CN105507078A - Wallpaper containing a volcanic rock-polylactic acid porous fiber modified acrylic resin emulsion coating - Google Patents
Wallpaper containing a volcanic rock-polylactic acid porous fiber modified acrylic resin emulsion coating Download PDFInfo
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- CN105507078A CN105507078A CN201510827400.4A CN201510827400A CN105507078A CN 105507078 A CN105507078 A CN 105507078A CN 201510827400 A CN201510827400 A CN 201510827400A CN 105507078 A CN105507078 A CN 105507078A
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- polylactic acid
- emulsion
- volcanic rock
- acrylic resin
- wallpaper
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
- C08F251/02—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof on to cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/02—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/64—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
The invention discloses wallpaper containing a volcanic rock-polylactic acid porous fiber modified acrylic resin emulsion coating. A cellulose acetate-copolymerized modified waterborne acrylic resin emulsion is adopted as a resin adhesive in coating slurry used for the wallpaper, and is stable in performance and free of toxic compounds slow in volatilization such as formaldehyde. The formed coating is smooth and elastic and has waterproof, antifouling and antibacterial functions and other functions. Compared with traditional PVC paste, plasticizing temperature of the coating is lower, and the coating is more energy-saving and environmental friendly. Graphene-doped volcanic rock-polylactic acid porous fibers have functions of high strength, heat preservation, thermal insulation, sound absorption, porosity, formaldehyde removing, and the like. Adsorbability with a substrate is improved. The service lifetime of the wallpaper is effectively prolonged. The wallpaper has a certain indoor air cleaning function.
Description
Technical field
The present invention relates to wallpaper technical field, particularly relate to a kind of wallpaper containing volcanic rock-polylactic acid porous fibre modification emulsion acrylic resin coating.
Background technology
Wallpaper has another name called wallpaper, because of it, to have color various, pattern enriches, the advantage such as luxurious style, safety and environmental protection, easy construction, affordable is applied more and more extensive in house ornamentation, common wallpaper is greatly using the material such as pure paper, nonwoven fabric as base material, at its surperficial coated with resins slurry, make through operations such as high temperature plasticizing, printing embossing.
Modal coating paste is mainly made up of polyvinyl chloride resin and filler in the market, although this coating material has the advantages such as attractive and durable waterproof, but its poor air permeability, and containing organic solvent, long-time use can pollute room air, along with the raising of people's environmental consciousness, require also more and more higher to the feature of environmental protection of wallpaper, this needs to use new coating material to replace polyvinyl chloride resin undoubtedly.In recent years market emerges the water-base resin coating material of a collection of environmental protection, although this kind of material is not containing volatile organic solvent, but its gas permeability, plasticization temperature, additional functional and with the stickiness of base material etc. in still Shortcomings.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of wallpaper containing volcanic rock-polylactic acid porous fibre modification emulsion acrylic resin coating.
The present invention is achieved by the following technical solutions:
A kind of wallpaper containing volcanic rock-polylactic acid porous fibre modification emulsion acrylic resin coating, this wallpaper is made up after super-dry, plasticizing, embossing of non-woven fabrics base material and the coating paste being coated on substrate surface, and described coating paste is made up of the raw material of following weight portion: composite water soluble emulsion acrylic resin 80-100, volcanic rock micro mist 2-3, Graphene 0.01-0.02, polylactic acid slice 8-10, vinyl two stearic amide 0.1-0.2, silane coupler kh5500.1-0.2.
Described coating paste preparation method is:
(1) volcanic rock-polylactic acid porous fiber preparation: first polylactic acid slice, volcanic rock micro mist, Graphene, the two stearic amide of vinyl, silane coupler kh550 are carried out melt spinning after being uniformly mixed, making length is 80-100 μm, and diameter is the porous staple fibre of 30-50 μm;
(2) volcanic rock-polylactic acid porous fiber is dropped in composite water soluble emulsion acrylic resin, add other leftover materials after being uniformly mixed 30-50min, strong stirring mixing 4-5h, leave standstill after placing 30-40min subsequently and get final product.
Described composite water soluble emulsion acrylic resin is made up of the raw material of following weight portion: nano silicon 0.5-0.8, cellulose acetate 4-5, N, dinethylformamide 12-15, butyl acrylate 18-25, methyl methacrylate 15-20, acrylic acid 10-15, ammonium persulfate 5-8, emulsifier op-10 2-3, lauryl sodium sulfate 1-3, ammoniacal liquor are appropriate, deionized water 50-60, and preparation method is:
(1) first drop in DMF by cellulose acetate, be stirred to it and dissolve completely, drop in solution subsequently by nano silicon, closed ultrasonic dispersed with stirring 3-4h, the cellulose acetate solution obtaining blending nano silicon is for subsequent use;
(2) emulsifier op-10, lauryl sodium sulfate are dropped in reactor, add the deionized water of 10-15 weight portion subsequently, be stirred to after dissolving completely, material prepared by input step (1) and butyl acrylate, methyl methacrylate, acrylic acid, be warming up to 70-75 DEG C, be uniformly mixed 2-3h, obtain pre-emulsion for subsequent use;
(3) seed emulsion preparation: ammonium persulfate and appropriate ammoniacal liquor are dissolved in the deionized water of surplus, regulator solution pH value is 6.0-7.5, and be heated to 65-75 DEG C, then pre-emulsion prepared by this solution of 2/3 weight portion and 1/4 weight portion step (2) is got respectively, be added drop-wise in reaction vessel simultaneously, rate of addition is that 45-60 drips/min, stops dripping, obtain seed emulsion when question response system is blue-fluorescence;
(4) gained seed emulsion drips ammonium persulfate solution and the pre-emulsion of surplus again after leaving standstill 15-20min, after dropping terminates under 70-75 DEG C of condition constant temperature 50-60min, be heated to 75-80 DEG C subsequently, strong stirring mixing 1.5-2h under constant temperature, stop subsequently stirring, when emulsion naturally cools to below 50 DEG C, ammoniacal liquor regulator solution pH value is 7.0, filters discharging subsequently and get final product.
Resin adhesive in the coating paste that wallpaper of the present invention uses is cellulose acetate modification by copolymerization water-borne acrylic resin emulsion, this resin emulsion stable performance, not containing chronic volatility toxic compounds such as formaldehyde, the coating formed is smooth flexible, possesses water resistant, anti-soil, the function such as antibacterial, lower than traditional PVC paste material plasticization temperature, more energy-conserving and environment-protective, volcanic rock-polylactic acid porous the fiber of blending Graphene has high strength, insulation, heat insulation, sound-absorbing, porous, except effects such as formaldehyde, absorption affinity between enhancement and base material, effectively extend the service life of wallpaper, also certain catharsis is had to the air of indoor.
Detailed description of the invention
This embodiment wallpaper is made up after super-dry, plasticizing, embossing of non-woven fabrics base material and the coating paste being coated on substrate surface, and wherein coating paste is made up of the raw material of following weight portion: composite water soluble emulsion acrylic resin 80, volcanic rock micro mist 2, Graphene 0.01, polylactic acid slice 8, vinyl two stearic amide 0.1, silane coupler kh5500.1.
This coating paste preparation method is:
(1) volcanic rock polylactic acid porous fiber preparation: first polylactic acid slice, volcanic rock micro mist, Graphene, the two stearic amide of vinyl, silane coupler kh550 are carried out melt spinning after being uniformly mixed, making length is 80 μm, and diameter is the porous staple fibre of 30 μm;
(2) polylactic acid porous for volcanic rock fiber is dropped in composite water soluble emulsion acrylic resin, add other leftover materials after being uniformly mixed 30min, strong stirring mixing 4h, leave standstill after placing 30min subsequently and get final product.
Wherein composite water soluble emulsion acrylic resin is made up of the raw material of following weight portion: nano silicon 0.5, cellulose acetate 4, N, dinethylformamide 12, butyl acrylate 18, methyl methacrylate 15, acrylic acid 10, ammonium persulfate 5, polyoxyethylene nonylphenol ether 2, lauryl sodium sulfate 1, ammoniacal liquor are appropriate, deionized water 50, and preparation method is:
(1) first drop in DMF by cellulose acetate, be stirred to it and dissolve completely, drop in solution subsequently by nano silicon, closed ultrasonic dispersed with stirring 3h, the cellulose acetate solution obtaining blending nano silicon is for subsequent use;
(2) polyoxyethylene nonylphenol ether, lauryl sodium sulfate are dropped in reactor, add the deionized water of 10 weight portions subsequently, be stirred to after dissolving completely, material prepared by input step (1) and butyl acrylate, methyl methacrylate, acrylic acid, be warming up to 70 DEG C, be uniformly mixed 2h, obtain pre-emulsion for subsequent use;
(3) seed emulsion preparation: ammonium persulfate and appropriate ammoniacal liquor are dissolved in the deionized water of surplus, regulator solution pH value is 6.0, and be heated to 65 DEG C, then pre-emulsion prepared by this solution of 2/3 weight portion and 1/4 weight portion step (2) is got respectively, be added drop-wise in reaction vessel simultaneously, rate of addition is 45/min, stops dripping, obtain seed emulsion when question response system is blue-fluorescence;
(4) gained seed emulsion drips ammonium persulfate solution and the pre-emulsion of surplus again after leaving standstill 15min, after dropping terminates under 70 DEG C of conditions constant temperature 50min, be heated to 75 DEG C subsequently, strong stirring mixing 1.5h under constant temperature, stop subsequently stirring, when emulsion naturally cools to below 50 DEG C, ammoniacal liquor regulator solution pH value is 7.0, filters discharging subsequently and get final product.
Coating paste is coated in nonwoven fabric base paper surface, control coating weight is 15g/m
2, after its drying, plastify embossing under 135 DEG C of conditions, carry out performance test to product according to relevant criterion after cooling forming, test result is:
Formaldehyde clearance:
0h：45.5%；24h：80.5%；48h：92.8%；72h：95.5%；96h:97.5%；120h:98.0%。
Regain: 0.70%; Air permeability: 10.4L/(m
2s); Tensile strength: 3280N/m, bursting strength: 182KPa.
Antibacterial and mouldproof: can 96.8% be reached to staphylococcus aureus bacteriostasis rate; Can 98.0% be reached to Escherichia coli bacteriostasis rate; It is 0 grade to the antibacterial grade of aspergillus niger, chaetomium globosum, green sticky broom bacterium.
Wallpaper prepared by this embodiment meets the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer.
Claims (3)
1. the wallpaper containing volcanic rock-polylactic acid porous fibre modification emulsion acrylic resin coating, this wallpaper is made up after super-dry, plasticizing, embossing of non-woven fabrics base material and the coating paste being coated on substrate surface, it is characterized in that, described coating paste is made up of the raw material of following weight portion: composite water soluble emulsion acrylic resin 80-100, volcanic rock micro mist 2-3, Graphene 0.01-0.02, polylactic acid slice 8-10, vinyl two stearic amide 0.1-0.2, silane coupler kh5500.1-0.2.
2. a kind of wallpaper containing volcanic rock-polylactic acid porous fibre modification emulsion acrylic resin coating as claimed in claim 1, it is characterized in that, described coating paste preparation method is:
(1) volcanic rock-polylactic acid porous fiber preparation: first polylactic acid slice, volcanic rock micro mist, Graphene, the two stearic amide of vinyl, silane coupler kh550 are carried out melt spinning after being uniformly mixed, making length is 80-100 μm, and diameter is the porous staple fibre of 30-50 μm;
(2) volcanic rock-polylactic acid porous fiber is dropped in composite water soluble emulsion acrylic resin, add other leftover materials after being uniformly mixed 30-50min, strong stirring mixing 4-5h, leave standstill after placing 30-40min subsequently and get final product.
3. a kind of wallpaper containing volcanic rock-polylactic acid porous fibre modification emulsion acrylic resin coating as claimed in claim 1 or 2, it is characterized in that, described composite water soluble emulsion acrylic resin is made up of the raw material of following weight portion: nano silicon 0.5-0.8, cellulose acetate 4-5, N, dinethylformamide 12-15, butyl acrylate 18-25, methyl methacrylate 15-20, acrylic acid 10-15, ammonium persulfate 5-8, emulsifier op-10 2-3, lauryl sodium sulfate 1-3, ammoniacal liquor are appropriate, deionized water 50-60, and preparation method is:
(1) first drop in DMF by cellulose acetate, be stirred to it and dissolve completely, drop in solution subsequently by nano silicon, closed ultrasonic dispersed with stirring 3-4h, the cellulose acetate solution obtaining blending nano silicon is for subsequent use;
(2) emulsifier op-10, lauryl sodium sulfate are dropped in reactor, add the deionized water of 10-15 weight portion subsequently, be stirred to after dissolving completely, material prepared by input step (1) and butyl acrylate, methyl methacrylate, acrylic acid, be warming up to 70-75 DEG C, be uniformly mixed 2-3h, obtain pre-emulsion for subsequent use;
(3) seed emulsion preparation: ammonium persulfate and appropriate ammoniacal liquor are dissolved in the deionized water of surplus, regulator solution pH value is 6.0-7.5, and be heated to 65-75 DEG C, then pre-emulsion prepared by this solution of 2/3 weight portion and 1/4 weight portion step (2) is got respectively, be added drop-wise in reaction vessel simultaneously, rate of addition is that 45-60 drips/min, stops dripping, obtain seed emulsion when question response system is blue-fluorescence;
(4) gained seed emulsion drips ammonium persulfate solution and the pre-emulsion of surplus again after leaving standstill 15-20min, after dropping terminates under 70-75 DEG C of condition constant temperature 50-60min, be heated to 75-80 DEG C subsequently, strong stirring mixing 1.5-2h under constant temperature, stop subsequently stirring, when emulsion naturally cools to below 50 DEG C, ammoniacal liquor regulator solution pH value is 7.0, filters discharging subsequently and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510827400.4A CN105507078A (en) | 2015-11-25 | 2015-11-25 | Wallpaper containing a volcanic rock-polylactic acid porous fiber modified acrylic resin emulsion coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510827400.4A CN105507078A (en) | 2015-11-25 | 2015-11-25 | Wallpaper containing a volcanic rock-polylactic acid porous fiber modified acrylic resin emulsion coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105507078A true CN105507078A (en) | 2016-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510827400.4A Pending CN105507078A (en) | 2015-11-25 | 2015-11-25 | Wallpaper containing a volcanic rock-polylactic acid porous fiber modified acrylic resin emulsion coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107164998A (en) * | 2017-05-18 | 2017-09-15 | 青岛瑞利特新材料科技有限公司 | A kind of graphene removes the heat-insulated wallpaper of aldehyde, wall paper and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497729A (en) * | 2009-02-20 | 2009-08-05 | 上海三瑞化学有限公司 | Nano silicasol / acrylic ester composite emulsion and preparation thereof |
| CN103469576A (en) * | 2013-09-29 | 2013-12-25 | 句容市石狮冲压件厂 | Coating non-woven fabric |
| JP5544033B1 (en) * | 2013-03-19 | 2014-07-09 | 東洋紡株式会社 | Resin coated nonwoven fabric |
| CN104088137A (en) * | 2014-06-20 | 2014-10-08 | 华南理工大学 | Method for preparing functional wallpaper by using iron-magnesium tourmaline and palygorskite |
-
2015
- 2015-11-25 CN CN201510827400.4A patent/CN105507078A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101497729A (en) * | 2009-02-20 | 2009-08-05 | 上海三瑞化学有限公司 | Nano silicasol / acrylic ester composite emulsion and preparation thereof |
| JP5544033B1 (en) * | 2013-03-19 | 2014-07-09 | 東洋紡株式会社 | Resin coated nonwoven fabric |
| CN103469576A (en) * | 2013-09-29 | 2013-12-25 | 句容市石狮冲压件厂 | Coating non-woven fabric |
| CN104088137A (en) * | 2014-06-20 | 2014-10-08 | 华南理工大学 | Method for preparing functional wallpaper by using iron-magnesium tourmaline and palygorskite |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107164998A (en) * | 2017-05-18 | 2017-09-15 | 青岛瑞利特新材料科技有限公司 | A kind of graphene removes the heat-insulated wallpaper of aldehyde, wall paper and preparation method |
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Application publication date: 20160420 |
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