CN105696341A - 一种抗静电纺织浆料及其制备方法 - Google Patents
一种抗静电纺织浆料及其制备方法 Download PDFInfo
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- 238000009987 spinning Methods 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- IYRMWMYZSQPJKC-UHFFFAOYSA-N kaempferol Chemical compound C1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 IYRMWMYZSQPJKC-UHFFFAOYSA-N 0.000 claims abstract description 26
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims abstract description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 14
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 14
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims abstract description 14
- 229930195725 Mannitol Natural products 0.000 claims abstract description 14
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 14
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 14
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 14
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 14
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 14
- 239000000594 mannitol Substances 0.000 claims abstract description 14
- 235000010355 mannitol Nutrition 0.000 claims abstract description 14
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 14
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 14
- WCRMDMYSQWZTSF-UHFFFAOYSA-N 2-hydroxy-1-methoxy-3-methylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=C(C)C(O)=C2OC WCRMDMYSQWZTSF-UHFFFAOYSA-N 0.000 claims abstract description 13
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960001748 allylthiourea Drugs 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 238000004513 sizing Methods 0.000 claims description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 20
- 150000001412 amines Chemical group 0.000 claims description 13
- 150000002596 lactones Chemical class 0.000 claims description 13
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 claims description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 12
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052749 magnesium Inorganic materials 0.000 claims description 12
- 239000011777 magnesium Substances 0.000 claims description 12
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims description 11
- 229930003633 citronellal Natural products 0.000 claims description 11
- 235000000983 citronellal Nutrition 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- UBSCDKPKWHYZNX-UHFFFAOYSA-N Demethoxycapillarisin Natural products C1=CC(O)=CC=C1OC1=CC(=O)C2=C(O)C=C(O)C=C2O1 UBSCDKPKWHYZNX-UHFFFAOYSA-N 0.000 abstract 1
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical compound O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 abstract 1
- 235000008777 kaempferol Nutrition 0.000 abstract 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 abstract 1
- 229940078490 n,n-dimethylglycine Drugs 0.000 abstract 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract 1
- 238000011056 performance test Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000004744 fabric Substances 0.000 description 6
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- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 239000002657 fibrous material Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
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- 239000002904 solvent Substances 0.000 description 1
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Abstract
本发明公开了一种抗静电纺织浆料及其制备方法，上述抗静电纺织浆料，由包含以下重量份的组分制成：丙烯腈纤维60-70份、聚乙二醇30-40份、甘露醇12-16份、偏二氯乙烯8-12份、羧甲基纤维素5-8份、环氧聚硅烷丙烯酸酯3-5份、十二烷基二甲基胺乙内酯2-3份、烯丙基硫脲0.5-1份、聚二甲基硅氧烷二季胺盐0.5-1份、2-甲基-3-羟基-4-甲氧基蒽醌0.2-0.8份、硅铝酸镁0.2-0.6份和山柰酚0.02-0.08份。本发明还提供了一种抗静电纺织浆料的制备方法。
Description
技术领域
本发明属于纺织材料领域，特别涉及一种抗静电纺织浆料及其制备方法。
背景技术
纤维材料中，常含有亲水性-OH和-NH2等基团，因此易发生电荷的蓄存。随着人们对于各类织物的洗涤和去污剂要求的不断提高，在对洗涤和去污剂的去污能力有着较高要求的同时，还要求洗涤和去污剂对织物有一定的保养作用。
中国专利CN1553978A公开了一种织物处理剂，包含一种水分散体，该水分散体主要由一种封闭的聚氨酯和一种疏水性溶剂组成，制得的处理剂在低温下仍具有良好的稳定性，使经过本发明的织物处理剂处理过的纺织品具备柔软的手感和改进的耐收缩性。但经该处理剂处理后的纺织材料的防静电性能持久性较差，不能满足长期需求。
因此，亟需一种具有防静电面料，但现有的该类面料的透气性和耐磨性却不佳。
发明内容
针对上述的需求，本发明特别提供了一种抗静电纺织浆料及其制备方法。
本发明的目的可以通过以下技术方案实现：
一种抗静电纺织浆料，由包含以下重量份的组分制成：
丙烯腈纤维60-70份，
聚乙二醇30-40份，
甘露醇12-16份，
偏二氯乙烯8-12份，
羧甲基纤维素5-8份，
环氧聚硅烷丙烯酸酯3-5份，
十二烷基二甲基胺乙内酯2-3份，
烯丙基硫脲0.5-1份，
聚二甲基硅氧烷二季胺盐0.5-1份，
2-甲基-3-羟基-4-甲氧基蒽醌0.2-0.8份，
硅铝酸镁0.2-0.6份，
山柰酚0.02-0.08份。
所述组分还包括氧化锌0-1重量份。
所述组分还包括3，7-二甲基-6-辛烯醛0-1重量份。
一种抗静电纺织浆料的制备方法，该方法包括以下步骤：
（1）称取丙烯腈纤维60-70重量份、聚乙二醇30-40重量份、甘露醇12-16重量份、偏二氯乙烯8-12重量份、环氧聚硅烷丙烯酸酯3-5重量份、十二烷基二甲基胺乙内酯2-3重量份、烯丙基硫脲0.5-1重量份、2-甲基-3-羟基-4-甲氧基蒽醌0.2-0.8重量份和山柰酚0.02-0.08重量份，在反应釜中90-100℃下搅拌1-3小时；
（2）将体系pH值调节到6-7，依次加入羧甲基纤维素5-8重量份、聚二甲基硅氧烷二季胺盐0.5-1重量份、硅铝酸镁0.2-0.6重量份、氧化锌0-1重量份和3，7-二甲基-6-辛烯醛0-1重量份，在50-60℃下搅拌10-20分钟，得到抗静电纺织浆料。
所述反应釜中的压强为8-12MPa。
本发明与现有技术相比，其有益效果为：
（1）本发明的抗静电纺织浆料以丙烯腈纤维为主要原料，通过加入聚乙二醇、甘露醇、偏二氯乙烯、羧甲基纤维素、环氧聚硅烷丙烯酸酯、十二烷基二甲基胺乙内酯、烯丙基硫脲、聚二甲基硅氧烷二季胺盐、2-甲基-3-羟基-4-甲氧基蒽醌、硅铝酸镁和山柰酚，本发明的抗静电纺织浆料制得的织物具有良好的力学强度、韧性和耐磨性。
（2）本发明的抗静电纺织浆料制得的织物具有良好的防静电性能。
（3）本发明的抗静电纺织浆料，其制备方法简单，易于工业化生产。
具体实施方式
以下结合实施例对本发明作进一步的说明。
实施例1
（1）称取丙烯腈纤维60kg、聚乙二醇30kg、甘露醇12kg、偏二氯乙烯8kg、环氧聚硅烷丙烯酸酯3kg、十二烷基二甲基胺乙内酯2kg、烯丙基硫脲0.5kg、2-甲基-3-羟基-4-甲氧基蒽醌0.2kg和山柰酚0.02kg，在反应釜中90℃、8MPa下搅拌1小时；
（2）将体系pH值调节到6，依次加入羧甲基纤维素5kg、聚二甲基硅氧烷二季胺盐0.5kg和硅铝酸镁0.2kg，在50℃下搅拌10分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
实施例2
（1）称取丙烯腈纤维60kg、聚乙二醇30kg、甘露醇12kg、偏二氯乙烯8kg、环氧聚硅烷丙烯酸酯3kg、十二烷基二甲基胺乙内酯2kg、烯丙基硫脲0.5kg、2-甲基-3-羟基-4-甲氧基蒽醌0.2kg和山柰酚0.02kg，在反应釜中90℃、8MPa下搅拌1小时；
（2）将体系pH值调节到6，依次加入羧甲基纤维素5kg、聚二甲基硅氧烷二季胺盐0.5kg、硅铝酸镁0.2kg、氧化锌1kg和3，7-二甲基-6-辛烯醛1kg，在50℃下搅拌10分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
实施例3
（1）称取丙烯腈纤维70kg、聚乙二醇40kg、甘露醇16kg、偏二氯乙烯12kg、环氧聚硅烷丙烯酸酯5kg、十二烷基二甲基胺乙内酯3kg、烯丙基硫脲1kg、2-甲基-3-羟基-4-甲氧基蒽醌0.8kg和山柰酚0.08kg，在反应釜中100℃、12MPa下搅拌3小时；
（2）将体系pH值调节到7，依次加入羧甲基纤维素8kg、聚二甲基硅氧烷二季胺盐1kg、硅铝酸镁0.6kg、氧化锌1kg和3，7-二甲基-6-辛烯醛1kg，在60℃下搅拌20分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
实施例4
（1）称取丙烯腈纤维70kg、聚乙二醇40kg、甘露醇16kg、偏二氯乙烯12kg、环氧聚硅烷丙烯酸酯5kg、十二烷基二甲基胺乙内酯3kg、烯丙基硫脲0.5kg、2-甲基-3-羟基-4-甲氧基蒽醌0.8kg和山柰酚0.02kg，在反应釜中100℃、12MPa下搅拌3小时；
（2）将体系pH值调节到7，依次加入羧甲基纤维素8kg、聚二甲基硅氧烷二季胺盐1kg、硅铝酸镁0.6kg、氧化锌1kg和3，7-二甲基-6-辛烯醛1kg，在60℃下搅拌20分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
实施例5
（1）称取丙烯腈纤维65kg、聚乙二醇35kg、甘露醇14kg、偏二氯乙烯10kg、环氧聚硅烷丙烯酸酯4kg、十二烷基二甲基胺乙内酯2.5kg、烯丙基硫脲0.8kg、2-甲基-3-羟基-4-甲氧基蒽醌0.5kg和山柰酚0.05kg，在反应釜中95℃、10MPa下搅拌2小时；
（2）将体系pH值调节到6.5，依次加入羧甲基纤维素6kg、聚二甲基硅氧烷二季胺盐0.7kg、硅铝酸镁0.4kg、氧化锌0.5kg和3，7-二甲基-6-辛烯醛0.5kg，在55℃下搅拌15分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
对比例1
（1）称取丙烯腈纤维70kg、聚乙二醇40kg、甘露醇16kg、偏二氯乙烯12kg、环氧聚硅烷丙烯酸酯5kg、十二烷基二甲基胺乙内酯3kg、2-甲基-3-羟基-4-甲氧基蒽醌0.8kg和山柰酚0.08kg，在反应釜中100℃、12MPa下搅拌3小时；
（2）将体系pH值调节到7，依次加入羧甲基纤维素8kg、聚二甲基硅氧烷二季胺盐1kg、硅铝酸镁0.6kg、氧化锌1kg和3，7-二甲基-6-辛烯醛1kg，在60℃下搅拌20分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
对比例2
（1）称取丙烯腈纤维70kg、聚乙二醇40kg、甘露醇16kg、偏二氯乙烯12kg、环氧聚硅烷丙烯酸酯5kg、十二烷基二甲基胺乙内酯3kg、烯丙基硫脲1kg和山柰酚0.08kg，在反应釜中100℃、12MPa下搅拌3小时；
（2）将体系pH值调节到7，依次加入羧甲基纤维素8kg、聚二甲基硅氧烷二季胺盐1kg、硅铝酸镁0.6kg、氧化锌1kg和3，7-二甲基-6-辛烯醛1kg，在60℃下搅拌20分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
对比例3
（1）称取丙烯腈纤维70kg、聚乙二醇40kg、甘露醇16kg、偏二氯乙烯12kg、环氧聚硅烷丙烯酸酯5kg、十二烷基二甲基胺乙内酯3kg、烯丙基硫脲1kg、2-甲基-3-羟基-4-甲氧基蒽醌0.8kg，在反应釜中100℃、12MPa下搅拌3小时；
（2）将体系pH值调节到7，依次加入羧甲基纤维素8kg、聚二甲基硅氧烷二季胺盐1kg、氧化锌1kg和3，7-二甲基-6-辛烯醛1kg，在60℃下搅拌20分钟，得到抗静电纺织浆料。
制得抗静电纺织浆料的性能测试结果如表1所示。
将实施例1-5和对比例1-3的抗静电纺织浆料制成厚度为0.2的膜，测试其具体性能，结果如表1所示。
表1
| 测试项目 | 点对点电阻（Ω） | 断裂强度（N/mm2) | 磨耗（mg/cm2） |
| 实施例1 | 6.6×106 | 73 | 0.26 |
| 实施例2 | 3.6×107 | 75 | 0.15 |
| 实施例3 | 6.1×107 | 84 | 0.13 |
| 实施例4 | 5.9×107 | 77 | 0.14 |
| 实施例5 | 7.0×107 | 78 | 0.14 |
| 对比例1 | 6.6×104 | 35 | 0.36 |
| 对比例2 | 6.8×104 | 40 | 0.42 |
| 对比例3 | 5.5×104 | 38 | 0.35 |
本发明不限于这里的实施例，本领域技术人员根据本发明的揭示，不脱离本发明范畴所做出的改进和修改都应该在本发明的保护范围之内。
Claims (5)
1.一种抗静电纺织浆料，其特征在于，由包含以下重量份的组分制成：
丙烯腈纤维60-70份，
聚乙二醇30-40份，
甘露醇12-16份，
偏二氯乙烯8-12份，
羧甲基纤维素5-8份，
环氧聚硅烷丙烯酸酯3-5份，
十二烷基二甲基胺乙内酯2-3份，
烯丙基硫脲0.5-1份，
聚二甲基硅氧烷二季胺盐0.5-1份，
2-甲基-3-羟基-4-甲氧基蒽醌0.2-0.8份，
硅铝酸镁0.2-0.6份，
山柰酚0.02-0.08份。
2.根据权利要求1所述抗静电纺织浆料，其特征在于，所述组分还包括氧化锌0-1重量份。
3.根据权利要求1所述抗静电纺织浆料，其特征在于，所述组分还包括3，7-二甲基-6-辛烯醛0-1重量份。
4.一种抗静电纺织浆料的制备方法，其特征在于，该方法包括以下步骤：
（1）称取丙烯腈纤维60-70重量份、聚乙二醇30-40重量份、甘露醇12-16重量份、偏二氯乙烯8-12重量份、环氧聚硅烷丙烯酸酯3-5重量份、十二烷基二甲基胺乙内酯2-3重量份、烯丙基硫脲0.5-1重量份、2-甲基-3-羟基-4-甲氧基蒽醌0.2-0.8重量份和山柰酚0.02-0.08重量份，在反应釜中90-100℃下搅拌1-3小时；
（2）将体系pH值调节到6-7，依次加入羧甲基纤维素5-8重量份、聚二甲基硅氧烷二季胺盐0.5-1重量份、硅铝酸镁0.2-0.6重量份、氧化锌0-1重量份和3，7-二甲基-6-辛烯醛0-1重量份，在50-60℃下搅拌10-20分钟，得到抗静电纺织浆料。
5.根据权利要求4所述的抗静电纺织浆料的制备方法，其特征在于，所述反应釜中的压强为8-12MPa。
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106592212A (zh) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | 一种用于纤维织物的防静电纺织浆料及其制备方法 |
| CN107268115A (zh) * | 2017-07-03 | 2017-10-20 | 苏州舒而适纺织新材料科技有限公司 | 一种添加有山奈酚的复合纺织材料及其制备方法 |
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| CN108103781A (zh) * | 2017-12-26 | 2018-06-01 | 安徽羽洁家纺有限公司 | 一种抗静电纺织浆料及其制备方法 |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313423A (zh) * | 2000-03-13 | 2001-09-19 | 张猷道 | 一种纺织浆料 |
| CN1932136A (zh) * | 2006-10-25 | 2007-03-21 | 徐建新 | 纺织经纱的纱浆制作方法 |
| CN105113243A (zh) * | 2015-09-18 | 2015-12-02 | 杨洋 | 一种用于纺织材料的除静电清洗剂及其制备方法 |
| CN105220490A (zh) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | 一种新型纺织材料用防静电剂及其制备方法 |
-
2016
- 2016-04-05 CN CN201610205865.0A patent/CN105696341B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313423A (zh) * | 2000-03-13 | 2001-09-19 | 张猷道 | 一种纺织浆料 |
| CN1932136A (zh) * | 2006-10-25 | 2007-03-21 | 徐建新 | 纺织经纱的纱浆制作方法 |
| CN105113243A (zh) * | 2015-09-18 | 2015-12-02 | 杨洋 | 一种用于纺织材料的除静电清洗剂及其制备方法 |
| CN105220490A (zh) * | 2015-10-20 | 2016-01-06 | 湖州博润实业有限公司 | 一种新型纺织材料用防静电剂及其制备方法 |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106592212A (zh) * | 2016-12-15 | 2017-04-26 | 吴江市北厍盛源纺织品助剂厂 | 一种用于纤维织物的防静电纺织浆料及其制备方法 |
| CN107268115A (zh) * | 2017-07-03 | 2017-10-20 | 苏州舒而适纺织新材料科技有限公司 | 一种添加有山奈酚的复合纺织材料及其制备方法 |
| CN107841870A (zh) * | 2017-11-29 | 2018-03-27 | 苏州润弘贸易有限公司 | 一种改进型纺织浆料 |
| CN108103781A (zh) * | 2017-12-26 | 2018-06-01 | 安徽羽洁家纺有限公司 | 一种抗静电纺织浆料及其制备方法 |
| CN116590821B (zh) * | 2023-05-10 | 2024-02-06 | 潮州市苏菲亚时装有限公司 | 一种透气涤纶面料的合成方法及应用 |
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