CN105690896A - Aluminum alloy and ceramic board composite board and formula technology - Google Patents

Aluminum alloy and ceramic board composite board and formula technology Download PDF

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Publication number
CN105690896A
CN105690896A CN201610132363.XA CN201610132363A CN105690896A CN 105690896 A CN105690896 A CN 105690896A CN 201610132363 A CN201610132363 A CN 201610132363A CN 105690896 A CN105690896 A CN 105690896A
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layer
ceramic
aluminium alloy
formula
glaze paint
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CN105690896B (en
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程石明
任富国
李利方
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MANLEY (CHINA) Co Ltd
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MANLEY (CHINA) Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/005—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising one layer of ceramic material, e.g. porcelain, ceramic tile
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
    • B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B9/041—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3436—Alkaline earth metal silicates, e.g. barium silicate
    • C04B2235/3445—Magnesium silicates, e.g. forsterite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention discloses an aluminum alloy and ceramic board composite board and a formula technology. The aluminum alloy and ceramic board composite board consists of an aluminum alloy layer and a flat board ceramic layer, the aluminum alloy layer is an aluminum alloy profile with the space between upper and lower flat board surfaces spaced into a honeycomb structure, the flat board ceramic layer is a large-specification planar composite ceramic board comprising a green body layer and a glaze surface, the green body layer comprises a front surface and an adhesive surface, the front surface is a plane while the adhesive surface is a concave-convex surface with grooves, the specification of the green body layer is at least 900 mm*1,800 mm, the thickness is 5.5 mm, the glaze layer comprises a glaze bottom layer, a pattern layer and a glaze surface layer, and the adhesive surface of the flat board ceramic layer is adhered to the flat board surface of the aluminum alloy layer. A formula comprises a green body layer formula, a glaze bottom layer formula and a glaze surface layer formula; the firing temperature in the technological process ranges from 1,193 DEG C to 1,196 DEG C, and the firing period is 73 min.

Description

The composite plate of a kind of aluminium alloy and ceramic wafer and Recipe
Technical field
The present invention relates to a kind of composite plate, particularly to composite plate and the Recipe of a kind of aluminium alloy and ceramic wafer, belong to pottery and technical field of hardware。
Background technology
Aluminium alloy extrusions, because quality is light and soft and plasticity strong, is widely applied to furniture and building decoration field, but aluminium alloy the mirror effect on surface, hardness, antiacid alkali and weather-proof in have its congenital defect。Although ceramic the mirror effect on surface, hardness, antiacid alkali and weather-proof in have its an inborn advantage, but ceramic heavy, not plastic and frangible be its inborn deficiency。But the needs that this two classes material advantageous characteristic is merged are had at furniture and field of constructional ornament, this just proposes brand-new problem to ceramic industry and hardware industry。
Summary of the invention
For the particular/special requirement solving above-mentioned aluminium alloy and ceramic material superior function combines together, the present invention provides composite plate and the Recipe of a kind of aluminium alloy and ceramic wafer。
The technical solution adopted in the present invention is: the composite plate of a kind of aluminium alloy and ceramic wafer and Recipe, the composite plate of aluminium alloy and ceramic wafer is made up of aluminium alloy layer and flat board ceramic layer, aluminium alloy layer is the aluminium alloy extrusions that in upper and lower platen surface, interval sky becomes alveolate texture, flat ceramic layer is big specification Planar Compound ceramic wafer, composite ceramic slab is divided into green body layer and glazed layer, green body layer is divided into front and bonding plane, front is plane and bonding plane is reeded male and fomale(M&F), the specification of green body layer is at least 900mm × 1800mm, thickness is 5.5mm, glazed layer is divided into glaze paint bottom, patterned layer and glaze paint surface layer, glaze paint bottom uniform fold is in the front of green body layer, patterned layer optionally covers above glaze paint bottom according to patterning, glaze paint surface layer covers patterned layer and glaze paint substratum, the bonding plane of flat ceramic layer is bonded in the platen surface of aluminium alloy layer；Recipe is the Recipe of composite ceramic slab, and formula includes green body layer formula, glaze paint bottom formula and glaze paint surface layer formula；Dry-pressing formed pressure in technological process is 240MPa, and baking temperature is 120 DEG C～286 DEG C, and arid cycle is 62min, and firing temperature is upper temperature 1196 DEG C, lower temperature 1193 DEG C, and firing period is 73min。
Green body layer formula includes Longhai City's Anhydrite 15.2%, Yongan albite 13.63% by weight percentage, and water is sand 13.12% first; east of a river washing soil 12.11%, Changtai washing soil 10.1%, big level ground Herba Epigeneii fargesii 10.09%; Zhangping land waste 7.07%, Longhai City's dirt 7.07%, bauxite 6.05%; bentonite 3%; attapulgite 1.0%, sodium humate 0.55%, sodium silicate 0.55%; lignin 0.45%, methylcellulose 0.01%。
Glaze paint bottom formula includes quartz 44% by weight percentage, Longyan albite 13%, planetesimal Kaolin 9.8%, calcined kaolin 6.6%, Zirconium orthosilicate. 5.98%, calcite 5.28%, silicon pyroxene 5.27%, lucky polo soil 4.97%, Pulvis Talci 2.64%, zinc oxide 2%, sodium tripolyphosphate 0.4%, methylcellulose 0.06%。
Glaze paint surface layer formula includes Silicon stone 30.1%, white frit 19.38%, calcined kaolin 16.7%, Longyan albite 13.5% by weight percentage, burns Talcum 8.7%, lucky polo soil 8.6%, aluminium oxide 2.5%, sodium tripolyphosphate 0.46%, methylcellulose 0.06%。
The invention has the beneficial effects as follows: adopt the composite ceramic slab of special formulation technique and cellular aluminium alloy extrusions to paste compound, merge the good characteristic of two kinds of certain materials, effectively overcome the congenital defect that ceramic wafer is frangible, be difficult to connect Hardware fitting, after aluminum alloy honeycomb plate compound, allow ceramic wafer become the door-plate of cabinet etc., side plate and panel and become a reality。
Accompanying drawing explanation
Below in conjunction with accompanying drawing, the present invention is further described:
Fig. 1 is the cross-sectional structure schematic diagram of the present invention。
In figure 1, aluminium alloy layer, 2, flat ceramic layer, 3, green body layer, 4, glaze paint bottom, 5, patterned layer, 6, glaze paint surface layer。
Detailed description of the invention
In the embodiment in figure 1, the composite plate of a kind of aluminium alloy and ceramic wafer and Recipe, the composite plate of aluminium alloy and ceramic wafer is made up of aluminium alloy layer 1 and flat board ceramic layer 2, aluminium alloy layer 1 is the aluminium alloy extrusions that in upper and lower platen surface, interval sky becomes alveolate texture, flat ceramic layer 2 is big specification Planar Compound ceramic wafer, composite ceramic slab is divided into green body layer 3 and glazed layer, green body layer 3 is divided into front and bonding plane, front is plane and bonding plane is reeded male and fomale(M&F), the specification of green body layer 3 is at least 900mm × 1800mm, thickness is 5.5mm, glazed layer is divided into glaze paint bottom 4, patterned layer 5 and glaze paint surface layer 6, glaze paint bottom 4 uniform fold is in the front of green body layer 3, patterned layer 5 optionally covers above glaze paint bottom 4 according to patterning, glaze paint surface layer 6 covers above patterned layer 5 and glaze paint bottom 4, the bonding plane of flat ceramic layer 2 is bonded in the platen surface of aluminium alloy layer 1；Recipe is the Recipe of composite ceramic slab, and formula includes green body layer 3 formula, glaze paint bottom 4 formula and glaze paint surface layer 6 formula；Dry-pressing formed pressure in technological process is 240MPa, and baking temperature is 120 DEG C～286 DEG C, and arid cycle is 62min, and firing temperature is upper temperature 1196 DEG C, lower temperature 1193 DEG C, and firing period is 73min。
Green body layer 3 formula includes Longhai City's Anhydrite 15.2%, Yongan albite 13.63% by weight percentage, and water is sand 13.12% first; east of a river washing soil 12.11%, Changtai washing soil 10.1%, big level ground Herba Epigeneii fargesii 10.09%; Zhangping land waste 7.07%, Longhai City's dirt 7.07%, bauxite 6.05%; bentonite 3%; attapulgite 1.0%, sodium humate 0.55%, sodium silicate 0.55%; lignin 0.45%, methylcellulose 0.01%。
Glaze paint bottom 4 formula includes quartz 44% by weight percentage, Longyan albite 13%, planetesimal Kaolin 9.8%, calcined kaolin 6.6%, Zirconium orthosilicate. 5.98%, calcite 5.28%, silicon pyroxene 5.27%, lucky polo soil 4.97%, Pulvis Talci 2.64%, zinc oxide 2%, sodium tripolyphosphate 0.4%, methylcellulose 0.06%。
Glaze paint surface layer 6 formula includes Silicon stone 30.1%, white frit 19.38%, calcined kaolin 16.7%, Longyan albite 13.5% by weight percentage, burns Talcum 8.7%, lucky polo soil 8.6%, aluminium oxide 2.5%, sodium tripolyphosphate 0.46%, methylcellulose 0.06%。
Embodiment 1: when making flat ceramic layer 2, first in proportion that raw material preparation is good, again raw material is added water and put into ball mill and wear into the mud of high fineness, after deironing of sieving, send into powder drying tower after mud milled carry out spray drying, dried powder is passed through large-sized hydraulic press dry-pressing formed on mould, the big specification flat ceramic slab body after molding is sent into drying kiln and dries；Carry out patterned layer 5 ink jet printing after the ceramic body reaching certain degree of drying is applied glaze paint bottom 4, then apply glaze paint surface layer 6。Finally the composite ceramic slab base substrate completing early stage technique is sent into roller kiln burning and make the big specification composite ceramic slab including green body layer 3, glaze paint bottom 4, patterned layer 5 and glaze paint surface layer 6, can be used as finished product warehouse-in then through after edging sorting packing。
Embodiment 2: apply adhesive in the platen surface of aluminium alloy layer 1 and the bonding plane of flat board ceramic layer 2, after having the platen surface of applying glue to fasten, press and heat the bonding plane of flat ceramic layer 2 and aluminium alloy layer 1, the composite plate of aluminium alloy and pottery is just made。

Claims (4)

1. the composite plate of an aluminium alloy and ceramic wafer and Recipe, it is characterized in that: the composite plate of aluminium alloy and ceramic wafer is made up of aluminium alloy layer and flat board ceramic layer, aluminium alloy layer is the aluminium alloy extrusions that in upper and lower platen surface, interval sky becomes alveolate texture, flat ceramic layer is big specification Planar Compound ceramic wafer, composite ceramic slab is divided into green body layer and glazed layer, green body layer is divided into front and bonding plane, front is plane and bonding plane is reeded male and fomale(M&F), the specification of green body layer is at least 900mm × 1800mm, thickness is 5.5mm, glazed layer is divided into glaze paint bottom, patterned layer and glaze paint surface layer, glaze paint bottom uniform fold is in the front of green body layer, patterned layer optionally covers above glaze paint bottom according to patterning, glaze paint surface layer covers patterned layer and glaze paint substratum, the bonding plane of flat ceramic layer is bonded in the platen surface of aluminium alloy layer；Recipe is the Recipe of composite ceramic slab, and formula includes green body layer formula, glaze paint bottom formula and glaze paint surface layer formula；Dry-pressing formed pressure in technological process is 240MPa, and baking temperature is 120 DEG C～286 DEG C, and arid cycle is 62min, and firing temperature is upper temperature 1196 DEG C, lower temperature 1193 DEG C, and firing period is 73min。
2. the composite plate of a kind of aluminium alloy according to claim 1 and ceramic wafer and Recipe; it is characterized in that: described green body layer formula includes Longhai City's Anhydrite 15.2% by weight percentage; Yongan albite 13.63%; water is sand 13.12% first; east of a river washing soil 12.11%; Changtai washing soil 10.1%, big level ground Herba Epigeneii fargesii 10.09%, Zhangping land waste 7.07%; Longhai City's dirt 7.07%; bauxite 6.05%, bentonite 3%, attapulgite 1.0%; sodium humate 0.55%; sodium silicate 0.55%, lignin 0.45%, methylcellulose 0.01%。
3. the composite plate of a kind of aluminium alloy according to claim 1 and ceramic wafer and Recipe, is characterized in that: the formula of described glaze paint bottom includes quartz 44%, Longyan albite 13% by weight percentage, planetesimal Kaolin 9.8%, calcined kaolin 6.6%, Zirconium orthosilicate. 5.98%, calcite 5.28%, silicon pyroxene 5.27%, lucky polo soil 4.97%, Pulvis Talci 2.64%, zinc oxide 2%, sodium tripolyphosphate 0.4%, methylcellulose 0.06%。
4. the composite plate of a kind of aluminium alloy according to claim 1 and ceramic wafer and Recipe, it is characterized in that: the formula of described glaze paint surface layer includes Silicon stone 30.1% by weight percentage, white frit 19.38%, calcined kaolin 16.7%, Longyan albite 13.5%, burns Talcum 8.7%, lucky polo soil 8.6%, aluminium oxide 2.5%, sodium tripolyphosphate 0.46%, methylcellulose 0.06%。
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107650241A (en) * 2017-09-20 2018-02-02 宁波伏尔肯陶瓷科技有限公司 A kind of preparation method of bulletproof ceramic plate
CN111214890A (en) * 2018-11-23 2020-06-02 深圳市优美环境治理有限公司 Sea sand desalting and draining device and silt separation device

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CN2036530U (en) * 1988-08-30 1989-04-26 佛山市石湾东平陶瓷厂 Antiskid colour enamelled brick
WO2011032292A1 (en) * 2009-09-16 2011-03-24 9228-6327 Quebec Inc. Panel installation kit with cardboard substrate
US20110129640A1 (en) * 2009-11-30 2011-06-02 George Halsey Beall Method and binder for porous articles
CN203271016U (en) * 2013-04-25 2013-11-06 江苏丰顺新材料科技有限公司 Aluminum cellular board with ceramic face
CN203569855U (en) * 2013-11-25 2014-04-30 广东蒙娜丽莎新型材料集团有限公司 Architectural ceramic sheet honeycomb ground system
CN203833839U (en) * 2014-05-15 2014-09-17 新嘉理（江苏）陶瓷有限公司 Earthenware slab with concave-convex glaze

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2036530U (en) * 1988-08-30 1989-04-26 佛山市石湾东平陶瓷厂 Antiskid colour enamelled brick
WO2011032292A1 (en) * 2009-09-16 2011-03-24 9228-6327 Quebec Inc. Panel installation kit with cardboard substrate
US20110129640A1 (en) * 2009-11-30 2011-06-02 George Halsey Beall Method and binder for porous articles
CN203271016U (en) * 2013-04-25 2013-11-06 江苏丰顺新材料科技有限公司 Aluminum cellular board with ceramic face
CN203569855U (en) * 2013-11-25 2014-04-30 广东蒙娜丽莎新型材料集团有限公司 Architectural ceramic sheet honeycomb ground system
CN203833839U (en) * 2014-05-15 2014-09-17 新嘉理（江苏）陶瓷有限公司 Earthenware slab with concave-convex glaze

Cited By (3)

* Cited by examiner, † Cited by third party
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CN107650241A (en) * 2017-09-20 2018-02-02 宁波伏尔肯陶瓷科技有限公司 A kind of preparation method of bulletproof ceramic plate
CN111214890A (en) * 2018-11-23 2020-06-02 深圳市优美环境治理有限公司 Sea sand desalting and draining device and silt separation device
CN111214890B (en) * 2018-11-23 2021-12-31 深圳市优美环境治理有限公司 Sea sand desalting and draining device and silt separation device

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