CN105670063A - Preparation method of insulating layer of rubber insulated cable for mine - Google Patents

Preparation method of insulating layer of rubber insulated cable for mine Download PDF

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Publication number
CN105670063A
CN105670063A CN201610065620.2A CN201610065620A CN105670063A CN 105670063 A CN105670063 A CN 105670063A CN 201610065620 A CN201610065620 A CN 201610065620A CN 105670063 A CN105670063 A CN 105670063A
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CN
China
Prior art keywords
parts
agent
plasticizer
rubber
mine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610065620.2A
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Chinese (zh)
Inventor
范先义
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Huafeng Cable Group Co Ltd
Original Assignee
Anhui Huafeng Cable Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Huafeng Cable Group Co Ltd filed Critical Anhui Huafeng Cable Group Co Ltd
Priority to CN201610065620.2A priority Critical patent/CN105670063A/en
Publication of CN105670063A publication Critical patent/CN105670063A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/08Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a preparation method of an insulating layer of a rubber insulated cable for mine. The insulating layer is prepared from raw materials in parts as follows: 20-30 parts of elastomers, 22-36 parts of a compatilizer, 10-20 parts of an antioxidant, 12-28 parts of a vinyl acetate copolymer, 30-36 parts of natural rubber STR20, 33-50 parts of butadiene styrene rubber, 10.6-12.8 parts of conductive carbon black, 9-26.9 parts of modified pottery clay, 25-33 parts of organic bentonite, 2.8-3.9 parts of stearic acid, 20-23 parts of paraffin, 15-30 parts of zinc oxide, 30-42 parts of a flame retardant, 22-36 parts of a plasticizer, 30-50 parts of a reinforcing agent, 9-20 parts of a coupling agent, 30-32 parts of a vulcanizing agent, 20-25 parts of a vulcanization accelerator, 30-33 parts of an anti-ageing agent, 60-80 parts of a plasticizer and 50-63 parts of a filling reinforcing agent. By means of the preparation method, processing is facilitated, the cost is lower, the voltage resistance, the cracking resistance and the fire resistance of an insulating material of the cable are improved, the shielding performance is excellent, and the service life is long.

Description

A kind of mine rubber insulated cable insulating barrier compounding method
Technical field
The present invention relates to a kind of mine rubber insulated cable insulating barrier compounding method.
Background technology
Generally speaking, conductor shielding material of main part mainly adopts the neoprene containing chlorine element or chlorinated polyethylene, containing chlorine element in this rubber molecule structure, when cable fire or conductor operating temperature are too high, producing conductor and insulate prejudicial HCl gas attack conductor and insulant, safe operation and life-span to cable bring strong influence.
In view of the defect existed in above prior art, it is necessary to it is improved further so that it is more for practicality, just can meet actually used situation.
Summary of the invention
In order to overcome the defect of above-mentioned prior art, it is an object of the invention to provide a kind of mine rubber insulated cable insulating barrier compounding method.
Invention takes techniques below scheme to realize: a kind of mine rubber insulated cable insulating barrier compounding method, it is made up of following raw material: take by component, elastomer 20-30 part, compatilizer 22-36 part, antioxidant 10-20 part, acetate ethylene copolymer 12-28 part, natural rubber STR2030-36 part, butadiene-styrene rubber 33-50 part, conductive black 10.6-12.8 part, modified potter's clay 9-26.9 part, organobentonite 25-33 part, stearic acid 2.8-3.9 part, paraffin 20-23 part, zinc oxide 15-30 part, fire retardant 30-42 part, plasticizer 22-36 part, reinforcing agent 30-50 part, coupling agent 9-20 part, vulcanizing agent 30-32 part, vulcanization accelerator 20-25 part, age resistor 30-33 part plasticizer 60-80 part, packing strengthening agent 50-63 part.
Specifically, the present invention it be made up of following raw material: take by component, 25 parts of elastomer, compatilizer 28 parts, 18 parts of antioxidant, acetate ethylene copolymer 14 parts, natural rubber STR2036 part, 40 parts of butadiene-styrene rubber, conductive black 11 parts, modified 15 parts of potter's clay, organobentonite 30 parts, stearic acid 3.1 parts, 21 parts of paraffin, zinc oxide 18 parts, fire retardant 32 parts, plasticizer 23 parts, reinforcing agent 36 parts, coupling agent 18 parts, vulcanizing agent 31 parts, vulcanization accelerator 22 parts, 31 parts of plasticizers of age resistor 70 parts, packing strengthening agent 55 parts.
Beneficial effects of the present invention: the present invention by formula adjustment, having certain strengthening action, can improve the stress at definite elongation of CABLE MATERIALS, hardness, intensity and wearability to CABLE MATERIALS.The conductive shield material that the present invention produces not only has excellent mechanical and physical performance, peeling force, electric conductivity, and also there is good resistant of high or low temperature, corrosion resistance, resistance to water, wearability, resistance to ozone, the advantage such as ageing-resistant simultaneously, durable in use, it is fully able to the requirement meeting high pressure rubber sheathed flexible cable for mine.
Detailed description of the invention
For making existing technological means, the creation characteristic of the present invention, reach purpose and effect is easy to understand, below in conjunction with detailed description of the invention, the present invention is expanded on further.
The present invention takes techniques below scheme to realize: a kind of mine rubber insulated cable insulating barrier compounding method, it is made up of following raw material: take by component, elastomer 20-30 part, compatilizer 22-36 part, antioxidant 10-20 part, acetate ethylene copolymer 12-28 part, natural rubber STR2030-36 part, butadiene-styrene rubber 33-50 part, conductive black 10.6-12.8 part, modified potter's clay 9-26.9 part, organobentonite 25-33 part, stearic acid 2.8-3.9 part, paraffin 20-23 part, zinc oxide 15-30 part, fire retardant 30-42 part, plasticizer 22-36 part, reinforcing agent 30-50 part, coupling agent 9-20 part, vulcanizing agent 30-32 part, vulcanization accelerator 20-25 part, age resistor 30-33 part plasticizer 60-80 part, packing strengthening agent 50-63 part.
Preferred version as the present invention, the present invention it be made up of following raw material: take by component, 25 parts of elastomer, compatilizer 28 parts, 18 parts of antioxidant, acetate ethylene copolymer 14 parts, natural rubber STR2036 part, 40 parts of butadiene-styrene rubber, conductive black 11 parts, modified 15 parts of potter's clay, organobentonite 30 parts, stearic acid 3.1 parts, 21 parts of paraffin, zinc oxide 18 parts, fire retardant 32 parts, plasticizer 23 parts, reinforcing agent 36 parts, coupling agent 18 parts, vulcanizing agent 31 parts, vulcanization accelerator 22 parts, 31 parts of plasticizers of age resistor 70 parts, packing strengthening agent 55 parts.
Although above the specific embodiment of the present invention being given detailed description and explanation; but it should be noted that; above-mentioned embodiment can be carried out various equivalence according to the conception of the present invention and change and amendment by us; function produced by it still without departing from description contain spiritual time, all should within protection scope of the present invention.

Claims (2)

1. a mine rubber insulated cable insulating barrier compounding method, it is characterized in that, it is made up of following raw material: take by component, elastomer 20-30 part, compatilizer 22-36 part, antioxidant 10-20 part, acetate ethylene copolymer 12-28 part, natural rubber STR2030-36 part, butadiene-styrene rubber 33-50 part, conductive black 10.6-12.8 part, modified potter's clay 9-26.9 part, organobentonite 25-33 part, stearic acid 2.8-3.9 part, paraffin 20-23 part, zinc oxide 15-30 part, fire retardant 30-42 part, plasticizer 22-36 part, reinforcing agent 30-50 part, coupling agent 9-20 part, vulcanizing agent 30-32 part, vulcanization accelerator 20-25 part, age resistor 30-33 part plasticizer 60-80 part, packing strengthening agent 50-63 part.
2. a kind of mine rubber insulated cable insulating barrier compounding method according to claim 1, it is characterized in that, it is made up of following raw material: take by component, 25 parts of elastomer, compatilizer 28 parts, 18 parts of antioxidant, acetate ethylene copolymer 14 parts, natural rubber STR2036 part, 40 parts of butadiene-styrene rubber, conductive black 11 parts, modified 15 parts of potter's clay, organobentonite 30 parts, stearic acid 3.1 parts, 21 parts of paraffin, zinc oxide 18 parts, fire retardant 32 parts, plasticizer 23 parts, reinforcing agent 36 parts, coupling agent 18 parts, vulcanizing agent 31 parts, vulcanization accelerator 22 parts, 31 parts of plasticizers of age resistor 70 parts, packing strengthening agent 55 parts.
CN201610065620.2A 2016-02-01 2016-02-01 Preparation method of insulating layer of rubber insulated cable for mine Pending CN105670063A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610065620.2A CN105670063A (en) 2016-02-01 2016-02-01 Preparation method of insulating layer of rubber insulated cable for mine

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610065620.2A CN105670063A (en) 2016-02-01 2016-02-01 Preparation method of insulating layer of rubber insulated cable for mine

Publications (1)

Publication Number Publication Date
CN105670063A true CN105670063A (en) 2016-06-15

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CN201610065620.2A Pending CN105670063A (en) 2016-02-01 2016-02-01 Preparation method of insulating layer of rubber insulated cable for mine

Country Status (1)

Country Link
CN (1) CN105670063A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832475A (en) * 2016-12-30 2017-06-13 安徽德源电缆集团有限公司 A kind of anti-corrosion electric wire cable insulation dispensing
CN115058061A (en) * 2022-05-19 2022-09-16 青岛昂记橡塑科技有限公司 Rubber additive for improving aging resistance of rubber, and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010021761A1 (en) * 1999-03-11 2001-09-13 Petty Herbert B. Silicone oligomers with heigher alkoxy groups
CN101928434A (en) * 2010-07-30 2010-12-29 江苏巨业电缆有限公司 Low-smoke, zero-halogen and flame-retardant multi-core controlled cable sheath rubber for railway vehicles
CN102977420A (en) * 2012-11-19 2013-03-20 中特华星电缆股份有限公司 Conductor shield material of mine cabtyre cable and preparation method of conductor shield material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010021761A1 (en) * 1999-03-11 2001-09-13 Petty Herbert B. Silicone oligomers with heigher alkoxy groups
CN101928434A (en) * 2010-07-30 2010-12-29 江苏巨业电缆有限公司 Low-smoke, zero-halogen and flame-retardant multi-core controlled cable sheath rubber for railway vehicles
CN102977420A (en) * 2012-11-19 2013-03-20 中特华星电缆股份有限公司 Conductor shield material of mine cabtyre cable and preparation method of conductor shield material

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832475A (en) * 2016-12-30 2017-06-13 安徽德源电缆集团有限公司 A kind of anti-corrosion electric wire cable insulation dispensing
CN115058061A (en) * 2022-05-19 2022-09-16 青岛昂记橡塑科技有限公司 Rubber additive for improving aging resistance of rubber, and preparation method and application thereof
CN115058061B (en) * 2022-05-19 2024-02-09 青岛昂记橡塑科技有限公司 Rubber additive for improving ageing resistance of rubber, preparation method and application

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Application publication date: 20160615