CN105419564A - Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof - Google Patents
Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof Download PDFInfo
- Publication number
- CN105419564A CN105419564A CN201510992801.5A CN201510992801A CN105419564A CN 105419564 A CN105419564 A CN 105419564A CN 201510992801 A CN201510992801 A CN 201510992801A CN 105419564 A CN105419564 A CN 105419564A
- Authority
- CN
- China
- Prior art keywords
- component
- graphene oxide
- aqueous epoxy
- oxide modified
- protective system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
- C09D5/106—Anti-corrosive paints containing metal dust containing Zn
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The invention relates to a nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and a preparation method thereof. The preparation method includes the steps of a) modifying the surface of graphene oxide with a dispersing agent and resin to prepare graphene oxide pre-dispersed slurry; b) placing the graphene oxide pre-dispersed slurry into a stirring container according to proportion and then stirring the slurry uniformly; c) adding an aqueous epoxy emulsion, an anti-rust pigment, a filling material, a dispersing agent and an anti-flash-rust agent, performing high-speed dispersion and grinding to obtain a first component A of the graphene oxide modified double-component aqueous epoxy anti-corrosion coating; d) diluting an epoxy curing agent in deionized water to obtain a second component B of the graphene oxide modified double-component aqueous epoxy anti-corrosion coating; and e) mixing the component A and the component B uniformly, curing the mixture for 10 min to 15 days at 10-120 DEG C to obtain the coating. The coating is simple in process, is low in cost, is suitable for large-scale production, maintains excellent properties of epoxy resin, is better in corrosion resistance, anti-seepage property, mechanical performance and anti-wear property, and has wide industrial application prospect.
Description
Technical field
The present invention relates to coating technology, particularly relate to a kind of nano graphene oxide modified bi-component aqueous epoxy protective system and preparation method thereof.
Background technology
At present, about there is the iron and steel corrosion of 30% in the annual whole world, and the iron and steel of 10% becomes useless iron rust, every year because corroding the financial loss that causes up to 7,000 hundred million dollars.Metallic corrosion not only brings loss economically to the mankind, and is unfavorable for the protection of natural resources and enviroment, sometimes even jeopardizes personnel safety.In order to prevent and slowing down corrosion, in production practice and scientific experiment, develop many anti-corrosion methods.Wherein convenient, economical with coating protection, thus obtain a wide range of applications.
Chinese patent CN1456705 (publication date 2003.11.19) discloses a kind of corrosion-resistant finishes Rail Production technique, after rail pre-treatment, at Rail Surface spraying zinc-rich paint, makes rail adapt to comparatively rugged environment.
Existing epoxy zinc-enriched paint existing problems: 1, due to the relative density large (7.14) of zinc powder, very easily sink to the bottom in the epoxy; When 2, using as shop primer, easily produce the aerosol of zinc, affect the healthy of operator, therefore need the epoxy zinc-enriched paint developing low zinc-type, but the solidity to corrosion of the epoxy coating of low zinc-type compared with the epoxy coating of rich zinc-type decreases.
Chinese patent CN102604533A discloses a kind of protective system based on polyaniline and graphene composite material and preparation method.The protective system of this invention, can realize passivation and the inhibition of metal base, avoid the use of the heavy metals such as the zinc that can cause environmental pollution simultaneously, and preparation is simple, cost is low, be easy to industrialized mass production.But in the protective system described in CN102604533A, the dispersion effect being improved Graphene by the addition means of the Graphene of complexity has limitation.
The present invention utilizes pretreated nano graphene oxide in water to have the structure peeled off completely, and the existence of energy stable and uniform in aqueous epoxy emulsion, graphene oxide becomes tiny lamella, dispersion evenly, to the water-thinned epoxy zinc-rich coating, anti-medium permeability, the mechanical property that improve water-thinned epoxy zinc-rich coating, thermal characteristics is more favourable.In addition we select aqueous epoxy emulsion, with water as solvent, save ample resources; Fire hazard when water-borne coatings eliminates construction; Reduce topsoil; Also improve operating environmental condition simultaneously.
Summary of the invention
The object of the invention is some shortcoming and defect in order to overcome existing graphene oxide coating, the nano graphene oxide modified bi-component aqueous epoxy protective system adopting the mode of easy economy to obtain.The nano graphene oxide modified bi-component aqueous epoxy protective system obtained has excellent storage stability, not easily sink to the bottom, and reduce the content of zinc, reduce the pollution of heavy metal to environment and the potential threat to human health thereof, utilize Graphene significantly to improve antiseptic property simultaneously.
Technical scheme of the present invention is: the proportioning that nano graphene oxide modified bi-component aqueous epoxy protective system forms component A and B component by following two component A and B is 100:1 ~ 100:80;
Count by weight, component A comprises following component and content:
Count by weight, B component comprises following component and content:
Solidifying agent 20 ~ 100;
Deionized water 0 ~ 75;
Described graphene oxide is treated graphene oxide, and its particle diameter is 500 ~ 20000 orders.
Present invention also offers the preparation method of nano graphene oxide modified bi-component aqueous epoxy protective system:
1) the pre-dispersed slurry preparation of graphene oxide: graphene oxide is mixed with the aqueous solution of 20 ~ 80%, add 1 ~ 5% dispersion agent and 10 ~ 50% aqueous epoxy emulsions according to mass ratio simultaneously, use high speed dispersor to be ground to 500 ~ 20000 object particles, obtain the pre-dispersed slurry of graphene oxide;
2) the component A preparation of graphene oxide modified bi-component aqueous epoxy protective system: pre-dispersed for above-mentioned graphene oxide slurry and aqueous epoxy emulsion, active rust-stabilising pigment, zinc powder, filler, dispersion agent, defoamer, anti-layer agent etc. are added high-speed dispersion equipment according to proportioning, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system;
3) the B component preparation of graphene oxide modified bi-component aqueous epoxy protective system: the B component preparation of graphene oxide modified bi-component aqueous epoxy protective system: count by weight, namely the deionized water mixed diluting of the solidifying agent of 20 ~ 100 parts and 0 ~ 75 part is obtained graphene oxide modified bi-component aqueous epoxy protective system B component;
4) add in component A by B component, the proportioning of component A and B component is 100:1 ~ 100:80, solidify to form graphene oxide modified bi-component aqueous epoxy protective system.
The present invention utilizes pretreated nano graphene oxide in water to have the structure peeled off completely, and the existence of energy stable uniform in aqueous epoxy emulsion, graphene oxide becomes tiny lamella, dispersion evenly, to the water-thinned epoxy zinc-rich coating, anti-medium permeability, the mechanical property that improve water-thinned epoxy zinc-rich coating, thermal characteristics is more favourable.The present invention adopts 2 component packagings, easily controls proportioning; Field mix can not produce dust, and environmental protection is harmless; Field mix is easy, only needs simple agitation to mix, improves operating efficiency; In addition, priming paint of the present invention is with water-base epoxy dispersion for main base, and emulsion good mechanical stability, together can grind with pigment, decreases the consumption as the water of dispersion medium and hydrophilic dispersion agent, wetting agent; Improve solid part of coating, improve the antiseptic property of coating: select aqueous epoxy emulsion, with water as solvent, save ample resources; Fire hazard when water-borne coatings eliminates construction; Reduce topsoil; Improve operating environmental condition.Nano graphene oxide modified bi-component aqueous epoxy protective system of the present invention have nontoxic, do not fire, easy construction, fast drying, paint film physical strength is high, strong adhesion, antiseptic property are excellent, the advantages such as coating excellent storage stability.Good suitability is had in protection against corrosion in the air of this coating ferrous materials in the facilities such as train, automobile, boats and ships, bridge, pipeline, freight container, basin.
Accompanying drawing explanation
Fig. 1 is salt-fog test contrast picture, and wherein (a) is common water borne corrosion-resistant epoxy paint, and (b) is nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment
For enabling above-mentioned purpose of the present invention, feature and advantage become apparent more, are described in detail below in conjunction with the specific embodiment of the present invention.Set forth a lot of detail in the following description so that fully understand the present invention.But the present invention can be much different from alternate manner described here to implement, those skilled in the art can when without prejudice to doing similar improvement when intension of the present invention, therefore the present invention is by the restriction of following public concrete enforcement.
Be specific embodiment part below.
Embodiment 1
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 20%, add 1% dispersion agent and 10% bisphenol A-type aqueous epoxy resin emulsion simultaneously, use high speed dispersion agent to be ground to 1000 object particles, obtain the pre-dispersed slurry of graphene oxide.Below by weight proportion, pre-dispersed for graphene oxide slurry 0.1, bisphenol A-type aqueous epoxy resin emulsion 20, zinc phosphate 1, aluminium triphosphate 5,500 order zinc flake 70, water-based wilkinite 2, mica powder 10, dispersion agent 0.5, defoamer 0.3, anti-settling agent 0.2 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 60 parts of deionized water dilutions of 40 portions of polyamide modified epoxy hardeners are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 1:2, at 40 DEG C of solidification 8h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 2
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 30%, add 2% dispersion agent and 20% bisphenol-f type aqueous epoxy resin emulsion simultaneously, use high speed dispersion agent to be ground to 500 object particles, obtain the pre-dispersed slurry of graphene oxide.Below by weight proportion, pre-dispersed for graphene oxide slurry 1, bisphenol-f type aqueous epoxy resin emulsion 20, zinc phosphate 2, aluminium triphosphate 3,1000 order spherical zinc powder 60, water-based wilkinite 1, light calcium carbonate 7, dispersion agent 0.5, defoamer 0.4, anti-settling agent 0.2 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 40 parts of deionized water dilutions of 60 portions of polyamide modified epoxy hardeners are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 1:1, at 28 DEG C of solidification 10h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 3
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 40%, add 1% dispersion agent and 5% bisphenol-f type aqueous epoxy resin emulsion simultaneously, use high speed dispersion agent to be ground to 2000 object particles, obtain the pre-dispersed slurry of graphene oxide.Below by weight proportion, pre-dispersed for graphene oxide slurry 5, bisphenol A-type aqueous epoxy resin emulsion 10, aluminium triphosphate 5,2000 order zinc flake 70, calcined kaolin 2, mica powder 8, dispersion agent 0.4, defoamer 0.4, hydroxylated cellulose 0.4 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 40 parts of deionized water dilutions of 60 parts of aliphatic amide modified epoxy solidifying agent are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 1:1, at 30 DEG C of solidification 24h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 4
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 50%, add 5% dispersion agent and the dimer acid modified epoxy resin latex of 50% high purity simultaneously, use high speed dispersion agent to be ground to 800 object particles, obtain the pre-dispersed slurry of graphene oxide.Below by weight proportion, epoxy resin latex 40 dimer acid modified to pre-dispersed for graphene oxide slurry 2, high purity, aluminium triphosphate 5,500 order zinc flake 40, calcined kaolin 5, mica powder 5, dispersion agent 0.4, defoamer 0.4, hydroxylated cellulose 0.4 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 50 parts of deionized water dilutions of 50 parts of aliphatic amide modified epoxy solidifying agent are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 2:1, at 80 DEG C of solidification 2h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 5
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 30%, add 1.5% dispersion agent and 30% aqueous acrylic modified epoxy emulsion simultaneously, use high speed dispersion agent to be ground to 1000 object particles, obtain the pre-dispersed slurry of graphene oxide.Below by weight proportion, pre-dispersed for graphene oxide slurry 0.5, aqueous acrylic modified epoxy emulsion 10, aluminium triphosphate 8,1000 order zinc flake 80, calcined kaolin 2, mica powder 3, dispersion agent 0.4, defoamer 0.4, hydroxylated cellulose 0.4 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 20 parts of deionized water dilutions of 80 parts of aliphatic amide modified epoxy solidifying agent are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 1:3, at 50 DEG C of solidification 6h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 6
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 20%, add 1% dispersion agent and 20% aqueous acrylic modified epoxy emulsion simultaneously, use high speed dispersion agent to be ground to 1000 object particles, obtain the pre-dispersed slurry of graphene oxide.Pre-dispersed for graphene oxide slurry 0.5, aqueous acrylic modified epoxy emulsion 15, aluminium triphosphate 8,800 order zinc flake 70, calcined kaolin 3, mica powder 5, dispersion agent 0.4, defoamer 0.4, hydroxylated cellulose 0.4 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 10 parts of deionized water dilutions of 90 portions of polyamide modified epoxy hardeners are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 1:4, at 30 DEG C of solidification 10h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 7
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 70%, add 5% dispersion agent and 40% aqueous acrylic modified epoxy emulsion simultaneously, use high speed dispersion agent to be ground to 800 object particles, obtain the pre-dispersed slurry of graphene oxide.Pre-dispersed for graphene oxide slurry 2, aqueous acrylic modified epoxy emulsion 40, aluminium triphosphate 10,1000 order spherical zinc powder 40, calcined kaolin 5, mica powder 4, dispersion agent 0.2, defoamer 0.8, hydroxylated cellulose 0.6 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 50 parts of deionized water dilutions of 50 portions of polyamide modified epoxy hardeners are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 3:1, at 30 DEG C of solidification 10h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
Embodiment 8
A kind of nano graphene oxide modified bi-component aqueous epoxy protective system, first graphene oxide is mixed with the aqueous solution of 30%, add 5% dispersion agent and 10% aqueous acrylic modified epoxy emulsion simultaneously, use high speed dispersion agent to be ground to 2000 object particles, obtain the pre-dispersed slurry of graphene oxide.Pre-dispersed for graphene oxide slurry 0.5, aqueous acrylic modified epoxy emulsion 20, aluminium triphosphate 8,500 order zinc flake 60, calcined kaolin 6, mica powder 5, dispersion agent 0.4, defoamer 0.4, hydroxylated cellulose 0.4 are stirred, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system.Namely the 70 parts of deionized water dilutions of 30 portions of polyamide modified epoxy hardeners are obtained graphene oxide modified bi-component aqueous epoxy protective system B component simultaneously.Survey the index of central control of component A and B, qualified rear packaging.B component is added in component A according to 5:1, at 30 DEG C of solidification 6h, forms nano graphene oxide modified bi-component aqueous epoxy protective system.
The nano graphene oxide modified bi-component aqueous epoxy protective system performance prepared by above-mentioned formula lists in table 1.
Table 1 nano graphene oxide modified bi-component aqueous epoxy protective system performance
Claims (11)
1. a nano graphene oxide modified bi-component aqueous epoxy protective system, it is characterized in that described nano graphene oxide modified bi-component aqueous epoxy protective system is made up of component A and B component, the proportioning of component A and B component is 100:1 ~ 100:80;
Count by weight, component A comprises following component and content:
Count by weight, B component comprises following component and content:
Solidifying agent 20 ~ 100;
Deionized water 0 ~ 75;
Wherein said graphene oxide is treated graphene oxide, and its particle diameter is 500 ~ 20000 orders.
2. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that: described aqueous epoxy emulsion is the dimer acid modified epoxy resin latex of bisphenol A-type aqueous epoxy resin emulsion, bisphenol-f type aqueous epoxy resin emulsion, aqueous acrylic modified epoxy emulsion, high purity.
3. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that: described active rust-stabilising pigment is one or both the mixture in zinc phosphate, aluminium triphosphate; Its content is 1 ~ 20wt%.
4. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, it is characterized in that: described zinc powder is spherical or sheet zinc powder, its particle diameter is 500 ~ 2000 orders.
5. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, it is characterized in that: described filler is the mixture of one or more in talcum powder, mica powder, light calcium carbonate, calcined kaolin, process white, and filler content is 5 ~ 30wt%.
6. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that: described dispersion agent is the sodium of alkenyl monomer and copolymers of unsaturated carboxylic acids, amine or ammonium salt.
7. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that: described defoamer is organic silicon modified by polyether.
8. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that: described anti-settling agent is Natvosol; Its content is 0.1 ~ 0.2wt%.
9. nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that: described solidifying agent is solid part is the aliphatic amide modification of 50 ~ 70wt% or polyamide modified aqueous epoxy curing agent.
10. the preparation method of nano graphene oxide modified bi-component aqueous epoxy protective system according to claim 1, is characterized in that carrying out with step in the following order:
1) the pre-dispersed slurry preparation of graphene oxide: graphene oxide is mixed with the aqueous solution of 20 ~ 80%, add 1 ~ 5% dispersion agent and 10 ~ 50% aqueous epoxy emulsions according to mass ratio simultaneously, use high speed dispersor to be ground to 500 ~ 20000 object particles, obtain the pre-dispersed slurry of graphene oxide;
2) the component A preparation of graphene oxide modified bi-component aqueous epoxy protective system: pre-dispersed for above-mentioned graphene oxide slurry and aqueous epoxy emulsion, active rust-stabilising pigment, zinc powder, filler, dispersion agent, defoamer, anti-layer agent etc. are added high-speed dispersion equipment according to proportioning in claim 1, high speed dispersion is also ground to fineness through grinding plant and reaches less than 35 microns, obtains the component A of graphene oxide modified bi-component aqueous epoxy protective system;
3) the B component preparation of graphene oxide modified bi-component aqueous epoxy protective system: count by weight, namely the deionized water mixed diluting of the solidifying agent of 20 ~ 100 parts and 0 ~ 75 part is obtained graphene oxide modified bi-component aqueous epoxy protective system B component;
4) add in component A by B component, the proportioning of component A and B component is 100:1 ~ 100:80, solidify to form graphene oxide modified bi-component aqueous epoxy protective system.
The preparation method of 11. nano graphene oxide modified bi-component aqueous epoxy protective systems according to claim 10, it is characterized in that: when described B component adds component A, 10 DEG C ~ 120 DEG C solidifications 5 minutes ~ 15 days, form graphene oxide modified bi-component aqueous epoxy protective system.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510992801.5A CN105419564A (en) | 2015-12-24 | 2015-12-24 | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510992801.5A CN105419564A (en) | 2015-12-24 | 2015-12-24 | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105419564A true CN105419564A (en) | 2016-03-23 |
Family
ID=55498119
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510992801.5A Pending CN105419564A (en) | 2015-12-24 | 2015-12-24 | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105419564A (en) |
Cited By (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838187A (en) * | 2016-04-23 | 2016-08-10 | 上海大学 | Ball milling preparation method and application of graphene oxide anticorrosive coating |
| CN105838195A (en) * | 2016-05-13 | 2016-08-10 | 江苏科技大学 | Waterborne epoxy anti-corrosion paint containing graphene oxide and preparing method of waterborne epoxy anti-corrosion paint |
| CN105949946A (en) * | 2016-05-17 | 2016-09-21 | 中国科学院宁波材料技术与工程研究所 | Wear-resistant and anti-corrosion coating and preparation method thereof |
| CN106047077A (en) * | 2016-07-20 | 2016-10-26 | 太原理工大学 | Carbon nanomaterial composite conductive mica/epoxy-group static conducting anticorrosive coating material and preparation method |
| CN106118364A (en) * | 2016-07-08 | 2016-11-16 | 上海晶顿科技有限公司 | A kind of graphene oxide anticorrosive paint |
| CN106280992A (en) * | 2016-08-29 | 2017-01-04 | 天津美士邦涂料化工有限公司 | A kind of water-base epoxy organosilicon Graphene coating |
| CN106366908A (en) * | 2016-08-29 | 2017-02-01 | 天津美士邦涂料化工有限公司 | Preparation method of waterborne epoxy organic silicon graphene coating |
| CN106398536A (en) * | 2016-09-18 | 2017-02-15 | 科顺防水科技股份有限公司 | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof |
| CN106497338A (en) * | 2016-11-11 | 2017-03-15 | 上海碳源汇谷新材料科技有限公司 | Graphene oxide modified waterborne epoxy corrosion resistant coating |
| CN106497330A (en) * | 2016-10-28 | 2017-03-15 | 安徽新大陆特种涂料有限责任公司 | A kind of Graphene modified epoxy resin paint and preparation method thereof |
| CN106590359A (en) * | 2016-12-14 | 2017-04-26 | 河南省豫星华晶微钻有限公司 | Inner-pipeline anti-corrosion coating containing nano diamond alkene and preparation method of inner-pipeline anti-corrosion coating |
| CN106634461A (en) * | 2016-12-16 | 2017-05-10 | 深圳大学 | Oxidized graphene heat insulation glass double-ingredient paint and preparation method thereof |
| CN106634448A (en) * | 2016-12-30 | 2017-05-10 | 上海美东生物材料股份有限公司 | Waterborne epoxy flash-rust preventing paint |
| CN106752886A (en) * | 2016-12-05 | 2017-05-31 | 江西龙正科技发展有限公司 | A kind of marine ship Graphene anti-corrosive organic coatings |
| CN106752723A (en) * | 2016-12-30 | 2017-05-31 | 上海美东生物材料股份有限公司 | A kind of water-base epoxy antiseptic varnish and preparation method thereof |
| CN106752763A (en) * | 2016-12-01 | 2017-05-31 | 浙江大学常州工业技术研究院 | Nano graphene oxide modified epoxy type powdery paints and preparation method thereof |
| CN106905819A (en) * | 2017-03-31 | 2017-06-30 | 哈尔滨工业大学（威海） | A kind of aqueous epoxide resin paint |
| CN106947354A (en) * | 2017-03-09 | 2017-07-14 | 河北晨阳工贸集团有限公司 | Aqueous acrylic modified two component epoxy paint for priming paint and top lacquer and preparation method thereof |
| CN107189638A (en) * | 2017-07-06 | 2017-09-22 | 浩力森涂料（上海）有限公司 | Watersoluble plumbago alkene anticorrosive paint |
| CN107384084A (en) * | 2017-09-06 | 2017-11-24 | 哈尔滨绿科科技有限公司 | A kind of high-strength anti-corrosion water paint and preparation method thereof |
| CN107641445A (en) * | 2017-09-26 | 2018-01-30 | 信和新材料股份有限公司 | A kind of fast-drying aqueous zinc powder shop primer of ultra high solids part being modified based on graphene and preparation method thereof |
| CN107903755A (en) * | 2017-12-26 | 2018-04-13 | 海安常州大学高新技术研发中心 | A kind of preparation method of graphene oxide modified aqueous acrylic acid anticorrosive paint |
| CN107987680A (en) * | 2017-12-20 | 2018-05-04 | 海洋化工研究院有限公司 | Water-base epoxy graphene anticorrosive paint |
| CN108342177A (en) * | 2018-03-28 | 2018-07-31 | 黑龙江省科学院石油化学研究院 | A kind of preparation method of high dispersive graphene oxide reinforced epoxy adhesive |
| CN108395752A (en) * | 2018-03-24 | 2018-08-14 | 厦门中凯新材石墨烯科技有限公司 | Coating and preparation method thereof is applied in a kind of graphene anticorrosion |
| CN108424705A (en) * | 2018-03-15 | 2018-08-21 | 厦门大学 | A kind of high dispersion modified graphene oxide, preparation method and its anticorrosive paint |
| CN108441077A (en) * | 2018-04-17 | 2018-08-24 | 常州市润金木环保科技有限公司 | Aqueous heavy anti-corrosion paint and preparation method thereof |
| CN108531033A (en) * | 2018-03-29 | 2018-09-14 | 湖北铁神化工有限公司 | A kind of dispersion type water-base epoxy zinc alkene band rust antirust heavy antisepsis priming paint |
| CN108690456A (en) * | 2018-03-15 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of water-based epoxy zinc-rich primer and preparation method thereof |
| CN108912607A (en) * | 2018-06-27 | 2018-11-30 | 王丽鹏 | A kind of epoxy graphene oxide film and preparation method thereof |
| CN109021621A (en) * | 2018-07-25 | 2018-12-18 | 广东好邦石墨烯新材料科技有限公司 | A kind of zinc powder of graphene modified, preparation method and its application in water-based anticorrosive paint |
| CN109517481A (en) * | 2018-10-30 | 2019-03-26 | 西安理工大学 | A kind of preparation method of the water corrosion-resistant epoxy paint of containing graphene |
| CN109517482A (en) * | 2018-10-30 | 2019-03-26 | 湖南航天三丰科工有限公司 | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof |
| CN110396343A (en) * | 2018-04-25 | 2019-11-01 | 河北晨阳工贸集团有限公司 | A kind of water-base epoxy anti-corrosion primer and preparation method thereof |
| CN110499093A (en) * | 2019-08-14 | 2019-11-26 | 东华大学 | A kind of environmentally protective graphene self-lubricating composite coating and its preparation method and application |
| CN110724432A (en) * | 2018-07-16 | 2020-01-24 | 深圳市烯世传奇科技有限公司 | Graphene water-based anticorrosive paint and preparation method thereof |
| CN112063272A (en) * | 2020-08-13 | 2020-12-11 | 珠海展辰新材料股份有限公司 | Water-based antirust coating and preparation method thereof |
| CN112680056A (en) * | 2020-12-10 | 2021-04-20 | 珠海复旦创新研究院 | Anticorrosive paint and preparation method and application thereof |
| CN112778869A (en) * | 2019-11-05 | 2021-05-11 | 宜兴汉光高新石化有限公司 | Water-based two-component epoxy anticorrosive paint for storage tank weld joint and preparation method thereof |
| CN114163899A (en) * | 2022-01-06 | 2022-03-11 | 浙江华昱科技有限公司 | Preparation method of ultramicro bamboo charcoal biomass-based anticorrosive coating |
| CN114410186A (en) * | 2022-02-08 | 2022-04-29 | 安徽陶博士环保科技有限公司 | Self-corrosion-resistant water-based organic zinc-rich coating and preparation method thereof |
| GB2565048B (en) * | 2017-07-26 | 2023-04-19 | Talga Tech Limited | Functionalised graphene composition |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173095A (en) * | 2013-03-06 | 2013-06-26 | 常州第六元素材料科技股份有限公司 | Zinc-rich epoxy anticorrosion paint and preparation method thereof |
| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN104356860A (en) * | 2014-10-29 | 2015-02-18 | 中国科学院宁波材料技术与工程研究所 | Epoxy resin-oxidized graphene composite coating and application method thereof |
| CN104371500A (en) * | 2014-11-24 | 2015-02-25 | 张家港保税区冠祥贸易有限公司 | High-corrosion-resistance metal anti-corrosive paint and preparation method thereof |
| CN105176321A (en) * | 2015-10-08 | 2015-12-23 | 江苏华夏制漆科技有限公司 | Water-based phenolic aldehyde epoxy graphene anticorrosion primer and preparation method thereof |
-
2015
- 2015-12-24 CN CN201510992801.5A patent/CN105419564A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103173095A (en) * | 2013-03-06 | 2013-06-26 | 常州第六元素材料科技股份有限公司 | Zinc-rich epoxy anticorrosion paint and preparation method thereof |
| CN103497636A (en) * | 2013-09-07 | 2014-01-08 | 中国科学院合肥物质科学研究院 | Waterborne epoxy zinc-rich paint modified by nanometer conductive carbon material and preparation method thereof |
| CN104356860A (en) * | 2014-10-29 | 2015-02-18 | 中国科学院宁波材料技术与工程研究所 | Epoxy resin-oxidized graphene composite coating and application method thereof |
| CN104371500A (en) * | 2014-11-24 | 2015-02-25 | 张家港保税区冠祥贸易有限公司 | High-corrosion-resistance metal anti-corrosive paint and preparation method thereof |
| CN105176321A (en) * | 2015-10-08 | 2015-12-23 | 江苏华夏制漆科技有限公司 | Water-based phenolic aldehyde epoxy graphene anticorrosion primer and preparation method thereof |
Cited By (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105838187A (en) * | 2016-04-23 | 2016-08-10 | 上海大学 | Ball milling preparation method and application of graphene oxide anticorrosive coating |
| CN105838195A (en) * | 2016-05-13 | 2016-08-10 | 江苏科技大学 | Waterborne epoxy anti-corrosion paint containing graphene oxide and preparing method of waterborne epoxy anti-corrosion paint |
| CN105838195B (en) * | 2016-05-13 | 2018-12-14 | 江苏科技大学 | A kind of water corrosion-resistant epoxy paint and preparation method thereof containing graphene oxide |
| CN105949946A (en) * | 2016-05-17 | 2016-09-21 | 中国科学院宁波材料技术与工程研究所 | Wear-resistant and anti-corrosion coating and preparation method thereof |
| CN106118364A (en) * | 2016-07-08 | 2016-11-16 | 上海晶顿科技有限公司 | A kind of graphene oxide anticorrosive paint |
| CN106047077B (en) * | 2016-07-20 | 2018-03-06 | 太原理工大学 | Carbon nanomaterial composite conducting mica/epoxy radicals static conductive anticorrosion coating material and preparation method |
| CN106047077A (en) * | 2016-07-20 | 2016-10-26 | 太原理工大学 | Carbon nanomaterial composite conductive mica/epoxy-group static conducting anticorrosive coating material and preparation method |
| CN106280992A (en) * | 2016-08-29 | 2017-01-04 | 天津美士邦涂料化工有限公司 | A kind of water-base epoxy organosilicon Graphene coating |
| CN106366908A (en) * | 2016-08-29 | 2017-02-01 | 天津美士邦涂料化工有限公司 | Preparation method of waterborne epoxy organic silicon graphene coating |
| CN106398536A (en) * | 2016-09-18 | 2017-02-15 | 科顺防水科技股份有限公司 | Anionic water-based non-curing rubber asphalt waterproof coating and preparation method thereof |
| CN106398536B (en) * | 2016-09-18 | 2019-04-12 | 科顺防水科技股份有限公司 | Anion-type water-thinned uncured rubber asphalt waterproof coating of one kind and preparation method thereof |
| CN106497330A (en) * | 2016-10-28 | 2017-03-15 | 安徽新大陆特种涂料有限责任公司 | A kind of Graphene modified epoxy resin paint and preparation method thereof |
| CN106497338A (en) * | 2016-11-11 | 2017-03-15 | 上海碳源汇谷新材料科技有限公司 | Graphene oxide modified waterborne epoxy corrosion resistant coating |
| CN106752763A (en) * | 2016-12-01 | 2017-05-31 | 浙江大学常州工业技术研究院 | Nano graphene oxide modified epoxy type powdery paints and preparation method thereof |
| CN106752886A (en) * | 2016-12-05 | 2017-05-31 | 江西龙正科技发展有限公司 | A kind of marine ship Graphene anti-corrosive organic coatings |
| CN106590359A (en) * | 2016-12-14 | 2017-04-26 | 河南省豫星华晶微钻有限公司 | Inner-pipeline anti-corrosion coating containing nano diamond alkene and preparation method of inner-pipeline anti-corrosion coating |
| CN106634461A (en) * | 2016-12-16 | 2017-05-10 | 深圳大学 | Oxidized graphene heat insulation glass double-ingredient paint and preparation method thereof |
| CN106634448A (en) * | 2016-12-30 | 2017-05-10 | 上海美东生物材料股份有限公司 | Waterborne epoxy flash-rust preventing paint |
| CN106752723A (en) * | 2016-12-30 | 2017-05-31 | 上海美东生物材料股份有限公司 | A kind of water-base epoxy antiseptic varnish and preparation method thereof |
| CN106947354A (en) * | 2017-03-09 | 2017-07-14 | 河北晨阳工贸集团有限公司 | Aqueous acrylic modified two component epoxy paint for priming paint and top lacquer and preparation method thereof |
| CN106905819B (en) * | 2017-03-31 | 2020-07-03 | 哈尔滨工业大学（威海） | Water-based epoxy resin coating |
| CN106905819A (en) * | 2017-03-31 | 2017-06-30 | 哈尔滨工业大学（威海） | A kind of aqueous epoxide resin paint |
| CN107189638A (en) * | 2017-07-06 | 2017-09-22 | 浩力森涂料（上海）有限公司 | Watersoluble plumbago alkene anticorrosive paint |
| GB2565048B (en) * | 2017-07-26 | 2023-04-19 | Talga Tech Limited | Functionalised graphene composition |
| CN107384084A (en) * | 2017-09-06 | 2017-11-24 | 哈尔滨绿科科技有限公司 | A kind of high-strength anti-corrosion water paint and preparation method thereof |
| CN107641445A (en) * | 2017-09-26 | 2018-01-30 | 信和新材料股份有限公司 | A kind of fast-drying aqueous zinc powder shop primer of ultra high solids part being modified based on graphene and preparation method thereof |
| CN107987680A (en) * | 2017-12-20 | 2018-05-04 | 海洋化工研究院有限公司 | Water-base epoxy graphene anticorrosive paint |
| CN107987680B (en) * | 2017-12-20 | 2020-02-07 | 海洋化工研究院有限公司 | Water-based epoxy graphene anticorrosive paint |
| CN107903755B (en) * | 2017-12-26 | 2019-07-05 | 海安常州大学高新技术研发中心 | A kind of preparation method of graphene oxide modified aqueous acrylic acid anticorrosive paint |
| CN107903755A (en) * | 2017-12-26 | 2018-04-13 | 海安常州大学高新技术研发中心 | A kind of preparation method of graphene oxide modified aqueous acrylic acid anticorrosive paint |
| CN108424705B (en) * | 2018-03-15 | 2019-10-25 | 厦门大学 | A kind of high dispersion modified graphene oxide, preparation method and its anticorrosive paint |
| CN108690456A (en) * | 2018-03-15 | 2018-10-23 | 河北晨阳工贸集团有限公司 | A kind of water-based epoxy zinc-rich primer and preparation method thereof |
| CN108424705A (en) * | 2018-03-15 | 2018-08-21 | 厦门大学 | A kind of high dispersion modified graphene oxide, preparation method and its anticorrosive paint |
| CN108395752A (en) * | 2018-03-24 | 2018-08-14 | 厦门中凯新材石墨烯科技有限公司 | Coating and preparation method thereof is applied in a kind of graphene anticorrosion |
| CN108342177A (en) * | 2018-03-28 | 2018-07-31 | 黑龙江省科学院石油化学研究院 | A kind of preparation method of high dispersive graphene oxide reinforced epoxy adhesive |
| CN108531033A (en) * | 2018-03-29 | 2018-09-14 | 湖北铁神化工有限公司 | A kind of dispersion type water-base epoxy zinc alkene band rust antirust heavy antisepsis priming paint |
| CN108441077A (en) * | 2018-04-17 | 2018-08-24 | 常州市润金木环保科技有限公司 | Aqueous heavy anti-corrosion paint and preparation method thereof |
| CN110396343A (en) * | 2018-04-25 | 2019-11-01 | 河北晨阳工贸集团有限公司 | A kind of water-base epoxy anti-corrosion primer and preparation method thereof |
| CN108912607A (en) * | 2018-06-27 | 2018-11-30 | 王丽鹏 | A kind of epoxy graphene oxide film and preparation method thereof |
| CN110724432A (en) * | 2018-07-16 | 2020-01-24 | 深圳市烯世传奇科技有限公司 | Graphene water-based anticorrosive paint and preparation method thereof |
| CN109021621A (en) * | 2018-07-25 | 2018-12-18 | 广东好邦石墨烯新材料科技有限公司 | A kind of zinc powder of graphene modified, preparation method and its application in water-based anticorrosive paint |
| CN109517482A (en) * | 2018-10-30 | 2019-03-26 | 湖南航天三丰科工有限公司 | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof |
| CN109517481A (en) * | 2018-10-30 | 2019-03-26 | 西安理工大学 | A kind of preparation method of the water corrosion-resistant epoxy paint of containing graphene |
| CN110499093A (en) * | 2019-08-14 | 2019-11-26 | 东华大学 | A kind of environmentally protective graphene self-lubricating composite coating and its preparation method and application |
| CN112778869A (en) * | 2019-11-05 | 2021-05-11 | 宜兴汉光高新石化有限公司 | Water-based two-component epoxy anticorrosive paint for storage tank weld joint and preparation method thereof |
| CN112063272A (en) * | 2020-08-13 | 2020-12-11 | 珠海展辰新材料股份有限公司 | Water-based antirust coating and preparation method thereof |
| CN112680056A (en) * | 2020-12-10 | 2021-04-20 | 珠海复旦创新研究院 | Anticorrosive paint and preparation method and application thereof |
| CN114163899A (en) * | 2022-01-06 | 2022-03-11 | 浙江华昱科技有限公司 | Preparation method of ultramicro bamboo charcoal biomass-based anticorrosive coating |
| CN114410186A (en) * | 2022-02-08 | 2022-04-29 | 安徽陶博士环保科技有限公司 | Self-corrosion-resistant water-based organic zinc-rich coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105419564A (en) | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof | |
| CN105838195B (en) | A kind of water corrosion-resistant epoxy paint and preparation method thereof containing graphene oxide | |
| CN104231866B (en) | A kind of water corrosion-resistant epoxy paint and preparation method thereof | |
| CN102732130B (en) | High solid anticorrosive paint and preparation method thereof | |
| CN101824265A (en) | Low-surface treatment moisture cured heavy anti-corrosion coating | |
| CN105733405A (en) | Graphene-based enhanced high-solid epoxy anticorrosive coating and method for preparing same | |
| CN104087126A (en) | Marine anticorrosive coating | |
| CN104530911B (en) | Preparation method for high-performance water-based environmentally-friendly anticorrosive paint used for metal base material | |
| CN101555379B (en) | Epoxy nano composite anticorrosion coating for low surface treatment and preparation method thereof | |
| CN103788343A (en) | VOC (Volatile Organic Compounds)-free water-based epoxy curing agent | |
| CN106634373A (en) | Waterborne zinc aluminum phosphate anti-rusting primer and preparation method thereof | |
| CN106634437A (en) | Graphene-modified water-based epoxy zinc-enriched coating as well as preparation method and application thereof | |
| CN104231864B (en) | A kind of water-based epoxy micaceous sheet iron strip rust anti-corrosive primer | |
| CN105273454B (en) | Nano inorganic zinc-rich composite anticorrosion coating and preparation method thereof | |
| CN105820706A (en) | High-performance anticorrosive nanomaterial for power transmission and transformation equipment, and preparation method thereof | |
| CN104140735A (en) | High-specific-weight high-zinc-content heavy-duty epoxy zinc-rich primer and preparation method thereof | |
| CN102173647A (en) | Organic-resin-free inorganic zinc silicate shop primer | |
| CN102408816B (en) | Epoxy ballast tank paint and preparation method thereof | |
| CN106867357B (en) | A kind of nanometer modified high-solid body divides epoxy primer | |
| CN105219253B (en) | A kind of asphalt modification epoxy phosphate zinc heavy antisepsis priming paint and preparation method thereof | |
| CN109517482A (en) | A kind of watersoluble plumbago alkene anticorrosive paint and preparation method thereof | |
| CN108977003A (en) | Watery anti-corrosion low temperature self-drying paint and anti-flash rusting coating process for ironcasting | |
| CN104629579A (en) | Special coating for lightweight oil intermediate feedstock storing tank | |
| CN105017922A (en) | Aqueous zinc-rich flake cathode protection prime coat, preparation method and uses thereof | |
| CN104263157B (en) | A kind of water soluble acrylic acid red lead anti-corrosive paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160323 |
|
| RJ01 | Rejection of invention patent application after publication |