CN105670063A - 一种矿用橡胶绝缘电缆绝缘层制配方法 - Google Patents

一种矿用橡胶绝缘电缆绝缘层制配方法 Download PDF

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CN105670063A
CN105670063A CN201610065620.2A CN201610065620A CN105670063A CN 105670063 A CN105670063 A CN 105670063A CN 201610065620 A CN201610065620 A CN 201610065620A CN 105670063 A CN105670063 A CN 105670063A
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parts
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mine
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范先义
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Anhui Huafeng Cable Group Co Ltd
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Anhui Huafeng Cable Group Co Ltd
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    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene
    • H—ELECTRICITY
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    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
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    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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Abstract

本发明公开了一种矿用橡胶绝缘电缆绝缘层制配方法，它由以下原料组成：按分量计取，弹性体20-30份、相容剂22-36份、抗氧剂10-20份、醋酸乙烯共聚物12-28份、天然橡胶STR20？30-36份、丁苯橡胶33-50份、导电炭黑10.6-12.8份、改性陶土9-26.9份、有机膨润土25-33份、硬脂酸2.8-3.9份、石蜡20-23份、氧化锌15-30份、阻燃剂30-42份、增塑剂22-36份、补强剂30-50份、偶联剂9-20份、硫化剂30-32份、硫化促进剂20-25份、防老剂30-33份增塑剂60-80份、填充补强剂50-63份。本发明加工方便、本发明成本较低，提高了电缆绝缘材料耐压、抗开裂及耐火性能、屏蔽性能优异，使用寿命长。

Description

一种矿用橡胶绝缘电缆绝缘层制配方法
技术领域
本发明涉及一种矿用橡胶绝缘电缆绝缘层制配方法。
背景技术
一般而言，导体屏蔽主体材料主要采用含有氯元素的氯丁橡胶或氯化聚乙烯，这种橡胶分子结构中含有氯元素，当电缆燃烧或导体工作温度过高时，会产生对导体及绝缘有损害的HCl气体腐蚀导体及绝缘材料，对电缆的安全运行和寿命带来极大的影响。
鉴于以上现有技术中存在的缺陷，有必要将其进一步改进，使其更具备实用性，才能符合实际使用情况。
发明内容
为了克服上述现有技术的缺陷，本发明的目的是提供一种矿用橡胶绝缘电缆绝缘层制配方法。
发明是采取以下技术方案来实现的：一种矿用橡胶绝缘电缆绝缘层制配方法，它由以下原料组成：按分量计取，弹性体20-30份、相容剂22-36份、抗氧剂10-20份、醋酸乙烯共聚物12-28份、天然橡胶STR2030-36份、丁苯橡胶33-50份、导电炭黑10.6-12.8份、改性陶土9-26.9份、有机膨润土25-33份、硬脂酸2.8-3.9份、石蜡20-23份、氧化锌15-30份、阻燃剂30-42份、增塑剂22-36份、补强剂30-50份、偶联剂9-20份、硫化剂30-32份、硫化促进剂20-25份、防老剂30-33份增塑剂60-80份、填充补强剂50-63份。
具体地，本发明它由以下原料组成：按分量计取，弹性体25份、相容剂28份、抗氧剂18份、醋酸乙烯共聚物14份、天然橡胶STR2036份、丁苯橡胶40份、导电炭黑11份、改性陶土15份、有机膨润土30份、硬脂酸3.1份、石蜡21份、氧化锌18份、阻燃剂32份、增塑剂23份、补强剂36份、偶联剂18份、硫化剂31份、硫化促进剂22份、防老剂31份增塑剂70份、填充补强剂55份。
本发明的有益效果：本发明通过对配方调整，对电缆料有一定的补强作用，可提高电缆料的定伸应力、硬度、强度和耐磨性。本发明生产出来的导电屏蔽料不仅具有优良的机械物理性能、剥离力、导电性能，而且同时还具有良好的耐高低温性、耐腐蚀性、耐水性、耐磨性、耐臭氧、耐老化等优点，经久耐用，完全能够满足高压矿用橡套软电缆的要求。
具体实施方式
为使本发明现的技术手段、创作特征、达成目的与功效易于明白了解，下面结合具体实施方式，进一步阐述本发明。
本发明是采取以下技术方案来实现的：一种矿用橡胶绝缘电缆绝缘层制配方法，它由以下原料组成：按分量计取，弹性体20-30份、相容剂22-36份、抗氧剂10-20份、醋酸乙烯共聚物12-28份、天然橡胶STR2030-36份、丁苯橡胶33-50份、导电炭黑10.6-12.8份、改性陶土9-26.9份、有机膨润土25-33份、硬脂酸2.8-3.9份、石蜡20-23份、氧化锌15-30份、阻燃剂30-42份、增塑剂22-36份、补强剂30-50份、偶联剂9-20份、硫化剂30-32份、硫化促进剂20-25份、防老剂30-33份增塑剂60-80份、填充补强剂50-63份。
作为本发明的优选方案，本发明它由以下原料组成：按分量计取，弹性体25份、相容剂28份、抗氧剂18份、醋酸乙烯共聚物14份、天然橡胶STR2036份、丁苯橡胶40份、导电炭黑11份、改性陶土15份、有机膨润土30份、硬脂酸3.1份、石蜡21份、氧化锌18份、阻燃剂32份、增塑剂23份、补强剂36份、偶联剂18份、硫化剂31份、硫化促进剂22份、防老剂31份增塑剂70份、填充补强剂55份。
尽管上文对本发明的具体实施方式给予了详细描述和说明，但是应该指明的是，我们可以依据本发明的构想对上述实施方式进行各种等效改变和修改，其所产生的功能作用仍未超出说明书所涵盖的精神时，均应在本发明的保护范围之内。

Claims (2)

1.一种矿用橡胶绝缘电缆绝缘层制配方法，其特征在于，它由以下原料组成：按分量计取，弹性体20-30份、相容剂22-36份、抗氧剂10-20份、醋酸乙烯共聚物12-28份、天然橡胶STR2030-36份、丁苯橡胶33-50份、导电炭黑10.6-12.8份、改性陶土9-26.9份、有机膨润土25-33份、硬脂酸2.8-3.9份、石蜡20-23份、氧化锌15-30份、阻燃剂30-42份、增塑剂22-36份、补强剂30-50份、偶联剂9-20份、硫化剂30-32份、硫化促进剂20-25份、防老剂30-33份增塑剂60-80份、填充补强剂50-63份。
2.根据权利要求1所述的一种矿用橡胶绝缘电缆绝缘层制配方法，其特征在于，它由以下原料组成：按分量计取，弹性体25份、相容剂28份、抗氧剂18份、醋酸乙烯共聚物14份、天然橡胶STR2036份、丁苯橡胶40份、导电炭黑11份、改性陶土15份、有机膨润土30份、硬脂酸3.1份、石蜡21份、氧化锌18份、阻燃剂32份、增塑剂23份、补强剂36份、偶联剂18份、硫化剂31份、硫化促进剂22份、防老剂31份增塑剂70份、填充补强剂55份。
CN201610065620.2A 2016-02-01 2016-02-01 一种矿用橡胶绝缘电缆绝缘层制配方法 Pending CN105670063A (zh)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832475A (zh) * 2016-12-30 2017-06-13 安徽德源电缆集团有限公司 一种防腐蚀电线电缆绝缘层配料
CN115058061A (zh) * 2022-05-19 2022-09-16 青岛昂记橡塑科技有限公司 一种提高橡胶耐老化性能的橡胶添加剂及制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010021761A1 (en) * 1999-03-11 2001-09-13 Petty Herbert B. Silicone oligomers with heigher alkoxy groups
CN101928434A (zh) * 2010-07-30 2010-12-29 江苏巨业电缆有限公司 一种低烟无卤阻燃轨道车辆用多芯控制电缆护套橡胶
CN102977420A (zh) * 2012-11-19 2013-03-20 中特华星电缆股份有限公司 矿用橡套电缆用导体屏蔽料及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010021761A1 (en) * 1999-03-11 2001-09-13 Petty Herbert B. Silicone oligomers with heigher alkoxy groups
CN101928434A (zh) * 2010-07-30 2010-12-29 江苏巨业电缆有限公司 一种低烟无卤阻燃轨道车辆用多芯控制电缆护套橡胶
CN102977420A (zh) * 2012-11-19 2013-03-20 中特华星电缆股份有限公司 矿用橡套电缆用导体屏蔽料及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832475A (zh) * 2016-12-30 2017-06-13 安徽德源电缆集团有限公司 一种防腐蚀电线电缆绝缘层配料
CN115058061A (zh) * 2022-05-19 2022-09-16 青岛昂记橡塑科技有限公司 一种提高橡胶耐老化性能的橡胶添加剂及制备方法和应用
CN115058061B (zh) * 2022-05-19 2024-02-09 青岛昂记橡塑科技有限公司 一种提高橡胶耐老化性能的橡胶添加剂及制备方法和应用

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Application publication date: 20160615