CN105567005B - A kind of UV driography CD blueness ink and preparation method thereof - Google Patents
A kind of UV driography CD blueness ink and preparation method thereof Download PDFInfo
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- CN105567005B CN105567005B CN201610124737.3A CN201610124737A CN105567005B CN 105567005 B CN105567005 B CN 105567005B CN 201610124737 A CN201610124737 A CN 201610124737A CN 105567005 B CN105567005 B CN 105567005B
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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Abstract
The present invention provides a kind of UV driography CD blueness ink and preparation method thereof.UV driography CD blueness ink of the present invention is mainly prepared by green pigment, prepolymer, monomer, photoinitiator, filler, levelling agent, wetting agent, surfactant and adhesion promoter.UV driography CD blueness ink of the present invention is prepared using specified raw material and dosage, have many advantages, such as that good anti-scumming, rheologic behavio(u)r and ink transfer performance are excellent, it can be used for optical disc surface printing, and without using fountain solution in printing process, high production efficiency, printing quality is good and lower production costs.For the preparation method of the method for the present invention UV driography CD blueness ink by the way of directly mixing pre-dispersed, grinding, simple process is suitable for large-scale production.
Description
Technical field
The present invention relates to ultraviolet lights to solidify (UV) waterless offset ink technical field, anhydrous in particular to a kind of UV
Offset printing CD blueness ink and preparation method thereof.
Background technique
The mode that traditional CD printing technology generallys use silk-screen printing carries out, but due to silk-screen printing technique itself
Defect, cause using silk-screen printing printing CD when print speed printing speed is low, tone reproduction is poor, printing quality is poor.
Driography is a kind of emerging printing technology, is widely applied in CD printing in recent years.It is anhydrous
Offset printing is actually a kind of lithography technique, and difference is it without using the profit in tradition offset printing compared with common offset printing
Version liquid, but the ink for the silicone rubber coating printing plate, special rheological property for using one kind special and a set of stringent temperature control
System processed come complete printing offset lithography technology.Using the CD of driography technology print printing quality with higher and
Color reprodubility, and driography has high production efficiency, printing quality good, lower-cost excellent relative to silk-screen printing
Point.
But the anti-scumming of the waterless offset ink of CD printing at present is poor, rheologic behavio(u)r and ink transfer
It can there is also larger problems.
In view of this, the present invention is specifically proposed.
Summary of the invention
The first object of the present invention is to provide a kind of UV driography CD blueness ink, the UV driography CD
Green ink has many advantages, such as that good anti-scumming, rheologic behavio(u)r and ink transfer performance are excellent, can be used for optical disc surface printing, and
And without using fountain solution in printing process, high production efficiency, printing quality is good and lower production costs.
The second object of the present invention is to provide the preparation method of UV driography CD blueness ink described in one kind, the party
Method simple process is suitable for large-scale production.
In order to realize above-mentioned purpose of the invention, the following technical scheme is adopted:
A kind of UV driography CD blueness ink, the UV driography CD blueness ink is mainly by following mass fraction
Raw material is prepared:
10-16 parts of green pigment, 33-56 parts of prepolymer, 7-18 parts of monomer, 5-8 parts of photoinitiator, 5-16 parts of filler, stream
Flat agent 1.5-2.5 parts, 1-2 parts of wetting agent, 0.01-0.1 parts of surfactant, 1-3 parts of adhesion promoter;
The UV driography CD blueness ink is preferably mainly prepared by the raw material of following mass fraction:
12-14 parts of green pigment, 45-55 parts of prepolymer, 12-16 parts of monomer, 5-7 parts of photoinitiator, 8-12 parts of filler, stream
Flat agent 1.5-2.5 parts, 1-2 parts of wetting agent, 0.03-0.07 parts of surfactant, 1.5-2.5 parts of adhesion promoter;
Further, the UV driography CD blueness ink is preferably mainly prepared by the raw material of following mass fraction
It arrives:
13 parts of green pigment, 50 parts of prepolymer, 14 parts of monomer, 6 parts of photoinitiator, 10 parts of filler, 2 parts of levelling agent, wetting
1.5 parts of agent, 0.05 part of surfactant, 2 parts of adhesion promoter.
UV driography CD blueness ink of the present invention is prepared using specified raw material and dosage, good with anti-scumming,
The advantages that rheologic behavio(u)r and excellent ink transfer performance, can be used for optical disc surface printing, and without making in printing process
With fountain solution, high production efficiency, printing quality is good and lower production costs.
Preferably, commercially available green pigment can be selected in the green pigment, preferably non-aqueous green pigment powder.
Preferably, the prepolymer includes polyester acrylate, urethane acrylate, epoxy acrylate, polyethers third
One of olefin(e) acid ester and unsaturated polyester (UP) are a variety of, preferably include polyester acrylate, urethane acrylate and epoxy third
One of olefin(e) acid ester is a variety of, further preferably includes one or both of polyester acrylate and epoxy acrylate.
Preferably, the monomer includes monofunctional monomer, bifunctionality monomer, three-functionality-degree monomer and polyfunctionality list
One of body is a variety of, and the monomer preferably includes ethoxyethoxyethyl acrylate (EOEOEA), two contractings 3 the third two
Two acrylic ester of alcohol (TPGDA), neopentylglycol diacrylate (NPGDA), two contracting propylene glycol double methacrylates (DPGDA), adjacent benzene
Dicarboxylic omega-diol diacrylate (PDDA), trimethylolpropane trimethacrylate (TMPTA), ethoxylation trihydroxy methyl
One of propane triacrylate (EO3-TMPTA) and propoxylation trimethylolpropane trimethacrylate (PO3-TMPTA)
Or it is a variety of, it further preferably include phthalic acid diethylene glycol diacrylate (PDDA), trimethylolpropane tris acrylic acid
One of ester (TMPTA) and ethoxylated trimethylolpropane triacrylate (EO3-TMPTA) are a variety of.
Preferably, the photoinitiator includes one in hydrogen-capture-type light initiator, crack type photoinitiator and aided initiating
Kind is a variety of, preferably includes 2- methyl-1-[4- methyl mercapto phenyl]-2- morpholinyl-1- acetone, 2- isopropyl thioxanthone, 2,
4,6- trimethylbenzoy-dipheny phosphine oxide, benzophenone, 2,4- diethyl thioxanthone, 2- hydroxy-2-methyl -1-
One of phenyl-1- acetone and 2-EHA are a variety of, further preferably include 2- methyl-1-[4- methyl mercapto
Phenyl] one of -2- morpholinyl -1- acetone, 2- isopropyl thioxanthone and 2,4- diethyl thioxanthone or a variety of.
UV driography CD blueness ink of the present invention uses prepolymer, monomer and the photoinitiator of special component, facilitates
Under UV illumination, photoinitiator causes rapidly monomer and prepolymer reaction, completes solidification, is formed and stablizes printed patterns, guarantees print
Brush quality.
Preferably, the filler is one of fumed silica, kaolin, talcum powder, calcium carbonate or a variety of, gas phase
One of silica, talcum powder, calcium carbonate are a variety of, further preferably one or both of talcum powder, calcium carbonate.
UV driography CD blueness ink of the present invention uses the filler of special component, helps to improve gained UV driography
Viscosity, the thixotropic property of CD blueness ink, moreover it is possible to improve the rheologic behavio(u)r and ink transfer performance of ink, improve gained UV without
The comprehensive performance of glue print CD blueness ink.
Preferably, the levelling agent includes one of UV photocuring levelling agent or a variety of, is preferably included acrylic acid modified
One of organosilicon is a variety of, further preferably includes silicone acrylate.
UV driography CD blueness ink of the present invention uses the levelling agent of special component, can promote gained UV driography light
Disk blueness ink forms smooth, smooth, uniform film layer in printing process, and the green oil of gained UV driography CD can be effectively reduced
The surface tension of ink, improves its levelability and uniformity, can improve the permeability of gained UV driography CD blueness ink, can subtract
A possibility that generating spot and spot when printing less, increases spreadability, keeps printing film forming uniform, natural.
Preferably, the wetting agent includes one of non-ionic wetting agent or a variety of, preferably includes polyoxyethylene alkane
One in base phenolic ether, polyoxyethylene aliphatic alcohol ether, polyox-yethylene-polyoxypropylene block copolymer and silanol class non-ionic wetting agent
Kind is a variety of, further preferably includes that polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and PULLRONIC F68 are embedding
One of section copolymer is a variety of.
UV driography CD blueness ink of the present invention uses the wetting agent of special component, helps to improve substrate and stock chart
Surface properties improve the adhesive force of ink, moreover it is possible to improve the rheologic behavio(u)r and ink transfer performance of ink.
Preferably, the surfactant includes one of nonionic surface active agent or a variety of, preferably includes rouge
One of fatty acid glyceride and polyalcohol are a variety of, further preferably include glycerin monostearate, sucrose ester, fatty acid mountain
Pears are smooth and one of polysorbate or a variety of.
UV driography CD blueness ink of the present invention uses the surfactant of special component, helps to improve raw material and base
The surface nature of material promotes different material to be mutually mixed sufficiently, moreover it is possible to improve the rheologic behavio(u)r and ink transfer performance of ink.
Preferably, the adhesion promoter includes methacrylic acid phosphoric acid ester monomer, silane coupling agent, phosphorus metering system
One of acid ester monomer, acrylic acid dicyclopentadiene ester monomer are a variety of.
UV driography CD blueness ink of the present invention uses the adhesion promoter of special component, can effectively improve ink
In the adhesive force of substrate surface, stable printed patterns are contributed to form, guarantee printing quality.
UV driography CD blueness ink of the present invention is prepared using specified raw material and dosage, has excellent printing suitable
Ying Xing, the viscosity of the UV driography CD blueness ink are 1700-2400Pas, and viscosity is 10-14, surface tension 23-
25mN/m。
UV driography CD blueness ink of the present invention is prepared using specified raw material and dosage, has excellent printing quality
Amount, for the dot gain rate for the product for using the UV driography CD blueness ink to be printed for 8%-14%, 75% printing is anti-
Difference is 18%-27%, field density 1.25-1.45.
A kind of preparation method of above-mentioned UV driography CD blueness ink, includes the following steps:
It will carry out pre-dispersed after each raw material mixes in proportion, then be ground, until pigment dispersion is equal on a glass
It is even, continue to be ground to required fineness, obtains a kind of preparation method of UV driography CD blueness ink.
The preparation method of the method for the present invention UV driography CD blueness ink is using the side for directly mixing pre-dispersed grinding
Formula, simple process are suitable for large-scale production.
Preferably, the grinding is carried out using grinder.
Preferably, the grinder is three-roll grinder.
Preferably, during the grinding process in due course adjustment three-roll grinder roll gap gap, and to the fineness of ink carry out with
Track test, until ink reaches required fineness.
Preferably, the fineness of the UV driography CD blueness ink be 10 microns hereinafter, further preferably 5 microns with
Under.
UV driography CD blueness ink of the present invention has particular fineness, helps to improve printing quality, improvement was printed
The problems such as color difference for being likely to occur in journey, unintelligible, paste plate site.
Compared with prior art, the invention has the benefit that
UV driography CD blueness ink of the present invention is prepared using specified raw material and dosage, good with anti-scumming,
The advantages that rheologic behavio(u)r and excellent ink transfer performance, can be used for optical disc surface printing, and without making in printing process
With fountain solution, high production efficiency, printing quality is good and lower production costs.The method of the present invention UV driography CD blueness ink
For preparation method by the way of directly mixing pre-dispersed, grinding, simple process is suitable for large-scale production.
Specific embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.It is not specified in embodiment specific
Condition person carries out according to conventional conditions or manufacturer's recommended conditions.Reagents or instruments used without specified manufacturer is
The conventional products that can be obtained by commercially available purchase.
Embodiment 1
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 15 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 45 parts of the mixture (mass ratio 1:1) being made of epoxy acrylate and polyester acrylate, 13 parts by PDDA
With monomer mixture (mass ratio 1:1), 6 parts of photoinitiator 2- methyl-1-[4- methyl mercapto phenyl]-2- of TMPTA composition
Morpholinyl -1- acetone, 15 parts of fumed silica, 1.4 parts of silicone acrylate, 2 parts of polyoxyethylated alkyl phenol,
0.1 part of glycerin monostearate, 2.5 parts of methacrylic acid phosphoric acid ester monomer, then on a glass by above-mentioned each component
It carries out pre-dispersed, then is ground with three-roll grinder, until pigment is uniformly dispersed, adjust three-roll grinder in process of lapping in due course
Roll gap gap, and to the fineness of ink carry out tracking and testing, until the fineness of ink reach 5 microns hereinafter, stop grinding to get
A kind of UV driography CD blueness ink.
Embodiment 2
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 16 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 46.5 parts of the mixture (mass ratio 1:1) being made of epoxy acrylate and urethane acrylate, 10 parts by
PDDA and EO3-TMPTA composition monomer mixture (mass ratio 1:1), 5 parts by 2- isopropyl thioxanthone, 2,4- diethyl
The photoinitiator mixtures (mass ratio 1:1) of base thioxanthone composition, 16 parts of talcum powder, 1.5 parts of silicone acrylic
Ester, 1.9 parts of polyoxyethylene aliphatic alcohol ether, 0.1 part of polysorbate, 2 parts of acrylic acid dicyclopentadienyl ester, then will be above-mentioned
Each component carries out pre-dispersed on a glass, then is ground with three-roll grinder, until pigment is uniformly dispersed, in process of lapping in due course
Adjust three-roll grinder roll gap gap, and to the fineness of ink carry out tracking and testing, until the fineness of ink reach 5 microns with
Under, stop grinding to get a kind of UV driography CD blueness ink.
Embodiment 3
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 10 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 33 parts of epoxy acrylate, 7 parts of PDDA, 5 parts of 2- methyl-1-[4- methyl mercapto phenyl]-2- morpholinyl-1- third
Ketone, 5 parts of kaolin, 1.5 parts of silicone acrylate, 1 part of polyoxyethylene aliphatic alcohol ether, 0.01 part of polysorbate, 1
Part acrylic acid dicyclopentadienyl ester, then above-mentioned each component is carried out pre-dispersed on a glass, then is ground with three-roll grinder
Mill adjusts the roll gap gap of three-roll grinder, and carry out to the fineness of ink until pigment is uniformly dispersed in due course in process of lapping
Tracking and testing, until the fineness of ink reaches 10 microns hereinafter, stopping grinding to get a kind of UV driography CD blueness ink.
Embodiment 4
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 16 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 56 parts of urethane acrylate, 18 parts of EO3-TMPTA, 8 parts of 2,4- diethyl thioxanthone, 16 parts of talcum
Powder, 2.5 parts of silicone acrylate, 2 parts of polyoxyethylene aliphatic alcohol ether, 0.1 part of sucrose ester, 3 parts of methacrylic acid
Phosphate ester monomer, then carries out above-mentioned each component pre-dispersed on a glass, then is ground with three-roll grinder, until pigment point
It dissipates uniformly, adjusts the roll gap gap of three-roll grinder in process of lapping in due course, and tracking and testing is carried out to the fineness of ink, until
The fineness of ink reaches 10 microns hereinafter, stopping grinding to get a kind of UV driography CD blueness ink.
Embodiment 5
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 12 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 45 parts of epoxy acrylate, 12 parts of PDDA, 5 parts of 2- isopropyl thioxanthone, 8 parts of talcum powder, 1.5 parts of silicon
Oxygen alkane acrylate, 1 part of polyoxyethylated alkyl phenol, 0.03 part of polysorbate, 1.5 parts of acrylic acid dicyclopentadiene
Ester, then carries out above-mentioned each component pre-dispersed on a glass, then is ground with three-roll grinder, until pigment is uniformly dispersed,
The roll gap gap of three-roll grinder is adjusted in process of lapping in due course, and tracking and testing is carried out to the fineness of ink, until ink
Fineness reaches 5 microns hereinafter, stopping grinding to get a kind of UV driography CD blueness ink.
Embodiment 6
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 14 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 55 parts of urethane acrylate, 16 parts of TMPTA, 7 parts of 2,4- diethyl thioxanthone, 12 parts of calcium carbonate, 2.5
Silicone acrylate, 2 parts of the polyoxyethylene aliphatic alcohol ether, 0.07 part of polysorbate, 2.5 parts of methacrylic acid phosphorus of part
Acid ester monomer, then carries out above-mentioned each component pre-dispersed on a glass, then is ground with three-roll grinder, until pigment disperses
Uniformly, the roll gap gap of three-roll grinder is adjusted in process of lapping in due course, and tracking and testing is carried out to the fineness of ink, until oil
The fineness of ink reaches 5 microns hereinafter, stopping grinding to get a kind of UV driography CD blueness ink.
Embodiment 7
A kind of preparation method of UV driography CD blueness ink, includes the following steps:
In terms of mass fraction, weigh in the balance 13 parts green pigment (4G-K green pigment, manufacturer be Switzerland's gas Bagong
Department), 50 parts of polyester acrylate, 14 parts of PDDA, 6 parts of 2- isopropyl thioxanthone, 10 parts of talcum powder, 2 parts of silicon
Oxygen alkane acrylate, 1.5 parts of polyoxyethylated alkyl phenol, 0.05 part of sucrose ester, 2 parts of acrylic acid dicyclopentadienyl ester,
Then above-mentioned each component is carried out pre-dispersed on a glass, then is ground with three-roll grinder, until pigment is uniformly dispersed, grinding
It adjusts the roll gap gap of three-roll grinder in due course in the process, and tracking and testing is carried out to the fineness of ink, until the fineness of ink
Reach 5 microns hereinafter, stopping grinding to get a kind of UV driography CD blueness ink.
Experimental example
The resulting UV driography CD blueness ink of Example 1- embodiment 7 carry out printing performance test, and by its
It is printed on the CD of the preparatory silk-screen printing chalk of ground, carries out printing quality test, printing performance and printing quality index
It is shown in Table 1.
The printing performance and printing quality index of the UV driography CD blueness ink of the present invention of table 1
It can be seen from Table 1 that UV driography CD blueness ink of the present invention has excellent printing adaptability, the UV
The viscosity of driography CD blueness ink is 1700-2400Pas, and viscosity is 10-14, surface tension 23-25mN/m;This hair
Bright UV driography CD blueness ink has excellent printing quality, is printed using the UV driography CD blueness ink
The dot gain rate of product is 8%-14%, and 75% print contrast is 18%-27%, field density 1.25-1.45.
In addition, UV driography CD blueness ink of the present invention is prepared using specified raw material and dosage, there is anti-scumming
Property it is good, rheologic behavio(u)r and ink transfer performance are excellent the advantages that, can be used for optical disc surface printing, and the nothing in printing process
Fountain solution need to be used, high production efficiency, printing quality is good and lower production costs.The green oil of the method for the present invention UV driography CD
For the preparation method of ink by the way of directly mixing pre-dispersed, grinding, simple process is suitable for large-scale production.
Although illustrate and describing the present invention with specific embodiment, it will be appreciated that without departing substantially from of the invention
Many other change and modification can be made in the case where spirit and scope.It is, therefore, intended that in the following claims
Including belonging to all such changes and modifications in the scope of the invention.
Claims (13)
1. a kind of UV driography CD blueness ink, which is characterized in that the UV driography CD blueness ink is mainly by following
The raw material of mass fraction is prepared:
10-16 parts of green pigment, 33-56 parts of prepolymer, 7-18 parts of monomer, 5-8 parts of photoinitiator, 5-16 parts of filler, levelling agent
1.5-2.5 parts, 1-2 parts of wetting agent, 0.01-0.1 parts of surfactant, 1-3 parts of adhesion promoter;
The prepolymer includes polyester acrylate, urethane acrylate, epoxy acrylate, polyether acrylate and insatiable hunger
With one of polyester or a variety of;
The monomer includes ethoxyethoxyethyl acrylate, two acrylic ester of tripropylene glycol, two propylene of neopentyl glycol
Acid esters, two contracting propylene glycol double methacrylates, phthalic acid diethylene glycol diacrylate, trimethylolpropane tris acrylic acid
One of ester, ethoxylated trimethylolpropane triacrylate and propoxylation trimethylolpropane trimethacrylate are more
Kind;
The photoinitiator include 2- methyl-1-[4- methyl mercapto phenyl]-2- morpholinyl-1- acetone, 2- isopropyl thioxanthone,
2,4,6- trimethylbenzoy-dipheny phosphine oxide, benzophenone, 2,4- diethyl thioxanthone, 2- hydroxy-2-methyl-
One of 1- phenyl -1- acetone and 2-EHA are a variety of;
The filler is one of fumed silica, kaolin, talcum powder, calcium carbonate or a variety of;
The levelling agent includes one of UV photocuring levelling agent or a variety of;
The wetting agent includes polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether, PULLRONIC F68 block copolymerization
One of object and silanol class non-ionic wetting agent are a variety of;
The surfactant includes one of fatty glyceride and polyalcohol or a variety of;
The adhesion promoter includes methacrylic acid phosphoric acid ester monomer, silane coupling agent, phosphorus methacrylate monomers, third
One of olefin(e) acid dicyclopentadiene ester monomer is a variety of;
The viscosity of the UV driography CD blueness ink is 1700-2400Pas, and viscosity is 10-14, surface tension 23-
25mN/m, fineness are 10 microns or less;
The dot gain rate for the product for using the UV driography CD blueness ink to be printed is 8%-14%, 75% print contrast
For 18%-27%, field density 1.25-1.45.
2. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the UV driography light
Disk blueness ink is mainly prepared by the raw material of following mass fraction:
12-14 parts of green pigment, 45-55 parts of prepolymer, 12-16 parts of monomer, 5-7 parts of photoinitiator, 8-12 parts of filler, levelling agent
1.5-2.5 parts, 1-2 parts of wetting agent, 0.03-0.07 parts of surfactant, 1.5-2.5 parts of adhesion promoter.
3. a kind of UV driography CD blueness ink according to claim 2, which is characterized in that the UV driography light
Disk blueness ink is mainly prepared by the raw material of following mass fraction:
13 parts of green pigment, 50 parts of prepolymer, 14 parts of monomer, 6 parts of photoinitiator, 10 parts of filler, 2 parts of levelling agent, wetting agent 1.5
Part, 0.05 part of surfactant, 2 parts of adhesion promoter.
4. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the prepolymer includes poly-
One of ester acrylate, urethane acrylate and epoxy acrylate are a variety of.
5. a kind of UV driography CD blueness ink according to claim 4, which is characterized in that the prepolymer includes poly-
One or both of ester acrylate and epoxy acrylate.
6. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the monomer includes adjacent benzene
Three acrylic acid of dicarboxylic omega-diol diacrylate, trimethylolpropane trimethacrylate and ethoxylated trimethylolpropane
One of ester is a variety of.
7. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the photoinitiator includes
2- methyl-1-[4- methyl mercapto phenyl]-2- morpholinyl-1- acetone, 2- isopropyl thioxanthone and 2,4- diethyl thioxanthone
One of or it is a variety of.
8. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the filler is gas phase two
One of silica, talcum powder, calcium carbonate are a variety of.
9. a kind of UV driography CD blueness ink according to claim 8, which is characterized in that the filler is talcum
One or both of powder, calcium carbonate.
10. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the levelling agent includes
One of acryl-modified silicone resin is a variety of.
11. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the wetting agent includes
One of polyoxyethylated alkyl phenol, polyoxyethylene aliphatic alcohol ether and polyox-yethylene-polyoxypropylene block copolymer are a variety of;
The surfactant include one of glycerin monostearate, sucrose ester, fatty acid sorbitan and polysorbate or
It is a variety of.
12. a kind of UV driography CD blueness ink according to claim 1, which is characterized in that the UV driography
The fineness of CD blueness ink is 5 microns or less.
13. a kind of preparation method of UV driography CD blueness ink as described in any in claim 1-12, feature exist
In including the following steps:
It will carry out pre-dispersed after each raw material mixes in proportion, then be ground on a glass, until pigment is uniformly dispersed, after
It is continuous to be ground to required fineness, obtain a kind of UV driography CD blueness ink.
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CN108084773B (en) * | 2018-01-12 | 2020-08-18 | 杭州电子科技大学 | Plastic film gravure table printing ink and preparation method thereof |
CN115093746A (en) * | 2022-06-17 | 2022-09-23 | 美盈森集团股份有限公司 | Offset printing UV metal ink and preparation method thereof |
CN115433515B (en) * | 2022-09-19 | 2023-06-23 | 广东希贵光固化材料有限公司 | High-hardness super-wear-resistant UV transfer printing adhesive and preparation method thereof |
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CN102898893A (en) * | 2012-09-26 | 2013-01-30 | 深圳市深赛尔股份有限公司 | Ultraviolet (UV) offset printing ink suitable for different film substrates and preparation method thereof |
CN103351709A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Environment-friendly waterless offset ink |
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2016
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CN102898893A (en) * | 2012-09-26 | 2013-01-30 | 深圳市深赛尔股份有限公司 | Ultraviolet (UV) offset printing ink suitable for different film substrates and preparation method thereof |
CN103351709A (en) * | 2013-07-08 | 2013-10-16 | 苏州凹凸彩印厂 | Environment-friendly waterless offset ink |
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