CN105658741B - water-based printing ink composition - Google Patents
water-based printing ink composition Download PDFInfo
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- CN105658741B CN105658741B CN201580002302.5A CN201580002302A CN105658741B CN 105658741 B CN105658741 B CN 105658741B CN 201580002302 A CN201580002302 A CN 201580002302A CN 105658741 B CN105658741 B CN 105658741B
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- ink composition
- printing ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of water-based printing ink composition, it is used ethylene acrylic acid co polymer as adhesive, just make the favorable dispersibility of pigment without using dispersants such as the strong surfactants of hydrophily, and will not cause immiscible between the raw materials such as gelation.The water-based printing ink composition of the present invention is characterized in that, contains pigment and using α-methylstyrene monomer and the alcohol for containing carbon number 14~18 and the ester compounds of α, β unsaturated carboxylic acid as copolymer obtained by the monomer class copolymerization of required component.
Description
Technical field
The present invention relates to a kind of with the resistance to chemical reagents such as high alkali resistance and excellent water-based of printing adaptability, operability
Print ink composition.
Background technology
In the past, towards food, daily necessities packaging in the intaglio plate of used flexible packing material, flexographic printing, from
From the aspect of printing adaptability, flowed based on solvent-borne type black liquid.However, in recent years from the viewpoint of earth environment is saved from damage,
In flexible packing material market, since the air discharge of the solvent vapour from solvent-borne type black liquid can cause environmental pressure to increase, because
This is gradually considered as problem.Therefore, for the purpose of significantly cutting down solvent usage amount, the Water-borne modification of black liquid is being promoted.
On the other hand, in the packaging towards health products such as detergent, soap, these product compositions etc. can scheme with printing
Case contacts, and is considered the water soluble acrylic acid that water dispersible is better and is used as adhesive for printing black liquid etc. before this
It is that lotion does not have alkali resistance, the problem of damaging printed pattern dissolved can be produced.Therefore, it is proposed to employ can obtain it is resistance to
The water-based printing black liquid of the ethylene-acrylic copolymer of the good film of medicine manufacture method (such as patent document 1 and
2) black liquid of special surfactant (acetylenediol class), is coordinated with specific ratio in identical resin component and pigment
Composition (such as patent document 3).However, black liquid is made in the operation for disperseing pigment, using ink composition in addition
Operation in, can also it is different with the species of pigment and because produced immiscible between raw material gelation, solid part precipitation,
Floating etc..In addition, in the case where being disperseed pigment using surfactant, to the profit of the low polar plas film base material such as polyethylene
Moist variation, the printing such as become easily to cause printed article concentration to reduce are bad etc., there is performance of the infringement as printing black liquid
The problem of.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Application 60-181178
Patent document 2：Japanese Unexamined Patent Publication 7-41719
Patent document 3：Japanese Unexamined Patent Publication 2011-144335
The content of the invention
Problems to be solved by the invention
Thus, it is an object of the present invention to provide a kind of water-based printing ink composition, it is by ethylene-acrylic acid copolymer
Thing is used as adhesive, and the favorable dispersibility of pigment is just made without using dispersants such as the strong surfactants of hydrophily, and
It will not produce immiscible between the raw materials such as gelation.
The method used for solving the problem
The present inventor conducts in-depth research to solve the problem, it turns out that, containing pigment and by α-
Methyl styrene monomer and the water-based printing ink for having used copolymer obtained by the monomer class copolymerization of specific esters of unsaturated carboxylic acids
The dispersion stabilization of liquid composition is good, so as to complete invention.
That is, the present invention provides a kind of water-based printing ink composition, it is characterised in that containing pigment and by Alpha-Methyl benzene
Vinyl monomer and contain the alcohol of carbon number 14~18 and α, beta-unsaturated carboxylic acid ester compounds as must component monomer
Copolymer obtained by class copolymerization.
In addition, the present invention provides a kind of water-based printing ink composition, wherein, the α-methylstyrenemonomer contains
Rate is 5~25mol% of the copolymer total amount, and the containing ratio of the ester compounds is 5~60mol%.
In addition, the present invention provides a kind of water-based printing ink composition, wherein, the acid number of the copolymer for 60~
200mgKOH/g, weight average molecular weight (Mw) are 10,000~50,000.
In addition, the present invention also provides the water-based printing black liquid for having used the water-based printing ink composition.
Invention effect
The water-based printing ink composition of the present invention it is dispersed excellent, and used the water-based printing ink composition
Water-based printing black liquid stability, the resistance to chemical reagents of black liquid film it is excellent.
Embodiment
The pigment used in the water-based printing ink composition of the present invention it is scattered in acrylic acid series copolymer used be
By α-methylstyrene, with being used as required component using the alcohol of carbon number 14~18 and α, the ester compounds of beta-unsaturated carboxylic acid
Obtained by the copolymerization of polymerizable monomer class.
The water-based printing ink composition of the present invention becomes film formative by using α-methylstyrenemonomer
Well, in addition, immiscible between being not likely to produce the raw materials such as gelation, dispersiveness further improves, and uses the aqueous pigment point
The disposal for the aqueous ink composition that granular media makes improves.
In addition, the water-based printing ink composition of the present invention is with the alcohol of carbon number 14~18 and α, beta-unsaturated carboxylic acid
Ester compounds are as required component.
For the α-methylstyrenemonomer in the copolymer used in the water-based printing ink composition of the present invention
Containing ratio, preferably the containing ratio for copolymer total amount more than 5mol%~below 25mol% scope.For water-based printing
The containing ratio of α-methylstyrenemonomer in ink composition in the copolymer used, if containing ratio is total for copolymer
Below the 5mol% of amount, then be difficult to the resistance to chemical reagents and intensity for obtaining black liquid film, if more than 25mol%, then pigment point
Dissipating property reduces and produces gelation, pigment precipitation etc., and black liquid stability reduces.In addition, by using the α-methylstyrene
Monomer, compared with styrene monomer, further improves the dispersiveness of pigment, has used the stream of the water-based printing black liquid of said composition
Dynamic property is good, and the storage-stable of the aqueous ink made using the aqueous ink composition is improved.
On the other hand, for the ester compounds that are made of the alcohol and α, beta-unsaturated carboxylic acid of the carbon number 14~18
Containing ratio, if more than the 5mol% containing copolymer total amount, from the aspect of pigment-dispersing is improved preferably, if
Below the 60mol% of copolymer total amount, then from the side that the drying property and epithelium intensity of the epithelium formed using the dispersion are kept
Face considers preferred.
As the ester compounds, methacrylic acid tetradecane base ester, methacrylic acid cetyl ester, first can be enumerated
Base octadecyl acrylate etc..
In addition, if the acid number of the copolymer used in the present invention is set to more than 60mgKOH/g, then dissipated from moisture
Property it is good from the aspect of preferably, if set to below 200mgKOH/g, then from the aspect of water resistance is improved preferably.
In addition, the weight average molecular weight (Mw) of the copolymer used in the water-based printing ink composition of the present invention is preferred
For 10,000~50,000 scope.If Mw is less than 10,000, then the physical strength deficiency of black liquid film, if greater than 50,
000, then the viscosity of the copolymer is significantly raised and make the operability drop such as pigment-dispersing and dispersiveness in water, disposal property
It is low.
In addition, as by the copolymer used in the water-based printing ink composition of the present invention and when used wave
The alkaline matter of hair property, can enumerate ammonium hydroxide, triethylamine, diethylamine, mono aminoethane, tri-n-butylamine, dimethylethanolamine, monoethanol
Amine, morpholine, N- methyl formalin (N- メ チ Le ホ Le マ リ Application), 2-amino-2-methyl-1-propanol etc..
In addition, it can be added with Hexyl 2-propenoate, heptylacrylate, propylene in the water-based printing ink composition of the present invention
Misery ester, acrylic acid nonyl ester, decyl acrylate, acrylic acid hendecane base ester, dodecylacrylate, acrylic acid-2-ethyl
Own ester, acrylic acid -2- ethyl esters, hexyl methacrylate, metering system heptyl heptylate, 2-Propenoic acid, 2-methyl-, octyl ester, methacrylic acid nonyl
Ester, decyl-octyl methacrylate, methacrylic acid hendecane base ester, lauryl methacrylate, methacrylic acid -2- ethyls
The unsaturated carboxylic ester compound of the alcohol with carbon number below 13 such as own ester, methacrylic acid -2- ethyl esters, dihydroxypropyl second
Ester, the monomer that hydroxyethyl methacrylate is representative.
In addition, as needed can will be with polyester resin, polyurethane resin, chlorinated polypropylene, Styrene And Chloroalkyl Acrylates
Be resin, styrene-maleic acid system resin for representative polymer be added to the present invention water-based printing ink composition in.
In the water-based printing ink composition of the present invention, colouring agent, solvent, corresponding with other purposes can also use
Auxiliary agent.
As the colouring agent, inorganic pigment used in general water-based printing ink composition can be used, had
Machine pigment, filler pigment etc..
As the solvent, water can be used alone or using water and the organic solvent mixed with water.As organic solvent,
Such as there are the polyalcohols such as the alcohols such as methanol, ethanol, isopropanol, normal propyl alcohol or propane diols, glycerine, propylene glycol monomethyl ether, third
Ethers such as 2-ethoxyethanol, propane diols list positive propyl ether, ethyl carbitol etc..
In addition, as other auxiliary components, the alkane for assigning rub resistance, lubricity etc. can also be suitably used
The fatty acid acyl such as wax class or oleamide, stearmide, the erucyl amide amines such as hydrocarbon system wax, polyethylene-based wax, Brazil wax and
The silicon systems of foaming, non-silicon systems defoamer during for suppressing to print and improve various dispersants of wetability of pigment etc..
The present invention water-based printing ink composition be using intaglio plate, flexographic printing black liquid manufacture in generally use
Eiger Mill (mono- ミ Le of ア イ ガ), sand mixer, Gamma Mill (ガ Application マ ミ Le), pulverizer (ア ト ラ イ タ mono-) etc. come
Manufacture.
Moreover, the water-based printing ink composition of the present invention can print the general used printing side of black liquid by oiliness
Formula, i.e. intaglio printing, flexographic printing etc. and be printed in plastic foil, polyethylene coating paper etc..
Using the viscosity (Cai's grace cup No.3) of black liquid obtained from the water-based printing ink composition of the present invention usually recessed
It is 13~25 seconds in version printing purposes, is 22~30 seconds in flexographic printing purposes, but consider various printings
Adaptability and generally 10~23 seconds, are preferably 14~20 seconds.
Embodiment
Hereinafter, the present invention is specifically described using embodiment, comparative example.It should be noted that in embodiment
" part " " % " is exactly weight basis as long as no particularly pointing out.
Production Example 1
Into the reaction vessel for possessing mixer, reflux cooler, temperature control equipment and nitrogen ingress pipe, input
900 parts of 900 parts of isopropanol and ethanol, are warming up to 80 DEG C of temperature under the atmosphere of nitrogen.With 4 it is small when be added dropwise thereto comprising α-
100 parts of methyl styrene, 400 parts of methacrylic acid cetyl ester (C16), 155 parts of methyl methacrylate, ethyl acrylate
150 parts, 195 parts of methacrylic acid, 2, the mixture of 100 parts of 40 parts of 2 '-azo two (2- methylbutyronitriles) and isopropanol.
After completion of dropwise addition, continue to stir at the same temperature, after reaction when progress 15 is small, cool to 60 DEG C, add bag
Mixture containing 100 parts of 40 parts of dimethylethanolamine and water, is stirred until homogeneous.Then, 900 parts of ion exchange water is added, uniformly
After ground is stirred, using vacuum distillation, the major part of removing isopropanol and ethanol.Dimethanolamine is added, until the aqueous solution
PH be 8.0, obtain volatile ingredient be 42%, acid number 130mgKOH/g, weight average molecular weight 39,000, polymer proportion be
0.929 water-base resin.
Production Example 2
Using the step identical with Production Example 1, with 4 it is small when be added dropwise comprising 100 parts of α-methylstyrene, methacrylic acid ten
200 parts of six Arrcostabs (C16), 200 parts of methacrylic acid tetradecane base ester (C14), 155 parts of methyl methacrylate, acrylic acid
150 parts of ethyl ester, 195 parts of methacrylic acid, 2,40 parts of 2 '-azo two (2- methylbutyronitriles), the mixture of 100 parts of isopropanol.
After completion of dropwise addition, also continue to stir at the same temperature, reaction when progress 15 is small, then cools to 60 DEG C, add
Enter the mixture comprising 100 parts of 40 parts of dimethylethanolamine and water, be stirred until homogeneous.Then, 900 parts of ion exchange water is added,
After being equably stirred, using vacuum distillation, the major part of removing isopropanol and ethanol.Dimethanolamine is added to the aqueous solution
PH be 8.0, and be stirred until homogeneous, obtain nonvolatile component be 45%, acid number 120mgKOH/g, weight average molecular weight 37,
000th, polymer proportion is 0.928 water-base resin.
Production Example 3
Using the step identical with Production Example 1, with 4 it is small when be added dropwise comprising 100 parts of α-methylstyrene, methacrylic acid ten
400 parts of eight Arrcostabs (C18), 155 parts of methyl methacrylate, 150 parts of ethyl acrylate, 195 parts of methacrylic acid, 2,2 '-
40 parts of azo two (2- methylbutyronitriles), the mixture of 100 parts of isopropanol.
After completion of dropwise addition, also continue to stir at the same temperature, reaction when progress 15 is small, then cools to 60 DEG C, add
Enter the mixture comprising 100 parts of 40 parts of dimethylethanolamine and water, be stirred until homogeneous.Then, 900 parts of ion exchange water is added,
After being equably stirred, using vacuum distillation, the major part of removing isopropanol and ethanol.Dimethanolamine is added to the aqueous solution
PH be 8.0, and be stirred until homogeneous, obtain nonvolatile component be 42%, acid number 125mgKOH/g, weight average molecular weight 42,
000th, polymer proportion is 0.931 water-base resin.
Production Example 4
Using the step identical with Production Example 1, with 4 it is small when be added dropwise comprising 100 parts of styrene, methacrylic acid cetyl
400 parts of ester (C16), 155 parts of methyl methacrylate, 150 parts of ethyl acrylate, 195 parts of methacrylic acid, 2,2 '-azo two
40 parts of (2- methylbutyronitriles), the mixture of 100 parts of isopropanol.
After completion of dropwise addition, also continue to stir at the same temperature, reaction when progress 15 is small, then cools to 60 DEG C, add
Enter the mixture comprising 100 parts of 40 parts of dimethylethanolamine and water, be stirred until homogeneous.Then, 900 parts of ion exchange water is added,
After being equably stirred, using vacuum distillation, the major part of removing isopropanol and ethanol.Dimethanolamine is added to the aqueous solution
PH be 8.0, and be stirred until homogeneous, obtain nonvolatile component be 44%, acid number 115mgKOH/g, weight average molecular weight 39,
000th, polymer proportion is 0.930 water-base resin.
Production Example 5
Using the step identical with Production Example 1, with 4 it is small when be added dropwise comprising 100 parts of α-methylstyrene, methacrylic acid ten
400 parts of dialkyl ester (C12), 155 parts of methyl methacrylate, 150 parts of ethyl acrylate, 195 parts of methacrylic acid, 2,2 '-
40 parts of azo two (2- methylbutyronitriles), the mixture of 100 parts of isopropanol.
After completion of dropwise addition, also continue to stir at the same temperature, reaction when progress 15 is small, then cools to 60 DEG C, add
Enter the mixture comprising 100 parts of 40 parts of dimethylethanolamine and water, be stirred until homogeneous.Then, 900 parts of ion exchange water is added,
After being equably stirred, using vacuum distillation, the major part of removing isopropanol and ethanol.Dimethanolamine is added to the aqueous solution
PH be 8.0, and be stirred until homogeneous, obtain nonvolatile component be 43%, acid number 120mgKOH/g, weight average molecular weight 36,
000th, polymer proportion is 0.926 water-base resin.
Embodiment 1
By 20 parts of manufactured water-base resin, 40 parts of blue pigment FASTOGEN BLUE LDB 30, isopropyl in Production Example 1
36 parts of 4 parts of alcohol, water cooperations, after being fully stirred, are kneaded with sand mixer and obtain millbase (A).To the millbase
(A) 70 parts of ザ イ Network セ Application-L, 3.8 parts of Tissuemat E, 0.2 part of silicon systems defoamer are added in 26 parts, adds aqueous diluent
Adjust to viscosity and be calculated as 16 seconds with Cai's grace cup No.3, obtained aqueous ink.
Embodiment 2
Hereinafter, cooperation same as Example 1 and step similarly are utilized to 20 parts of manufactured water-base resin in Production Example 2
It is rapid to carry out viscosity adjustment, obtain aqueous ink.
Embodiment 3
Hereinafter, cooperation same as Example 1 and step similarly are utilized to 20 parts of manufactured water-base resin in Production Example 3
It is rapid to carry out viscosity adjustment, obtain aqueous ink.
Comparative example 1
Hereinafter, similarly 20 parts of manufactured water-base resin in Production Example 4 is tasted using cooperation same as Example 1
The adjustment of aqueous ink has been tried, but there occurs gelation, black liquid can not be prepared.
Comparative example 2
Hereinafter, similarly 20 parts of manufactured water-base resin in Production Example 5 is tasted using cooperation same as Example 1
The adjustment of aqueous ink has been tried, but there occurs gelation, black liquid can not be prepared.
Claims (4)
1. a kind of intaglio printing use or flexographic printing water-based printing ink composition, it is characterised in that
Containing pigment and by α-methylstyrenemonomer and the alcohol containing carbon number 14~18 and α, the ester of beta-unsaturated carboxylic acid
Compound is as copolymer obtained by the monomer class copolymerization of required component.
2. intaglio printing use according to claim 1 or flexographic printing water-based printing ink composition, wherein,
The containing ratio of α-methylstyrenemonomer is 5~25mol% of copolymer total amount, and the containing ratio of ester compounds is copolymer
5~60mol% of total amount.
3. intaglio printing use according to claim 1 or 2 or flexographic printing water-based printing ink composition, wherein,
The acid number of the copolymer is 60~200mgKOH/g, and weight average molecular weight is expressed as 10,000~50,000 with Mw.
4. a kind of water-based printing black liquid, it uses intaglio printing use according to any one of claims 1 to 3 or flexographic printing
With water-based printing ink composition.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2014-114806 | 2014-06-03 | ||
| JP2014114806 | 2014-06-03 | ||
| JP2014-120515 | 2014-06-11 | ||
| JP2014120515 | 2014-06-11 | ||
| PCT/JP2015/065038 WO2015186561A1 (en) | 2014-06-03 | 2015-05-26 | Aqueous printing ink composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105658741A CN105658741A (en) | 2016-06-08 |
| CN105658741B true CN105658741B (en) | 2018-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580002302.5A Active CN105658741B (en) | 2014-06-03 | 2015-05-26 | water-based printing ink composition |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP5846467B1 (en) |
| CN (1) | CN105658741B (en) |
| WO (1) | WO2015186561A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6870412B2 (en) * | 2017-03-22 | 2021-05-12 | 東洋インキＳｃホールディングス株式会社 | Aqueous flexo ink composition for paper containers |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1435455A (en) * | 2002-01-30 | 2003-08-13 | 罗姆和哈斯公司 | Ink composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3933491B2 (en) * | 2002-02-15 | 2007-06-20 | サカタインクス株式会社 | Aqueous pigment type ink jet ink composition |
| JP3909434B2 (en) * | 2002-07-04 | 2007-04-25 | サカタインクス株式会社 | Aqueous pigment type ink jet ink composition |
| WO2009119472A1 (en) * | 2008-03-28 | 2009-10-01 | Dic株式会社 | Lithographic printing ink |
| JP5746587B2 (en) * | 2011-08-09 | 2015-07-08 | サカタインクス株式会社 | Water based gravure printing ink composition for paper containers |
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2015
- 2015-05-26 CN CN201580002302.5A patent/CN105658741B/en active Active
- 2015-05-26 JP JP2015542498A patent/JP5846467B1/en active Active
- 2015-05-26 WO PCT/JP2015/065038 patent/WO2015186561A1/en active Application Filing
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1435455A (en) * | 2002-01-30 | 2003-08-13 | 罗姆和哈斯公司 | Ink composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2015186561A1 (en) | 2017-04-20 |
| WO2015186561A1 (en) | 2015-12-10 |
| CN105658741A (en) | 2016-06-08 |
| JP5846467B1 (en) | 2016-01-20 |
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