CN102286714A - Preparation method of copper-nickel-tin alloy - Google Patents
Preparation method of copper-nickel-tin alloy Download PDFInfo
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- CN102286714A CN102286714A CN2011102328322A CN201110232832A CN102286714A CN 102286714 A CN102286714 A CN 102286714A CN 2011102328322 A CN2011102328322 A CN 2011102328322A CN 201110232832 A CN201110232832 A CN 201110232832A CN 102286714 A CN102286714 A CN 102286714A
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Abstract
The invention discloses a preparation method of a copper-nickel-tin alloy, and the preparation method comprises the following steps of smelting and casting, solutionizing, rough rolling, annealing, cold rolling, aging, cold rolling and other processes. In the preparation method of the copper-nickel-tin alloy disclosed by the invention, homogenization treatment is not carried out between the smelting and rough rolling, and the high-temperature short-time solid solution heat treatment is directly carried out, so that the Sn-rich phase in the alloy can be solutionized in a copper matrix, the brittle phase NixSny generated in the casting process is eliminated and the alloy has excellent plastic processing performance, thereby facilitating the subsequent processing. In addition, the rough rolling is directly carried out after the solid solution treatment, and homogenization treatment and hot rolling processes in the existing preparation methods are omitted, thus saving energy, shortening the process, improving production efficiency and lowering production cost.
Description
Technical field
The invention belongs to the Cu alloy material processing technique field, refer to a kind of adonic preparation method especially.
Background technology
Adonic is because of having advantages such as high intensity, elasticity, good conductive stability and thermal stresses relaxation property, and is subjected to people's favor deeply, is considered to high strength of new generation, snappiness, the high property copper alloy of tool development prospect.But, because Sn too high levels in the adonic, the negative segregation that in the melting and casting process, has serious dendritic segregation and Sn, make its poor processability, product performance are inhomogeneous, surface quality is poor, before machining deformation, need carry out long high temperature annealing, be that homogenizing is handled (needing insulation 25～30 hours usually), energy consumption is big, technical process is long, production efficiency is low, production cost is high, be unfavorable for suitability for industrialized production.All adopted vacuum melting as domestic patent of invention CN87100204, CN91105605, also had the uneven components phenomenon in the as-cast structure, handled so need carry out the long homogenizing of high temperature.
In addition, some patents have been carried out some and have been improved on the basis of adonic both at home and abroad, to improve some performance of the inhomogeneous and alloy of alloy casting state structural constituent.For example domestic patent CN200410053071 adopts spray precipitation moulding method to produce the Cu-15Ni-8Sn-3.5Y alloy, this patent is less by the adonic component segregation of this method preparation, alloy functional, still, this method is difficult to realize the industrialization production of adonic strip material.Patent CN03151047, CN101517105A, in the Cu-15Ni-8Sn alloy, add an amount of Ti element respectively and utilize the agglomerating method to prepare adonic, can effectively improve the Sn segregation of this alloy and the wear resistance and the intensity of raising alloy, but this type of adonic is mainly used in the casting sliding shaft sleeve.
Summary of the invention
At the problem that prior art exists, the invention provides a kind of adonic preparation method who saves the energy, shortens technology, enhances productivity.
For achieving the above object, the preparation method of adonic of the present invention, concrete steps are as follows: 1) melting ingot casting: alloy is carried out melting, insulation, degasification, slagging-off in smelting furnace, right
After carry out ingot casting;
2) solution treatment: ingot casting is heated to 800-900 ℃ in being connected with the process furnace of protective gas, is incubated to carry out water-cooled after 2-5 hour;
3) roughing: will carry out the roughing distortion of 80-85% through the alloy of solution treatment;
4) process annealing: the alloy after the roughing is packed in the heat-treatment of annealing stove, carry out process annealing, annealing temperature is 600-700 ℃, is incubated to carry out furnace cooling after 4-10 hour;
5) cold rolling: the alloy of process annealing is carried out cold rolling, cold rolling working modulus 50-60%;
6) ageing treatment: the alloy after cold rolling carries out ageing treatment, and aging temp is 350-400 ℃, and soaking time is 6-8h, and the type of cooling is an air cooling;
7) cold rolling: will carry out through the alloy of ageing treatment cold rolling, cold rolling working modulus 25-30%.
Further, the melting ingot casting step of step 1) is specially: the electrolysis copper and mickel is put into smelting furnace together, be heated to after melt melts fully, add insulating covering agent insulation 5～10min, after degasification, removal of impurities, cover the calcination charcoal again, behind the insulation 10min, the Cu-P master alloy, Zn, the Sn that add oven dry fully stir, leave standstill tapping casting behind 5～10min, and pouring temperature is 1200 ℃-1250 ℃.
The preparation method of cupronickel tin alloy of the present invention is carrying out solution treatment between high temperature, short time behind the melting ingot casting, the rich Sn in the alloy is solidly soluted in the copper matrix mutually, eliminates the fragility phase Ni that produces in castingprocesses
xSn
y, make alloy have good plasticity, help follow-up processing.In addition, directly roughing after solution treatment has been saved homogenizing processing, hot-rolled process among the existing preparation method, thereby has been saved the energy, has shortened technical process, has improved production efficiency, has reduced production cost.
Description of drawings
Fig. 1 is an adonic preparation method's of the present invention FB(flow block);
Fig. 2 is 1 of the metallograph of alloy of the present invention after solution treatment;
Fig. 3 is 2 of the metallograph of alloy of the present invention after solution treatment;
Fig. 4 is 3 of the metallograph of alloy of the present invention after solution treatment;
Fig. 5 is the metallograph of alloy after homogenizing is handled.
Embodiment
Embodiment 1:
As shown in Figure 1, adonic preparation method of the present invention, concrete steps are:
1. melting ingot casting: adopt antivacuum induction furnace to carry out melting.The addition sequence of alloy is: electrolytic copper, pure nickel, be heated to after melt melts fully, and add insulating covering agent (charcoal) insulation 5～10min, after degasification, removal of impurities, cover the thick calcination charcoal in the 10mm left and right sides again.Behind the insulation 10min, add Cu-P, Zn, the Sn of oven dry, fully stir, leave standstill tapping casting behind 5～10min, pouring temperature is 1200 ℃-1250 ℃.
2. solution treatment: ingot casting carries out solution treatment in being connected with the process furnace of protective gas, and solid solubility temperature is 800 ℃, and soaking time is 2-5h, and the type of cooling is a water-cooled.
3. roughing: will carry out the roughing distortion of 80-85% through the alloy of solution treatment.
4. process annealing: the alloy after the roughing is packed in the heat-treatment of annealing stove, carry out process annealing, annealing temperature is 600-700 ℃, soaking time 4-10h, and the type of cooling is a furnace cooling.
5. cold rolling: the alloy of process annealing is carried out cold rolling, cold rolling working modulus 50-60%.
6. ageing treatment: the alloy after cold rolling carries out ageing treatment, and aging temp is 350-400 ℃, and soaking time is 6-8h, and the type of cooling is an air cooling.
7. cold rolling: the alloy of ageing treatment is carried out cold rolling, cold rolling working modulus 25-30%.
Obtain adonic through above-mentioned steps, its 50 μ m metallograph as shown in Figure 2.
Embodiment 2:
1. melting ingot casting: adopt antivacuum induction furnace to carry out melting.The addition sequence of alloy is: electrolytic copper, pure nickel, be heated to after melt melts fully, and add insulating covering agent (charcoal) insulation 5～10min, after degasification, removal of impurities, cover the thick calcination charcoal in the 10mm left and right sides again.Behind the insulation 10min, add Cu-P, Zn, the Sn of oven dry, fully stir, leave standstill tapping casting behind 5～10min, pouring temperature is 1200 ℃-1250 ℃.
2. solution treatment: ingot casting carries out solution treatment in being connected with the process furnace of protective gas, and solid solubility temperature is 850 ℃, and soaking time is 2-5h, and the type of cooling is a water-cooled.
3. roughing: will carry out the roughing distortion of 80-85% through the alloy of solution treatment.
4. process annealing: the alloy after the roughing is packed in the heat-treatment of annealing stove, carry out process annealing, annealing temperature is 600-700 ℃, soaking time 4-10h, and the type of cooling is a furnace cooling.
5. cold rolling: the alloy of process annealing is carried out cold rolling, cold rolling working modulus 50-60%.
6. ageing treatment: the alloy after cold rolling carries out ageing treatment, and aging temp is 350-400 ℃, and soaking time is 6-8h, and the type of cooling is an air cooling.
7. cold rolling: the alloy of ageing treatment is carried out cold rolling, cold rolling working modulus 25-30%.
Obtain adonic through above-mentioned steps, its 50 μ m metallograph as shown in Figure 3.
Embodiment 3:
1. melting ingot casting: adopt antivacuum induction furnace to carry out melting.The addition sequence of alloy is: electrolytic copper, pure nickel, be heated to after melt melts fully, and add insulating covering agent (charcoal) insulation 5～10min, after degasification, removal of impurities, cover the thick calcination charcoal in the 10mm left and right sides again.Behind the insulation 10min, add Cu-P, Zn, the Sn of oven dry, fully stir, leave standstill tapping casting behind 5～10min, pouring temperature is 1200 ℃-1250 ℃.
2. solution treatment: ingot casting carries out solution treatment in being connected with the process furnace of protective gas, and solid solubility temperature is 900 ℃, and soaking time is 2-5h, and the type of cooling is a water-cooled.
3. roughing: will carry out the roughing distortion of 80-85% through the alloy of solution treatment.
4. process annealing: the alloy after the roughing is packed in the heat-treatment of annealing stove, carry out process annealing, annealing temperature is 600-700 ℃, soaking time 4-10h, and the type of cooling is a furnace cooling.
5. cold rolling: the alloy of process annealing is carried out cold rolling, cold rolling working modulus 50-60%.
6. ageing treatment: the alloy after cold rolling carries out ageing treatment, and aging temp is 350-400 ℃, and soaking time is 6-8h, and the type of cooling is an air cooling.
7. cold rolling: the alloy of ageing treatment is carried out cold rolling, cold rolling working modulus 25-30%.
Obtain adonic through above-mentioned steps, its 50 μ m metallograph as shown in Figure 4.
Existing adonic preparation method through behind the long homogenizing annealing, still has Ni at the adonic ingot casting in the alloy
xSn
yCompound (as shown in Figure 5) can make alloy embrittlement, causes the limit portion cracking of alloy.And alloy by solution treatment between high temperature, short time after, the rich Sn in the alloy is solidly soluted in the copper matrix mutually, eliminate the fragility phase Ni that in castingprocesses, produces
xSn
y(shown in Fig. 2-4), solve thick dendritic crystal in the adonic as-cast structure, problems such as component segregation is serious, the more important thing is and saved hot rolling and the homogenizing annealing operation in the course of processing, saved the energy, shortened technology, improved production efficiency, for suitability for industrialized production is saved production cost.The adonic that obtains simultaneously and isonomic other alloy phase ratios, intensity is higher, and plasticity is better, and meanwhile, elasticity also improves greatly, is applicable to the short flow process processing of adonic.
Table 1 is method of the present invention and existing preparation method contrast, and the present invention shortens 2 of technologies as shown in Table 1, has efficient, energy-conservation, short flow process characteristics.
The contrast of table 1. alloy preparation technology step number
Table 2 is method of the present invention and existing preparation method contrast, and the present invention existing preparation method on the tensile strength of alloys of manufacturing and elongation parameter all is significantly improved as shown in Table 2.
The contrast of table 2 alloy property
| Comparative alloy | Tensile strength MPa | Elongation % |
| Embodiment 1 | 927 | 10 |
| Embodiment 2 | 1031 | 7.1 |
| Embodiment 3 | 968 | 6.9 |
| Cuprum-nickel-stannum C7270 | 835-980 | ≥3.0 |
It is to be noted that the concrete parameter in each step can make suitable adjustment according to actual needs, in the various distortion that meet inventive concept all within protection scope of the present invention.
Claims (2)
1. the preparation method of an adonic is specially:
1) melting ingot casting: alloy is carried out melting, insulation, degasification, slagging-off in smelting furnace, carry out ingot casting then;
2) solution treatment: ingot casting is heated to 800-900 ℃ in being connected with the process furnace of protective gas, is incubated to carry out water-cooled after 2-5 hour;
3) roughing: will carry out the roughing distortion of 80-85% through the alloy of solution treatment;
4) process annealing: the alloy after the roughing is packed in the heat-treatment of annealing stove, carry out process annealing, annealing temperature is 600-700 ℃, is incubated to carry out furnace cooling after 4-10 hour;
5) cold rolling: the alloy of process annealing is carried out cold rolling, cold rolling working modulus 50-60%;
6) ageing treatment: the alloy after cold rolling carries out ageing treatment, and aging temp is 350-400 ℃, and soaking time is 6-8h, and the type of cooling is an air cooling;
7) cold rolling: will carry out through the alloy of ageing treatment cold rolling, cold rolling working modulus 25-30%.
2. the preparation method of adonic as claimed in claim 1, it is characterized in that, the melting ingot casting step of step 1) is specially: the electrolysis copper and mickel is put into smelting furnace together, be heated to after melt melts fully, add insulating covering agent insulation 5～10min, after degasification, removal of impurities, cover the calcination charcoal again, behind the insulation 10min, add Cu-P master alloy, Zn, the Sn of oven dry, fully stir, leave standstill tapping casting behind 5～10min, pouring temperature is 1200 ℃-1250 ℃.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102747238A (en) * | 2012-07-18 | 2012-10-24 | 江西理工大学 | Production method of microalloyed tin bronze alloy |
| CN105229180A (en) * | 2013-03-14 | 2016-01-06 | 美题隆公司 | Superstrength copper-nickel-tin alloy |
| CN105886807A (en) * | 2016-06-01 | 2016-08-24 | 金川集团股份有限公司 | Preparation method for high-strength wear-resistant alloy Cu-15Ni-8Sn |
| CN106736307A (en) * | 2017-02-11 | 2017-05-31 | 兴化市兴成铜业有限公司 | A kind of high accuracy complexity copper-nickel alloy ternary alloy three-partalloy production technology |
| CN108642419A (en) * | 2018-05-31 | 2018-10-12 | 太原晋西春雷铜业有限公司 | A kind of corson alloy band and preparation method thereof that bending is excellent |
| CN113278846A (en) * | 2021-04-06 | 2021-08-20 | 中铝材料应用研究院有限公司 | Wear-resistant copper-nickel-tin alloy and preparation method thereof |
| CN113564415A (en) * | 2021-07-27 | 2021-10-29 | 中北大学 | Copper-nickel-tin-silicon alloy and preparation method and application thereof |
| CN113755716A (en) * | 2021-09-07 | 2021-12-07 | 大连理工大学 | High-performance copper-nickel-tin alloy and preparation method thereof |
| CN114507794A (en) * | 2022-02-11 | 2022-05-17 | 无锡日月合金材料有限公司 | Copper-nickel-tin alloy material for high-elasticity element and preparation method thereof |
| CN115927986A (en) * | 2022-12-28 | 2023-04-07 | 北冶功能材料(江苏)有限公司 | Hot processing method of homogeneous high-strength copper-nickel-tin alloy section |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3941620A (en) * | 1974-07-11 | 1976-03-02 | Olin Corporation | Method of processing copper base alloys |
| JPS52136829A (en) * | 1972-10-10 | 1977-11-15 | Western Electric Co | Method of making copperr nickell tin strip materials |
| US20040042928A1 (en) * | 2002-08-30 | 2004-03-04 | Fumiaki Sasaki | High strength copper alloy and manufacturing method therefor |
| CN1924049A (en) * | 2005-09-02 | 2007-03-07 | 日立电线株式会社 | Copper alloy material and method of making same |
| CN101824560A (en) * | 2009-03-05 | 2010-09-08 | 日立电线株式会社 | Copper alloy material and a method for fabricating the same |
| JP2010285671A (en) * | 2009-06-15 | 2010-12-24 | Hitachi Cable Ltd | High-strength and high-electrical conductivity copper alloy and method of producing the same |
| CN102146533A (en) * | 2011-03-25 | 2011-08-10 | 富威科技（吴江）有限公司 | Formula of copper nickel tin alloy strip and production process |
-
2011
- 2011-08-15 CN CN2011102328322A patent/CN102286714A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52136829A (en) * | 1972-10-10 | 1977-11-15 | Western Electric Co | Method of making copperr nickell tin strip materials |
| US3941620A (en) * | 1974-07-11 | 1976-03-02 | Olin Corporation | Method of processing copper base alloys |
| US20040042928A1 (en) * | 2002-08-30 | 2004-03-04 | Fumiaki Sasaki | High strength copper alloy and manufacturing method therefor |
| CN1924049A (en) * | 2005-09-02 | 2007-03-07 | 日立电线株式会社 | Copper alloy material and method of making same |
| CN101824560A (en) * | 2009-03-05 | 2010-09-08 | 日立电线株式会社 | Copper alloy material and a method for fabricating the same |
| JP2010285671A (en) * | 2009-06-15 | 2010-12-24 | Hitachi Cable Ltd | High-strength and high-electrical conductivity copper alloy and method of producing the same |
| CN102146533A (en) * | 2011-03-25 | 2011-08-10 | 富威科技（吴江）有限公司 | Formula of copper nickel tin alloy strip and production process |
Non-Patent Citations (1)
| Title |
|---|
| 蔡薇等: "Cu-10Ni-4.5Sn弹性合金的固溶时效与组织性能研究", 《稀有金属》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102747238A (en) * | 2012-07-18 | 2012-10-24 | 江西理工大学 | Production method of microalloyed tin bronze alloy |
| CN105229180A (en) * | 2013-03-14 | 2016-01-06 | 美题隆公司 | Superstrength copper-nickel-tin alloy |
| CN105229180B (en) * | 2013-03-14 | 2019-09-17 | 美题隆公司 | Superhigh intensity copper-nickel-tin alloy |
| CN105886807A (en) * | 2016-06-01 | 2016-08-24 | 金川集团股份有限公司 | Preparation method for high-strength wear-resistant alloy Cu-15Ni-8Sn |
| CN106736307A (en) * | 2017-02-11 | 2017-05-31 | 兴化市兴成铜业有限公司 | A kind of high accuracy complexity copper-nickel alloy ternary alloy three-partalloy production technology |
| CN108642419A (en) * | 2018-05-31 | 2018-10-12 | 太原晋西春雷铜业有限公司 | A kind of corson alloy band and preparation method thereof that bending is excellent |
| CN113278846A (en) * | 2021-04-06 | 2021-08-20 | 中铝材料应用研究院有限公司 | Wear-resistant copper-nickel-tin alloy and preparation method thereof |
| CN113564415A (en) * | 2021-07-27 | 2021-10-29 | 中北大学 | Copper-nickel-tin-silicon alloy and preparation method and application thereof |
| CN113564415B (en) * | 2021-07-27 | 2022-04-01 | 中北大学 | Copper-nickel-tin-silicon alloy and preparation method and application thereof |
| CN113755716A (en) * | 2021-09-07 | 2021-12-07 | 大连理工大学 | High-performance copper-nickel-tin alloy and preparation method thereof |
| CN114507794A (en) * | 2022-02-11 | 2022-05-17 | 无锡日月合金材料有限公司 | Copper-nickel-tin alloy material for high-elasticity element and preparation method thereof |
| CN115927986A (en) * | 2022-12-28 | 2023-04-07 | 北冶功能材料(江苏)有限公司 | Hot processing method of homogeneous high-strength copper-nickel-tin alloy section |
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