CN105543743B - A kind of process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy - Google Patents

A kind of process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy Download PDF

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CN105543743B
CN105543743B CN201610041123.9A CN201610041123A CN105543743B CN 105543743 B CN105543743 B CN 105543743B CN 201610041123 A CN201610041123 A CN 201610041123A CN 105543743 B CN105543743 B CN 105543743B
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electric current
passed
treatment
solution
square billet
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CN105543743A (en
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何立子
朱颖晖
崔建忠
郭雅萍
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Northeastern University China
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/057Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with copper as the next major constituent

Abstract

A kind of electric current solid-solution and aging heat treatment process of 7050 aluminium alloy, belongs to technical field of metal material heat treatment, specifically includes:(1) Homogenization Treatments:While 7050 aluminium alloy cast ingots are passed through into direct current, Homogenization Treatments are carried out, room temperature is air-cooled to;(2) hot extrusion:(3) solution treatment:While square billet is passed through into alternating current, solution treatment is carried out, at room temperature water cooling;(4) Ageing Treatment:While square billet is passed through into alternating current, Ageing Treatment is carried out.Present invention process method, reasonably the heating-up temperature and soaking time of control electric current intensity, homogenization, solution treatment and Ageing Treatment, on the premise of heat treatment energy consumption is significantly reduced, obtain significant solid solution strengthening effect, the workpiece of excellent mechanical property is finally obtained, applied to industrial production.

Description

A kind of process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy
Technical field
The invention belongs to technical field of metal material heat treatment, and in particular to a kind of electric current solid solution aging of 7050 aluminium alloy Process of thermal treatment method.
Background technology
Aluminium alloy is mainly strengthened by Precipitation, and the solution treatment before timeliness has weight to follow-up ag(e)ing process The influence wanted, therefore the quantity that increases Age-prrcipitation Phase carries to reach often through the degree of super saturation for improving Alloy solid solution The purpose of high strengthening effect.The solid solubility temperature of traditional Deformation structure is far below non-equilibrium low melting eutecticses point, causes thick compound It mutually can not thoroughly dissolve, the combination property to alloy is had a negative impact.The solute degree of super saturation that alloy quenching is obtained Both it is relevant with the composition of alloy, it is also relevant with solid solution degree.Therefore, on the premise of alloying element total content is not improved, how The degree of supersaturation of solid solution is improved, thick non-cementing crystalline phase is reduced, to improving Precipitation degree and improving break resistance tool There is positive effect.
Traditional solution treatment is that one kind is incubated a period of time under low-melting-point eutectic fusion temperature, then quick cooling Method to obtain certain degree of supersaturation.With the raising and the extension of solution time of solid solubility temperature, the satiety of Alloy solid solution It can be correspondingly improved with degree, but energy consumption is very big.Chen Kanghua etc. takes the Intensive intervention method progressively heated up, breaches low The eutectic point of melting eutectic, it is to avoid burning, so as to improve the Precipitation degree of alloy and improve break resistance. This Intensive intervention method is to improve an effective way of aluminium alloy combination property, especially significantly improves stress corrosion resistant Performance, but do not substantially reduce the higher temperature solid solution time, i.e., do not reduce the energy consumption of solution treatment.
Ageing Treatment is that the workpiece after solution hardening is kept into appropriate time under room temperature or higher temperature, to improve its power The method for learning performance.At present frequently with aging treatment process have:Single-stage aging (T6) has highest intensity, but crystal boundary is chain The continuous precipitate of shape, with higher Sensitivity of Stress Corrosion and relatively low fracture toughness;Two-stage time effect (T76, T74 and T73 the continuity of Grain Boundary Precipitates) is destroyed, is roughened the particle in crystal grain, reduces stress corrosion and Peeling Corrosion Sensitiveness, also improves fracture toughness, but sacrifice partial intensities;Three-step aging (T77) can by special three-step aging, return Return again timeliness (RRA processing) and deformation three kinds of methods of heat treatment to realize, be after peak value timeliness plus the high-temperature process of a short time (recurrence), makes transgranular hardening constituent weight molten, peak value timeliness (timeliness again) is then carried out again, alloy is being kept the intensity of T6 states The stress corrosion resistant ability close to T73 states is obtained simultaneously.Although above aging treatment method is improved to a certain extent The tissue and performance of alloy, but still there is very big energy consumption problem.
Liu Wei etc. applies electric field in 2091 aluminium lithium alloy Homogenization Process, it is found that the volume fraction of second phase particles subtracts Less, size diminishes, and the plasticity of alloy is obviously improved.Liu Beixing etc. has found to apply in the predeformation ag(e)ing process of 1420 aluminium lithium alloys Intensity can be improved by strengthening electrostatic field, refine the δ ' phases of Dispersed precipitate.
Existing electric field processing device haves the shortcomings that temperature distributing disproportionation, sample size be small, equipment is complicated huge, can only Doing pat is used for scientific research, without construction value.During the application of electric field, the generation of electric current is not (general Can detect only≤50 μm), and electric current directly or indirectly promotes the mobility of particle in joule heating effect mode, because This understands that electric current is greater than field effect to the effect of Particles Moving.But, estimated current processing is used for Cu-Cr-Zr and steel It is few about the application in terms of aluminium alloy electric current timeliness in iron material.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of technique of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy Method, is a kind of continuous solid solution of aluminium alloy and aging treatment process method for being applied to quickly heat, save energy consumption.
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys of the present invention, specifically includes following steps:
Step 1, Homogenization Treatments:
7050 aluminium alloy cast ingots are put into electric current heat-treatment furnace, electric current is passed through to ingot casting, 460~480 DEG C, guarantor are heated to 20~28h of temperature, stopping is passed through electric current, is air-cooled to room temperature, obtains ingot blank, wherein, current strength is 1~500A, and current type is Direct current.
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 480~520 DEG C are preheated to, 2~4h, come out of the stove carry out extrusion molding, acquisition side is incubated Base, wherein, extrusion speed is 1.5~4.0mm/s, and extrusion ratio is 8~10, and the square billet after extruding is air-cooled to room temperature;
Step 3, solution treatment:
Square billet is put into electric current heat-treatment furnace, electric current is passed through to square billet, 450~475 DEG C are heated to, 0.3~2h is incubated, Stopping is passed through electric current, water cooling at room temperature of coming out of the stove, wherein, current strength is 1~500A, and current type is alternating current;
Step 4, Ageing Treatment:
Square billet is put into electric current heat-treatment furnace, electric current is passed through to square billet, 120~140 DEG C are heated to, 1~48h is incubated, Stopping is passed through electric current, air cooling of then coming out of the stove, wherein, current strength is 1~500A, and current type is alternating current.
Wherein,
Described electric current heat-treatment furnace is air circulation heat-treatment furnace;
Firing rate in the step 1, step 2, step 3 and step 4 is 1~5 DEG C/min, by the maximum of the workpiece Thickness is determined;
In the step 1, step 3 and step 4, the method for being passed through electric current is:At the two ends of 7050 aluminium alloys or square billet, lead to Cross copper fixture and be passed through electric current;
In described step 1, temperature is 465 DEG C, and soaking time is 24h;
In described step 3, current strength is 500A, and temperature is 470 DEG C, and soaking time is 20min;
In described step 4, current strength is 500A, and temperature is 120 DEG C, and soaking time is 6h.
The final performance of alloy can be produced because solution treatment stage and Stages of Aging separately or concurrently apply electric current Significantly affect, so optimal soaking time selects the peak strength corresponding time under each state.
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys of the present invention, has the beneficial effect that:
Reasonably the heating-up temperature and soaking time of control electric current intensity, homogenization, solution treatment and Ageing Treatment, are showing On the premise of writing reduction heat treatment energy consumption, significant solid solution strengthening effect is obtained, the workpiece of excellent mechanical property is finally obtained, should For industrial production.
Embodiment
In following examples, the chemical composition of 7050 alloys is shown in Table 1.
The alloy composition of table 1 7050 (wt.%)
Embodiment 1
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 460 DEG C are heated to, 20h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 470 DEG C, firing rate is 5 DEG C/min, is incubated 0.33h, stopping is passed through electric current, come out of the stove in room temperature Lower water cooling, wherein, electric current is 500A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 120 DEG C, firing rate is 5 DEG C/min, is incubated 1h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current exchanges for 500A Electricity.
Embodiment 2
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 456 DEG C are heated to, 22h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 475 DEG C, firing rate is 5 DEG C/min, is incubated 0.33h, stopping is passed through electric current, come out of the stove in room temperature Lower water cooling, wherein, electric current is 500A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 130 DEG C, firing rate is 5 DEG C/min, is incubated 6h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current exchanges for 500A Electricity.
Embodiment 3
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 470 DEG C are heated to, 24h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 450 DEG C, firing rate is 5 DEG C/min, is incubated 2h, stopping is passed through electric current, water at room temperature of coming out of the stove It is cold, wherein, electric current is 500A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 140 DEG C, firing rate is 5 DEG C/min, is incubated 24h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current exchanges for 500A Electricity.
Embodiment 4
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 475 DEG C are heated to, 26h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 460 DEG C, firing rate is 5 DEG C/min, is incubated 1h, stopping is passed through electric current, water at room temperature of coming out of the stove It is cold, wherein, electric current is 500A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 130 DEG C, firing rate is 5 DEG C/min, is incubated 2h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current is 1A alternating currents.
Embodiment 5
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 480 DEG C are heated to, 28h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 465 DEG C, firing rate is 5 DEG C/min, is incubated 1.5h, stopping is passed through electric current, come out of the stove at room temperature Water cooling, wherein, electric current is 1A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 140 DEG C, firing rate is 5 DEG C/min, is incubated 12h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current exchanges for 500A Electricity.
Embodiment 6
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 465 DEG C are heated to, 24h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 470 DEG C, firing rate is 5 DEG C/min, is incubated 0.33h, stopping is passed through electric current, come out of the stove in room temperature Lower water cooling, wherein, electric current is 1A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 120 DEG C, firing rate is 5 DEG C/min, is incubated 48h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current exchanges for 1A Electricity.
Embodiment 7
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 465 DEG C are heated to, 24h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 470 DEG C, firing rate is 5 DEG C/min, is incubated 0.33h, stopping is passed through electric current, come out of the stove in room temperature Lower water cooling, wherein, electric current is 1A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 120 DEG C, firing rate is 5 DEG C/min, is incubated 24h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current exchanges for 500A Electricity.
Embodiment 8
The process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloys, specifically includes following steps:
Step 1, Homogenization Treatments:
Size is put into air circulation heat-treatment furnace for 160 × 160mm of Φ 7050 aluminium alloy as cast condition poles, to ingot casting Two ends, 500A direct currents are passed through by copper fixture, 465 DEG C are heated to, 24h is incubated, stopping is passed through electric current, and stove is air-cooled to room Temperature, obtains ingot blank;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 500 DEG C are preheated to, 2h is incubated, carry out extrusion molding of coming out of the stove, obtain size be 10 × 200 × 12000mm square billet, wherein, extrusion speed is 3.0mm/s, and extrusion ratio is 10, and the square billet after extruding carries out air cooling, cuts Cut;
Step 3, solution treatment:
Size is put into air circulation heat-treatment furnace for 10 × 20 × 580mm square billet, to the two ends of square billet, passes through copper Fixture is passed through electric current, is heated to 470 DEG C, firing rate is 5 DEG C/min, is incubated 0.5h, stopping is passed through electric current, come out of the stove at room temperature Water cooling, wherein, electric current is 500A alternating currents;
Step 4, Ageing Treatment:
Square billet is put into air circulation heat-treatment furnace, to the two ends of square billet, electric current is passed through by copper fixture, is heated to 120 DEG C, firing rate is 5 DEG C/min, is incubated 1h, and stopping is passed through electric current, air cooling of then coming out of the stove, wherein, electric current is 1A alternating currents.
Mechanics Performance Testing is carried out to the embodiment workpiece after Ageing Treatment, as a result as shown in table 2.
The embodiment 1-8 of table 2 mechanical property result

Claims (6)

1. a kind of process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy, it is characterised in that comprise the following steps:
Step 1, Homogenization Treatments:
7050 aluminium alloy cast ingots are put into electric current heat-treatment furnace, electric current is passed through to ingot casting, 460~480 DEG C, insulation 20 are heated to ~28h, stopping is passed through electric current, is air-cooled to room temperature, obtains ingot blank, wherein, firing rate is 1~5 DEG C/min, and current strength is 1 ~500A, current type is direct current;
Step 2, hot extrusion:
Ingot blank is put into heating furnace, 480~520 DEG C are preheated to, 2~4h is incubated, carry out extrusion molding of coming out of the stove obtains square billet, Wherein, extrusion speed is 1.5~4.0mm/s, and extrusion ratio is 8~10, and the square billet after extruding is air-cooled to room temperature, wherein, heating speed Spend for 1~5 DEG C/min;
Step 3, solution treatment:
Square billet is put into electric current heat-treatment furnace, electric current is passed through to square billet, 450~475 DEG C are heated to, 0.3~2h is incubated, stopped Electric current is passed through, water cooling at room temperature of coming out of the stove, wherein, firing rate is 1~5 DEG C/min, and current strength is 1~500A, current capacity Type is alternating current;
Step 4, Ageing Treatment:
Square billet is put into electric current heat-treatment furnace, electric current is passed through to square billet, 120~140 DEG C are heated to, 1~48h is incubated, stopped Electric current is passed through, air cooling of then coming out of the stove, wherein, firing rate is 1~5 DEG C/min, and current strength is 1~500A, and current type is Alternating current.
2. the process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy according to claim 1, it is characterised in that Described electric current heat-treatment furnace is air circulation heat-treatment furnace.
3. the process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy according to claim 1, it is characterised in that In the step 1, step 3 and step 4, the method for being passed through electric current is:At the two ends of 7050 aluminium alloys or square billet, pass through copper fixture It is passed through electric current.
4. the process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy according to claim 1, it is characterised in that In described step 1, temperature is 465 DEG C, and soaking time is 24h.
5. the process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy according to claim 1, it is characterised in that In described step 3, current strength is 500A, and temperature is 470 DEG C, and soaking time is 20min.
6. the process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy according to claim 1, it is characterised in that In described step 4, current strength is 500A, and temperature is 120 DEG C, and soaking time is 6h.
CN201610041123.9A 2016-01-21 2016-01-21 A kind of process of the electric current solid-solution and aging heat treatment of 7050 aluminium alloy Expired - Fee Related CN105543743B (en)

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