass, Semen Euphorbiae, Herba Eleusines Indicae, Herba Digitariae, Amaranthus retroflexus, Herba Portulacae,
At least one in Herba seu Flos Convolvuli arvensis, field thistle, Herba Commelinae and Herba Abutili.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107535519A (en) * | 2017-09-26 | 2018-01-05 | 安徽国星生物化学有限公司 | A kind of glufosinate-ammonium synergist and its glufosinate-ammoniumaqua aqua of preparation |
| CN109418286A (en) * | 2017-08-31 | 2019-03-05 | 江西正邦生物化工有限责任公司 | A kind of dispersible oil-suspending agent of the Herbicidal combinations containing glufosinate-ammonium and flumioxazin and preparation method thereof |
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|---|---|---|---|---|
| WO2000008934A1 (en) * | 1998-08-13 | 2000-02-24 | Aventis Cropscience Gmbh | Herbicidal agents for tolerant or resistant soybean crops |
| JP2001139401A (en) * | 1999-11-12 | 2001-05-22 | Sumitomo Chem Co Ltd | Granular wettable powder |
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2016
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000008934A1 (en) * | 1998-08-13 | 2000-02-24 | Aventis Cropscience Gmbh | Herbicidal agents for tolerant or resistant soybean crops |
| JP2001139401A (en) * | 1999-11-12 | 2001-05-22 | Sumitomo Chem Co Ltd | Granular wettable powder |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109418286A (en) * | 2017-08-31 | 2019-03-05 | 江西正邦生物化工有限责任公司 | A kind of dispersible oil-suspending agent of the Herbicidal combinations containing glufosinate-ammonium and flumioxazin and preparation method thereof |
| CN107535519A (en) * | 2017-09-26 | 2018-01-05 | 安徽国星生物化学有限公司 | A kind of glufosinate-ammonium synergist and its glufosinate-ammoniumaqua aqua of preparation |
| CN107535519B (en) * | 2017-09-26 | 2020-01-31 | 安徽国星生物化学有限公司 | glufosinate synergist and glufosinate solution prepared from same |
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