CN105454233A - Pesticide composition containing cyhalodiamide and benzene kresoxim-methyl - Google Patents
Pesticide composition containing cyhalodiamide and benzene kresoxim-methyl Download PDFInfo
- Publication number
- CN105454233A CN105454233A CN201510861390.6A CN201510861390A CN105454233A CN 105454233 A CN105454233 A CN 105454233A CN 201510861390 A CN201510861390 A CN 201510861390A CN 105454233 A CN105454233 A CN 105454233A
- Authority
- CN
- China
- Prior art keywords
- insect amide
- chlorine fluorine
- composition pesticide
- cyanogen insect
- fluorine cyanogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides pesticide composition containing cyhalodiamide and benzene kresoxim-methyl in the weight ratio being (50:1)-(1:50). The pesticide composition is efficient, low in toxicity, long in lasting period and capable of effectively controlling diseases and pests of crops.
Description
Technical field
The invention belongs to pesticide field, be specifically related to the composition pesticide of a kind of containing chlorine fluorine cyanogen insect amide and ZJ0712.
Background technology
The resistance problem of pest is global problems.Along with Chemical Control of Harmful Insects continuity, the increase of Pesticide use amount and not scientifical use agricultural chemicals, pest resistance is day by day serious, and the pest species producing resistance is on the increase.Particularly to the Lepidoptera class pest that agricultural production is caused harm serious, resistance level is higher, and resistance development speed is relatively very fast.Meanwhile, the use agricultural chemicals of high strength, causes Practice for Pesticide Residue in Agricultural Products to exceed standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore, the pesticide of efficient, the low toxicity of research and development, environmental protection has positive effect to agricultural sustainable development.
In Rice Production, paddy rice is subject to the impact of many damage by disease and insect, particularly striped rice borer and rice blast etc. at seedling stage, brings considerable influence to agricultural production.At present, China is used for the agricultural chemicals of rice seedling and is essentially single and prevents insect pest or disease, can the product development of controlling disease and insect pest simultaneously less.Therefore, the composition pesticide of exploitation control rice pest, has positive effect for the agriculture large-scale development of propelling.
ZJ0712 is a kind of strobilurin fungicide, and fungicidal spectrum is wide, bactericidal activity is high, instant effect, and resistance of rainwater washing against, lasting period are long, belongs to efficient, low toxicity, less-persistent pesticide, effective to the disease of various crop.
Chlorine fluorine cyanogen insect amide is the novel pesticide that Zhejiang Provincial Chemical Engineering Research Inst is developed voluntarily, code name ZJ4042, and chemical name is: the chloro-N of 3-
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, shown in structural formula following (I):
This insecticide belongs to Novel ortho benzenedicarboxamide insecticides, by activating calcium release channel in blue Buddhist nun's alkali recipient cell, causing the runaway release of storing calcium ion, is the compounds acting on blue Buddhist nun's alkali (Ryanodine) acceptor of insect cell few in number at present.Wide spectrum preventive effect is had to lepidoptera pest.
When chlorine fluorine cyanogen insect amide or ZJ0712 are used alone, drug cost is higher, limits it to a certain extent and applies.Chlorine fluorine cyanogen insect amide or ZJ0712 mixture can be reduced times for spraying and drug cost, and expanding prevention spectrum.Therefore, chlorine fluorine cyanogen insect amide and ZJ0712 being carried out mixture, is a kind of effective ways preventing and treating agricultural pest.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of efficient, low toxicity and the lasting period is long, the composition pesticide that effectively can prevent and treat diseases and pests of agronomic crop, is conducive to the comprehensive regulation of damage by disease and insect.
For solving the problem, the technical solution adopted in the present invention is:
A kind of composition pesticide, it is characterized in that described composition pesticide contains chlorine fluorine cyanogen insect amide and ZJ0712, and the weight ratio of chlorine fluorine cyanogen insect amide and ZJ0712 is 50:1 ~ 1:50.
The chlorine fluorine cyanogen insect amide that the present invention uses, is the compound shown in structure above (I).
Composition pesticide of the present invention, chlorine fluorine cyanogen insect amide and ZJ0712 are as active component.Preferably, the weight ratio of chlorine fluorine cyanogen insect amide and ZJ0712 is 20:1 ~ 1:20.Further preferably, the weight ratio of chlorine fluorine cyanogen insect amide and ZJ0712 is 4:1 ~ 1:3.
Present invention also offers a kind of insecticidal bactericide, by weight containing 5 ~ 90% above-mentioned composition pesticides, all the other are agriculturally acceptable carrier and auxiliary agent.As preferred embodiment, the above-mentioned composition pesticide preferably containing 5 ~ 40% in insecticidal bactericide.
Carrier of the present invention can be solid or liquid, and any carrier being generally used for preparing insecticidal bactericide all can use.
Suitable solid carrier comprises: mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin such as, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is such as: calcium carbonate, dolomite.Sulfates as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.Plant is such as: citrus pulp, corncob cellulose, rice husk powder, rice husk, large soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride such as, sodium chloride.
Liquid-carrier comprises water and organic solvent.When active ingredient be aqueous emulsion or suspension emulsion time, organic solvent plays solubilising and antifreeze effect.Suitable organic solvent comprises aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, such as vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, such as petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol such as, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether such as, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidon such as; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone, also can be used in combination, can also mix together with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and antifreezing agent as required, can also comprise other auxiliary agents that the industry is conventional as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; The polycondensation product of the fatty acid containing at least 12 carbon atoms in molecule or fatty amine and oxirane and/expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; In the molecule at least containing the sulfuric acid of 10 carbon atoms or the alkali metal of sulfonic acid or alkali salt, be preferably sodium salt, as the sodium salt of lauryl sodium sulfate, Teepol, sulfonated castor oil, alkylaryl sodium sulfonate and neopelex; The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and commercially available emulsifier.The preferred polyoxyethylene fatty acid fat of nonionic emulsifier, polyoxyethylene aliphatic alcohol ether and Polyoxyethylene fatty ammonia, such as ethoxylated castor oil, polyoxyethylene (n
20) phenethyl phenol ether through reaction oleate, alkylaryl polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin APEO, triphenyl vinyl phenol polyoxyethylene (n
20), ether phosphoric acid triethanolamine salt, Diphenethyl phenolic group APEO (n
18) formaldehyde condensation products, diphenyl phenol polyethenoxy (n
18) polyethenoxy ether (n
20) etc.Commercially available emulsifier comprises: agriculture breast 0201B, agriculture breast 0203B, agriculture breast 100
#, agriculture breast 500
#, agriculture breast 600
#, agriculture breast 600-2
#, agriculture breast 1601, agriculture breast 2201, agriculture breast NP-10, agriculture breast NP-15, agriculture breast 507
#, agriculture breast OX-635, agriculture breast OX-622, agriculture breast OX-653, agriculture breast OX-667, agriculture breast CS-7, peaceful breast 36
#.
Dispersant of the present invention comprises: sodium lignin sulfonate, pull open powder, calcium lignosulfonate, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, naphthalene sulfonic acid-formaldehyde condensation product, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, to tertbutyl ether, dibutyl naphthalenesulfonic acid formaldehyde condensation products, phosphate is as calgon, alkylphenol-polyethenoxy based phosphates, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, N-methyl-fatty acyl group-sodium taurocholate alkylphenol polyoxyethylene formaldehyde condensation products, aralkyl phenol polyethenoxy ether phosphate alkylphenol polyoxyethylene, castor oil ethylene oxide adduct, ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene formaldehyde condensation products, alkylphenol-polyethenoxy polyethenoxy ether and methylcellulose.
Wetting agent of the present invention comprises: sldium lauryl sulfate, alkylol polyoxyethylene groups ether sodium sulfate, octylphenol polyethylene oxyethylene group ether sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products sulphate, sodium alkyl sulfonate, neopelex, Negel, dialkyl succinylsuccinate sulfonate, lauryl alcohol polyethylene glycol oxide base ether sulfonic acid sodium, alkyl amide sodium taurocholate, aliphatic alcohol polyethenoxy base ether, alkylphenol-polyethenoxy base ether, polyoxyethylene polyoxypropylene block polymer, sorbitan fatty acid ester polyoxyethylene ether etc.
Thickener of the present invention both can be Prof. Du Yucang, such as carboxymethyl alcohol, polyvinyl alcohol or polyvinyl acetate; Also can be natural water-soluble polymer, such as xanthans, gelatin, gum Arabic, polyvinylpyrrolidone, Magnesiumaluminumsilicate, polyvinyl alcohol, polyethylene glycol, phenolic resins, shellac, carboxymethyl cellulose and sodium alginate etc.
Defoamer of the present invention is preferably: bubble enemy, silicone, C
8 ~ 10fatty alcohol, C
10 ~ 20saturated fat acids and acid amides etc.
Composition pesticide of the present invention can be mixed with suspending agent, missible oil, water dispersible granules or oil suspending agent according to the method that this area is general.
Composition pesticide insecticidal bactericide of the present invention is suitable for preventing and treating lepidoptera pest and rice blast simultaneously, is particularly suitable for water prevention chilo suppressalis and rice blast simultaneously.
Composition pesticide of the present invention and insecticidal bactericide can be used by common method, as cast, injection, spraying.Amount of application is with weather conditions or crop condition change, and time of application can before or after pest damage.The duration of protective effect is usually relevant with the content of compound individualized in composition, also relevant to extraneous factor, such as weather, but by using suitable formulation to slow down climatic influences.
Composition pesticide of the present invention also can have weeding with other, the compound of bactericidal property uses, also can be used in combination with nematocide, protective agent, growth regulator, nutrient for plants or soil conditioner.
Composition pesticide of the present invention has following advantage compared to existing technology:
(1) in composition, two kinds of composite reagents show and obviously can expand agricultural chemicals spectrum effect in certain ratio range, reach the double effect controlled of disease worm, and have the advantages that the good and lasting effect of quick-acting grows;
(2) reduce times for spraying, reduce peasant's drug cost.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, but does not limit the invention to these embodiments.One skilled in the art would recognize that all alternatives, improvement project and the equivalents that present invention encompasses and may comprise in Claims scope.
In following embodiment, the proportioning of solid pharmaceutical preparation is weight percentage, and the proportioning of liquid preparation is percent by volume, and the treatment dosage of biologically-active moiety is effective content.
Embodiment 1,20% ZJ0712 chlorine fluorine cyanogen insect amide suspending agent
Be deionized water by ZJ0712 5%, chlorine fluorine cyanogen insect amide 15%, phosphate dispersant (FS3000) 4%, sulfonate wetting agent (SXC) 1%, aluminium-magnesium silicate 1%, xanthans 0.1%, silicone defoaming agent 0.3%, ethylene glycol 5%, surplus.Above-mentioned formula is pulverized in proportion in advance, then adds in sand mill and grind, the obtained 20% ZJ0712 chlorine fluorine cyanogen insect amide suspending agent of allotment after high shear mixing.
20% obtained ZJ0712 chlorine fluorine cyanogen insect amide suspending agent is applied to water prevention chilo suppressalis, rice blast.20% ZJ0712 chlorine fluorine cyanogen insect amide suspending agent presses active ingredient 5 grams/acre in striped rice borer egg hatching larva occurance peak, and rice blast initial stage of origination is watered even spraying, within after medicine 7 days, is respectively 90.3%, 85.8% to the preventive effect of striped rice borer, rice blast.Contrast single dose 30% ZJ0712 suspending agent (formulation rate is 15 grams/acre), 20% chlorine fluorine cyanogen insect amide suspending agent (active ingredient formulation rate is 3 grams/acre) are by same method dispenser, after medicine 7 days, the preventive effect of 50% ZJ0712 suspending agent to striped rice borer, rice blast is respectively 6.7%, 75.2%, and the preventive effect of 20% chlorine fluorine cyanogen insect amide suspending agent to striped rice borer, rice blast is respectively 80.5%, 2.1%.Obviously can increase control spectrum after ZJ0712 and chlorine fluorine cyanogen insect amide mixture, reach that disease worm is double controls effect, double preventive effect of controlling is better than single dose.
Embodiment 2,50% ZJ0712 chlorine fluorine cyanogen insect amide water-dispersible granules
By ZJ0712 10.0%, chlorine fluorine cyanogen insect amide 40%, dispersant (NNO+ wood sodium) 5%, Nekal BX 3%, K-12 (lauryl sodium sulfate) 4%, binding agent carboxymethyl (ethyl) cellulose 5%, disintegrant (glucose) 5%, diatomite 3%, kaolin are supplemented to 100%.By recipe requirements, former medicine, dispersant, wetting agent, disintegrant, filler etc. are mixed and becomes wetting powder through air-flow crushing, then add that suitable quantity of water carries out granulation, oven dry, whole grain obtain 50% ZJ0712 chlorine fluorine cyanogen insect amide water dispersion granule.
50% obtained ZJ0712 chlorine fluorine cyanogen insect amide water dispersion granule is applied to water prevention chilo suppressalis, rice blast.50% ZJ0712 chlorine fluorine cyanogen insect amide water dispersion granule presses active ingredient 5 grams/acre in striped rice borer egg hatching larva occurance peak, and rice blast initial stage of origination is watered even spraying, 95.2%, 87.5% was respectively to the preventive effect of striped rice borer, rice blast in after medicine 7 days.Contrast single dose 30% ZJ0712 missible oil (formulation rate is 15 grams/acre), 20% chlorine fluorine cyanogen insect amide suspending agent (active ingredient formulation rate is 3 grams/acre) are by same method dispenser, after medicine 7 days, 30% ZJ0712 is hanged the preventive effect of missible oil to striped rice borer, rice blast and is respectively 5.7%, 76.5%, and the preventive effect of 20% chlorine fluorine cyanogen insect amide suspending agent to striped rice borer, rice blast is respectively 81.1%, 3.7%.Obviously can increase control spectrum after ZJ0712 and chlorine fluorine cyanogen insect amide mixture, reach that disease worm is double controls effect, double preventive effect of controlling is better than single dose.
Embodiment 3,20% ZJ0712 chlorine fluorine cyanogen insect amide missible oil
ZJ0712 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP8%, surplus is dimethylbenzene.By above-mentioned formula in proportion mixing and stirring namely obtain 20% ZJ0712 chlorine fluorine cyanogen insect amide missible oil.
20% obtained ZJ0712 chlorine fluorine cyanogen insect amide missible oil is applied to water prevention chilo suppressalis, rice blast.20% ZJ0712 chlorine fluorine cyanogen insect amide missible oil presses active ingredient 5 grams/acre in striped rice borer egg hatching larva occurance peak, and rice blast initial stage of origination is watered even spraying, within after medicine 7 days, is respectively 95.8%, 84.2% to the preventive effect of striped rice borer, rice blast.Contrast single dose 30% ZJ0712 missible oil (formulation rate is 15 grams/acre), 20% chlorine fluorine cyanogen insect amide suspending agent (active ingredient formulation rate is 3 grams/acre) are by same method dispenser, after medicine 7 days, the preventive effect of 30% ZJ0712 missible oil to striped rice borer, rice blast is respectively 2.2%, 71.8%, and the preventive effect of 20% chlorine fluorine cyanogen insect amide suspending agent to striped rice borer, rice blast is respectively 83.2%, 5.2%.Obviously can increase control spectrum after ZJ0712 and chlorine fluorine cyanogen insect amide mixture, reach that disease worm is double controls effect, double preventive effect of controlling is better than single dose.
Embodiment 4,20% ZJ0712 chlorine fluorine cyanogen insect amide oil suspending agent
ZJ0712 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate is mended to 100%.After being mixed by above-mentioned formula, namely sand milling to certain particle diameter obtains 20% ZJ0712 chlorine fluorine cyanogen insect amide oil suspending agent.
20% obtained ZJ0712 chlorine fluorine cyanogen insect amide oil suspending agent is applied to water prevention chilo suppressalis, rice blast.20% ZJ0712 chlorine fluorine cyanogen insect amide oil suspending agent presses active ingredient 5 grams/acre in striped rice borer egg hatching larva occurance peak, and rice blast initial stage of origination is watered even spraying, within after medicine 7 days, is respectively 88.5%, 87.9% to the preventive effect of striped rice borer, rice blast.Contrast single dose 30% ZJ0712 missible oil (formulation rate is 15 grams/acre), 20% chlorine fluorine cyanogen insect amide suspending agent (active ingredient formulation rate is 3 grams/acre) are by same method dispenser, after medicine 7 days, the preventive effect of 30% ZJ0712 missible oil to striped rice borer, rice blast is respectively 3.5%, 75.0%, and the preventive effect of 20% chlorine fluorine cyanogen insect amide suspending agent to striped rice borer, rice blast is respectively 83.2%, 8.1%.Obviously can increase control spectrum after ZJ0712 and chlorine fluorine cyanogen insect amide mixture, reach that disease worm is double controls effect, double preventive effect of controlling is better than single dose.
Claims (8)
1. a composition pesticide, is characterized in that described composition pesticide contains chlorine fluorine cyanogen insect amide and ZJ0712, and the weight ratio of chlorine fluorine cyanogen insect amide and ZJ0712 is 50:1 ~ 1:50.
2., according to composition pesticide according to claim 1, it is characterized in that the weight ratio of described chlorine fluorine cyanogen insect amide and ZJ0712 is 20:1 ~ 1:20.
3., according to composition pesticide according to claim 2, it is characterized in that the weight ratio of described chlorine fluorine cyanogen insect amide and ZJ0712 is 4:1 ~ 1:3.
4. an insecticidal bactericide, it is characterized in that described insecticidal bactericide by weight containing 5 ~ 90% composition pesticide, all the other are agriculturally acceptable carrier and auxiliary agent.
5., according to insecticidal bactericide according to claim 4, it is characterized in that described insecticidal bactericide contains the composition pesticide of 5 ~ 40% by weight.
6., according to insecticidal bactericide according to claim 4, it is characterized in that described insecticidal bactericide is suspending agent, missible oil, water dispersible granules or oil suspending agent.
7., according to composition pesticide according to claim 1, it is characterized in that described composition pesticide is for preventing and treating striped rice borer and rice blast.
8., according to composition pesticide according to claim 7, it is characterized in that described composition pesticide is for water prevention chilo suppressalis and rice blast.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510861390.6A CN105454233A (en) | 2015-12-01 | 2015-12-01 | Pesticide composition containing cyhalodiamide and benzene kresoxim-methyl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510861390.6A CN105454233A (en) | 2015-12-01 | 2015-12-01 | Pesticide composition containing cyhalodiamide and benzene kresoxim-methyl |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105454233A true CN105454233A (en) | 2016-04-06 |
Family
ID=55592799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510861390.6A Pending CN105454233A (en) | 2015-12-01 | 2015-12-01 | Pesticide composition containing cyhalodiamide and benzene kresoxim-methyl |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105454233A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103109843A (en) * | 2013-03-04 | 2013-05-22 | 中化蓝天集团有限公司 | Insecticidal disease-preventing suspended seed coating containing thiamethoxam, thifluzamide and/or benzene kresoxim-methyl |
| CN105028421A (en) * | 2015-07-10 | 2015-11-11 | 广东中迅农科股份有限公司 | Insecticidal and bactericidal pesticide composition for rice |
-
2015
- 2015-12-01 CN CN201510861390.6A patent/CN105454233A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103109843A (en) * | 2013-03-04 | 2013-05-22 | 中化蓝天集团有限公司 | Insecticidal disease-preventing suspended seed coating containing thiamethoxam, thifluzamide and/or benzene kresoxim-methyl |
| CN105028421A (en) * | 2015-07-10 | 2015-11-11 | 广东中迅农科股份有限公司 | Insecticidal and bactericidal pesticide composition for rice |
Non-Patent Citations (1)
| Title |
|---|
| 陈定花 等: "新型广谱杀菌剂苯醚菌酯(ZJ0712)生物活性", 《农药》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103039450B (en) | Agricultural insecticidal composition containing spinosad and ZJ4042 | |
| CN104663679A (en) | Pest-killing and mite-killing composition containing macrolide insecticide | |
| CN102907453A (en) | Pesticide composition for agricultural pests | |
| CN103250720B (en) | A kind of containing chlorfluazuron and ZJ4042 agricultural pesticide composition | |
| CN103250727B (en) | Agricultural insecticidal composition containing indoxacarb and ZJ4042 | |
| CN102907444A (en) | Pest killing composition containing abamectin or methylamino abamectin | |
| CN104145965A (en) | Insecticidal and fungicidal composition containing hymexazol | |
| CN105613511B (en) | A kind of agricultural pesticide composition and application thereof | |
| CN105409958A (en) | Pesticide composition containing cyhalodiamide and fluazinam | |
| CN104488865B (en) | A kind of containing ZJ4042 with the Pesticidal combination of Cupric sulfate | |
| CN102696642B (en) | Acaricidal composition containing spirodiclofen and cyflumetofen | |
| CN102204561B (en) | Agricultural pesticide composition | |
| CN102246811B (en) | Insecticidal composition containing ZJ3265 and profenofos | |
| CN105454233A (en) | Pesticide composition containing cyhalodiamide and benzene kresoxim-methyl | |
| CN103250701B (en) | Agricultural insecticidal composition containing chlorfenapyr and ZJ4042 | |
| CN103355328B (en) | Mite-killing composition containing C20H22Cl2O5 and etoxazole | |
| CN102907438A (en) | Insecticidal composite containing ZJ3757 and pymetrozine | |
| CN104920412B (en) | A kind of Pesticidal combination containing flufenoxuron and chlorine fluorine cyanogen insect amide | |
| CN102613236B (en) | Farm chemical composition containing chlorpyrifos and ZJ3265 | |
| CN108617675A (en) | A kind of composition of ether compound containing loop coil and plant insecticide | |
| CN105475314A (en) | Insecticidal combination containing methomyl and cyhalodiamide | |
| CN104642347A (en) | Agricultural insecticidal and bactericidal composition | |
| CN104938487B (en) | A kind of Pesticidal combination containing dimehypo and chlorine fluorine cyanogen insect amide | |
| CN102907456A (en) | Pesticide combination containing ZJ3757 and profenofos | |
| CN108684694A (en) | A kind of composition of ether compound containing loop coil and Bifenazate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160406 |
|
| WD01 | Invention patent application deemed withdrawn after publication |