CN105713430A - Vinyl acetate-acrylic emulsion internal wall paint and preparation method thereof - Google Patents
Vinyl acetate-acrylic emulsion internal wall paint and preparation method thereof Download PDFInfo
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- CN105713430A CN105713430A CN201610264323.0A CN201610264323A CN105713430A CN 105713430 A CN105713430 A CN 105713430A CN 201610264323 A CN201610264323 A CN 201610264323A CN 105713430 A CN105713430 A CN 105713430A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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Abstract
The invention discloses a vinyl acetate-acrylic emulsion internal wall paint and a preparation method thereof. The vinyl acetate-acrylic emulsion internal wall paint is prepared from the following raw materials in parts by weight: 60-70 parts of vinyl acetate, 20-30 parts of butyl acrylate, 1-3 parts of acrylic acid, 1-3 parts of pentaerythritol, 1-3 parts of tributyl phosphate, 4-6 parts of dibutyl phthalate, 0.4-0.6 part of sodium carbonate, 45-55 parts of water, 1-3 parts of potassium silicate, 15-25 parts of ground calcium carbonate, 6-10 parts of titanium white, 20-30 parts of kaolin, 7-9 parts of silicon dioxide, 4-8 parts of citric acid, 1-2 parts of thickener, 1-2 parts of defoaming agent, and 5-7 parts of benzotriazole and dialkyldiphenylamine in a weight ratio of (4-6):1. The vinyl acetate-acrylic emulsion internal wall paint has the advantages of excellent brush resistance, excellent water resistance and excellent alkali resistance.
Description
Technical field
The invention belongs to chemistry painting industry field, be specifically related to a kind of acrylate and vinyl acetate emulsion interior wall coating and preparation method thereof.
Background technology
Emulsion and latex paint, refer to that the polymer emulsion using water as medium adds the coating of the allotment such as paint, filler and auxiliary agent, it be develop relatively early, at the maximum non-organic solvent type green coating of building field consumption.
Latex paint belongs to water-dispersible paint, for its composition, the same with common coating, is made up of four parts.
Main film forming substance: such as polyvinyl acetate emulsion, vinegar the third latex, styrene-acrylic latex, complete third latex, silicone acrylic emulsion, fluorine carbon emulsion etc..The main film forming substance of emulsion paint, or it is base material, it is the primary factor affecting emulsion paint performance quality.It had both been related to the hardness of film, flexibility, resistance to water, alkali resistance, scrub resistance, weatherability, stain resistance, was also related to the film-forming temperature of emulsion paint, to performances such as the bond strengths of base material.Therefore, when designing emulsion paint, first according to the environment of emulsion paint application and requirement, different polymer emulsion kinds should be selected as base material.
Pigment and filler: the performance of emulsion paint is influential by the type of pigment and filler and quantity, they are not only related to color, covering power, are also related to the performance such as paint film intensity and the adhesion of ground, hardness, gloss, stain resistance, colour retention, durability.In latex paint formulation designs, the pigment ratio of the volumetric concentration of base material (pigment with) is important parameter, uses different pigment, can prepare the film of various luster.For preparing the emulsion paint of half light and zero diopter, as long as the consumption adjusting pigment is not un-come-at-able.Emulsion paint increases along with pigment, the gloss of paint film, resistance to impact, flexibility decrease, and hardness, stain resistance improve.When pigment is beyond critical size concentration, then the scrub resistance of film and resistance to water are substantially deteriorated.
Each analog assistant: such as coalescents, wetting agent, dispersant, thickening agent, defoamer, dispersant, nertralizer, rheological agent, anti-settling agent, preservative and antifungus agent etc..
Medium: volatile media water.
The aqueous high molecular resin that acrylate and vinyl acetate emulsion is is major function monomer copolymerization with vinylacetate and butyl acrylate.It is particularly well-suited to prepare the zero diopter of the high-quality of high, medium and low PVC and half luminous environment friendly health interiro wall latex paint.
Summary of the invention
It is an object of the invention to provide a kind of acrylate and vinyl acetate emulsion interior wall coating and preparation method thereof, this acrylate and vinyl acetate emulsion interior wall coating has the number of times of resistance to brush and outstanding resistance to water, the alkali resistance of excellence.
Above-mentioned purpose is achieved by following technical solution:
A kind of acrylate and vinyl acetate emulsion interior wall coating, is made up of following raw material: vinylacetate, 60～70 parts；Butyl acrylate, 20～30 parts；Acrylic acid, 1～3 part；Tetramethylolmethane, 1～3 part；Tributyl phosphate, 1～3 part；Dibutyl phthalate, 4～6 parts；Sodium carbonate, 0.4～0.6 part；Water, 45～55 parts；Potassium silicate, 1～3 part；Ground calcium carbonate, 15～25 parts；Titanium dioxide, 6～10 parts；Kaolin, 20～30 parts；Silicon dioxide, 7～9 parts；Citric acid, 4～8 parts；Thickening agent, 1～2 part；Defoamer, 1～2 part；BTA and dialkyl diphenylamine totally 5～7 parts, BTA and dialkyl diphenylamine weight ratio are 4～6:1.
Further, described acrylate and vinyl acetate emulsion interior wall coating is made up of following raw material: vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 5:1.
Further, described acrylate and vinyl acetate emulsion interior wall coating is made up of following raw material: vinylacetate, 60 parts；Butyl acrylate, 20 parts；Acrylic acid, 1 part；Tetramethylolmethane, 1 part；Tributyl phosphate, 1 part；Dibutyl phthalate, 4 parts；Sodium carbonate, 0.4 part；Water, 45 parts；Potassium silicate, 1 part；Ground calcium carbonate, 15 parts；Titanium dioxide, 6 parts；Kaolin, 20 parts；Silicon dioxide, 7 parts；Citric acid, 4 parts；Thickening agent, 1 part；Defoamer, 1 part；BTA and dialkyl diphenylamine totally 5 parts, BTA and dialkyl diphenylamine weight ratio are 4:1.
Further, described acrylate and vinyl acetate emulsion interior wall coating is made up of following raw material: vinylacetate, 70 parts；Butyl acrylate, 30 parts；Acrylic acid, 3 parts；Tetramethylolmethane, 3 parts；Tributyl phosphate, 3 parts；Dibutyl phthalate, 6 parts；Sodium carbonate, 0.6 part；Water, 55 parts；Potassium silicate, 3 parts；Ground calcium carbonate, 25 parts；Titanium dioxide, 10 parts；Kaolin, 30 parts；Silicon dioxide, 9 parts；Citric acid, 8 parts；Thickening agent, 2 parts；Defoamer, 2 parts；BTA and dialkyl diphenylamine totally 7 parts, BTA and dialkyl diphenylamine weight ratio are 6:1.
Further, described thickening agent is CMC.
Further, described defoamer is OTD.
Advantages of the present invention:
Acrylate and vinyl acetate emulsion interior wall coating provided by the invention has the excellent number of times of resistance to brush and outstanding resistance to water and alkali resistance than existing acrylate and vinyl acetate emulsion interior wall coating.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit scope with this.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, it is possible to technical scheme is modified or equivalent replacement, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of acrylate and vinyl acetate emulsion interior wall coating
Proportioning raw materials:
Vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 5:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 2: the preparation of acrylate and vinyl acetate emulsion interior wall coating
Proportioning raw materials:
Vinylacetate, 60 parts；Butyl acrylate, 20 parts；Acrylic acid, 1 part；Tetramethylolmethane, 1 part；Tributyl phosphate, 1 part；Dibutyl phthalate, 4 parts；Sodium carbonate, 0.4 part；Water, 45 parts；Potassium silicate, 1 part；Ground calcium carbonate, 15 parts；Titanium dioxide, 6 parts；Kaolin, 20 parts；Silicon dioxide, 7 parts；Citric acid, 4 parts；Thickening agent, 1 part；Defoamer, 1 part；BTA and dialkyl diphenylamine totally 5 parts, BTA and dialkyl diphenylamine weight ratio are 4:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 3: the preparation of acrylate and vinyl acetate emulsion interior wall coating
Proportioning raw materials:
Vinylacetate, 70 parts；Butyl acrylate, 30 parts；Acrylic acid, 3 parts；Tetramethylolmethane, 3 parts；Tributyl phosphate, 3 parts；Dibutyl phthalate, 6 parts；Sodium carbonate, 0.6 part；Water, 55 parts；Potassium silicate, 3 parts；Ground calcium carbonate, 25 parts；Titanium dioxide, 10 parts；Kaolin, 30 parts；Silicon dioxide, 9 parts；Citric acid, 8 parts；Thickening agent, 2 parts；Defoamer, 2 parts；BTA and dialkyl diphenylamine totally 7 parts, BTA and dialkyl diphenylamine weight ratio are 6:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 4: the preparation of acrylate and vinyl acetate emulsion interior wall coating
Proportioning raw materials:
Vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 4:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 5: the preparation of acrylate and vinyl acetate emulsion interior wall coating
Proportioning raw materials:
Vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 6:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 6: embodiment 1 contrasts, BTA and dialkyl diphenylamine weight ratio are 3:1
Proportioning raw materials:
Vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 3:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 7: embodiment 1 contrasts, BTA and dialkyl diphenylamine weight ratio are 7:1
Proportioning raw materials:
Vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 7:1.Thickening agent is CMC, and defoamer is OTD.
Preparation method:
Prepared by slurry: by water, titanium dioxide, ground calcium carbonate, sodium carbonate, potassium silicate, Kaolin, silicon dioxide mix homogeneously in blending tank, be ground, obtain slurry；
Prepared by base material: vinylacetate, butyl acrylate, acrylic acid, thickening agent CMC, citric acid are stirred in blending tank, mix homogeneously, prepares base material；
Prepared by coating: slurry produced above and base material are placed in blending tank and mix, add tetramethylolmethane, tributyl phosphate, dibutyl phthalate, defoamer OTD, BTA and dialkyl diphenylamine to be stirred, after uniformly, then carry out sand milling extremely suitable fineness.
Embodiment 8: performance test
The acrylate and vinyl acetate emulsion interior wall coating of embodiment 1～7 preparation is carried out performance test, and test result is as follows.
The acrylate and vinyl acetate emulsion interior wall coating of embodiment 2,3 preparation is similar to acrylate and vinyl acetate emulsion interior wall coating performance prepared by embodiment 4,5.From upper table test result it can be seen that acrylate and vinyl acetate emulsion interior wall coating provided by the invention has the excellent number of times of resistance to brush and outstanding resistance to water and alkali resistance, this is likely to relevant with BTA in formula and dialkyl diphenylamine weight ratio.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit protection scope of the present invention with this.It will be understood by those within the art that, it is possible to technical scheme is modified or equivalent replacement, without deviating from essence and the protection domain of technical solution of the present invention.
Claims (6)
1. an acrylate and vinyl acetate emulsion interior wall coating, it is characterised in that be made up of following raw material: vinylacetate, 60～70 parts；Butyl acrylate, 20～30 parts；Acrylic acid, 1～3 part；Tetramethylolmethane, 1～3 part；Tributyl phosphate, 1～3 part；Dibutyl phthalate, 4～6 parts；Sodium carbonate, 0.4～0.6 part；Water, 45～55 parts；Potassium silicate, 1～3 part；Ground calcium carbonate, 15～25 parts；Titanium dioxide, 6～10 parts；Kaolin, 20～30 parts；Silicon dioxide, 7～9 parts；Citric acid, 4～8 parts；Thickening agent, 1～2 part；Defoamer, 1～2 part；BTA and dialkyl diphenylamine totally 5～7 parts, BTA and dialkyl diphenylamine weight ratio are 4～6:1.
2. acrylate and vinyl acetate emulsion interior wall coating according to claim 1, it is characterised in that be made up of following raw material: vinylacetate, 65 parts；Butyl acrylate, 25 parts；Acrylic acid, 2 parts；Tetramethylolmethane, 2 parts；Tributyl phosphate, 2 parts；Dibutyl phthalate, 5 parts；Sodium carbonate, 0.5 part；Water, 50 parts；Potassium silicate, 2 parts；Ground calcium carbonate, 20 parts；Titanium dioxide, 8 parts；Kaolin, 25 parts；Silicon dioxide, 8 parts；Citric acid, 6 parts；Thickening agent, 1.5 parts；Defoamer, 1.5 parts；BTA and dialkyl diphenylamine totally 6 parts, BTA and dialkyl diphenylamine weight ratio are 5:1.
3. acrylate and vinyl acetate emulsion interior wall coating according to claim 1, it is characterised in that be made up of following raw material: vinylacetate, 60 parts；Butyl acrylate, 20 parts；Acrylic acid, 1 part；Tetramethylolmethane, 1 part；Tributyl phosphate, 1 part；Dibutyl phthalate, 4 parts；Sodium carbonate, 0.4 part；Water, 45 parts；Potassium silicate, 1 part；Ground calcium carbonate, 15 parts；Titanium dioxide, 6 parts；Kaolin, 20 parts；Silicon dioxide, 7 parts；Citric acid, 4 parts；Thickening agent, 1 part；Defoamer, 1 part；BTA and dialkyl diphenylamine totally 5 parts, BTA and dialkyl diphenylamine weight ratio are 4:1.
4. acrylate and vinyl acetate emulsion interior wall coating according to claim 1, it is characterised in that be made up of following raw material: vinylacetate, 70 parts；Butyl acrylate, 30 parts；Acrylic acid, 3 parts；Tetramethylolmethane, 3 parts；Tributyl phosphate, 3 parts；Dibutyl phthalate, 6 parts；Sodium carbonate, 0.6 part；Water, 55 parts；Potassium silicate, 3 parts；Ground calcium carbonate, 25 parts；Titanium dioxide, 10 parts；Kaolin, 30 parts；Silicon dioxide, 9 parts；Citric acid, 8 parts；Thickening agent, 2 parts；Defoamer, 2 parts；BTA and dialkyl diphenylamine totally 7 parts, BTA and dialkyl diphenylamine weight ratio are 6:1.
5. according to the arbitrary described acrylate and vinyl acetate emulsion interior wall coating of Claims 1 to 4, it is characterised in that: described thickening agent is CMC.
6. according to the arbitrary described acrylate and vinyl acetate emulsion interior wall coating of Claims 1 to 4, it is characterised in that: described defoamer is OTD.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610264323.0A CN105713430A (en) | 2016-04-23 | 2016-04-23 | Vinyl acetate-acrylic emulsion internal wall paint and preparation method thereof |
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| CN201610264323.0A CN105713430A (en) | 2016-04-23 | 2016-04-23 | Vinyl acetate-acrylic emulsion internal wall paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111560201A (en) * | 2020-06-02 | 2020-08-21 | 东联北方科技(北京)有限公司 | Flexible acrylic emulsion |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571289A (en) * | 2013-11-08 | 2014-02-12 | 青岛益群漆业集团有限公司 | Research and development of scrubbing-resistant odor-removal paint for internal walls |
-
2016
- 2016-04-23 CN CN201610264323.0A patent/CN105713430A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571289A (en) * | 2013-11-08 | 2014-02-12 | 青岛益群漆业集团有限公司 | Research and development of scrubbing-resistant odor-removal paint for internal walls |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111560201A (en) * | 2020-06-02 | 2020-08-21 | 东联北方科技(北京)有限公司 | Flexible acrylic emulsion |
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Application publication date: 20160629 |