CN105585935B - A kind of solvent-free high solid marine antifouling coating - Google Patents
A kind of solvent-free high solid marine antifouling coating Download PDFInfo
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- CN105585935B CN105585935B CN201510395089.0A CN201510395089A CN105585935B CN 105585935 B CN105585935 B CN 105585935B CN 201510395089 A CN201510395089 A CN 201510395089A CN 105585935 B CN105585935 B CN 105585935B
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- solvent
- high solid
- free high
- antifouling coating
- ocean
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- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 23
- 239000011248 coating agent Substances 0.000 title claims abstract description 21
- 238000000576 coating method Methods 0.000 title claims abstract description 21
- 239000007787 solid Substances 0.000 title claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 44
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 39
- 239000003822 epoxy resin Substances 0.000 claims abstract description 23
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 23
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 23
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 23
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 23
- 239000011787 zinc oxide Substances 0.000 claims abstract description 22
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 19
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229940112669 cuprous oxide Drugs 0.000 claims abstract description 19
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims abstract description 17
- 238000003860 storage Methods 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000003973 paint Substances 0.000 claims description 19
- 150000001261 hydroxy acids Chemical class 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 238000004806 packaging method and process Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000001993 wax Substances 0.000 claims description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 238000012644 addition polymerization Methods 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- -1 Ether amines Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 241000238586 Cirripedia Species 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 231100000572 poisoning Toxicity 0.000 abstract description 3
- 230000000607 poisoning effect Effects 0.000 abstract description 3
- 239000002904 solvent Substances 0.000 abstract description 3
- 239000002519 antifouling agent Substances 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 3
- 238000009533 lab test Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 241000251557 Ascidiacea Species 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 235000009508 confectionery Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 241001269238 Data Species 0.000 description 1
- 241000243251 Hydra Species 0.000 description 1
- 241001541122 Linguatula serrata Species 0.000 description 1
- 241000237536 Mytilus edulis Species 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000013056 hazardous product Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- QRXWMOHMRWLFEY-UHFFFAOYSA-N isoniazide Chemical compound NNC(=O)C1=CC=NC=C1 QRXWMOHMRWLFEY-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000020638 mussel Nutrition 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 230000003248 secreting effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
A kind of solvent-free high solid marine antifouling coating, it is characterized in that：It is made up of epoxy resin, cuprous oxide, sodium benzoate, glycidol ether, zinc oxide, Tissuemat E and polyetheramine, the weight ratio of each component is 40 60：25‑35：2.5‑10：2.5‑5：5‑10：3‑6：20‑30.Manufacturing cost is low; without solvent; period of storage is grown, and good stability, is volatilized using VOC free; it is water-fast, wear-resisting, smooth hard; the biology for making ocean is difficult to be attached to hull surface, and have prevents the marine organisms such as barnacle to be stained hull bottom for a long time, keeps hull bottom bright and clean; also to marine organisms without poisoning, the environment of ocean is protected.
Description
Technical field
The present invention relates to a kind of antifouling paint, more particularly to a kind of solvent-free high solid marine antifouling coating.
Background technology
In marine environment, after object immerses seawater, its surface occur first it is miniature be stained, i.e., bacterium etc. is miniature
Biological attachment is growing, bred on body surface thereon；Then, the spore of macro and oceanic invertebrate be such as
Barnacle, mussel and the young of ascidian are attached on body surface, and the process is referred to as large-scale be stained.It is large-scale to be stained and be further
Be divided into soft be stained to be stained with hardness, it is soft be stained refer to algae, careless tongue worm, ascidian, hydra etc. biology caused by be stained, firmly
Property be stained and refer to biological being stained as caused by barnacle and extra large oyster etc. for secreting calcium carbonate shell.These marine fouling organisms adhere to
On hull facility surface, ship resistance, blocking pipeline and cultivation netting gear, influence acoustic instrument and other seas can be increased and set
Standby normal use, the burden of increase offshore oil and natural gas extraction platform, accelerate metal erosion etc. to seriously endanger, cause sea
The massive losses of foreign military activity, sea transport, industry and aquaculture production.
So far, solve that marine biofouling is most economical, effective and conventional method is in marine equipment surface brushing
Coating containing marine antifoulant, its main function are by the key component in coating --- marine antifoulant oozes out, spread
Or the mode such as hydrolysis progressively discharges anti-fouling agent, reaches the mesh for preventing marine fouling organism to be attached to marine Artificial facilities surface
's.Current marine antifoulant species largely contains heavy metal, has stronger toxicity, Marine Pollution ecological environment, and spot ship
Antifouling paint prepares the shortcomings of cost high, big to environmental hazard, antifouling persistence difference.
The content of the invention
For overcome the deficiencies in the prior art, the present invention provides a kind of new anti-fouling agent, and without solvent, period of storage is grown, surely
It is qualitative good, volatilized using VOC free, water-fast, wear-resisting, smooth hard, the biology for making ocean is difficult to be attached to hull surface, has length
Phase prevents the marine organisms such as barnacle to be stained hull bottom, keeps hull bottom bright and clean, also protects ocean without poisoning to marine organisms
Environment.
The technical scheme of the present invention solved the problems, such as is a kind of solvent-free high solid marine antifouling coating, it is characterized in that：Mainly
It is made up of epoxy resin, cuprous oxide, sodium benzoate, glycidol ether, zinc oxide, Tissuemat E and polyetheramine, each component
Weight ratio is 25-60：5-35：2.5-10：2.5-5：5-10：3-6：5-30.
Wherein the unsaturated polynary hydroxy acid polymer of addition, iron oxide red its weight ratio are 0.6-2：5-10, form solvent-free
High solid ocean ship bottom antifouling paint.
Wherein the unsaturated polynary hydroxy acid polymer of addition, titanium dioxide its weight ratio are 0.6-2：5-20, form solvent-free height
Solid ocean shell antifouling paint.
Wherein the unsaturated polynary hydroxy acid polymer of addition, titanium dioxide, mica powder its weight ratio are 0.6-2：5-20：10-25,
Form solvent-free high solid marine steel erection and apply antifouling paint.
Its preparation method：
(1) technological process：
As shown in Figure 1.
(2) specific preparation method：
By epoxy resin, by dissolving, addition polymerization ethylene waxes, glycidol ether, high speed are disperseed again first, and it is sub- to add oxidation
Copper, zinc oxide, sodium benzoate, in the scattered tank diameter of high speed, after high-speed stirred is well mixed the fineness for reaching certain, stop stirring
Mix, seal, paint is stirred after standing 24H, through examining viscosity, fineness to touch the mark, coating, packaging and storage,
Polyetheramine dispenses.
Solvent-free high solid marine antifouling coating, poisonous and hazardous material (such as tributyltin oxide (TBTF) arsenic is not added
Frost etc.) non-stimulated smell to the biological harmless of ocean, because having for paint in itself is water-fast, wear-resisting, smooth hard, makes the biology of ocean
It is difficult to be attached to hull surface, product has prevents the marine organisms such as barnacle from keeping hull bottom bright and clean being stained for hull bottom for a long time, from
And the marine organisms of hull are attached to kill without using poisonous and harmful substance, protect the environment of ocean also Marine Pollution useless.
Hereinafter beneficial effects of the present invention are further illustrated with two groups of experimental datas：
(1) recipe determination is tested：
According to the different qualities of material, 4 kinds of formulas are designed：
It is that index carries out screening experiment with formula 1 (to be formulated 4 best results)
| Formula 1 | Formula 2 | Formula 3 | Formula 4 | |
| Viscosity | 80KU | 80KU | 80KU | 80KU |
| Alkali resistance | 160 hours | 200 hours | 200 hours | 400 hours |
| Salt spray resistance | 500 hours | 600 hours | 600 hours | 800 hours |
| Water resistance | 360 hours | 400 hours | 400 hours | 600 hours |
| Solid content | 99% | 99% | 99% | 99% |
(2) contrast experiment：
Contrast experiment's (present invention has marked improvement) is carried out with following index and prior art
The present invention's has the advantages that manufacturing cost is low, without solvent, period of storage length, good stability, uses nothing
VOC volatilizees, and water-fast, wear-resisting, smooth hard, the biology for making ocean is difficult to be attached to hull surface, and have prevents barnacle etc. for a long time
Marine organisms are stained to hull bottom, keep hull bottom bright and clean, also to marine organisms without poisoning, protect the environment of ocean.
Brief description of the drawings
Fig. 1 is the process chart of the present invention.
Embodiment
Following embodiments are used for the formula and preparation technology for illustrating the present invention, but it can not be to the scope of the present invention structure
Into any restrictions.
Embodiment 1
With epoxy resin：Cuprous oxide：Sodium benzoate：Glycidol ether：Zinc oxide：Tissuemat E：Polyetheramine=40：
35：10：5：10：6：20 proportioning, is weighed respectively：Epoxy resin 40kg, cuprous oxide 35kg, sodium benzoate 10kg, shrink are sweet
Oily ether 5kg, zinc oxide 10kg, Tissuemat E 6kg, polyetheramine 20kg are standby.
By epoxy resin, by dissolving, addition polymerization ethylene waxes, glycidol ether, high speed are disperseed again first, and it is sub- to add oxidation
Copper, zinc oxide, sodium benzoate, in the scattered tank diameter of high speed, after high-speed stirred is well mixed the fineness for reaching certain, stop stirring
Mix, seal, paint is stirred after standing 24H, through examining viscosity, fineness to touch the mark, obtain coating, packaging and storage,
Polyetheramine dispenses
Products obtained therefrom is tested by laboratory, is met the technical requirements：
Embodiment 2
With epoxy resin：Cuprous oxide：Sodium benzoate：Glycidol ether：Zinc oxide：Tissuemat E：Polyetheramine=50：
30：5：3.5：7：5：25 proportioning, is weighed respectively：Epoxy resin 50kg, cuprous oxide 30kg, sodium benzoate 5kg, glycidol
Ether 3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, it is standby.
By epoxy resin, by dissolving, addition polymerization ethylene waxes, glycidol ether, high speed are disperseed again first, and it is sub- to add oxidation
Copper, zinc oxide, sodium benzoate, in the scattered tank diameter of high speed, after high-speed stirred is well mixed the fineness for reaching certain, stop stirring
Mix, seal, paint is stirred after standing 24H, through examining viscosity, fineness to touch the mark, coating, packaging and storage,
Polyetheramine dispenses.
Products obtained therefrom is tested by laboratory, meets technical indicator：
Embodiment 3
With epoxy resin：Cuprous oxide：Sodium benzoate：Glycidol ether：Zinc oxide：Tissuemat E：Polyetheramine=60：
25：2.5：2.5：5：3：30 proportioning, is weighed respectively：Epoxy resin 60kg, cuprous oxide 25kg, sodium benzoate 2.5kg, shrink
Glycerin ether 2.5kg, zinc oxide 5kg, Tissuemat E 3kg, polyetheramine 30kg, it is standby.
By epoxy resin, by dissolving, addition polymerization ethylene waxes, glycidol ether, high speed are disperseed again first, and it is sub- to add oxidation
Copper, zinc oxide, sodium benzoate, in the scattered tank diameter of high speed, after high-speed stirred is well mixed the fineness for reaching certain, stop stirring
Mix, seal, paint is stirred after standing 24H, through examining viscosity, fineness to touch the mark, coating, packaging and storage,
Polyetheramine dispenses
Products obtained therefrom is tested by laboratory, meets technical indicator：
Embodiment 4
With epoxy resin：Unsaturated polynary hydroxy acid polymer：Iron oxide red：Cuprous oxide：Sodium benzoate：Glycidol
Ether：Zinc oxide：Tissuemat E：Polyetheramine=50：2：8：30：5：3.5：7：5：25 proportioning, is weighed respectively：Epoxy resin
50kg, unsaturated polynary hydroxy acid polymer 2kg, iron oxide red 8kg, cuprous oxide 30kg, sodium benzoate 5kg, glycidol ether
3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, it is standby.
Epoxy resin is added into unsaturated polynary hydroxy acid polymer, iron oxide red, Tissuemat E, shrink by dissolving again first
Glycerin ether, it is scattered at a high speed, cuprous oxide, zinc oxide, sodium benzoate are added, in the scattered tank diameter of high speed, high-speed stirred is mixed
After conjunction uniformly reaches certain fineness, stop stirring, seal, paint is stirred after standing 24H, through inspection viscosity, carefully
Degree touches the mark, and obtains coating, packaging and storage, polyetheramine packing.
The new ship bottom antifouling paint laboratory test in the solvent-free high solid ocean of products obtained therefrom, meets the technical requirements：
Embodiment 5
With epoxy resin：Unsaturated polynary hydroxy acid polymer：Titanium dioxide：Cuprous oxide：Sodium benzoate：Glycidol ether：
Zinc oxide：Tissuemat E：Polyetheramine=50：2：15：30：5：3.5：7：5：25 proportioning, is weighed respectively：Epoxy resin 50kg,
Unsaturated polynary hydroxy acid polymer 2kg, titanium dioxide 15kg, cuprous oxide 30kg, sodium benzoate 5kg, glycidol ether 3.5kg,
Zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, it is standby.
Add unsaturated polynary hydroxy acid polymer, titanium dioxide, Tissuemat E, shrink sweet again by dissolving epoxy resin first
Oily ether, it is scattered at a high speed, cuprous oxide, zinc oxide, sodium benzoate are added, in the scattered tank diameter of high speed, high-speed stirred mixing
After uniformly reaching certain fineness, stop stirring, seal, paint is stirred after standing 24H, through examining viscosity, fineness
Touch the mark, obtain coating, packaging and storage, polyetheramine packing
The new ship bottom antifouling paint laboratory test in the solvent-free high solid ocean of products obtained therefrom, meets the technical requirements：
Embodiment 6
With epoxy resin：Unsaturated polynary hydroxy acid polymer：Titanium dioxide：Mica powder：Cuprous oxide：Sodium benzoate, shrink
Glycerin ether：Zinc oxide：Tissuemat E：Polyetheramine=50：2：15：20：30：5：3.5：7：5：25 proportioning, is weighed respectively：Epoxy
Resin 50kg, unsaturated polynary hydroxy acid polymer 2kg, titanium dioxide 15kg, mica powder 20kg, cuprous oxide 30kg, sodium benzoate
5kg, glycidol ether 3.5kg, zinc oxide 7kg, Tissuemat E 5kg, polyetheramine 25kg, it is standby.
Epoxy resin is added into unsaturated polynary hydroxy acid polymer, titanium dioxide, mica powder, polyethylene by dissolving again first
Wax, glycidol ether, it is scattered at a high speed, cuprous oxide, zinc oxide, sodium benzoate are added, in the scattered tank diameter of high speed, at a high speed
After being uniformly mixed the fineness for reaching certain, stop stirring, seal, paint is stirred after standing 24H, it is glutinous through examining
Degree, fineness touch the mark, and obtain coating, packaging and storage, polyetheramine packing
The new ship bottom antifouling paint laboratory test in the solvent-free high solid ocean of products obtained therefrom, meets the technical requirements：
Claims (5)
1. a kind of solvent-free high solid marine antifouling coating, it is characterized in that：By epoxy resin, cuprous oxide, sodium benzoate, shrink
Glycerin ether, zinc oxide, Tissuemat E and polyetheramine composition, the weight ratio of each component is 40-60：25-35：2.5-10：2.5-5：
5-10：3-6： 20-30.
2. the solvent-free high solid marine antifouling coating according to claim 1, it is characterized in that：Wherein addition is unsaturated
Its weight ratio of polynary hydroxy acid polymer, iron oxide red is 0.6-2：5-10, form solvent-free high solid ocean hull-bottom antifouling and apply
Material.
3. the solvent-free high solid marine antifouling coating according to claim 1, it is characterized in that：Wherein addition is unsaturated
Its weight ratio of polynary hydroxy acid polymer, titanium dioxide is 0.6-2：10-20, form solvent-free high solid ocean shell antifouling paint.
4. the solvent-free high solid marine antifouling coating according to claim 1, it is characterized in that：Wherein addition is unsaturated
Its weight ratio of polynary hydroxy acid polymer, titanium dioxide, mica powder is 0.6-2：10-20：15-25, form solvent-free high solid ocean
Steelframe facility antifouling paint.
5. according to the solvent-free high solid marine antifouling coating described in claim 1, it is characterized in that：Its preparation method：
By epoxy resin, by dissolving, addition polymerization ethylene waxes, glycidol ether, high speed are scattered again first；Add cuprous oxide, oxygen
Change zinc, sodium benzoate, in the scattered tank diameter of high speed, after high-speed stirred is well mixed the fineness for reaching certain, stop stirring,
Seal, after standing 24h, be stirred paint, through examining viscosity, fineness to touch the mark, coating, packaging and storage, gather
Ether amines dispense.
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| CN201510395089.0A CN105585935B (en) | 2015-07-07 | 2015-07-07 | A kind of solvent-free high solid marine antifouling coating |
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|---|---|---|---|
| CN201510395089.0A CN105585935B (en) | 2015-07-07 | 2015-07-07 | A kind of solvent-free high solid marine antifouling coating |
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| Publication Number | Publication Date |
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| CN105585935B true CN105585935B (en) | 2017-12-08 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967316A (en) * | 2010-09-08 | 2011-02-09 | 中国乐凯胶片集团公司 | Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint |
| CN103788811A (en) * | 2013-12-11 | 2014-05-14 | 青岛海洋新材料科技有限公司 | Environment-friendly marine antifouling coating |
| CN103805028A (en) * | 2014-02-20 | 2014-05-21 | 中国船舶重工集团公司第七二五研究所 | Preparation method of solvent-free antifouling paint for underwater construction |
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- 2015-07-07 CN CN201510395089.0A patent/CN105585935B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967316A (en) * | 2010-09-08 | 2011-02-09 | 中国乐凯胶片集团公司 | Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint |
| CN103788811A (en) * | 2013-12-11 | 2014-05-14 | 青岛海洋新材料科技有限公司 | Environment-friendly marine antifouling coating |
| CN103805028A (en) * | 2014-02-20 | 2014-05-21 | 中国船舶重工集团公司第七二五研究所 | Preparation method of solvent-free antifouling paint for underwater construction |
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