CN101213975B - Miticide composition containing fenpyroximate active ingredient and uses thereof - Google Patents
Miticide composition containing fenpyroximate active ingredient and uses thereof Download PDFInfo
- Publication number
- CN101213975B CN101213975B CN2008100173147A CN200810017314A CN101213975B CN 101213975 B CN101213975 B CN 101213975B CN 2008100173147 A CN2008100173147 A CN 2008100173147A CN 200810017314 A CN200810017314 A CN 200810017314A CN 101213975 B CN101213975 B CN 101213975B
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- China
- Prior art keywords
- agent
- composition
- parts
- sodium
- fenpyroximate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 239000000642 acaricide Substances 0.000 title claims abstract description 32
- 239000005657 Fenpyroximate Substances 0.000 title claims abstract description 27
- YYJNOYZRYGDPNH-MFKUBSTISA-N fenpyroximate Chemical compound C=1C=C(C(=O)OC(C)(C)C)C=CC=1CO/N=C/C=1C(C)=NN(C)C=1OC1=CC=CC=C1 YYJNOYZRYGDPNH-MFKUBSTISA-N 0.000 title claims abstract description 27
- 239000004480 active ingredient Substances 0.000 title claims description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- BOTNFCTYKJBUMU-UHFFFAOYSA-N 2-[4-(2-methylpropyl)piperazin-4-ium-1-yl]-2-oxoacetate Chemical compound CC(C)C[NH+]1CCN(C(=O)C([O-])=O)CC1 BOTNFCTYKJBUMU-UHFFFAOYSA-N 0.000 claims abstract description 18
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- 239000000945 filler Substances 0.000 claims abstract description 11
- 239000000463 material Substances 0.000 claims abstract description 8
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- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 4
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- ZITVKGIRQCDOSX-UHFFFAOYSA-N 1h-cyclopropa[a]naphthalene Chemical compound C1=CC=CC2=C3CC3=CC=C21 ZITVKGIRQCDOSX-UHFFFAOYSA-N 0.000 claims description 2
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- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 208000020939 vitelliform macular dystrophy 1 Diseases 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses miticide composition and application. The miticide composition has damaging effect and has the effective constituent of fenpyroximate. Component A is the fenpyroximate and component B is any one of azocyclotin and fenbutatin oxide. The weight ratio of A and B in the composition is 1-25: 80-1. The supplementary materials of the composition comprise surface active agent, diluent agent (e.g. water) added according to different preparation, cosolvent, fillers added if necessary such as antifreeze agent, thickening agent, stabilizer, disintegrating agent, antifoaming agent and cementitious agent. The invention has the advantages of the combination of rapidly available component and persistent effective component, and obvious synergism effect. In controlling pest mites of red spider, white spider, and rust spider, etc., which are common in fruit trees, the invention is characterized in high efficiency, low pollution, low residue, and that pesticide resistance is not easy to be generated in long-term usage and so on.
Description
Technical field
The present invention relates to the agricultural chemicals acaricide composition, particularly relate to various pests such as to prevent and treat the mandarin tree two spotted spider mite, and have the acaricide composition that contains fenpyroximate active ingredient and the application thereof of lethal effect.
Background technology
Two spotted spider mite is a disease more common on the mandarin tree, usually causes crushing disaster, particularly in the zone, south, and annual the generation.In some serious zone, the conventional pesticide composition uses separately and be difficult to control, and effect is very poor, and the Chinese government has made the time limit adjustment, eliminated the plan of high-toxic pesticide.The State Economic and Trade Commission and the Ministry of Agriculture just actively formulate high-toxic pesticide and cut down scheme, five organic phosphor high-toxic pesticides such as preliminary definite acephatemet, parathion, parathion-methyl, nuvacron and phosphamidon are the first batch of object of cutting down, determine on January 1st, 2004 to rise and forbid on the crop except that cotton, using that on January 1st, 2007 played complete prohibition and use above-mentioned medicine on agricultural.
Summary of the invention
It is little to the purpose of this invention is to provide a kind of pesticide resistance, low in the pollution of the environment, and the low control efficiency of production cost is good, and the lasting period is longer, the acaricide composition that contains fenpyroximate active ingredient that lethal effect is big.
Another object of the present invention provides the application of composition.
In order to overcome the deficiencies in the prior art, technical scheme of the present invention is to solve like this: a kind of acaricide composition that contains fenpyroximate active ingredient, its special character is that component A is an azoles mite ester, B component be selected from azacyclotin or fenbutatin oxide any one, the weight proportion of A and B is 1～25: 80～1 in the composition.
The described acaricide composition that contains fenpyroximate active ingredient, its special character are that component A is an azoles mite ester, B component be selected from azacyclotin or fenbutatin oxide any one, the weight proportion of A and B is 1～22: 70～1 in the composition.
The described acaricide composition that contains fenpyroximate active ingredient, its special character are that component A is an azoles mite ester, B component be selected from azacyclotin or fenbutatin oxide any one, the weight proportion of A and B is 1～20: 60～1 in the composition.
By the described acaricide composition that contains fenpyroximate active ingredient of mass ratio, its special character is that the accumulating weight of A and B in the acaricide composition is than between 1～80.
The described acaricide composition that contains fenpyroximate active ingredient is used, and comprises after its special character is composition and auxiliary material mixes being prepared into wetting powder, water dispersible granules, suspending agent, effervescent tablet.
Following tube will be introduced function effective components and the effect in the composition:
Azoles mite ester: azoles mite ester is the oximes miticide, and the E body is than Z body acaricidal activity height, and the mode of action is based on action of contace poison.It is wide to kill the mite spectrum, and has the desinsection effect of curing the disease concurrently.Benzene oxygen pyrazoles miticide.Can directly kill the mite class during high dose, can suppress mite class decortication during low dosage or lay eggs.Have knocking down and suppress decorticating, no systemic action.English agreement name: fenpyroximate, chemical name: (E)-and 4[1,3-dimethyl-(5-phenoxy group-1H-pyrazolyl) methene ammonia oxygen methyl] benzoic acid-1,1 dimethyl ethyl ester.
Structural formula:
Azacyclotin: be the stronger broad spectrum activity miticide of action of contace poison.Can kill if mite, one-tenth mite and summer egg are invalid to winter egg.Light and rainwater are had stability preferably, and the longevity of residure is longer.Under typical concentrations to crop safety.English common name: azocyclotin, chemical name: 1-(thricyclohexyl stannyl)-1-hydrogen-1,2,4-triazole.
Structural formula:
Molecular formula: C
20H
35N
3Sn, molecular weight: 435.84
Fenbutatin oxide: be the stronger broad spectrum activity miticide of action of contace poison.Can kill if mite, one-tenth mite and summer egg are invalid to winter egg.Light and rainwater are had stability preferably, and the longevity of residure is longer.Under typical concentrations to crop safety.English common name: fenbutatin oxide, chemical name: two [three 2-methyl-phenyl propyl) tin] oxide.
Structural formula:
The weight content of active component in the insecticides of the present invention (A+B) account for the composition total content 1～80% between.
For example, can suitably in Pesticidal combination of the present invention, be added into other adjuvant components, be mixed with wetting powder, water dispersible granules, suspending agent or effervescent tablet.
In these preparations, except that active component, all contain surfactant, and also can contain thinner such as water, cosolvent according to different preparations, and carrier (filler) etc.Add antifreeze, thickener, stabilizing agent, disintegrant, defoamer, binding agent etc. in case of necessity.
Surfactant can serve as dispersant, wetting agent or bleeding agent.Can be nonionic with ionic, also can be two or more compound uses.Described dispersant; wetting agent; bleeding agent is sodium lignin sulfonate (sodium salt or a calcium salt); alkyl is sodium sulfonate how; condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate; naphthalene sulfonic acid-formaldehyde condensation product; methanonaphthalene sodium sulfonate dibutyl naphthalene sulfonic acid-formaldehyde condensation product sulphate; the naphthalenesulfonateformaldehyde formaldehyde phosphate; the withered powder of tea; saponin; lignosulfite; aliphatic alcohol sulfate; lauryl sodium sulfate; alkylbenzenesulfonate; penetrant t; bleeding agent OT; fatty acid amide-N methyl taurine sodium salt; sodium sulfate of polyethenoxy ether of fatty alcohol; draw back powder and JFC etc.; can use separately, also can meet use.Penetrant t in the above-mentioned substance, bleeding agent OT, JFC are materials well known in the art, and there is production marketing the domestic market.
Described cosolvent is selected from toluene, dimethylbenzene, turpentine oil, carrene, acetophenone, ethyl acetate, N, dinethylformamide, dimethyl sulfoxide (DMSO), ethyl cellosolve etc.
Described carrier (filler) is white carbon, precipitated calcium carbonate, potter's clay, attapulgite, kaolin, diatomite, bentonite, sepiolite, river sand, quartz sand or talcum powder or the like, can use separately, but also two or more mixes use.
Described antifreeze is: ethylene glycol, glycerine, propane diols, urea, glycerine, polyethylene glycol or isopropyl alcohol etc.
Antioxidant BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine are arranged described stabilizing agent and monoethanolamine,, can use separately, also can mix use.
Affiliated thickener has: gum Arabic, sodium carboxymethylcellulose, xanthans, Magnesiumaluminumsilicate, polyvinyl alcohol, PAA, bentonite, silicic acid, can use separately, but also two or more mixes use.
Described disintegrant has: sodium alginate, sodium carboxymethyl starch, ammonium sulfate, bentonite, urea, calcium chloride.
Described defoamer has: bubble enemy, silicone, C8-10 fatty alcohol, C10-20 saturated fat acids and amide-type.
Described binding agent is starch, dextrin, gum Arabic, soybean protein, gelatine, sodium sulphate, gypsum, polyvinyl alcohol, polyethylene glycol, rosin, paraffin, sodium carboxymethylcellulose, sodium silicate, can use separately, also can two or more mix use.
The described acaricide composition that contains fenpyroximate active ingredient is used, its described composition auxiliary material comprises and contains dispersant, wetting agent or bleeding agent, and also can contain thinner such as water, cosolvent according to different preparations, binding agent adds antifreeze, thickener, stabilizing agent, disintegrant, defoamer, filler in case of necessity.By described 2 parts～15 dispersants of mass ratio, 0 part～50 parts wetting agents, 30 parts～80 parts antifreezing agents, 40 parts～80 parts adsorbents, 1 part～5 parts thickeners, 0 part～10 parts stabilizing agents, 10～50 portions of disintegrants, 1 part～10 parts defoamers, 10 parts～80 parts binding agents, surpluses is filler.
The acaricide composition that contains fenpyroximate active ingredient is used, and is filler by described 3 parts～60 parts powders of mass ratio, 0 part～30 parts wetting agents, 30 parts～60 parts antifreezing agents, 0 part～20 parts adsorbents, 1 part～3 parts thickeners, 0 part～10 parts stabilizing agents, 10 parts～50 portions disintegrants, 1 part～5 parts defoamers, 5～30 parts of binding agents, surpluses.
Formulation of the present invention is compared with the missible oil formulation, and drug effect is suitable, but saves a large amount of finish solvents, and cost reduces and can reduce widely the pollution to environment; Adopt azoles mite ester, azacyclotin composite, have consumption few, quick-acting good, active high, the lasting period is long, kill advantages such as mite is wide, improved the lethality of soup to insect, delayed the pesticide resistance of insect to unitary agent, Pesticidal combination of the present invention can use by commonsense method, as add water spray and make cauline leaf and handle, but also root is executed.Be mainly used on watercolor, cotton, corn, citrus, the Soybean and Other Crops, insects such as two spotted spider mite are had good control efficiency.
Embodiment
Below in conjunction with embodiment summary of the invention is described further:
Embodiment 1
A kind of acaricide composition that contains fenpyroximate active ingredient, its component A are azoles mite ester, B component be selected from azacyclotin or fenbutatin oxide any one, the weight proportion of A and B is 1～25: 80～1 in the composition.
Embodiment 2
The described acaricide composition that contains fenpyroximate active ingredient, its component A are azoles mite ester, B component be selected from azacyclotin or fenbutatin oxide any one, the weight proportion of A and B is 1～22: 70～1 in the composition.
Embodiment 3
The described acaricide composition that contains fenpyroximate active ingredient, its component A are azoles mite ester, B component be selected from azacyclotin or fenbutatin oxide any one, the weight proportion of A and B is 1～20: 60～1 in the composition.
Embodiment 4
The described acaricide composition that contains fenpyroximate active ingredient, the accumulating weight of A and B is than between 1～80 in its acaricide composition.
Embodiment 5
Use by the described acaricide composition that contains fenpyroximate active ingredient of mass ratio, its composition is prepared into wetting powder, water dispersible granules, suspending agent, effervescent tablet with comprising after auxiliary material mixes.
Embodiment 6
The described acaricide composition that contains fenpyroximate active ingredient is used, its described composition auxiliary material comprises and contains dispersant, wetting agent or bleeding agent, and also can contain thinner such as water according to different preparations, cosolvent, filler, add antifreeze in case of necessity, thickener, stabilizing agent, disintegrant, defoamer, binding agent is pressed described 3 parts～15 dispersants of mass ratio, 0 part～50 parts wetting agents, 30 parts～80 parts antifreezing agents, 40 parts～80 parts adsorbents, 1 part～5 parts thickeners, 0 part～10 parts stabilizing agents, 10～50 portions of disintegrants, 1 part～10 parts defoamers, 10～80 parts of binding agents, surplus is a filler.
Embodiment 7
The described acaricide composition that contains fenpyroximate active ingredient is used, and is filler by described 3 parts～15 parts dispersants of mass ratio, 0 part～30 parts wetting agents, 30 parts～60 parts antifreezing agents, 0 part～20 parts adsorbents, 1 part～3 parts thickeners, 0 part～10 parts stabilizing agents, 10～50 portions of disintegrants, 1 part～5 parts defoamers, 5～30 parts of binding agents, surpluses.
Essence for a better understanding of the present invention, the technology contents that describes in detail with its theory of constitution and embodiment below, but the content of invention is not limited to this than you.Suspending agent (Suspesion Concentrates) is a kind of new liquid formulation of developing in recent years, it is medium with water, acts on to water-fast effective active component, by homogenize technology by dispersion, emulsification etc., to be dispersed in the water, form the thermodynamic stable system of oil-in.Its advantage is:
(1), particle thin (VMD1-3 micron);
(2), good fluidity, be easy to the metering;
(3), suspensibility height (more than the 90-95%);
(4), wetability, spread, tackness be good, resistance of rainwater washing against;
(5), biologically active is than the WP height, to compare the lasting period long with missible oil, drug effect is higher than missible oil;
(6), no dust, do not contain solvent, thereby produce, use relative with the storing condition better, environmental pollution is few, and is safe;
(7), intermiscibility is preferably arranged, be convenient to mix with bucket such as other preparations, active component and auxiliary agent;
(8), processing charges is low, easy to use.
In addition, can conveniently can make high performance agricultural chemicals kind clothing agent (FS) easily if add suitable adhesive and film forming agent, warning colouration etc. in the suspending agent; Suspending agent can be made into the outstanding microcapsule formulations (ZC) of so-called water etc. if can be made into so-called suspension emulsion (SE) with aqueous emulsion (EW) composition with microcapsules (CS) combination.Be particularly suitable for the effectively compound of multiple different performance active component; Suspending agent more can be made into the water dispersible granules (WG) of function admirable through the spray-fluidized-bed drying granulation.
Be used for preparation method of the present invention and a series of instantiation be provided in order to make those of ordinary skill in the art understand the present invention better, to the invention provides:
(a) choose raw material according to the prescription of azoles mite ester and azacyclotin, the fenbutatin oxide system of being mixed;
(b) the whole mixing of each auxiliary agent are stirred limit adding azoles mite ester and azacyclotin, the former medicine of fenbutatin oxide;
(c) the above mixture in back that stirs joins and carries out sand milling in the sand mill;
(d) make above mixture reach desired granula after sand milling 2-3 hour and promptly obtain azoles mite ester, azacyclotin, fenbutatin oxide suspending agent.
Embodiment 8: control mandarin tree two spotted spider mite
By 10 parts of azoles mite ester weight proportions (unless he does not mentionlet alone bright, average is pressed mass ratio), 30 parts of azacyclotins, 15 parts of dispersant sodium lignin sulfonates, 3.5 parts in disintegrant aluminium chloride, 1.5 parts of stabilizing agent tributyl phosphates, wetting agent draws back 5 parts in powder, and 35 parts of carrier bentonites are made water dispersible granules.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effects are 98.61% behind the medicine.10% fenpyroximate water dispersible granule and 30% azocyclotin water dispersible granule are according to using with quadrat method, and 72 hours preventive effects are respectively 48.16% and 43.12% behind the medicine.
Embodiment 9: control mandarin tree two spotted spider mite
By 10 parts of azoles mite ester weight proportions (unless he does not mentionlet alone bright, average percentage by weight), 30 parts of azacyclotins, 15 parts of dispersant sodium lignin sulfonates, 4 parts of disintegrants, stabilizing agent BHT1.5 part, 5 parts of thickener gum Arabics, 0.5 part in antifreezing agent urea, wetting agent draws back 5 parts in powder, and water is mended to 100 parts.Make composition suspending agent.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effects are 90.98% behind the medicine.10% Enpyfoximate dispersant and 30% azacyclotin suspending agent are according to using with quadrat method, and 72 hours preventive effects are respectively 50.52% and 43.31% behind the medicine.
Embodiment 10: control mandarin tree two spotted spider mite
By 10 parts of azoles mite ester weight proportions (unless he does not mentionlet alone bright, average percentage by weight), 30 parts of azacyclotins, 17 parts of dispersant sodium lignin sulfonates, 3 parts of stabilizing agent tributyl phosphates, wetting agent draw back 5 parts in powder, and 35 parts of carrier bentonites are made wetting powder.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effects are 91.68% behind the medicine.10% azoles mite ester wetting powder and 30% azacyclotin wetting powder are according to using with quadrat method, and 72 hours preventive effects are respectively 50.38% and 42.8% behind the medicine
Can draw by embodiment 8,9,10: be to use single agent azoles mite ester or more than 2 times of azacyclotin with sample ingredient azoles mite ester and the composite back control efficiency of azacyclotin to two spotted spider mite.
Embodiment 11: control mandarin tree two spotted spider mite
By 10 parts of azoles mite ester weight proportions (unless he does not mentionlet alone bright, average percentage by weight), 30 parts of fenbutatin oxides, 15 parts of dispersant sodium lignin sulfonates, 3.5 parts in disintegrant aluminium chloride, 1.5 parts of stabilizing agent tributyl phosphates, wetting agent draws back 5 parts in powder, and 35 parts of carrier bentonites are made water dispersible granules.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effects are 97.86% behind the medicine.10% fenpyroximate water dispersible granule and 30% fenbutatin oxide water dispersible granule are according to using with quadrat method, and 72 hours preventive effects are respectively 49.05% and 48.67% behind the medicine.
Embodiment 12: control mandarin tree two spotted spider mite
By 10 parts of azoles mite ester weight proportions (unless he does not mentionlet alone bright, average percentage by weight), 30 parts of fenbutatin oxides, 15 parts of dispersant sodium lignin sulfonates, 4 parts of disintegrants, stabilizing agent BHT1.5 part, 5 parts of thickener gum Arabics, 0.5 part in antifreezing agent urea, wetting agent draws back 5 parts in powder, and water is mended to 100 parts.Make composition suspending agent.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effects are 94.25% behind the medicine.10% Enpyfoximate dispersant and 30% fenbutatin oxide suspending agent are according to using with quadrat method, and 72 hours preventive effects are respectively 53.62% and 46.01% behind the medicine.
Embodiment 13: control mandarin tree two spotted spider mite
By 10 parts of azoles mite ester weight proportions (unless he does not mentionlet alone bright, average percentage by weight), 30 parts of fenbutatin oxides, 17 parts of dispersant sodium lignin sulfonates, 3 parts of stabilizing agent tributyl phosphates, wetting agent draw back 5 parts in powder, and 35 parts of carrier bentonites are made wetting powder.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effects are 95.06% behind the medicine.10% azoles mite ester wetting powder and 30% fenbutatin oxide wetting powder are according to using with quadrat method, and 72 hours preventive effects are respectively 55.26% and 42.35% behind the medicine
Can draw by embodiment 11,12,13: be to use single agent azoles mite ester or more than 2 times of azacyclotin with sample ingredient azoles mite ester and the composite back control efficiency of fenbutatin oxide to two spotted spider mite.
Embodiment 14 laboratory experiment methods
Infusion process is adopted in this test.The citrus leaves that will have a two spotted spider mite is taken back indoor, is about to two-sided tape and is cut into long slide one end that is posted on of 3cm and selects individual size basic sticking be posted on viscose glue, 30 of every slides, after under the condition of preserving moisture, placing 4h earlier, check that with the bitubular anatomical lens two spotted spider mite of checkmating is chosen and abandons, and supplies again.It is moving that the slide that will be stained with two spotted spider mite then immerses in the soup jog, soak about 5 seconds and take out, remove viscose glue surface and soup on every side with the blotting paper suction, 0.0625,0.125,0.25,0.5,1.0g/mL experimentizes each is handled medicament and establishes following variable concentrations respectively promptly:, and establish the clear water contrast, and every processing repeats 4 times, and the survival number of two spotted spider mite is handled in inspection in 24 hours behind the medicine, calculate lethality, calculate control efficiency by following formula:
Table 1 azoles mite ester and azacyclotin combination are to the synergistic effect of mandarin tree two spotted spider mite
| Chemicals treatment | Virulence regression equation | Correlation coefficient | LC50(g/mL) | Co-toxicity coefficient |
| Azoles mite ester | Y＝5.9829+2.1158X | 0.9934 | 0.343 | - |
| Azacyclotin | Y＝5.0527+1.8244X | 0.9978 | 0.936 | - |
| A+B(1∶10) | Y＝5.3123+1.5536X | 0.9993 | 0.629 | 131.2614 |
| A+B(1∶15) | Y＝5.3938+1.4913X | 0.9886 | 0.544 | 159.072 |
| A+B(1∶20) | Y＝5.5596+1.4301X | 0.9886 | 0.316 | 213.847 |
| A+B(1∶25) | Y＝5.2522+1.1284X | 0.9994 | 0.598 | 150.393 |
| A+B(1∶30) | Y＝5.2344+1.3450X | 0.9908 | 0.669 | 120.175 |
Test shows that said composition has significant synergistic effect.
12 pairs of citrus red mite daejeon prevention tests of embodiment:
10.5 the invention of part azoles mite ester azacyclotin suspending agent is a sample.Sample is established 10.5 parts of azoles mites of the present invention ester azacyclotin suspending agent, 2000 (A), 2500 (B), 3000 (C), with 1.8 azoles mite emulsifiable concentrates 3000 times (D) and 25 parts of azacyclotin wetting powders 1500 times (E) is the contrast medicament, with clear water contrast (CK), it is as follows to have carried out the field medicine effect test result of the test respectively:
| Handle | A | B | C | D | E | CK | ||
| Borer population before the medicine | 698 | 546 | 625 | 692 | 818 | 805 | ||
| The drug effect data | 1 day | Borer population | 32 | 39 | 44 | 47 | 88 | 800 |
| 1 day | Preventive effect % | 95.4A | 92.8AB | 92.9AB | 93.2AB | 89.2B | - | |
| 3 days | Borer population | 5 | 19 | 21 | 25 | 42 | 795 | |
| 3 days | Preventive effect % | 99.2A | 96.5AB | 96.6AB | 96.3AB | 94.8B | - | |
| 10 days | Borer population | 6 | 13 | 12 | 24 | 36 | 790 | |
| 10 days | Preventive effect % | 99.1A | 97.6AB | 98.1AB | 96.5B | 95.5B | - | |
| 20 days | Borer population | 33 | 43 | 59 | 64 | 69 | 742 | |
| 20 days | Preventive effect % | 95.2A | 92.1AB | 90.5B | 90.7B | 91.5B | - | |
| 30 days | Borer population | 43 | 52 | 105 | 87 | 71 | 596 | |
| 30 days | Preventive effect % | 93.8A | 90.4AB | 83.3B | 87.4B | 91.3AB | - | |
By above test data as seen, described the present invention is combined under the same test conditions, tested number still less, preventive effect is higher, has significant synergistic insecticidal action.
The azoles mite ester azacyclotin suspending agent that adopts prescription of the present invention to process, its implementation result shows, this product has compatibility preferably, working substance suspensibility height, and in process of the test adhesion rate height, resistance of rainwater washing against lasting period length, no dust, do not contain solvent, thereby production, test are relative with the storing condition better, and environmental pollution is few, and is safe.The present invention has not only improved the insecticidal spectrum of each active ingredient in production application, and has improved the biologically active of active ingredient.Through evidence, the harmful mite of multiple fruit tree and vegetable all there is the better prevention effect; And safety is good, and crop is not had poisoning.
Claims (4)
1. acaricide composition that contains fenpyroximate active ingredient, it is characterized in that: component A is an azoles mite ester, B component is azacyclotin or fenbutatin oxide, and wherein the weight proportion of azoles mite ester and azacyclotin is 1:(1～30), the weight proportion of azoles mite ester and fenbutatin oxide is 1:3.
2. the acaricide composition that contains fenpyroximate active ingredient according to claim 1 is characterized in that: the weight content of A and B accounts for 1～80% of content in the composition in the acaricide composition.
3. the acaricide composition that contains fenpyroximate active ingredient according to claim 2 is characterized in that: composition be prepared into wetting powder, water dispersible granules, suspending agent, effervescent tablet after auxiliary material mixes.
4. the acaricide composition that contains fenpyroximate active ingredient according to claim 3 is characterized in that: described composition auxiliary material is selected from surfactant, diluent water, cosolvent, filler, antifreeze, thickener, stabilizing agent, disintegrant, defoamer, binding agent;
Surfactant serves as dispersant, wetting agent or bleeding agent, be nonionic with ionic, described dispersant, wetting agent, bleeding agent is selected from sodium lignin sulfonate, Negel, condensation compound of methyl naphthalene sulfonic acid and formaldehyde sulphate, naphthalene sulfonic acid-formaldehyde condensation product, methanonaphthalene sodium sulfonate dibutyl naphthalene sulfonic acid-formaldehyde condensation product sulphate, the naphthalenesulfonateformaldehyde formaldehyde phosphate, the withered powder of tea, saponin, lignosulfite, aliphatic alcohol sulfate, lauryl sodium sulfate, alkylbenzenesulfonate, penetrant t, bleeding agent OT, fatty acid amide-N methyl taurine sodium salt, sodium sulfate of polyethenoxy ether of fatty alcohol, draw back powder, JFC;
Described cosolvent is selected from toluene, dimethylbenzene, turpentine oil, carrene, acetophenone, ethyl acetate, N, dinethylformamide, dimethyl sulfoxide (DMSO), ethyl cellosolve;
Described filler is selected from white carbon, precipitated calcium carbonate, potter's clay, attapulgite, kaolin, diatomite, bentonite, sepiolite, river sand, quartz sand or talcum powder;
Described antifreeze is ethylene glycol, glycerine, propane diols, urea, polyethylene glycol or isopropyl alcohol;
Described stabilizing agent is selected from antioxidant BHT, triphenyl phosphite, epoxychloropropane, tributyl phosphate, triethanolamine, diethanol amine;
Described thickener is selected from gum Arabic, sodium carboxymethylcellulose, xanthans, Magnesiumaluminumsilicate, polyvinyl alcohol, PAA, bentonite, silicic acid;
Described disintegrant is selected from sodium alginate, sodium carboxymethyl starch, ammonium sulfate, bentonite, urea, calcium chloride;
Described defoamer is selected from bubble enemy, silicone, C8-10 fatty alcohol, C10-20 saturated fat acids and amide-type;
Described binding agent is selected from starch, dextrin, gum Arabic, soybean protein, gelatine, sodium sulphate, gypsum, polyvinyl alcohol, polyethylene glycol, rosin, paraffin, sodium carboxymethylcellulose, sodium silicate.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1252220A (en) * | 1998-10-23 | 2000-05-10 | 拜尔公司 | Composition with pesticide and miticide property active compound |
| CN1391810A (en) * | 2002-07-04 | 2003-01-22 | 胡凡 | Insecticide and acaricide composition containing abamectin |
| CN1918997A (en) * | 2006-07-24 | 2007-02-28 | 葛尧伦 | Complex miticide composition |
-
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1252220A (en) * | 1998-10-23 | 2000-05-10 | 拜尔公司 | Composition with pesticide and miticide property active compound |
| CN1391810A (en) * | 2002-07-04 | 2003-01-22 | 胡凡 | Insecticide and acaricide composition containing abamectin |
| CN1918997A (en) * | 2006-07-24 | 2007-02-28 | 葛尧伦 | Complex miticide composition |
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| Publication number | Publication date |
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| CN101213975A (en) | 2008-07-09 |
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Effective date of registration: 20170123 Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Patentee after: Shaanxi Meibang pesticide Co.,Ltd. Address before: 715500 Pucheng province Shaanxi County Chengguan Town Food City Street No. 23 Patentee before: Zhang Shaowu |
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Address after: 715500 Pucheng County High-tech Industrial Development Zone, Weinan City, Shaanxi Province Patentee after: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Address before: 715500 industrial base of agrochemical base, Pucheng County, Shaanxi Patentee before: Shaanxi Meibang pesticide Co.,Ltd. |
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Application publication date: 20080709 Assignee: SHAANXI SUNGER ROAD BIO-SCIENCE Co.,Ltd. Assignor: SHAANXI MEIBANG PHARMACEUTICAL GROUP Co.,Ltd. Contract record no.: X2021980003933 Denomination of invention: Acaricide composition containing effective component of pyracarid and its application Granted publication date: 20110608 License type: Common License Record date: 20210525 |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
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