CN105561745A - Health care negative oxygen ion magic cleaning ball and preparing raw materials, preparing method and application thereof - Google Patents
Health care negative oxygen ion magic cleaning ball and preparing raw materials, preparing method and application thereof Download PDFInfo
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- CN105561745A CN105561745A CN201510920353.8A CN201510920353A CN105561745A CN 105561745 A CN105561745 A CN 105561745A CN 201510920353 A CN201510920353 A CN 201510920353A CN 105561745 A CN105561745 A CN 105561745A
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
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Abstract
The invention provides a health care negative oxygen ion magic cleaning ball and preparing raw materials, a preparing method and application thereof, belonging to the technical field of environment protection and solving the problems such as low natural release concentration of negative oxygen ion in prior art, and the like. The preparing raw materials of the health care negative oxygen ion magic cleaning ball comprise following components: any one or two of tourmaline and six ring stone, any one or more of opal, gull rock, medical stone and diatomite and a binding material. The health care negative oxygen ion magic cleaning ball and preparing raw materials, the preparing method and application thereof have the advantages of being capable of durably releasing air negative oxygen ions with high concentration, emitting far infrared rays which is larger in a normal emitting rate and near to the far infrared wavelength emitted from a human body, saving power source without a power source, and being low in construction cost and good in economic benefits.
Description
Technical field
The invention belongs to environmental technology field, relate to purification of air, especially relate to the clean ball of a kind of health negative oxygen ion evil spirit and raw materials, preparation method and application.
Background technology
Formaldehyde is one of major pollutants of air in room, in passenger car.Result of study shows: in house fitting later six months, formaldehyde in air average content is 0.170mg/m
3, after finishing, in 2 to 3 years, indoor formaldehyde average content is 0.071mg/m
3, still have the eye of 16.7% to have irritation.Long Term Contact low dosage formaldehyde (i.e. 0.017mg/m
3-0.068mg/m
3), can cause chronic respiratory disease, feminine menstrual disorder, pregnancy syndrome, cause the reduction of neonate's physique, chromosome abnormality, even nasopharyngeal carcinoma occurs.The pollutants such as nineteen ninety-five international cancer research institution (IARC) determines that formaldehyde is suspect carcinogen, the benzene,toluene,xylene of passenger car interior trim existence simultaneously, are also defined as poisonous carcinogenic substance by international cancer research institution.Prove according to a large amount of scientific experiment: negative oxygen ion is that room, in-vehicle air pollution thing formaldehyde, benzene, toluene and dimethylbenzene decompose " weapon ", be described as " vitamin of air ", " the longevity element of human life ", just because of negative oxygen ion, there is such effect, in order to the air quality improving in room and in passenger car, various negative oxygen ion generator arises at the historic moment.
The operation principle of current existing negative oxygen ion generator can be divided into following three kinds of methods substantially: corona, tension discharge gunite, plant source adds electrical equipment combined techniques and traditional natural mineral sources method for releasing.Above-mentioned scheme improves the subproblem of prior art to a certain extent, but the program also at least exists following defect: the problem such as the negative oxygen ion concentration of release is low, poor to air pollutants adsorptivity, kill pathogenic bacteria and virus efficacy is low.
Summary of the invention
The object of the invention is for the problems referred to above, provide a kind of component compatibility reasonable, the negative oxygen ion that can discharge high concentration can launch again the clean ball raw materials of health negative oxygen ion evil spirit of the far infrared being suitable for human body simultaneously.
Second object of the present invention is for the problems referred to above, provides a kind of negative oxygen ion that can discharge high concentration can launch again the clean ball of health negative oxygen ion evil spirit of the far infrared being suitable for human body simultaneously.
3rd object of the present invention is for the problems referred to above, provides the health negative oxygen ion evil spirit clean ball health care bag that a kind of negative oxygen ion that can discharge high concentration can launch again the far infrared being suitable for human body simultaneously.
4th object of the present invention is for the problems referred to above, provides a kind of technological process simple, the preparation method of the convenient clean ball of negative oxygen ion evil spirit manufactured.
For achieving the above object, present invention employs following technical proposal: the clean ball raw materials of health negative oxygen ion of the present invention evil spirit comprises following component: any one or two kinds in tourmaline and six ring stones, in opal, sea-gull stone, medical stone and diatomite any one or multiple, and cohesive material.Tourmaline and six ring stones all have launches the far infrared useful to human body, wherein the far infrared wavelength that sends of the far infrared wavelength that sends of tourmaline and human body close, improve human absorptivity, normal emittance when six ring stones are emitting far-infrared can reach 0.88, launching effect is better, opal, sea-gull stone, medical stone and diatomite all have the function of the negative oxygen ion of Spontaneous release high concentration, and cohesive material is convenient to above-mentioned material to be bonded together.
In the present invention, the clean ball of health negative oxygen ion evil spirit is non-technical term, refers to have emitting negative oxygen ion and far infrared and the granule with adsorption capacity.But the clean ball of health negative oxygen ion evil spirit can be described as health negative oxygen ion particle.
At the clean ball raw materials of above-mentioned health negative oxygen ion evil spirit, this raw materials also comprises absorbent material.There is dehumidification function.
At the clean ball raw materials of above-mentioned health negative oxygen ion evil spirit, cohesive material is Concave-convex clay rod, and absorbent material is sepiolite.The raw material components such as above-mentioned ore obtain through test of many times based on Hua Luogeng mathematical optimization method, and the far infrared launching effect ensure that negative oxygen ion release concentration is high, being suitable for human body is good, is convenient to bonding simultaneously.And various ore easily obtains, and reduces production cost.
At the clean ball raw materials of above-mentioned health negative oxygen ion evil spirit, this raw materials comprises the component of following portions by weight: tourmaline 15-25, six ring stone 30-40, opal 5-15, Concave-convex clay rod 25-35 and diatomite 3-8.。
At the clean ball raw materials of above-mentioned health negative oxygen ion evil spirit, tourmaline, six ring stones, opal, Concave-convex clay rod, sea-gull stone, medical stone, diatomite and sepiolite are powdered granule, and the particle diameter of powdered granule is no more than 40 microns.Ensure that the fineness made needed for particle.
The clean ball of this health negative oxygen ion evil spirit is obtained to through Homogeneous phase mixing and by granulator by the clean ball raw materials of health negative oxygen ion evil spirit.Technique simply, is easily produced.
At the clean ball of above-mentioned health negative oxygen ion evil spirit, its granule size is 1-5mm, moisture content percentage by weight is no more than 10%.Ensure that the firmness of the clean ball of health negative oxygen ion evil spirit made, non-friable.
This health negative oxygen ion evil spirit clean ball health care bag, comprises the surrounding layer be made up of gas permeable material, is packaged with the clean ball of some health negative oxygen ions evil spirit in surrounding layer.Being convenient to just through surrounding layer, negative oxygen ion and far infrared outwards to be discharged without the need to tearing surrounding layer when the clean ball of health negative oxygen ion evil spirit uses, adding the convenience of use.
At above-mentioned health negative oxygen ion evil spirit clean ball health care bag, surrounding layer is attached with can the plant source extract of releasing negative oxygen ion.Improve the release concentration of negative oxygen ion.
The preparation method of the clean ball of this health negative oxygen ion evil spirit, comprises the steps: A, premix: the powdered granule choosing needed raw material as required, is then mixed by various powdered granule; B, granulation: adopt facility for granulating to be granulated by mixed powdered granule, acquisition degree size is the spherical particle of 1-5mm; C, finished product: spherical particle is carried out drying, the clean ball of obtained health negative oxygen ion evil spirit.Flow process is simple, is convenient to management.
In the preparation method of the clean ball of above-mentioned health negative oxygen ion evil spirit, the preparation process of the powdered granule of often kind of raw material is as follows: 1. carry out decontamination process according to the impurity content of the tcrude ore of often kind of raw material and obtain tcrude ore up to standard, high-temperature instantaneous sterilization sterilization is carried out to tcrude ore up to standard, then disintegrating machine coarse crushing is used, cross 30-50 mesh sieve, obtain the rough powder of 30-50 order; 2. by the second-time breakage of rough for 30-50 order powder jaw crusher, cross 250-350 mesh sieve, obtain 250-350 order mineral powder granular; Then 250-350 order mineral powder granular periodic is stirred cylinder type wet ball mill and carry out circular grinding, then carry out drying with freezing type drier, obtained particle diameter is no more than the mineral powder granular of 50 microns; 3. mineral powder granular flat air flow crusher particle diameter being no more than 50 microns processes, bleed pressure 0.7-0.9Mpa, charging aperture pressure 0.5Mpa wherein, and ending breeze obtains the powdered granule that particle diameter is no more than 40 microns.Technique is simple, convenient for production.
The present invention is based on Hua Luogeng mathematical optimization method, in existing natural mineral sources, carry out test of many times checking, give full play to each component synergy, wherein the effect brief introduction of each raw material is as follows.
Tourmaline: English Tourmaline by name, has another name called Tourmaline, have another name called broken evil gold, refined title tourmaline again.The chemical composition of tourmaline is (Na, K, Ca) (Al, Fe, Li, Mg, Mn)
3(Al, Cr, Fe, V)
6(Bo
3)
3(Si
6o
18) (OH, F)
4; Chemical general formula is NaR
3al
6[Si
6o
18] [Bo
3]
3(OH, F)
4.Chemical constitution: namely except silica backbone, also has (Bo
3) complex anion group, R position isomorphism is extensive, when R is Mg, is called dravite, when R is Mn, claims to receive tsilaisite, when R is iron, is called black iron tourmaline, when R is Li, Al, claims elbaite; Crystalline structure is basic characteristics is [SiO
4] tripartite's ring of tetrahedron composition, B ligancy is 3, and composition plane triangle, Mg ligancy is 6 (wherein have two OH
-) composition octahedron, with [Bo
3] oxygen connection altogether, at [SiO
4] have in space above tetrahedral multiple tripartite's ring ligancy be 91 valency cation Na
+distribution, between with [AlO
5(OH)] octahedra connection; Color is different and different with composition, and the tourmaline of rich Fe is black, rich Li, Mn and tourmaline be rose-colored; Physical property is glassy lustre, Mohs' hardness 7-8, density 3.06 (+0.20,-0.60) g/cm, photosensitiveness is characterized as heterogeneous body, uniaxial crystal, negative optics, refractive index is 1.624-1.644 (+0.011 ,-0.009), and birefringence is 0.018-0.040, be generally 0.020, dead color can reach 0.040, general without ultraviolet fluorescent, and pink, red (tourmaline) tourmaline length ripple F is weak red in purple, absorption spectrum is red and pink, green Region broad absorption band, has visible 525 nano narrow bands, 451 nanometers, 458 nanometer Absorption Lines.
Six ring stones: in recent years newfound, have crystalline texture, can be naturally emitting far-infrared, normal emittance is up to 0.88, and have the biological electricity function of uniqueness, negative oxygen ion release concentration reaches 1573/cm
3be that a kind of adsorptivity is powerful, anti-electromagnetic wave, anti-chemotherapy, antitumor, AIDS virus resisting ancient sedimentary rock, detect through test center of national building materials industry geologic engineering investigation research institute, its composition of ores is dolomite 83.6%, quartz 7.5%, feldspar 5.0%, calcite 2.3%, hematite 1.6%, wherein CaO, MgO, SiO
2content be respectively 25.6%, 17.8%, 7.5%, and a small amount of Al
2o
3, Fe
2o
3, K
2o, TiO
2, Na
2the metal oxides such as O, six ring stones are rich in the nutrient of the needed by human such as calcium, magnesium, sodium, potassium, iron, selenium, zinc, strontium, copper and noble metal germanium.The natural safe pit wood that six ring stones are nontoxic to environment, harmless, tasteless.
Opal: English Opal by name, also known as Ou Po, Ou Poshi, another name dodges mountain, Austria is precious; Classification is noncrystalline, belongs to bijouterie, is divided into your gem opal and two kinds, general opal; Chemical formula is SiO
2.nH
2o; Mohs' hardness is 5.5-7.5; Density is 2.15-2.23g/cm
3; Chemical composition is for removing SiO
2outward, also containing iron, calcium, magnesium, copper etc.; If your jewel is color be then for color gloss changes with angle, if the opal of white or color are glassy lustre or wax gloss, is then general jewel; Structure has compact massive, granular, earthy, stalactitic, concretion forms and cellular; It is the fiery Ou Po of the Hei Oupo of background color, the Bai Oupo be creamy white, salmon pink that background color has with black; Opal has unique natural nano level microcellular structure, has powerful adsorption function, has again the speciality of release air negative oxgyen ion, can discharge 1000/cm
3natural negative oxygen ion.
Concave-convex clay rod: another name palygorskite or Palygorskite, be a kind of chain layer structure containing Shuifu County's magnesium silicate clay minerals, desirable chemical formula is Mg
5(H
2o)
4[Si
4o
10]
2(OH)
2, chemical composition theoretical value is that MgO accounts for 23.8%, SiO
2account for 56.96%, H
2o accounts for 19.21%, due to Al
3+, Fe
3+isomorphic replacemnt, forms aluminium attapulgite and the mutation of iron attapulgite, usually exist with Concave-convex clay rod, divided by containing outside attapulgite, often containing mineral such as montmorillonite, kaolin, hydromica, sepiolite, quartz, opal and carbonates, attapulgite form is for being hair shape or threadiness, and be generally woollen blanket shape or earthy aggregate, Mohs' hardness is 2-3, and proportion is 2.05-2.32, because attapulgite has unique crystal structure, there is again many special materializations and processing performance, if cation interchangeability, water imbibition, decolourising property, specific area are 9.6-36m
2/ g, and colloid index and expansion capacity, make it in environmental protection (as sewage, purification, the deodorizing of ight soil and sewage), chemical industry, decolouring, binding agent, duplicate, casting, silicate industry, medicine is (as removing aspergillus flavus B, purification dextrin, except deproteinized residue), agricultural chemicals, chemical fertilizer is (as farm chemical carrier, make dry stable potash fertilizer and amine fertilizer), construction material is (as coating, chemical enamel, materials for wall etc.), as high-quality stream slurry raw material in deep-sea oil and drilling well and geothermal drilling, printing is (as printing paper, manifolding Reiceiver sheet, reactive dye, printed base plate, quality image composite), atomic energy industry (namely making atomic radiations mass treatment) etc., of many uses.The present invention mainly utilizes the adhesive property of Concave-convex clay rod and stronger adsorption function, and water suction, deodorizing, purification characteristic.
Sea-gull stone: English name Health; Main component is CaO, SiO
2and variable valency metal Fe; Internal structure has the hole of 20-60nm, therefore possesses powerful adsorption function; When water in air fractionated molecule enters sea-gull stone internal capillary, hydrone is ionized by the electric microfield that the iron that appraises at the current rate produces, and produce natural negative oxygen ion, every cubic centimetre of negative oxygen ion concentration reaches 1700, and sea-gull stone inside is containing a small amount of TiO simultaneously
2, therefore there is photoelectrocatalysis effect, can harmful bacteria, viral kill in air, according to test, sea-gull stone to staphylococcus aureus, Escherichia coli, white read coccus, hay bacillus antibiotic rate up to more than 90%.
Medical stone: English Maifanshi by name, the long-lived stone that has another name called, Shen Xianshi, refining mountain stone, gingival cyst of mucous gland in the newborn sand, bean dregs, formal name used at school is adamellite, is a kind of natural silicates mineral; Main chemical compositions is SiO
2, Al
2o
3, Fe
2o
3, FeO, MgO, CaO, K
2o, Na
2o, TiO
2, P
2o
5, macroelement is K, Na, Ca, Mg, Cu, Mo and 58 kinds of elements such as micronutrient boron, germanium, zinc, tin, gallium, chromium, nickel, indium, vanadium, cobalt, niobium, tantalum, zirconium, selenium, beryllium, barium, strontium and rare-earth elements of lanthanum, cerium, yttrium, ytterbium; The aperture surface area of medical stone is large especially, 1 gram of medical stone has the aperture surface area of hundreds of square metre, than many 20,000 times of equal 1 gram of active carbon specific area, therefore medical stone has and reaches more than 95% to harmful bacteria, colibacillary adsorption rate, produces air negative oxgyen ion simultaneously.
Diatomite: English Diatomitel by name; Chemical formula is SiO
2.nH
2o; Chemical composition is SiO
2, containing a small amount of Al
2o
3, Fe
2o
3, CaO, MgO etc. and organic, wherein SiO
2account for more than 80%, be up to 94%; Physical characteristic is density is 1.9-2.3g/cm
3, bulk density is 0.34-0.65g/cm
3, specific area is 40-65m
2/ g, pore volume is 0.45-0.98m
3, water absorption rate is 2-4 times of own vol, and fusing point is 1050 DEG C-1750 degrees Celsius, observes the structure of special porous under Electronic Speculum; Because diatom is a kind of special plant in ocean, on the ancient times earth, more than 70% oxygen is that diatom is made, and diatomite is made up of diatom, and therefore it has the function of release air negative oxgyen ion.
Sepiolite: English Sepiolite by name; Chemical formula is (SiO
2) (Mg
8) O
30(OH)
4(OH
2)
4.8H
2o; Mineral density is 2-2.5g/cm
3, specific area is 900m greatly
2/ g; Sepiolite is a kind of fibrous hydrous magnesium silicate, and in white, light gray, the color such as pale yellow, some shapes are as soil block, and some shapes become a strange cot or tuberculosis building, and under Electronic Speculum, can see is got together by countless silk lines up sheet; Water imbibition is greater than 150% of own wt, limbers up after water suction, hardening again after drying.Sepiolite has that corrosion resistance, radioresistance and heat endurance are strong, decolouring, heat insulation, insulation, but containing a small amount of asbestos (about 5-30%), need to remove asbestos in processing technology.
Compared with prior art, the advantage of the clean ball of this guarantor health negative oxygen ion evil spirit and raw materials thereof, preparation method and application is: can not emit bad smell compared with existing negative oxygen ion product, guarantee non-secondary pollution; Compare with existing corona, voltage method, do not need power supply, save power supply, and cost is low, good in economic efficiency; The negative oxygen ion hair device adding electrical equipment method with existing employing plant source compares, and does not need separately to power up pulse electrical equipment transmitter, saves production cost, has saved power supply; Compare with traditional natural mineral sources negative oxygen ion generator, the far infrared wavelength that because the negative oxygen ion concentration of release is high, the normal emittance of far infrared is large, wavelength sends with human body is close, and therefore better, range of application is wider for health-care effect; It is that natural microporous materials, specific area are large, so the ability of absorbed air pollutant, harmful bacteria, virus is enhanced, the efficiency of kill harmful bacterium and virus is high; Packaging material adopt the concentration having the Extracts from Plant Recourses of releasing negative oxygen ion and the cancellated fibrous material of green, further increase the air negative oxgyen ion of release.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is only some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 provides health negative oxygen ion evil spirit ball and the structural representation wrapped that keeps healthy thereof only in the embodiment of the present invention.
In figure, the clean ball 2 of surrounding layer 1, health negative oxygen ion evil spirit.
Detailed description of the invention
Below in conjunction with accompanying drawing, also by embodiment, the present invention is described in further detail, and following examples are explanation of the invention and the present invention is not limited to following examples.
In the present invention, the clean ball of health negative oxygen ion evil spirit is non-technical term, refers to have emitting negative oxygen ion and far infrared and the granule with adsorption capacity.But the clean ball of health negative oxygen ion evil spirit can be described as health negative oxygen ion particle.
The clean ball raw materials of this health negative oxygen ion evil spirit comprises following component: any one or two kinds in tourmaline and six ring stones, in opal, sea-gull stone, medical stone and diatomite any one or multiple, and cohesive material.Tourmaline and six ring stones all have launches the far infrared useful to human body, wherein the far infrared wavelength that sends of the far infrared wavelength that sends of tourmaline and human body close, improve human absorptivity, normal emittance when six ring stones are emitting far-infrared can reach 0.88, launching effect is better, opal, sea-gull stone, medical stone and diatomite all have the function of the negative oxygen ion of Spontaneous release high concentration, and cohesive material is convenient to above-mentioned material to be bonded together.
As a kind of technical scheme comparatively optimized, in the present embodiment, the clean ball raw materials of this health negative oxygen ion evil spirit here also comprises absorbent material, has dehumidification function; Here cohesive material is Concave-convex clay rod, and absorbent material is sepiolite, easily obtains, and reduces production cost; This raw materials here comprises the component of following portions by weight: tourmaline 15-25, six ring stone 30-40, opal 5-15, Concave-convex clay rod 25-35 and diatomite 3-8, this component obtains through test of many times based on Hua Luogeng mathematical optimization method, the far infrared launching effect ensure that negative oxygen ion release concentration is high, being suitable for human body is good, is convenient to bonding simultaneously; Here tourmaline, six ring stones, opal, Concave-convex clay rod, sea-gull stone, medical stone, diatomite and sepiolite are powdered granule, and the particle diameter of powdered granule is no more than 40 microns, ensure that the fineness made needed for particle.In the present embodiment, the composition by weight of raw materials is as follows: tourmaline 20, six ring stones 35, opal 10, Concave-convex clay rod 30 and diatomite 5.
The present invention is based on Hua Luogeng mathematical optimization method, in existing natural mineral sources, carry out test of many times checking, give full play to each component synergy, wherein the effect brief introduction of each raw material is as follows.
Tourmaline: English Tourmaline by name, has another name called Tourmaline, have another name called broken evil gold, refined title tourmaline again.The chemical composition of tourmaline is (Na, K, Ca) (Al, Fe, Li, Mg, Mn)
3(Al, Cr, Fe, V)
6(Bo
3)
3(Si
6o
18) (OH, F)
4; Chemical general formula is NaR
3al
6[Si
6o
18] [Bo
3]
3(OH, F)
4.Chemical constitution: namely except silica backbone, also has (Bo
3) complex anion group, R position isomorphism is extensive, when R is Mg, is called dravite, when R is Mn, claims to receive tsilaisite, when R is iron, is called black iron tourmaline, when R is Li, Al, claims elbaite; Crystalline structure is basic characteristics is [SiO
4] tripartite's ring of tetrahedron composition, B ligancy is 3, and composition plane triangle, Mg ligancy is 6 (wherein have two OH
-) composition octahedron, with [Bo
3] oxygen connection altogether, at [SiO
4] have in space above tetrahedral multiple tripartite's ring ligancy be 91 valency cation Na
+distribution, between with [AlO
5(OH)] octahedra connection; Color is different and different with composition, and the tourmaline of rich Fe is black, rich Li, Mn and tourmaline be rose-colored; Physical property is glassy lustre, Mohs' hardness 7-8, density 3.06 (+0.20,-0.60) g/cm, photosensitiveness is characterized as heterogeneous body, uniaxial crystal, negative optics, refractive index is 1.624-1.644 (+0.011 ,-0.009), and birefringence is 0.018-0.040, be generally 0.020, dead color can reach 0.040, general without ultraviolet fluorescent, and pink, red (tourmaline) tourmaline length ripple F is weak red in purple, absorption spectrum is red and pink, green Region broad absorption band, has visible 525 nano narrow bands, 451 nanometers, 458 nanometer Absorption Lines.The present embodiment selects the tourmaline of Fu Tie, i.e. black iron tourmaline.There is unique piezo-electric effect and pyroelectric effect.Can electric charge be produced when being heated pressurized or being subject to other energy excitations, automatically can launch the far infrared useful to human body, wavelength 4-14 micron, resonance phenomena can be produced with the far infrared of human-body emitting, and be absorbed by the body, promote capillary blood circulation.
Six ring stones: in recent years newfound, have crystalline texture, can be naturally emitting far-infrared, normal emittance is up to 0.88, and have the biological electricity function of uniqueness, negative oxygen ion release concentration reaches 1573/cm
3be that a kind of adsorptivity is powerful, anti-electromagnetic wave, anti-chemotherapy, antitumor, AIDS virus resisting ancient sedimentary rock, detect through test center of national building materials industry geologic engineering investigation research institute, its composition of ores is dolomite 83.6%, quartz 7.5%, feldspar 5.0%, calcite 2.3%, hematite 1.6%, wherein CaO, MgO, SiO
2content be respectively 25.6%, 17.8%, 7.5%, and a small amount of Al
2o
3, Fe
2o
3, K
2o, TiO
2, Na
2the metal oxides such as O, six ring stones are rich in the nutrient of the needed by human such as calcium, magnesium, sodium, potassium, iron, selenium, zinc, strontium, copper and noble metal germanium.The natural safe pit wood that six ring stones are nontoxic to environment, harmless, tasteless.
Opal: English Opal by name, also known as Ou Po, Ou Poshi, another name dodges mountain, Austria is precious; Classification is noncrystalline, belongs to bijouterie, is divided into your gem opal and two kinds, general opal; Chemical formula is SiO
2.nH
2o; Mohs' hardness is 5.5-7.5; Density is 2.15-2.23g/cm
3; Chemical composition is for removing SiO
2outward, also containing iron, calcium, magnesium, copper etc.; If your jewel is color be then for color gloss changes with angle, if the opal of white or color are glassy lustre or wax gloss, is then general jewel; Structure has compact massive, granular, earthy, stalactitic, concretion forms and cellular; It is the fiery Ou Po of the Hei Oupo of background color, the Bai Oupo be creamy white, salmon pink that background color has with black; Opal has unique natural nano level microcellular structure, has powerful adsorption function, has again the speciality of release air negative oxgyen ion, can discharge 1000/cm
3natural negative oxygen ion.
Concave-convex clay rod: another name palygorskite or Palygorskite, be a kind of chain layer structure containing Shuifu County's magnesium silicate clay minerals, desirable chemical formula is Mg
5(H
2o)
4[Si
4o
10]
2(OH)
2, chemical composition theoretical value is that MgO accounts for 23.8%, SiO
2account for 56.96%, H
2o accounts for 19.21%, due to Al
3+, Fe
3+isomorphic replacemnt, forms aluminium attapulgite and the mutation of iron attapulgite, usually exist with Concave-convex clay rod, divided by containing outside attapulgite, often containing mineral such as montmorillonite, kaolin, hydromica, sepiolite, quartz, opal and carbonates, attapulgite form is for being hair shape or threadiness, and be generally woollen blanket shape or earthy aggregate, Mohs' hardness is 2-3, and proportion is 2.05-2.32, because attapulgite has unique crystal structure, there is again many special materializations and processing performance, if cation interchangeability, water imbibition, decolourising property, specific area are 9.6-36m
2/ g, and colloid index and expansion capacity, make it in environmental protection (as sewage, purification, the deodorizing of ight soil and sewage), chemical industry, decolouring, binding agent, duplicate, casting, silicate industry, medicine is (as removing aspergillus flavus B, purification dextrin, except deproteinized residue), agricultural chemicals, chemical fertilizer is (as farm chemical carrier, make dry stable potash fertilizer and amine fertilizer), construction material is (as coating, chemical enamel, materials for wall etc.), as high-quality stream slurry raw material in deep-sea oil and drilling well and geothermal drilling, printing is (as printing paper, manifolding Reiceiver sheet, reactive dye, printed base plate, quality image composite), atomic energy industry (namely making atomic radiations mass treatment) etc., of many uses.The present invention mainly utilizes the adhesive property of Concave-convex clay rod and stronger adsorption function, and water suction, deodorizing, purification characteristic.
Sea-gull stone: English name Health; Main component is CaO, SiO
2and variable valency metal Fe; Internal structure has the hole of 20-60nm, therefore possesses powerful adsorption function; When water in air fractionated molecule enters sea-gull stone internal capillary, hydrone is ionized by the electric microfield that the iron that appraises at the current rate produces, and produce natural negative oxygen ion, every cubic centimetre of negative oxygen ion concentration reaches 1700, and sea-gull stone inside is containing a small amount of TiO simultaneously
2, therefore there is photoelectrocatalysis effect, can harmful bacteria, viral kill in air, according to test, sea-gull stone to staphylococcus aureus, Escherichia coli, white read coccus, hay bacillus antibiotic rate up to more than 90%.
Medical stone: English Maifanshi by name, the long-lived stone that has another name called, Shen Xianshi, refining mountain stone, gingival cyst of mucous gland in the newborn sand, bean dregs, formal name used at school is adamellite, is a kind of natural silicates mineral; Main chemical compositions is SiO
2, Al
2o
3, Fe
2o
3, FeO, MgO, CaO, K
2o, Na
2o, TiO
2, P
2o
5, macroelement is K, Na, Ca, Mg, Cu, Mo and 58 kinds of elements such as micronutrient boron, germanium, zinc, tin, gallium, chromium, nickel, indium, vanadium, cobalt, niobium, tantalum, zirconium, selenium, beryllium, barium, strontium and rare-earth elements of lanthanum, cerium, yttrium, ytterbium; The aperture surface area of medical stone is large especially, 1 gram of medical stone has the aperture surface area of hundreds of square metre, than many 20,000 times of equal 1 gram of active carbon specific area, therefore medical stone has and reaches more than 95% to harmful bacteria, colibacillary adsorption rate, produces air negative oxgyen ion simultaneously.
Diatomite: English Diatomitel by name; Chemical formula is SiO
2.nH
2o; Chemical composition is SiO
2, containing a small amount of Al
2o
3, Fe
2o
3, CaO, MgO etc. and organic, wherein SiO
2account for more than 80%, be up to 94%; Physical characteristic is density is 1.9-2.3g/cm
3, bulk density is 0.34-0.65g/cm
3, specific area is 40-65m
2/ g, pore volume is 0.45-0.98m
3, water absorption rate is 2-4 times of own vol, and fusing point is 1050 DEG C-1750 degrees Celsius, observes the structure of special porous under Electronic Speculum; Because diatom is a kind of special plant in ocean, on the ancient times earth, more than 70% oxygen is that diatom is made, and diatomite is made up of diatom, and therefore it has the function of release air negative oxgyen ion.
Sepiolite: English Sepiolite by name; Chemical formula is (SiO
2) (Mg
8) O
30(OH)
4(OH
2)
4.8H
2o; Mineral density is 2-2.5g/cm
3, specific area is 900m greatly
2/ g; Sepiolite is a kind of fibrous hydrous magnesium silicate, and in white, light gray, the color such as pale yellow, some shapes are as soil block, and some shapes become a strange cot or tuberculosis building, and under Electronic Speculum, can see is got together by countless silk lines up sheet; Water imbibition is greater than 150% of own wt, limbers up after water suction, hardening again after drying.Sepiolite has that corrosion resistance, radioresistance and heat endurance are strong, decolouring, heat insulation, insulation, but containing a small amount of asbestos (about 5-30%), need to remove asbestos in processing technology.
The clean ball of this health negative oxygen ion evil spirit is obtained to through Homogeneous phase mixing and by granulator by the clean ball raw materials of health negative oxygen ion evil spirit, and technique simply, is easily produced; Here the clean ball granule size of health negative oxygen ion evil spirit is 1-5mm, moisture content percentage by weight is no more than 10%, ensure that the firmness of the clean ball of health negative oxygen ion evil spirit made, non-friable.The clean ball granule size of preferred health negative oxygen ion evil spirit is 2-3mm.The clean ball of negative oxygen ion evil spirit can discharge the air negative oxgyen ion of high concentration naturally lastingly, and interior releasing negative oxygen ion per second reaches as high as 9600/cm
3, 4000-5000/cm under usual conditions, can be remained on lastingly
3; The large far infrared of normal emittance can be launched simultaneously, normal emittance is 0.88, the far infrared wavelength that its far infrared wavelength and human body send is close, wave band is 4-16 micron, and stability is good, is beneficial to and improves blood of human body microcirculation, promote human metabolism, improve immunity.
As shown in Figure 1, this health negative oxygen ion evil spirit clean ball health care bag, comprise the surrounding layer 1 be made up of gas permeable material, the clean ball 2 of some health negative oxygen ions evil spirit is packaged with in surrounding layer 1, being convenient to just through surrounding layer 1, negative oxygen ion and far infrared outwards to be discharged without the need to tearing surrounding layer 1 when the clean ball 2 of health negative oxygen ion evil spirit uses, adding the convenience of use; Here surrounding layer 1 is attached with can the plant source extract of releasing negative oxygen ion, improves the release concentration of negative oxygen ion.
The preparation method of the clean ball of this health negative oxygen ion evil spirit, comprises the steps: A, premix: the powdered granule choosing needed raw material as required, is then mixed by various powdered granule; B, granulation: adopt facility for granulating to be granulated by mixed powdered granule, acquisition degree size is the spherical particle of 1-5mm; C, finished product: spherical particle is carried out drying, the clean ball of obtained health negative oxygen ion evil spirit, flow process is simple, is convenient to management.The clean ball granule size of preferred health negative oxygen ion evil spirit is 2-3mm.
Particularly, the preparation process of the powdered granule of often kind of raw material is here as follows: 1. carry out decontamination process according to the impurity content of the tcrude ore of often kind of raw material and obtain tcrude ore up to standard, high-temperature instantaneous sterilization sterilization is carried out to tcrude ore up to standard, then disintegrating machine coarse crushing is used, cross 30-50 mesh sieve (preferential 40 mesh sieves), obtain 30-50 order (preferential 40 mesh sieves) rough powder; 2. by 30-50 order (preferential 40 mesh sieves) rough powder jaw crusher second-time breakage, cross 250-350 mesh sieve (preferably 300 mesh sieves), obtain 250-350 order (preferably 300 orders) mineral powder granular; Then 250-350 order (preferably 300 orders) mineral powder granular periodic is stirred cylinder type wet ball mill and carry out circular grinding, carry out drying with freezing type drier again, obtained particle diameter is no more than the mineral powder granular of 50 microns (preferably more than 40 microns); 3. mineral powder granular flat air flow crusher particle diameter being no more than 50 microns (preferably more than 40 microns) processes, wherein interior bleed pressure 0.7-0.9Mpa, charging aperture pressure 0.5Mpa, ending breeze obtains the powdered granule that particle diameter is no more than 40 microns (preferably more than 20 microns), technique is simple, convenient for production.
Experimental test data:
1, the survey report provided of and industrial electroheat product quality supervision and inspection center Wuhan Product Quality Supervision and Inspection Institute infrared through country: with reference to GB/T7287-2008 " infrared radiation heater test method ", the present invention reaches 0.88 to total emissivity, relative radiation power spectrum is at infrared emission wavelength scope 14-16 micron, normal human's far infrared wavelength is at 5.0-15.0 micron, there is resonance in both, is conducive to human body and improves microcirculation.
2, the survey report provided of and industrial electroheat product quality supervision and inspection center Wuhan Product Quality Supervision and Inspection Institute infrared through country: the present invention has carried out detecting for five times under friction or dither state, every cubic centimetre of negative oxygen ion release number still at 650, and detects concentration of the present invention in a stationary situation at 3000/cm
3.
3, through Hangzhou Zheng Xiao car detailing repacking company's Site Detection 44 samples of the present invention, in the highest every cc of air, negative oxygen ion concentration is 9600, and on average every cubic centimetre of release air negative oxgyen ion concentration is at 4273.
The examining report (examining report is numbered 20150073986) of the relevant formaldehyde removing ability 4, provided through China Guangzhou Analysis &. Test Center: before putting into sample of the present invention, the concentration of formaldehyde is 1.47mg/m
3, the concentration recording formaldehyde after putting into the sample of invention after 24 hours is 0.081mg/m
3, under experimental condition, formaldehyde clearance 94.5%.
Specific embodiment described herein is only to the explanation for example of the present invention's spirit.Those skilled in the art can make various amendment or supplement or adopt similar mode to substitute to described specific embodiment, but can't depart from spirit of the present invention or surmount the scope that appended claims defines.
Although more employ the term such as surrounding layer 1, the clean ball 2 of health negative oxygen ion evil spirit herein, do not get rid of the possibility using other term.These terms are used to be only used to describe and explain essence of the present invention more easily; The restriction that they are construed to any one additional is all contrary with spirit of the present invention.
Claims (11)
1. the clean ball raw materials of health negative oxygen ion evil spirit, it is characterized in that, this raw materials comprises following component: any one or two kinds in tourmaline and six ring stones, in opal, sea-gull stone, medical stone and diatomite any one or multiple, and cohesive material.
2. the clean ball raw materials of health negative oxygen ion evil spirit according to claim 1, it is characterized in that, this raw materials also comprises absorbent material.
3. the clean ball raw materials of health negative oxygen ion evil spirit according to claim 2, it is characterized in that, described cohesive material is Concave-convex clay rod, and described absorbent material is sepiolite.
4. the clean ball raw materials of health negative oxygen ion evil spirit according to claim 3, it is characterized in that, this raw materials comprises the component of following portions by weight: tourmaline 15-25, six ring stone 30-40, opal 5-15, Concave-convex clay rod 25-35 and diatomite 3-8.
5. the clean ball raw materials of health negative oxygen ion evil spirit according to claim 3, it is characterized in that, described tourmaline, six ring stones, opal, Concave-convex clay rod, sea-gull stone, medical stone, diatomite and sepiolite are powdered granule, and the particle diameter of powdered granule is no more than 40 microns.
6. one kind adopts the clean ball raw materials of health negative oxygen ion evil spirit in claim 1-5 described in any one through Homogeneous phase mixing and the clean ball of health negative oxygen ion evil spirit obtained by granulator.
7. the clean ball of health negative oxygen ion evil spirit according to claim 6, is characterized in that, the granule size of the described clean ball of health negative oxygen ion evil spirit is 1-5mm; The moisture content percentage by weight of the described clean ball of health negative oxygen ion evil spirit is no more than 10%.
8. the health negative oxygen ion evil spirit clean ball health care bag containing the clean ball of health negative oxygen ion evil spirit described in claim 6 or 7, it is characterized in that, comprise the surrounding layer (1) be made up of gas permeable material, in described surrounding layer (1), be packaged with the clean ball (2) of some health negative oxygen ions evil spirit.
9. health negative oxygen ion according to claim 8 evil spirit clean ball health care bag, is characterized in that, described surrounding layer (1) is attached with can the plant source extract of releasing negative oxygen ion.
10. adopt the clean ball raw materials of the evil spirit of the health negative oxygen ion in claim 1-5 described in any one to prepare a preparation method for the clean ball of health negative oxygen ion evil spirit, it is characterized in that, this preparation method comprises the steps:
A, premix: the powdered granule choosing needed raw material as required, then mix various powdered granule;
B, granulation: adopt facility for granulating to be granulated by mixed powdered granule, acquisition degree size is the spherical particle of 1-5mm;
C, finished product: spherical particle is carried out drying, the clean ball of obtained health negative oxygen ion evil spirit.
The preparation method of the clean ball of 11. health negative oxygen ion evil spirit according to claim 10, it is characterized in that, the preparation process of the powdered granule of often kind of raw material is as follows:
1. carry out decontamination process according to the impurity content of the tcrude ore of often kind of raw material and obtain tcrude ore up to standard, high-temperature instantaneous sterilization sterilization is carried out to tcrude ore up to standard, then uses disintegrating machine coarse crushing, cross 30-50 mesh sieve, obtain the rough powder of 30-50 order;
2. by the second-time breakage of rough for 30-50 order powder jaw crusher, cross 250-350 mesh sieve, obtain 250-350 order mineral powder granular; Then 250-350 order mineral powder granular periodic is stirred cylinder type wet ball mill and carry out circular grinding, then carry out drying with freezing type drier, obtained particle diameter is no more than the mineral powder granular of 50 microns;
3. mineral powder granular flat air flow crusher particle diameter being no more than 50 microns processes, bleed pressure 0.7-0.9Mpa, charging aperture pressure 0.5Mpa wherein, and ending breeze obtains the powdered granule that particle diameter is no more than 40 microns.
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CN104072084A (en) * | 2014-06-30 | 2014-10-01 | 南通蛇类治疗研究所 | Nano mineral powder multiple-effect elastic ceramic ware |
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CN107051154A (en) * | 2017-03-20 | 2017-08-18 | 吴瑛 | Negative-ion energy liquid and its application |
CN109422543A (en) * | 2017-08-21 | 2019-03-05 | 王东 | A kind of preparation method of the dedicated Diatomite-based Porous Ceramic Balls of health pillow |
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