CN105504905B - 一种金属表面用的高耐磨透明涂料 - Google Patents
一种金属表面用的高耐磨透明涂料 Download PDFInfo
- Publication number
- CN105504905B CN105504905B CN201610077552.1A CN201610077552A CN105504905B CN 105504905 B CN105504905 B CN 105504905B CN 201610077552 A CN201610077552 A CN 201610077552A CN 105504905 B CN105504905 B CN 105504905B
- Authority
- CN
- China
- Prior art keywords
- sol
- silicate
- modified
- phosphate
- dispersion liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 20
- 239000002184 metal Substances 0.000 title claims abstract description 20
- 238000005299 abrasion Methods 0.000 title claims abstract 6
- 239000007788 liquid Substances 0.000 claims abstract description 18
- 239000006185 dispersion Substances 0.000 claims abstract description 13
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003112 inhibitor Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims description 29
- 239000011248 coating agent Substances 0.000 claims description 27
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 7
- 239000005416 organic matter Substances 0.000 claims description 7
- 229910000077 silane Inorganic materials 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 6
- 239000004111 Potassium silicate Substances 0.000 claims description 5
- 239000004115 Sodium Silicate Substances 0.000 claims description 5
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 5
- 229910000318 alkali metal phosphate Inorganic materials 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 5
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims description 5
- 229910052912 lithium silicate Inorganic materials 0.000 claims description 5
- 229910052913 potassium silicate Inorganic materials 0.000 claims description 5
- 235000019353 potassium silicate Nutrition 0.000 claims description 5
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000001506 calcium phosphate Substances 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000011010 calcium phosphates Nutrition 0.000 claims description 2
- 239000000378 calcium silicate Substances 0.000 claims description 2
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 2
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 2
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims description 2
- 229910021485 fumed silica Inorganic materials 0.000 claims description 2
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 2
- 239000004137 magnesium phosphate Substances 0.000 claims description 2
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 2
- 229960002261 magnesium phosphate Drugs 0.000 claims description 2
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 2
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims description 2
- 229920000136 polysorbate Chemical class 0.000 claims description 2
- 229950008882 polysorbate Drugs 0.000 claims description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 claims description 2
- 235000011009 potassium phosphates Nutrition 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 235000011008 sodium phosphates Nutrition 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002585 base Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 8
- 239000003973 paint Substances 0.000 abstract description 4
- 239000000758 substrate Substances 0.000 abstract description 4
- 238000004381 surface treatment Methods 0.000 abstract description 3
- 229910019142 PO4 Inorganic materials 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 239000010452 phosphate Substances 0.000 abstract description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 2
- 230000003670 easy-to-clean Effects 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
本发明公开了一种金属表面用的高耐磨透明涂料，包括以下组分：硅酸盐或溶胶或有机物改性溶胶中的至少一种、纳米氧化物分散液、碱金属的磷酸盐、抑制剂、润湿剂和溶剂；本发明的金属表面用的高耐磨透明涂料相对于目前的耐磨涂料具有更高的耐磨性、耐酸耐碱性和易清洁性，适合用于厨具、卫具等金属器皿的表面处理，对基材具有良好的保护作用，防止基材被磨损，并使基材表面具有易清洁的作用。
Description
技术领域
本发明涉及涂料技术领域，尤其是涉及一种金属表面用的高耐磨透明涂料。
背景技术
金属基材在人们的日常生活中起着非常重要的作用，是设备组合过程中必不可少的部件。如何提高金属基材的耐磨性能一直需要解决的问题。现有的金属基材表面用涂料的耐磨性能低，并且其抗划伤性能和光泽差，耐老化性能低。
发明内容
为了解决上述现有技术问题，本发明提供了一种金属表面用的高耐磨透明涂料，能有效保护基材，防止基材被磨损，具有更高的耐磨性、耐酸耐碱性、耐洗刷性和易清洁性，适合用于厨具、卫具及玻璃等表面处理。
本发明的技术方案为：一种金属表面用的高耐磨透明涂料，包括以下组分：硅酸盐或溶胶或有机物改性溶胶中的至少一种、纳米氧化物分散液、碱金属的磷酸盐、抑制剂、润湿剂和溶剂；其中，
所述硅酸盐为硅酸锂、硅酸钠、硅酸钾、硅酸钙或硅酸锆中的至少一种；
所述溶胶为硅溶胶、铝溶胶中的至少一种；
所述有机物改性溶胶为有机物改性硅溶胶或有机物改性铝溶胶中的至少一种；
所述纳米氧化物分散液为气相二氧化硅分散液、纳米氧化钙分散液、纳米碳酸钙分散液、纳米氧化锌分散液或纳米氧化锆分散液中的至少一种；
所述碱金属的磷酸盐为磷酸镁、磷酸铝、磷酸钠、磷酸钾和磷酸钙中的至少一种；
所述抑制剂为三乙醇胺或二乙醇胺中的至少一种；
所述润湿剂为乙二醇单丁醚、二乙二醇单丁醚、改性硅氧烷或聚山梨醇酯中的至少一种；
所述溶剂为水。
所述有机物改性溶胶的有机物成分占改性溶胶重量比为0.5％-3％，优选为1％-2％。
所述有机物成分为γ-缩水甘油醚基丙基三甲氧基硅烷或环氧硅烷低聚物。
所述润湿剂的添加量为涂料总量的0.01％～2％，优选为0.05％～1％；
优选地，本发明的金属表面用的高耐磨透明涂料，其包括下列按质量百分比的组分：硅酸盐0-30％、溶胶0-20％、改性溶胶0-20％、纳米氧化物分散液1-5％、碱金属的磷酸盐1-5％、抑制剂1-10％、润湿剂0.01-2％、水余量。
优选地，本发明的金属表面用的高耐磨透明涂料，其包括下列按质量百分比的组分：硅酸锂7％、硅酸纳3％、硅酸钾12％、硅溶胶13％、铝溶胶2.5％、纳米氧化锆分散液2％、磷酸铝2.2％、三乙醇胺6.5％、改性硅氧烷0.8％、水51％。
优选地，本发明的金属表面用的高耐磨透明涂料，其包括下列按质量百分比的组分：硅酸锂7％、硅酸纳3％、硅酸钾12％、铝溶胶3.7％、2％环氧硅烷低聚物改性的硅溶胶12.8％、纳米氧化锆分散液2％、磷酸铝2.2％、三乙醇胺6.5％、改性硅氧烷0.8％、水50％。
本发明所述的硅酸盐与溶胶或改性溶胶对涂料的成模性具有影响，硅酸盐与溶胶或改性溶胶的比例优选为1:(0.7-1)，溶胶或改性溶胶的含量过多会影响涂料的透明性与成模性，使得涂料透明度不够以及附着力差涂层易脱落。
本发明所述的有机物改性溶胶有助于提高涂料的附着力、耐刮花性和耐水煮性。
本发明所述的纳米氧化物分散液具有耐水、耐洗刷、耐污性能，有助于提高涂料的成膜性，提高附着力，提高涂料涂层的耐摩擦性、耐水煮、耐洗刷性。
本发明所述的磷酸盐有助于提高涂料的亲水性，有利于基材的清洁。
本发明的有益效果为：本发明的金属表面用的高耐磨透明涂料相对于目前的耐磨涂料具有更高的耐磨性、耐酸耐碱性和易清洁性，适合用于厨具、卫具等金属器皿的表面处理，对基材具有良好的保护作用，防止基材被磨损，且具有亲水性、耐水煮，使基材表面具有易清洁的作用。
具体实施方式
下面结合具体实施例对本发明作进一步阐述。
实施例1至实施例5的金属表面用的高耐磨透明涂料，其各组分配比见表1：
表1
按照表1中的实施例1～实施例7的配方制备涂料，采用喷涂方式在120mm×150mm的拉丝不锈钢板上制作涂层；先在低温下(如50℃)烘烤10min，再在180℃烘烤60min；实施例1～5的检测性能见表2。
表2
从上述性能检测结果可得：实施例1至实施例3涂层各项性能较优，尤其是采用了环氧硅烷低聚物改性硅溶胶的实施例3，虽然其亲水角较大，但是其耐摩擦力较其他实施例优，经过5000次摩擦试验后亲水角从15°变化为18°，变化不明显，可见环氧硅烷低聚物改性硅溶胶对提高涂料的耐摩擦性具有明显帮助；实施例4不采用纳米氧化物分散液时，耐摩擦性最差，而实施例5不采用磷酸铝时，其亲水角较大且耐摩擦性较差。
本发明使用的环氧硅烷低聚物改性硅溶胶购自信越化学工业株式会社MP200。
以上所述，仅为本发明的较佳实施例，并不用以限制本发明，凡是依据本发明的技术实质对以上实施例所作的任何细微修改、等同替换和改进，均应包含在本发明技术方案的保护范围内。
Claims (4)
1.一种金属表面用的高耐磨透明涂料，其特征在于，包括以下组分：硅酸盐、溶胶、有机物改性溶胶、纳米氧化物分散液、碱金属的磷酸盐、抑制剂、润湿剂和溶剂；其中，
所述硅酸盐为硅酸锂、硅酸钠、硅酸钾、硅酸钙或硅酸锆中的至少一种；
所述溶胶为硅溶胶、铝溶胶中的至少一种；
所述有机物改性溶胶为有机物改性硅溶胶或有机物改性铝溶胶中的至少一种；所述有机物改性溶胶中的有机物成分占改性溶胶重量比为0.5％-3％，所述有机物成分为γ-缩水甘油醚基丙基三甲氧基硅烷或环氧硅烷低聚物；
所述纳米氧化物分散液为气相二氧化硅分散液、纳米氧化钙分散液、纳米碳酸钙分散液、纳米氧化锌分散液或纳米氧化锆分散液中的至少一种；
所述碱金属的磷酸盐为磷酸镁、磷酸铝、磷酸钠、磷酸钾和磷酸钙中的至少一种；
所述抑制剂为三乙醇胺或二乙醇胺中的至少一种；
所述润湿剂为乙二醇单丁醚、二乙二醇单丁醚、改性硅氧烷或聚山梨醇酯中的至少一种；所述润湿剂的添加量为涂料总量的0.01％～2％；
所述溶剂为水。
2.根据权利要求1所述的金属表面用的高耐磨透明涂料，其特征在于，所述有机物成分占改性溶胶重量比为1％-2％。
3.根据权利要求1所述的金属表面用的高耐磨透明涂料，其特征在于，所述润湿剂的添加量为涂料总量的0.05％～1％。
4.根据权利要求1所述的金属表面用的高耐磨透明涂料，其特征在于，包括下列按质量百分比的组分：硅酸锂7％、硅酸纳3％、硅酸钾12％、铝溶胶3.7％、2％环氧硅烷低聚物改性的硅溶胶12.8％、纳米氧化锆分散液2％、磷酸铝2.2％、三乙醇胺6.5％、改性硅氧烷0.8％、水50％。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610077552.1A CN105504905B (zh) | 2016-02-03 | 2016-02-03 | 一种金属表面用的高耐磨透明涂料 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610077552.1A CN105504905B (zh) | 2016-02-03 | 2016-02-03 | 一种金属表面用的高耐磨透明涂料 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105504905A CN105504905A (zh) | 2016-04-20 |
| CN105504905B true CN105504905B (zh) | 2018-07-03 |
Family
ID=55713224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610077552.1A Active CN105504905B (zh) | 2016-02-03 | 2016-02-03 | 一种金属表面用的高耐磨透明涂料 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105504905B (zh) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106317974B (zh) * | 2016-08-23 | 2018-11-23 | 江阴市大阪涂料有限公司 | 一种改性有机硅铝耐有机溶剂双组份涂料及制备方法 |
| CN107033642B (zh) * | 2017-05-04 | 2019-11-08 | 广州希森美克新材料科技有限公司 | 用于金属表面的防污耐磨涂料及其制备方法 |
| WO2019051753A1 (zh) * | 2017-09-14 | 2019-03-21 | 吴金凤 | 一种高耐磨易清洁纳米涂层的制备方法 |
| CN110054979A (zh) * | 2018-01-19 | 2019-07-26 | 中国科学院福建物质结构研究所 | 一种塑料用水性涂料及其制备方法和用途 |
| CN108977006A (zh) * | 2018-06-27 | 2018-12-11 | 安徽国成顺风风力发电有限公司 | 一种风力发电机叶片用防护涂料及其制备方法 |
| CN109439042A (zh) * | 2018-11-15 | 2019-03-08 | 九牧厨卫股份有限公司 | 一种亲水面层涂料、相关的不锈钢水槽和制备方法 |
| CN111073360A (zh) * | 2019-12-19 | 2020-04-28 | 湖南太子化工涂料有限公司 | 一种工程机械设备用耐酸耐碱水性金属涂料 |
| CN111423751A (zh) * | 2020-04-10 | 2020-07-17 | 浙江大学 | 一种高效防静电的常温固化磷酸盐防腐涂层及其制备方法 |
| CN111362589B (zh) * | 2020-04-29 | 2022-07-01 | 东莞南玻太阳能玻璃有限公司 | 一种耐候双层高增透镀膜玻璃及其制备方法 |
| CN112961520A (zh) * | 2021-04-06 | 2021-06-15 | 广州大学 | 一种耐水长效无机氧化锌超亲水涂料及其制备方法与应用 |
| CN115537794B (zh) * | 2022-09-29 | 2023-05-26 | 东莞市颖兴金属表面处理材料有限公司 | 一种金属表面多功能处理液及其制备方法 |
| CN115975408B (zh) * | 2022-12-26 | 2024-04-26 | 杭州老板电器股份有限公司 | 耐高温易清洁无机涂料、耐高温易清洁无机涂层及应用 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007920A (zh) * | 2007-01-22 | 2007-08-01 | 陈东阜 | 无机耐腐蚀耐火耐磨纳米胶结料 |
| CN103627227A (zh) * | 2013-11-27 | 2014-03-12 | 天津市职业大学 | 一种太阳能玻璃自清洁减反射涂料及其生产方法 |
| CN103665973A (zh) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | 仿铜无机涂料的制备工艺及将其用于取代金属表面防护装饰性铜层的工艺 |
| CN104725903A (zh) * | 2015-03-30 | 2015-06-24 | 佛山市新战略知识产权文化有限公司 | 一种不粘耐磨耐高温涂料及其制备方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02142859A (ja) * | 1988-11-24 | 1990-05-31 | O K Furitsuto Service:Kk | 無機塗料 |
| KR20020007274A (ko) * | 2001-12-15 | 2002-01-26 | 정승교 | 콘크리트 구조물의 표면처리제 |
-
2016
- 2016-02-03 CN CN201610077552.1A patent/CN105504905B/zh active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101007920A (zh) * | 2007-01-22 | 2007-08-01 | 陈东阜 | 无机耐腐蚀耐火耐磨纳米胶结料 |
| CN103627227A (zh) * | 2013-11-27 | 2014-03-12 | 天津市职业大学 | 一种太阳能玻璃自清洁减反射涂料及其生产方法 |
| CN103665973A (zh) * | 2013-12-11 | 2014-03-26 | 哈尔滨工业大学 | 仿铜无机涂料的制备工艺及将其用于取代金属表面防护装饰性铜层的工艺 |
| CN104725903A (zh) * | 2015-03-30 | 2015-06-24 | 佛山市新战略知识产权文化有限公司 | 一种不粘耐磨耐高温涂料及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105504905A (zh) | 2016-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105504905B (zh) | 一种金属表面用的高耐磨透明涂料 | |
| CN105482536B (zh) | 一种透明抗菌亲水涂料 | |
| CN100584908C (zh) | 环保型镀锌金属表面处理剂 | |
| US9458539B2 (en) | Metal surfaces compromising a thin glass- or ceramic type protective layer having high chemical resistance and improved non-stick properties | |
| AU2013352514B2 (en) | Glass containers with delamination resistance and improved damage tolerance | |
| KR101300382B1 (ko) | 친수막 | |
| US9169402B2 (en) | Titanium-containing ceramic paint and protective coating | |
| JP5168332B2 (ja) | 亜鉛系めっき鋼板用の表面処理液ならびに亜鉛系めっき鋼板およびその製造方法 | |
| JP5499773B2 (ja) | 亜鉛系めっき鋼板用の表面処理液ならびに亜鉛系めっき鋼板およびその製造方法 | |
| TWI476166B (zh) | Method for manufacturing anti - reflective tempered glass | |
| US20070218297A1 (en) | Non-stick ceramic coating composition and process | |
| CN102686685A (zh) | 用于硬质表面的全氟聚醚涂料组合物 | |
| US11339081B2 (en) | Antimicrobial strengthened glass and preparation process thereof | |
| JP6154829B2 (ja) | 疎油性コーティング | |
| EP1489146B1 (en) | Process for producing a hydrophilic film | |
| CN108276812B (zh) | 用于木材、金属和塑料表面的高硬度透明易清洁疏水涂料 | |
| JP2010236074A (ja) | 表面処理剤、該表面処理剤を用いためっき鋼板の製造方法およびめっき鋼板 | |
| TW201532994A (zh) | 太陽電池用附防眩機能玻璃板 | |
| TW201809066A (zh) | 組成物 | |
| CN108300299B (zh) | 一种具有防滑功能的保护性涂层组合物、涂布制品及其制备方法 | |
| Wei et al. | Superior mechanical properties of hybrid organic-inorganic superhydrophilic thin film on plastic substrate | |
| CN111040486B (zh) | 亲水型易清洁涂料及其制备方法和应用 | |
| CN109369947A (zh) | 一种耐磨树脂镜片及其制备方法 | |
| JP6737271B2 (ja) | 硬質部材 | |
| JP2011006653A (ja) | 硬化被膜付き基材 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Highly wear-resistant transparent coating for metal surface Effective date of registration: 20190701 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY CO.,LTD. Registration number: 2019440000247 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP01 | Change in the name or title of a patent holder |
Address after: Ke Feng Lu Science City, Guangzhou hi tech Development Zone in Guangdong province 510000 No. 31 Southern China new material innovation park building G2 321 Patentee after: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Address before: Ke Feng Lu Science City, Guangzhou hi tech Development Zone in Guangdong province 510000 No. 31 Southern China new material innovation park building G2 321 Patentee before: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY Co.,Ltd. |
|
| CP01 | Change in the name or title of a patent holder | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20200826 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: GUANGZHOU SYSMYK NEW MATERIAL TECHNOLOGY Co.,Ltd. Registration number: 2019440000247 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high wear resistant transparent coating for metal surface Effective date of registration: 20200826 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2020980005427 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| CP02 | Change in the address of a patent holder |
Address after: Room 601, G11 building, South China new materials innovation park, No.31 Kefeng Road, Science City, Guangzhou high tech Industrial Development Zone, Guangdong Province 510000 Patentee after: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Address before: Ke Feng Lu Science City, Guangzhou hi tech Development Zone in Guangdong province 510000 No. 31 Southern China new material innovation park building G2 321 Patentee before: Guangzhou Hisense Meike New Material Technology Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20211020 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2020980005427 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A high wear-resistant transparent coating for metal surface Effective date of registration: 20211022 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2021980011154 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230223 Granted publication date: 20180703 Pledgee: Zhujiang Branch of Guangzhou Bank Co.,Ltd. Pledgor: Guangzhou Hisense Meike New Material Technology Co.,Ltd. Registration number: Y2021980011154 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right |