CN105593351A - 费托衍生的气油 - Google Patents

费托衍生的气油 Download PDF

Info

Publication number
CN105593351A
CN105593351A CN201480053592.1A CN201480053592A CN105593351A CN 105593351 A CN105593351 A CN 105593351A CN 201480053592 A CN201480053592 A CN 201480053592A CN 105593351 A CN105593351 A CN 105593351A
Authority
CN
China
Prior art keywords
fischer
oil
tropsch derived
derived gas
boiling point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201480053592.1A
Other languages
English (en)
Inventor
R·J·维斯玛
J·图夫博尔
R·雷梅斯玛
J·B·W·莫辛克
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CN105593351A publication Critical patent/CN105593351A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1616—Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/308—Gravity, density, e.g. API
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2200/00—Components of fuel compositions
    • C10L2200/04—Organic compounds
    • C10L2200/0461—Fractions defined by their origin
    • C10L2200/0469—Renewables or materials of biological origin
    • C10L2200/0492—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/08—Specifically adapted fuels for small applications, such as tools, lamp oil, welding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/42—Fischer-Tropsch steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/543—Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17—Fisher Tropsch reaction products
    • C10M2205/173—Fisher Tropsch reaction products used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/011—Cloud point
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/015—Distillation range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/017—Specific gravity or density
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/069—Linear chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/071—Branched chain compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/255—Gasoline engines
    • C10N2040/26—Two-strokes or two-cycle engines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Lubricants (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

本发明提供了初沸点为至少165℃且终沸点为最高360℃的费托衍生的气油。在另一方面，本发明提供了包含初沸点为至少165℃且终沸点为最高360℃的费托衍生的气油的功能流体制品。

Description

费托衍生的气油
本发明涉及费托(Fischer-Tropsch)衍生的气油，以及包含其的功能流体制品。
可通过各种方法获得费托衍生的气油。使用所谓的费托法获得费托衍生的气油。这样的方法的实例公开在WO02/070628中。
现在令人惊讶地发现，特定的费托衍生的气油可有利地用于溶剂和功能流体应用中。
为了此目的，本发明提供了初沸点为至少165℃且终沸点为最高360℃的费托气油。
本发明的优点在于费托衍生的气油具有令人惊讶的低粘度、低倾点同时具有高闪点，这些性质的组合在要求低粘度的溶剂和功能流体应用中提供了优点。
典型地，根据本发明的费托衍生的气油具有非常低水平的芳族化合物、环烷烃和杂质。
使用费托衍生的气油因此在溶剂和/或功能流体应用中改善了可生物降解性以及提供了较低的毒性。
根据本发明的费托衍生的气油源自费托法。费托衍生的气油在现有技术中是已知的。术语“费托衍生的”表示气油是或来源于费托法的合成产物。在费托法中，合成气转化成合成产物。合成气体或合成气是通过含烃原料转化而获得的氢气和一氧化碳的混合物。合适的原料包括天然气、原油、重油馏分、煤、生物质和木质素。费托衍生的气油也可以称作GTL(气制液(Gas-to-Liquids))气油。
费托衍生的气油主要是异链烷烃。优选地，费托衍生的气油包含超过75重量％、优选超过80重量％的异链烷烃。
根据本发明，费托衍生的气油在大气条件下具有至少165℃的初沸点和最高360℃的终沸点。合适地，费托衍生的气油在大气条件下具有至少170℃的初沸点。进一步地，费托衍生的气油优选在大气条件下具有至少175℃的初沸点。
费托衍生的气油在大气条件下优选具有333-351℃、更优选336-348℃、且最优选339-345℃的终沸点。
大气条件下的沸点表示大气沸点，该沸点通过ASTMD86测定。
优选地，费托气油的T10体积％沸点为198-220℃、更优选202-216℃、最优选205-213℃，且T90体积％沸点为319-333℃、优选321-331℃且更优选323-328℃。T10体积％是对应于其中产物的10体积％的累积量被回收的大气沸点的温度。类似地，T90体积％是对应于其中产物的90体积％的累积量被回收的大气沸点的温度。可使用大气蒸馏法ASTMD86来确定回收水平，或者气相色谱法例如ASTMD2887，其已被校正来传递类似的结果。
费托衍生的气油优选地包含具有9-25个碳原子的链烷烃；费托衍生的链烷烃气油优选包含至少70重量％、更优选至少85重量％、更优选至少90重量％、更优选至少95重量％、且最优选至少98重量％的具有9-25个碳原子的费托衍生的链烷烃，其基于费托衍生的链烷烃的总量，优选地基于具有7-30个碳原子的费托衍生的链烷烃的量。
进一步地，费托衍生的气油优选地具有根据ASTMD4052、在15℃下，从774kg/m3至779kg/m3、更优选从775kg/m3至778kg/m3、且最优选从776kg/m3至777kg/m3的密度。
合适地，根据ASTMD445的在40℃下的运动粘度为2.3-2.8cSt、优选2.4-2.7cSt、且更优选2.5-2.6cSt。
进一步地，费托衍生的气油的倾点(根据ASTMD97)优选低于-10℃、更优选低于-15℃、更优选低于-20℃、更优选低于-22℃、更优选低于-25℃、和最优选低于-36℃以及优选最多高于-40℃。
合适地，费托衍生的气油的浊点(根据ASTMD2500)优选低于-10℃、更优选低于-15℃、更优选低于-17℃、更优选低于-20℃、最优选低于-22℃、更优选低于-25℃、最优选低于-36℃以及优选最多高于-40℃。
优选地，费托衍生的气油具有根据ASTMD93的至少68℃、更优选至少70℃且最优选至少72℃的闪点。
典型地，费托衍生的气油根据ASTMD93的闪点低于85℃、优选低于75℃。
费托衍生的气油具有根据ASTMD1322的超过50mm的发烟点。
典型地，根据本发明的费托气油包含小于500ppm芳族化合物、优选小于200ppm的芳族化合物、小于3ppm的硫、优选小于1ppm的硫、更优选小于0.2ppm的硫、小于1ppm的氮且小于2重量％的环烷烃。
进一步地，费托衍生的气油优选包含小于0.1重量％的多环芳烃、优选小于25ppm的多环芳烃且更优选小于1ppm的多环芳烃。
异链烷烃的量合适地超过75重量％，优选超过80重量％，基于具有9-25个碳原子的链烷烃的总量。
进一步地，费托衍生的气油可包含正链烷烃和环烷烃。
具有至少165℃的初沸点且最高360℃的终沸点的费托衍生的气油的制备已描述在例如WO02/070628中。
在进一步的方面，本发明提供了功能流体制品，其包含根据本发明的费托衍生的气油，进一步包含添加剂化合物。典型地，功能流体制品可用于许多领域，例如油气开发和生产、建筑业、食品和相关行业、纸、织物和皮革以及各种家用和消费产品。此外，用于根据本发明的功能流体制品中的添加剂的种类取决于流体制品的类型。用于功能流体制品的添加剂包括但不限于腐蚀和流变控制产品、乳化剂和湿润剂、钻孔稳定剂、高压和抗磨损添加剂、消泡沫剂和抗泡沫剂、倾点下降剂和抗氧化剂。
在功能流体制品中使用费托衍生的气油的优点在于费托衍生的气油具有低粘度和低倾点同时具有高闪点。
典型地，费托衍生的气油的这些物理特征的这种组合对于其用于功能流体制品是高度期望的。
在另一方面，本发明提供了根据本发明的费托衍生的气油作为用于溶剂和/或功能流体应用的稀释油或基础油的用途。
术语稀释油的意思是用于降低溶剂和功能流体制品的粘度和/或改善其其它性质的油。
术语基础油的意思是向其中添加其它油、溶剂或物质以产生溶剂或功能流体制品的油。
使用费托衍生的气油作为用于溶剂和/或功能流体制品的稀释油或基础油的优点与如上对于包含根据本发明的费托衍生的气油、还包含添加剂化合物的功能流体制品所述的相同。
使用根据本发明的费托衍生的气油作为稀释油或基础油的优选的溶剂和/或功能流体应用包括但不限于钻探流体、加热燃料、灯油、烧烤点火机、混凝土脱模、杀虫剂喷雾油、水处理、清洁剂、抛光剂、车脱蜡剂、放电加工、变压器油、硅氧烷胶粘剂、二冲程发动机循环油、金属清洁、干洗、润滑剂、金属工作流体、铝辊油、***、氯化链烷烃、热定型印刷油墨、木料处理、聚合物加工油、防锈油、减震器、温室燃料、压裂流体、燃料添加剂制品。
通常的溶剂和功能流体应用例如描述在“TheIndexofSolvents”，MichaelAsh,IreneAsh,GowerpublishingLtd,1996,ISBN0-566-07884-8和“HandbookofSolvents”,GeorgeWypych,WillemAndrewpublishing,2001,ISBN0-8155-1458-1中。在进一步的方面，本发明提供了根据本发明的费托衍生的气油用于在溶剂和/或功能流体应用中改善可生物降解性以及降低毒性的用途。
如上所述，费托衍生的气油优选地具有非常低水平的芳族化合物、硫、氮化合物并优选不具有多环芳烃。这些低水平可导致、但不限于所述费托衍生的气油的低的水生生物毒性、低的沉积物有机体毒性和低的陆生生物毒性。根据本发明的费托衍生的气油的分子结构可导致费托衍生的气油容易生物降解。
本发明参考下面的实施例描述如下，所述实施例不旨在以任何方式限制本发明的范围。
实施例
实施例1
具有至少165℃的初沸点和最高360℃的终沸点的费托衍生的气油的制备
费托产物以类似于WO-A-9934917的实施例III所述的方法，使用WO-A-9934917的实施例III的催化剂进行制备。由此获得的产物的C5+馏分(在环境条件下为液体)被连续进料到加氢裂化步骤(步骤(a))。C5+馏分包含约60重量％的C30+产物。C60+/C30+的比率为约0.55。在加氢裂化步骤中，馏分与EP-A-532118的实施例1的加氢裂化催化剂接触。步骤(a)的流出物在真空下连续蒸馏以得到轻产物、燃料和残余物“R”，其沸点为370℃和更高。沸点高于370℃的产物转化为沸点低于370℃的产物为45-55重量％。将残余物“R”再循环至步骤(a)。加氢裂化步骤(a)的条件为：新鲜进料重时空速(WHSV)为0.8kg/l.h、再循环进料WHSV为0.4kg/l.h、氢气速率＝1000Nl/kg、总压＝40巴、反应器温度在330-340℃范围内。
获得的燃料馏分(C5+，370℃)在塔顶区段中在50-70毫巴的压力和125-145℃的温度下连续蒸馏，以得到作为塔底产物的气油馏分。
表1和2中给出物理性质，以及表3中给出气油的环境性质。
表1
表2
表3
DT50＝消失时间50，其是其中测试物质的浓度降低50％的时间。消失时间包括物理和生物流失二者。
EL50＝用于制备在给定时间内引起对暴露物质的50％的不利效应的WAF的负荷率。
NOEL＝没有观察到有效水平——用于制备在暴露的有机体中没有发现不利效应的WAF(水溶性组分)的最低负荷率。
EC50＝在给定时间内导致对暴露物质的50％的不利效应的浓度。
NOEC＝没有观察到有效浓度——在暴露的有机体中没有发现不利效应的最低测试浓度。
实施例2
使用费托衍生的气油作为用于溶剂和/或功能流体应用的稀释油/基础油。
表1-3中给出的费托衍生的气油的性质是费托衍生的气油在以下应用中有利地使用的关键性质：钻探流体、加热燃料、灯油、烧烤点火机、混凝土脱模、杀虫剂喷雾油、水处理、清洁剂、抛光剂、车脱蜡剂、放电加工、变压器油、硅氧烷胶粘剂、二冲程发动机循环油、金属清洁、干洗、润滑剂、金属工作流体、铝辊油、***、氯化链烷烃、热定型印刷油墨、木料处理、聚合物加工油、防锈油、减震器、温室燃料、压裂流体、以及燃料添加剂制品。
使用具有表1-3中给出的性质的费托衍生的气油的实验在灯油、加热流体、BBQ流体和放电加工以及变压器油应用中进行。结果在表4中给出。
*ShellSolD70TM和ShellSolD100TM获自ShellChemicals。
讨论
表1和2中的结果表明获得了具有低倾点、低粘度和高闪点的费托衍生的气油。而且，表3表明费托衍生的气油易于生物降解，且具有低的水生毒性、低的沉积物有机体毒性和低的陆生生物毒性。
费托衍生的气油的化学性质、物理性质和生态毒性表明使用费托衍生的气油提供了在溶剂和功能流体应用中的优点。表4的结果实际上表明，与原油衍生的气油用于灯油、加热流体、BBQ流体、和放电加工以及变压器油应用相比，费托衍生的气油(参见表4：根据本发明的费托衍生的气油的较高的发烟点和较高的电击穿事件)有利地用于这些应用中。

Claims (12)

1.具有至少165℃的初沸点和最高360℃的终沸点的费托衍生的气油。
2.根据权利要求1所述的费托衍生的气油，其具有至少170℃的初沸点。
3.根据权利要求1或2所述的费托衍生的气油，其具有333-351℃、优选336-348℃和更优选339-345℃的终沸点。
4.根据权利要求1至3任一项所述的费托衍生的气油，其具有198-220℃、优选202-216℃、更优选205-213℃的10体积％沸点，和319-333℃、优选321-331℃、更优选323-328℃的T90体积％沸点。
5.根据权利要求1至4任一项所述的费托衍生的气油，其具有根据ASTMD4052的在15℃下774-779kg/m3、优选775-778kg/m3、更优选776-777kg/m3的密度。
6.根据权利要求1至5任一项所述的费托衍生的气油，其具有根据ASTMD445的在40℃下2.3-2.8cSt、优选2.4-2.7cSt、且更优选2.5-2.6cSt的运动粘度。
7.根据权利要求1至6任一项所述的费托衍生的气油，其具有根据ASTMD97的低于-10℃、优选低于-15℃、更优选低于-20℃、更优选低于-22℃、更优选低于-25℃、和最优选低于-36℃以及优选最多高于-40℃的倾点。
8.根据权利要求1至7任一项所述的费托衍生的气油，其具有根据ASTMD93的至少68℃、优选至少70℃、更优选至少72℃的闪点。
9.根据权利要求1至8任一项所述的费托衍生的气油，其中所述费托衍生的气油具有根据ASTMD1322的超过50mm的发烟点。
10.包含根据权利要求1-9任一项所述的费托衍生的气油的功能流体，其进一步包含添加剂化合物。
11.根据前述权利要求1-10的一项或多项所限定的费托衍生的气油作为用于溶剂和/或功能流体制品的稀释油或基础油的用途。
12.根据前述权利要求1-11的一项或多项所限定的费托衍生的气油用于在溶剂和/或功能流体应用中改善可生物降解性以及降低毒性的用途。
CN201480053592.1A 2013-09-30 2014-09-25 费托衍生的气油 Pending CN105593351A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13186732.7 2013-09-30
EP13186732 2013-09-30
PCT/EP2014/070508 WO2015044278A1 (en) 2013-09-30 2014-09-25 Fischer-tropsch derived gas oil

Publications (1)

Publication Number Publication Date
CN105593351A true CN105593351A (zh) 2016-05-18

Family

ID=49237146

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201480053592.1A Pending CN105593351A (zh) 2013-09-30 2014-09-25 费托衍生的气油

Country Status (7)

Country Link
US (1) US20160215225A1 (zh)
EP (1) EP3052589A1 (zh)
JP (1) JP2016535117A (zh)
KR (1) KR20160064219A (zh)
CN (1) CN105593351A (zh)
BR (1) BR112016006773A2 (zh)
WO (1) WO2015044278A1 (zh)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1207118A (zh) * 1995-12-08 1999-02-03 埃克森研究工程公司 可生物降解的高性能烃类基础油
CN1500133A (zh) * 2001-03-05 2004-05-26 ���ʿ����о����޹�˾ 制备润滑基础油和粗柴油的方法
CN1692152A (zh) * 2001-03-05 2005-11-02 国际壳牌研究有限公司 中间馏分油的制备方法
EP1835011A1 (en) * 1998-10-05 2007-09-19 Sasol Technology (Pty) Ltd Biodegradable middle distillates and production thereof
CN101400768A (zh) * 2006-03-10 2009-04-01 新日本石油株式会社 烃油的制造方法以及烃油
CN101415807A (zh) * 2006-03-31 2009-04-22 新日本石油株式会社 多功能性烃油组合物

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4565834B2 (ja) * 2003-12-19 2010-10-20 昭和シェル石油株式会社 灯油組成物
EP2006365B1 (en) * 2006-03-31 2018-02-21 Nippon Oil Corporation Use of a polyfunctional hydrocarbon oil composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1207118A (zh) * 1995-12-08 1999-02-03 埃克森研究工程公司 可生物降解的高性能烃类基础油
EP1835011A1 (en) * 1998-10-05 2007-09-19 Sasol Technology (Pty) Ltd Biodegradable middle distillates and production thereof
CN1500133A (zh) * 2001-03-05 2004-05-26 ���ʿ����о����޹�˾ 制备润滑基础油和粗柴油的方法
CN1692152A (zh) * 2001-03-05 2005-11-02 国际壳牌研究有限公司 中间馏分油的制备方法
CN101400768A (zh) * 2006-03-10 2009-04-01 新日本石油株式会社 烃油的制造方法以及烃油
CN101415807A (zh) * 2006-03-31 2009-04-22 新日本石油株式会社 多功能性烃油组合物

Also Published As

Publication number Publication date
US20160215225A1 (en) 2016-07-28
BR112016006773A2 (pt) 2017-08-01
JP2016535117A (ja) 2016-11-10
WO2015044278A1 (en) 2015-04-02
KR20160064219A (ko) 2016-06-07
EP3052589A1 (en) 2016-08-10

Similar Documents

Publication Publication Date Title
CN105579561A (zh) 费托衍生的气油馏分
CN105593350A (zh) 费托衍生的气油馏分
CN105593351A (zh) 费托衍生的气油
CN105593352A (zh) 费托衍生的气油馏分
CN106459771A (zh) 费‑托气油馏分
CN105579559A (zh) 费托衍生的气油馏分
CN105579560A (zh) 费托衍生的气油馏分
CN105579562A (zh) 费托衍生的气油馏分
KR20170010770A (ko) 피셔-트롭쉬 가스유 분획물
WO2015181124A1 (en) Fischer-tropsch gasoil fraction
WO2015181131A1 (en) Fischer-tropsch gasoil fraction
WO2015181120A1 (en) Fischer-tropsch gasoil fraction
WO2015044290A1 (en) Fischer-tropsch derived gas oil fraction

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20160518

WD01 Invention patent application deemed withdrawn after publication