CN105624747B - 一种铜/石墨烯复合多层散热膜 - Google Patents
一种铜/石墨烯复合多层散热膜 Download PDFInfo
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- CN105624747B CN105624747B CN201511022980.6A CN201511022980A CN105624747B CN 105624747 B CN105624747 B CN 105624747B CN 201511022980 A CN201511022980 A CN 201511022980A CN 105624747 B CN105624747 B CN 105624747B
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- graphene
- copper
- heat dissipation
- graphene oxide
- metallic matrix
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 147
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 139
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 50
- 239000010949 copper Substances 0.000 title claims abstract description 50
- 230000017525 heat dissipation Effects 0.000 title claims abstract description 30
- 239000002131 composite material Substances 0.000 title claims abstract description 24
- 239000011159 matrix material Substances 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 23
- 238000002360 preparation method Methods 0.000 claims abstract description 12
- 229910052751 metal Inorganic materials 0.000 claims description 28
- 239000002184 metal Substances 0.000 claims description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 150000001336 alkenes Chemical class 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 10
- 229910021641 deionized water Inorganic materials 0.000 claims description 10
- 229910002804 graphite Inorganic materials 0.000 claims description 10
- 239000010439 graphite Substances 0.000 claims description 10
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 10
- 230000033228 biological regulation Effects 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 5
- 230000000694 effects Effects 0.000 claims description 5
- 238000001962 electrophoresis Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000001509 sodium citrate Substances 0.000 claims description 5
- 235000010344 sodium nitrate Nutrition 0.000 claims description 5
- 239000004317 sodium nitrate Substances 0.000 claims description 5
- 239000000758 substrate Substances 0.000 claims description 5
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 5
- 229940038773 trisodium citrate Drugs 0.000 claims description 5
- 230000005611 electricity Effects 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 229910001431 copper ion Inorganic materials 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 230000002000 scavenging effect Effects 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- -1 Graphite alkene Chemical class 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 230000010148 water-pollination Effects 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 description 22
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000002245 particle Substances 0.000 description 3
- 239000007853 buffer solution Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000007770 graphite material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 241000416536 Euproctis pseudoconspersa Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/38—Electroplating: Baths therefor from solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/2039—Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (7)
Priority Applications (1)
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CN201511022980.6A CN105624747B (zh) | 2015-12-29 | 2015-12-29 | 一种铜/石墨烯复合多层散热膜 |
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CN201511022980.6A CN105624747B (zh) | 2015-12-29 | 2015-12-29 | 一种铜/石墨烯复合多层散热膜 |
Publications (2)
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CN105624747A CN105624747A (zh) | 2016-06-01 |
CN105624747B true CN105624747B (zh) | 2017-10-13 |
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CN201511022980.6A Expired - Fee Related CN105624747B (zh) | 2015-12-29 | 2015-12-29 | 一种铜/石墨烯复合多层散热膜 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2562805A (en) * | 2017-05-26 | 2018-11-28 | Graphitene Ltd | Heat spreader and method of manufacture thereof |
Families Citing this family (14)
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---|---|---|---|---|
CN108866412B (zh) * | 2017-05-08 | 2020-09-29 | 清华大学 | 三维多孔复合材料的制备方法 |
CN107579201B (zh) * | 2017-09-14 | 2023-07-18 | 珠海格力电器股份有限公司 | 一种多层体及其制备方法 |
CN107815720B (zh) * | 2017-09-15 | 2020-04-17 | 广东工业大学 | 一种自支撑还原氧化石墨烯涂层及其制备方法和应用 |
CN107739869B (zh) * | 2017-11-09 | 2019-09-13 | 天津工业大学 | 纳米多孔铜复合材料及其制备方法 |
CN109161941B (zh) * | 2018-08-09 | 2020-09-11 | 浙江工业大学 | 一种烧结钕铁硼磁体铜复合石墨烯镀层打底以提高耐蚀性的方法及产品 |
CN109748267B (zh) * | 2019-02-21 | 2021-05-14 | 苏州市安派精密电子有限公司 | 一种基于多道清洗的石墨烯散热部件制备方法 |
CN111481994A (zh) * | 2020-04-14 | 2020-08-04 | 广州康滤净化科技有限公司 | 通过铜网镀铜协同生长石墨烯制备的过滤膜及其制备方法 |
CN111690963B (zh) * | 2020-06-24 | 2022-10-04 | 上海理工大学 | 一种制备高导热性能的铜/石墨/铜叠层复合材料的方法 |
CN112064077B (zh) * | 2020-09-21 | 2021-05-14 | 江西理工大学 | 一种铜箔/碳纳米管/铜箔复合箔的制备方法 |
CN112490204B (zh) * | 2020-11-26 | 2024-04-02 | 西安交通大学 | 一种基于石墨烯的三明治结构散热薄膜、半导体器件及其制备方法 |
CN113873750A (zh) * | 2021-08-31 | 2021-12-31 | 华为技术有限公司 | 复合铜箔结构、其制备方法及覆铜箔层压板和印刷电路板 |
CN113622007A (zh) * | 2021-09-08 | 2021-11-09 | 苏州市安派精密电子有限公司 | 一种高柔韧性石墨材质或石墨烯材质散热部件制备方法 |
CN114686944B (zh) * | 2022-04-08 | 2024-01-26 | 北京科技大学 | 一种降低无氧铜二次电子产额的表面处理方法 |
CN114951610A (zh) * | 2022-05-13 | 2022-08-30 | 中车工业研究院有限公司 | 精确浇铸和化学气相沉积相结合的石墨烯/铜复合材料及制备方法 |
Citations (5)
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CN102061504A (zh) * | 2009-11-13 | 2011-05-18 | 中国科学院兰州化学物理研究所 | 一种含有石墨烯复合薄膜材料的合成方法 |
CN102548353A (zh) * | 2010-12-31 | 2012-07-04 | 上海杰远环保科技有限公司 | 一种叠积型膜散热结构及其实现方法 |
CN102555324A (zh) * | 2010-12-31 | 2012-07-11 | 上海杰远环保科技有限公司 | 高散热膜型金属复合材料及其制造方法 |
KR20140003218A (ko) * | 2012-06-29 | 2014-01-09 | 세종대학교산학협력단 | 그래핀의 적층 방법, 그래핀 적층체, 및 이를 포함하는 소자 |
CN103625029A (zh) * | 2013-11-25 | 2014-03-12 | 许子寒 | 一种石墨烯导热器件 |
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2015
- 2015-12-29 CN CN201511022980.6A patent/CN105624747B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102061504A (zh) * | 2009-11-13 | 2011-05-18 | 中国科学院兰州化学物理研究所 | 一种含有石墨烯复合薄膜材料的合成方法 |
CN102548353A (zh) * | 2010-12-31 | 2012-07-04 | 上海杰远环保科技有限公司 | 一种叠积型膜散热结构及其实现方法 |
CN102555324A (zh) * | 2010-12-31 | 2012-07-11 | 上海杰远环保科技有限公司 | 高散热膜型金属复合材料及其制造方法 |
KR20140003218A (ko) * | 2012-06-29 | 2014-01-09 | 세종대학교산학협력단 | 그래핀의 적층 방법, 그래핀 적층체, 및 이를 포함하는 소자 |
CN103625029A (zh) * | 2013-11-25 | 2014-03-12 | 许子寒 | 一种石墨烯导热器件 |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2562805A (en) * | 2017-05-26 | 2018-11-28 | Graphitene Ltd | Heat spreader and method of manufacture thereof |
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